• Bulletin of the Korean Chemical Society
• /
• v.33 no.3
• /
• pp.833-838
• /
• 2012

The thermal degradation products of polytrimethylene terephthalate (PTT) obtained by heating the sample in the temperature range of $250-360^{\circ}C$ under non-oxidative conditions was characterized using MALDI-TOF (matrix assisted laser desorption/ionization) mass spectrometry. The structures of the degradation products were determined and the relative compositions were estimated. The MALDI-TOF mass spectra of the thermally degraded PTT sample showed three main series of oligomer products with different end groups, which were carboxyl/carboxyl, carboxyl/allyl, and allyl/allyl. In contrast to the thermal degradation of polyethylene terephthalate (PET), the oligomers containing terephthalic anhydrides were not detected, whereas the formation of oligomers containing the unsaturated allyl ester group was confirmed by mass assignment. From these results, it was concluded that the thermal degradation of PTT proceeds exclusively through the ${\beta}$-CH hydrogen transfer mechanism, which is in accordance with the proposed reaction mechanism for the thermal degradation of polybutylene terephthalate (PBT).

• Journal of the Korean Chemical Society
• /
• v.41 no.3
• /
• pp.157-165
• /
• 1997

The transesterification reaction could be used to the technical production as it forms an in-situ compatibilizer during the processing of polymer blends. Thus, TR-4,6(poly(tetramethylene-4,4'-terephthaloyldioxydibenzoate-co-hexametylene-4,4'-terephthaloyldioxydibenzoate), one of thermotropic liquid crystalline polymers was synthesized and was blended with PBT(polybutylene terephthalate), one of engineering plastics, to study the transesterification reaction. The transesterification reactions between two components, TR-4,6 and PBT, were monitored by IR, DSC and $^{13}C-NMR$ and analyzed by a statistical treatment method. Also, the reaction rates and the sequence distributions of repeating unit were (calculated and) invesitigated.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.51 no.1
• /
• pp.94-101
• /
• 2015

The heat treatment machine based on immersion was developed to reduce temperature difference during netting process and appraised it performance compared current heat treatment machine using high pressure. It was also reviewed the optimum heat treatment procedures for PBSAT monofilament net in accordance with the immersion time and temperature. The procedure was based on physical measurement such as breaking load, elongation and angle of the mesh for PBSAT monofilament. The water temperature gap of the treatment machine based on immersion was less than $1^{\circ}C$. and the energy consumption was also increased in high temperature condition. It was identified that the optimum temperature was $75^{\circ}C$ and its optimum processing time was between 15 minutes and 20 minutes to get qualified physical properties.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2004.10a
• /
• pp.58-64
• /
• 2004

The shrinkages of injection molded parts are different in molding operational conditions, resins and additives. The shrinkage of injection molded part for crystalline polymer, PBT (polybutylene terephthalate) has been studied for various operational conditions of injection molding and content of additives. Mica was used as a additive to PBT to examine the part shrinkage according to the mica content. The part shrinkages of mica contained PBT decreased as mica content increases. Higher injection temperature and injection pressure resulted in a lower shrinkage. As mold temperature increases the part shrinkage decreased. The part shrinkage of flow direction was less than that of the perpendicular direction to the flow for both pure and mica contained PBT. However the shrinkage difference between flow and perpendicular to flow directions decreased as mica content increased.

• Journal of the Korean Society of Safety
• /
• v.18 no.3
• /
• pp.101-108
• /
• 2003

Polymeric positive temperature coefficient(PTC) composites have been prepared by incorporating carbon black(CB) into high density polyethylene(HDPE), polyphenylene sulfide(PPS) and polybutylene terephthalate(PBT) matrices. A PTC effect was observed in the composite, caused by the large thermal expansion due to He consecutive melting of HDPE, PPS and PBT crystallites. This theory is based upon the premise that the PTC phenomenon is due to a critical separation distance between carbon particles in the polymer matrix at the higher temperature. The influence of PTC characteristics of the PPS/CB composite can be explained by DSC result. HDPE, one of prepared composition, exhibit the higher performance PTC behavior that decreaseing of negative temperature coefficient(NTC) effect and improved reproducibility by chemically crosslinking. Also, PBT/CB and PPS/CB composites exhibit the higher PTC peack temperature than HDPE/CB PTC composite, individually $200^{\circ}C$ and $230^{\circ}C$. These PTC composite put to good use in a number of safety application, such as self$.$controlled heater, over-current protectors, auto resettable switch, high temperature proctection sensor, etc.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.33 no.2
• /
• pp.81-93
• /
• 2020

