• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.277-280
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• 2004

Recently, as structure is more higher and bigger, we need high strength and high performance concrete. Therefore it is necessary superplasticizer for high strength and high performance concrete. In this study, it is examined the properties of flow, air content and strength of concrete with polycarboxylate superplasticizer in comparison with existing superplasticizer. First, The slump loss of concrete used polycarboxylate superplasticizer showed 2cm until 120 minutes. Second, The air content loss of concrete used polycarboxylate superplasticizer showed $1\%$ until 120 minutes. Third, It is possible to manufacture $1000kgf/cm^2$ strength concrete using polycarboxylate superplasticizer with $806kg/m^3$ cement content, $18\%$ water-binder ratio, $15\%$ silica fume, $10\%$ fly-ash content.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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• pp.813-816
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• 2008

본 연구에서는 시멘트페이스트의 유동성 및 수화반응속도에 미치는 폴리카르본산계 고성능AE감수제의 영향에 대해서 첨가율, 분자구조 등의 관점에서 검토를 하였다. 시멘트페이스트의 유동성은 폴리카르본산계 고성능AE감수제를 첨가하는 것에 따라 증가하였다. 또한 그래프트가 짧은 폴리카르본산계 고성능AE감수제를 사용한 경우가 그래프트가 긴 것에 비해 저첨가율에서의 유동성은 향상되었다. 시멘트페이스트의 최고수화발열속도까지의 도달시간에 미치는 폴리카르본산계 고성능AE감수제의 영향은 첨가율이 증가함에 따라 증가하였다. 더욱이 시멘트페이스트의 유동성이 동일할 정도의 첨가량에 있어서도 그래프트가 긴 폴리카르본산계 고성능AE감수제의 경우가 그래프트의 길이가 짧은것의 경우보다 최고수화발열속도까지의 도달시간에 미치는 영향은 작다는 것을 알 수 있었다.

• 한국세라믹학회지
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• 제55권2호
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• pp.126-134
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• 2018

Using aqueous solution free radical polymerization with glacial acrylic acid (GAA), maleic anhydride (MA) and sodium methallyl disulfonate (SMADS), a novel linear polycarboxylate dispersant was synthesized for ceramics. Dispersant linear structural characterization was done by FTIR, $^1H$ NMR, HPLC and GPC, and the ratio of monomers was determined using an orthogonal experiment. This research is focused on the effects of polymerization temperature, monomer mole ratios and dosage of initiator on ceramic slurry viscosity with linear polycarboxylate dispersant for ceramic dosage rate of 0.30% (based on dry slurry), all of which were investigated by single factor test. The best polymerization conditions for linear GAA-MA-SMADS are when n(AA) : n(MA) : n(SMADS) equals 3.0 : 1.0 : 0.5, the molecular weight of the polymer is 4600 daltons, the initiator sodium persulfate accounts for 7% of the total mass of polymerized monomers, the polymerization temperature is $90^{\circ}C$ and the reaction time is 2 h. The ceramic body slurry viscosity drops from $820mPa{\cdot}s$ to $46mPa{\cdot}s$ when the concentration of the polycarboxylate dispersant is 0.30%.

• 한국세라믹학회지
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• 제47권5호
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• pp.387-393
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• 2010

To improve concrete quality one of the most widely used chemical admixtures is polycarboxylate type superplasticizer. Unlike lignosulfonate and naphthalene-sulfonate, it has high dispersion property and excellent sustainable dispersion property for cement and concrete. Thus, polycarboxylate type superplasticizer has been widely used as a high-performance water reducing admixture together with silica fume in high-performance concrete and other applications for the dispersion of high-strength concrete over 100 MPa. However, even though there have been many studied on the dispersion of concrete by the structure of polycarboxylate type superplasticizer, there have a few studied that clarified the relationships between its rheological properties and microstructure properties in the early hydration behavior of ordinary portland cement. To investigate the correlations between the rheological properties and microstructure of cementitious materials with polycarboxylate type superplasticizer, this study experimented on the rheology, pore structure, heat evolution, and consistency in early hydration as well as on the compressive strength by early dispersion characteristics.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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• pp.200-203
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• 2004

In this study, it is examined the properties of flow and early strength of concrete according to superplasticizer. For this experiment, it is analyzed that the flow and strength properties according to the mixture factors, compared with naphthalene superplasticizer(normal & delay type) focused on polycarboxylate superplasticizer. (1) The slump loss of concrete used polycarboxylate superplasticizer showed $4\~8cm$, it is judged that slump loss according to the time lapse can be minimized. (2) The performance of polycarboxylate superplasticizer is about $70\%$ level of the normal naphthalene type, it is superior to the delay type, but the performance showed so lowly. The 28days, early strength didn't differ according to the kind of superplasticizer.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.671-674
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• 2005

In this study, it is examined the properties of early strength of concrete mixed with polycarboxylate superplasticizer. For this experiment, it is analyzed that the slump and strength properties according to the mixture factors, compared with cements and superplasticizers of each company and curing temperature($15,\;20^{\circ}C$). (1) The slump loss of concrete used polycarboxylate superplasticizer(rapid strength type) showed $0.5\~1.5cm$, it is judged that slump loss according to the time lapse can be minimized. (2) The performance of polycarboxylate superplasticizer kept up consistency and accelerated strength development. it is possible to reveal 12MPa within $18\~20$hours at $20^{\circ}C$ curing, but impossible within 24hours at $15^{\circ}C$. (3) It is necessary to studies about rapid strength development in the low temperature.

