• Journal of the Korean Electrochemical Society
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• v.22 no.4
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• pp.155-163
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• 2019

Mixture electrodes of a graphite having a good cycle performance and a silicon monoxide (SiO) having a high capacity are fabricated and their cycle performances are evaluated as negative electrodes for lithium-ion batteries. The electrode prepared by mixing the natural graphite and carbon-coated SiO in a mass ratio of 9:1 shows a reversible capacity of $480mAh\;g^{-1}$, 33% higher than that of graphite. However, the capacity deteriorates continuously upon cycling due to the volume change of silicon monoxide. In this study, the factors that can improve the cycle performance have been discussed through the change in the configurations of the electrode and the electrolyte. The electrode using the carboxymethyl cellulose (CMC) binder shows the best cycle performance compared to the conventional binders. The electrode sing the CMC and styrene-butadiene rubber (SBR) binder not only has almost the similar cycle characteristics with the electrode using the CMC binder but also has the better rate capability. When the fluoroethylene carbonate (FEC) is used as an electrolyte additive, the cycle life is improved. However, the electrolyte with 5 wt% of FEC is appropriate because the rate capability decreases when the content of FEC is increased to 10 wt%. In addition, when the mass loading of the electrode is lowered, the cycle performance is greatly improved. Also, enhanced cycle performance is achieved using the roughened Cu current collector polished by abrasive paper.

• Korean Chemical Engineering Research
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• v.58 no.2
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• pp.209-223
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• 2020

Executions of SCM in a chemical company of which divisions produce petrochemicals, compounds, batteries, IT material and medicine directly affect their own profit. Execution level of SCM or optimization is very important. This work presents activities of SCM and optimization of inefficient issues in several industrial divisions using mathematical optimization method. The meaning is not only academic research but also making a useful tool which active partner deals with in his work. It is explained how to do beforehand and afterward optimization problem. The benefits are mentioned in the sections. The first of examples would be cover supply plan optimization, optimal profit business plan, and scheduling of a stretching process of polarizer based on minimizing raw material loss in polarizer production. The second example would be cover the optimization of production/packaging plans to maximize productivity of Poly Olefin processes, and the third example is minimization of transition loss in the production of battery electrodes. The fourth example would be cover scheduling of vessel approaching to berth. Because transportation of large portion of raw material and products of petrochemical industry is dealt with vessel, scheduling of vessel approaching to berth is important at the shore of large difference of tide. The final example would be scheduling problem to minimization of change over time of ABS semi products.

• Particle and aerosol research
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• v.7 no.3
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• pp.79-85
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• 2011

Porous $TiO_2-SiO_2$ particles were synthesized by co-assembly of nanoparticles of $TiO_2$ and $SiO_2$ in evaporating aerosol droplets. Poly styrene latex (PSL) particles were employed as a template of porous particles. Flowrate of dispersion gas, weight ratio of $TiO_2/SiO_2$ and $SiO_2$ concentration in the precursor, and PSL size were chosen as process variables. The morphology, crystal structure, chemical bonding, and pore size distribution were analyzed by FE-SEM, XRD, FT-IR, BET. The morphology of porous $TiO_2-SiO_2$ particles was spherical and the average particle size range were from 1 to $10{\mu}m$. The particles were composed of meso and macro pores. The average particle diameter and pore volume of the as prepared particles were dependant on process variables. It was found that UV-Vis absorption of the porous particles was comparable with pure $TiO_2$ nanoparticles even though $TiO_2/SiO_2$ ratio is low in the porous particles.

• Journal of the Korea Institute of Building Construction
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• v.8 no.6
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• pp.131-137
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• 2008

In recent years, the light-weight aggregate has widely been used to reduce the weight of construction structures, and to achieve the thermal insulation of building structures. The purpose of this study is to evaluate the heat resistance of polymer concrete composites with light-weight aggregate made by binders as resin and cement with polymer dispersion. The light-weight polymer concrete composites are prepared with various conditions such as binder content, filler content, void-filling ratio, light-weight aggregate content and polymer-cement ratio, and tested for heat resistant test, and measured the weight reducing ratio, strengths and exhaustion content of gas such as CO, NO and $SO_2$. From the test results, the weight reducing ratio of light weight polymer concrete using UP binder after heat resistance test increase with an increase in the UP content irrespective of the filler content. The weight reducing ratio of polymer cement concrete is considerably smaller than that of UP concrete. In general, the strengths after heat resistance of polymer concrete composites are reduced about 40 to 65% compared with those before test. The exhausted quantity of CO, NO and $SO_2$ gases in polymer concrete composites is less than EPS(Expanded poly styrene). From the this study, it is confirmed that the many types gases discharge according to binder type of polymer concrete composites, its amount is controlled by selection of the binder type and mix proportions.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.1
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• pp.46-55
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• 2014

In this study, we modified the surface of nanofibrillated cellulose (NFC) through LbL (Layer-by-Layer) multilayering process with polyelectrolytes and investigated the effects of the NFC modification on the charge of NFC surface and the dewatering ability of NFC suspension. The multilayering process was done onto NFC fibers using polydiallyldimethylammonium chloride (PDADMAC) and poly-sodium 4-styrene sulfonate (PSS) under different dosage and washing conditions. When the washing was carried out in every adsorption stage, the modified NFC had strong cationic or anionic charge depending on the type of polyelectrolyte in the outermost layer and the dewatering ability was not affected. In the case of no washing treatment or washing in the final adsorption stage, however, the zeta potential of NFC was close to an isoelectric point so that the dewatering ability increased remarkably. Low addition level of polyelectrolytes also showed the similar results. The mixing of NFC suspensions with opposite charge resulted in higher network strength and improved dewatering ability due to the flocculation.