The fatigue characteristics of glass fiber reinforced plastic (GFRP) composites were studied under repeated loads using the finite element method (FEM). To realize the material characteristics of GFRP composites, Digimat, a mean-field homogenization tool, was employed. Additionally, the micro-structures and material models of GFRP composites were defined with it to predict the fatigue behavior of composites more realistically. Specifically, the fatigue characteristics of polybutylene terephthalate with short fiber fractions of 30wt% were investigated with respect to fiber orientation, stress ratio, and thickness. The injection analysis was conducted using Moldflow software to obtain the information on fiber orientations. It was mapped over FEM concerned with fatigue specimens. LS-DYNA, a typical finite element commercial software, was used in the coupled analysis of Digimat to calculate the stress amplitude of composites. FEMFAT software consisting of various numerical material models was used to predict the fatigue life. The results of coupled analysis of linear and nonlinear material models of Digimat were analyzed to identify the fatigue characteristics of GFRP composites using FEMFAT. Neuber's rule was applied to the linear material model to analyze the fatigue behavior in LCF regimen. Additionally, to evaluate the morphological and mechanical structure of GFRP composites, the coupled and fatigue analysis were conducted in terms of thickness.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.32 no.6
• /
• pp.349-357
• /
• 2019

Finite element method (FEM) is utilized in the development of products to realistically analyze and predict the mechanical behavior of materials in various fields. However, the approach based on the numerical analysis of glass fiber reinforced plastic (GFRP) composites, for which the fiber orientation and strain rate affect the mechanical properties, has proven to be challenging. The purpose of this study is to define and evaluate the mechanical properties of glass fiber reinforced plastic composites using the numerical analysis models of Digimat, a linear, nonlinear multi-scale modeling program for various composite materials such as polymers, rubber, metal, etc. In addition, the aim is to predict the behavior of realistic polymeric composites. In this regard, the tensile properties according to the fiber orientation and strain rate of polybutylene terephthalate (PBT) with short fiber weight fractions of 30wt% among various polymers were investigated using references. Information on the fiber orientation was calculated based on injection analysis using Moldflow software, and was utilized in the finite element model for tensile specimens via a mapping process. LS-Dyna, an explicit commercial finite element code, was used for coupled analysis using Digimat to study the tensile properties of composites according to the fiber orientation and strain rate of glass fibers. In addition, the drawbacks and advantages of LS-DYNA's various anisotropic material models were compared and evaluated for the analysis of glass fiber reinforced plastic composites.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.18 no.8
• /
• pp.378-385
• /
• 2017

This study investigated the design of a snap fit, which is widely used for fastening plastic parts. We analyzed the assembly mechanism of a lock snapfit, measured the assembly force and separation force based on the design of experiments, and derived a regression equation through an analysis of variance. The response surface methodology was also used. Polybutylene terephthalate was used to fabricate specimens, and the assembly force and separation force were measured using a micro-tensile tester. The length, width, thickness, and interference were considered as factors. A second-order regression model was used to derive the regression equation. The assembly force decreased with increasing length and width, but it increased with increasing thickness and interference. The finite element method was used to analyze the assembly mechanics. The width decreased the assembly force by increasing the ductility. The influences of the factors for low assembly force and high release force were shown to be opposite to each other. It was necessary to design a structure that minimized the assembly force while maintaining an appropriate level of separation force.

• Journal of Radiation Industry
• /
• v.5 no.2
• /
• pp.145-149
• /
• 2011

Poly(butylenes terephthalate) have made large strides in applications of injection, extrusion, and molding material due to their excellent thermal resistance and appropriate mechanical properties. However, PBT was not hard polymer but a soft polymer which caused low absorption of external energy and the defect of being easily broken with the strong impact. Thus, the electron beam irradiation was carried out over a range of irradiation doses from 100 to 1,000 kGy for enhancing the properties. The decreases of $T_m$, $T_c$, and enthalpy were observed as increasing the absorbed dose in the results of DSC analysis. The improvement in the impact strength of PBT was clearly observed as the absorbed dose was increased. This was probably due to the 3-dimensional network structures, resulting in increasing the absorption of impact energy. In addition, the wear properties had increased at higher than 300 kGy. The negative deviation of weight loss confirmed the improvement of the wear properties of PBT, as evidenced by SEM observation on the wear surfaces.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2004.05a
• /
• pp.159-165
• /
• 2004

The shrinkages of injection molded parts are different in molding operational conditions and mold design. It also differs from resins. The shrinkages of injection molded parts for PBT (polybutylene terephthalate), PC (polycarbonate),and glass reinforced PBT and PC have been studied for various operational conditions of injection molding. The part shrinkage of crystalline polymer, PBT was higher than that of amorphous polymer, PC by about two times. The part shrinkages of both polymers decreased as glass fiber content increases. Higher Injection temperature and lower injection pressure resulted in a higher shrinkage in both PBT and PC resins. As mold temperature increases the part shrinkage of PC decreased. However, the part shrinkage of PBT increased as mold temperature increases. The part shrinkage of both PBT and PC resins decreased as gate size increases since the pressure delivery is mush easier for a larger gate size. The part shrinkage of flow direction was less than that of the perpendicular direction to the flow for both pure and glass fiber reinforced resins. The part shrinkage at the position close to the gate was less than that of the position far from the gate.