• Restorative Dentistry and Endodontics
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• 제2권1호
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• pp.32-37
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• 1976

The author has studied comparatively the sealing quality of polycarboxylate cement, one of the newest dental cement systems, and zinc oxide eugenol cement by means of penetration of 2% methylene blue solution through the root apex of human teeth in 72 cases as time elapsed. Followings are the results obtained from this study. 1) In all groups, there was no increase in penetration related to increased time of immersion in the dye. 2) In polycarboxylate cement groups, there was a significant difference in depth of dye penetration of each tooth, but in zinc oxide eugenol cement group, there was a slight difference. 3) The depth of dye penetration of zinc oxide eugenol cement group is slightly lower than that of poly carboxylate cement groups. 4) In polycarboxylate cement groups, Carbolit cement group showed comparatively lower grade of dye penetration than Carbo cement group.

• 대한치과보철학회지
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• 제17권1호
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• pp.23-34
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• 1979

In this study, the adhesive strength of three commercial polycarboxylate cements to ten types of dental casting alloys, such as gold, palladium, silver, indium, copper, nickel, chromium, and human enamel and dentine were measured and compared with that of a conventional zinc phosphate cement. The $8.0mm{\times}3.0mm$ cylindrical alloy specimens were made by casting. The enamel specimens were prepared from the labial surface of human upper incisor, and the dentine specimens were prepared from the occulusal surface of the human molar respectively. Sound extracted human teeth, which had been kept in a fresh condition since, extraction, were mounted in a wax box with a cold-curing acrylic resin to expose the flattened area. The mounted teeth were then placed in a Specimen Cutter (Technicut) and were cut down under a water spray, and then the flat area on the all specimens were ground by hand with 400 and 600 grit wet silicone carbide paper. Two such specimens were then cemented together face-to-face with freshly mixed cement, and moderate finger pressure was applied to squeeze the cement to a thin and uniform film. All cemented specimens were then kept in a thermostatic humidor cabinet regulated at $23{\pm}2^{\circ}C.$ and more than 95 per cent relative humidity and tested after 24 hours and 1 week. Link chain was attached to each alloy specimen to reduce the rigidity of the jig assembly, and then all the specimens were mounted in the grips of the Instron Universal Testing Machine, and a tensile load was delivered to the adhering surface at a cross head speed of 0.20 mm/min. The loads to which the specimens were subjected were recorded on a chart moving at 0.50 mm/min. The adhesive strength was determined by measuring the load when the specimen separated from the cement block and by dividing the load by the area. The test was performed in a room at $23{\pm}2^{\circ}C.$ and $50{\pm}10$ per cent relative humidity. A minimum of five specimens were tested each material and those which deviated more than 15 per cent from the mean were discarded and new specimens prepared. From the experiments, the following results were obtained. 1) It was found that the adhesive strength of the polycarboxylate cement to all alloys tested was considerably greater than that of the zinc phosphate cement. 2) The adhesive strength of the polycarboxylate cements was superior to the non precious alloys, such as the copper, indium, nickel and chromium alloys, but it was inferior to the precious gold, silver and palladium alloys. 3) Surface treatment of the alloy was found to be an important factor in achieving adhesion. It appears that a polycarboxylate cement will adhere better to a smooth surface than to a rough one. This contrasts with zinc phosphate cements, where a rough helps mechanical interlocking. 4) The adhesion of the polycarboxylate cement with enamel was found superior to its adhesion with dentine.

• 한국건축시공학회지
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• 제9권6호
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• pp.175-181
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• 2009

본 연구에서는 폴리카본산계에 혼합 사용된 혼화제의 혼입율 변화에 따른 조강용 혼화제로서의 실무에서의 활용가능성 여부를 판단하고자한 실험연구 결과이다. 유동성은 만족하는 경향으로 나타났으며, 공기량은 KS규정보다 다소 작고 단위용적질량은 만족하는 것으로 나타났다. 블리딩 량은 B2가 가장 적게 나타났고, 응결시간은 A1, B1, C1에서 초결 및 종결이 빠르게 나타났다. 경화 콘크리트의 특성으로 조기재령의 압축강도 발형 경향은 7일 재령에서 C2의 모든 첨가율이 가장 높은 강도 값을 나타내었고 그 중 1.3%의 첨가율이 가장 큰 강도 발현경향을 나타내었다. 인장강도 역시 압축강도에 비해 약 1/10정도의 강도 발현율을 나타내고 있다. 건조 수축에 의한 길이 변화율은 양호한 편으로 나타났는데, 적당한 AE공기 연행제를 사용하면 실무에서 매우 유용한 혼화제로써의 사용이 가능할 것으로 판단된다.

• Restorative Dentistry and Endodontics
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• 제18권2호
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• pp.507-513
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• 1993

본 연구의 목적은 3종의 일반적 glass ionomer cement과 1종의 광중합형 glass ionomer cement을 자료로 하여 연화후 3, 5, 7, 10분 경과시켜 methylene blue용액에 침적하여 그침투를 측정하여 물의 영향을 관찰하고 이상의 시간과 관련하여 수분과 접촉시 그 용해도를 zinc phosphate와 polycarboxylate cement와 비교관찰하였다. blue stained zone은 모든 glass ionomer cement에서 나타났고 inner opaque zone은 두종의 regular glass ionomer cement에서만 나타났다. 연화시작부터 물에 침적시키는 사이시간이 연장되매 따라 모든 cement에서 두 zone의 후경이 감소하였고 regular glass ionomer cement의 면으로 부터 물질의 손실량은 현저히 감소하였으며 물질의 손실량에 대해서는 light curing glass ionomer cement는 시간에 거의 영향을 받지 않았으며 zinc phosphate cement파 polycarboxylate cement도 이와 유사성을 보였다.