• Analytical Science and Technology
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• v.30 no.2
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• pp.75-81
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• 2017

5-methylthioninhydrin (5-MTN) is an amino acid sensitive reagent used for the development of latent fingermarks deposited on porous surfaces such as paper and wood. The present study demonstrates that the 5-MTN can be used as a latent footwear impression enhancement reagent, by reacting with trace multivalent metal ions, which are the main components of the latent footwear impression. 5-MTN and L-alanine complex (MTN-ALA) used for the latent footwear impression development was prepared, by mixing $4.5{\times}10^{-3}M$ 5-MTN (in methanol) and $4.5{\times}10^{-3}M$ L-alanine (in methanol) in 1:1 ratio, and keeping undisturbed at room temperature for 24 h. The latent footwear impressions were deposited on white and black non-porous surfaces (glass plate, polyethylene panel, polypropylene panel, acryl panel, polyvinyl chloride (PVC) panel, poly(methyl methacrylate) (PMMA) panel, acrylonitrile-butadiene-styrene (ABS) panel, tile), and a semi-porous surfaces (painted wood). The latent footwear impressions on these surfaces were treated with MTN-ALA complex by spraying. The fluorescence of footwear impressions (occurred due to the reaction between MTN-ALA and metal complexes) was observed under a 505 nm forensic light source and an orange barrier filter. The enhancement of latent footwear impression was achieved from black surfaces without any blurring. However, the fluorescence (enhancement) of footwear impression was not observed on the white PVC, PMMA, and ABS surfaces, because the incident light interfered and reflected on the surface. The sensitivity of MTN-ALA was superior to 2,2'-dipyridil, which is a representative non-fluorescing footwear impression enhancement reagent, and similar to 8-hydroxyquinoline, which is a representative fluorescing footwear impression enhancement reagent.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.300-300
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• 2006

Nondestructive nanostructural analysis is indispensable in the development of nano-materials and nano-fabrication processes for use in nanotechnology applications. In this paper, we demonstrate for the first time a quantitative, nondestructive analysis of nanostructured thin films supported on substrates and their templated nanopores by using grazing incidence X-ray scattering and data analysis with a derived scattering theory. Our analysis disclosed that vertically oriented nanodomain cylinders had formed in 20-100 nm thick films supported on substrates consisting of a mixture of poly(styrene-b-methyl methacrylate) (PS-b-PMMA) and PMMA homopolymer, and that the PMMA nanodomains were selectively etched out by ultraviolet light exposure and a subsequent rinse with acetic acid, resulting in a structure consisting of hexagonally packed cylindrical nanopores.

• Journal of the Korean GEO-environmental Society
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• v.15 no.10
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• pp.5-13
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• 2014

In this research, in order to study insulation effect of commercial XPS and recycled PE aggregates for prevention of frost heave in the roadbed of railroad track from the freezing temperature, model tests were carried out in the large freezing room. For this, thermal conductivities were measured for various dry densities, water contents, temperatures and mixing ratios of PE aggregates. From the tests, it can be seen that thermal conductivities of roadbed decrease with the increase of the ratio of mixed PE aggregates. However it was sensitive to the changes of temperature and water content due to the amount of water in the voids. From the model test of railroad track, it can be seen that the time to reach $0^{\circ}C$ was longer for XPS than that for the PE aggregates. Also the test shows best insulation effect can be achieved when XPS board was installed above the PE aggregate layer rather than the opposite order.

• Journal of the Korea Concrete Institute
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• v.15 no.6
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• pp.888-893
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• 2003

The purpose of this study is to make clear the durability of the polymer films formed in the autoclaved polymer-modified mortars and concretes. The polymer films prepared with polymer dispersions such as a styrene-butadiene rubber (SBR) latex, a poly (ethylene-vinyl acetate)(EVA) emulsion and a polyacrylic ester (PAE) emulsion for polymeric admixtures are exposed to autoclaving at 18$0^{\circ}C$ in temperature and 1.01 MPa in vapor pressure, and subjected to tensile test and infrared spectroscopy. The durability of the polymer films is evaluated from the application of autoclaving to the polymer films under saturated Ca(OH)$_2$ solution immersion causes no degradation for SBR films and a significant degradation due to the saponification of the polymers for EVA and PAE films. Accordingly, in the application of autoclaving to polymer-modified mortars and concretes, it is suggested that SBR-modified mortars and concretes are hardly degraded but EVA- and PAE-modified mortars and concretes are markedly degraded by the saponification of the polymers.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.27 no.10
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• pp.1644-1652
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• 2003

The monitor product is packed by cushioning materials because the monitor can be broken during transportation. However, the addition of the cushioning material increased the volume of the product. Therefore, it is required that the usage of cushioning material be minimized. In practice, design engineers have followed the ad hoc design with experiences of predecessors. Automation of the design process is very important for the reduction of engineering cost, and can be achieved by an excellent design process and software development. According to Axiomatic design, a design flow is defined and a software system is developed for automated design. At first, a basic model is defined. A user can modify the model from menus and design is carried out according to the input from the user. Finite element models are automatically generated based on the design. A nonlinear finite element analysis program called LS/DYNA3D is linked for the impact analysis. The process of Design of Experiments using orthogonal array is installed to minimize the maximum acceleration in drop test. Therefore, a new design can be proposed by the system. The program is designed according to the Independence Axiom of Axiomatic design. FRs and DPs of the software system are defined and decomposed by zigzagging process. Independent modules can be generated by analysis of the full design matrix and each module is coded as class in Object Oriented Programming (OOP). Design results are discussed.