• 한국세라믹학회지
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• 제24권5호
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• pp.477-483
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• 1987

Cr2O3 doped Pb(Zr0.525 Ti0.475)O3 piezoelectric ceramics were prepared from reagent grade oxide mixture, PbO, ZrO2, TiO2 and Cr2O3. Piezoelectric and aging properties of specimens were measured for various additions of Cr2O3. Generally, it has been known that aging rate decreased with Cr2O3 addition by stabilizing the domain wall. But hysteresis loops showed that the domain destabilization was occurred at high electric field (larger than 10KV/cm). In smaller additions of Cr2O3 (0-0.2mol%), aging rate increased and microcracks were created with increasing poling filed due to increasing internal stress. In larger additions of Cr2O3(0.4∼0.6mol%), aging rate decreased with increasing poling field.

• Journal of the Korean Physical Society
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• 제73권10호
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• pp.1561-1565
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• 2018

The dielectric properties of the uniaxial relaxor ferroelectric $Sr_xBa_{1-x}Nb_2O_6$ with x = 0.75 were investigated along the polar [001] direction as a function of temperature. The capacitance maximum showed the frequency dispersion commonly observed in relaxors. Additional weak dielectric anomalies were observed in the paraelectric phase; they were only seen during the heating process and disappeared upon subsequent cooling. These were attributed to the existence of large polar clusters strongly pinned at defects and/or to random fields and their metastable characters. Aligning the ferroelectric domains along the polar axis at room temperature removed the high-temperature dielectric anomalies. The dependences of the capacitance and the dielectric maximum temperature on the magnitude of the poling field were investigated.

• 한국전기전자재료학회논문지
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• 제27권1호
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• pp.27-32
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• 2014

In this paper, PZT piezoelectric ceramic specimens with 4 compositions (Zr/Ti=50/50, 53/47, 56/44, 58/42) in $Pb(Zr,Ti)O_3$ system were fabricated. We studied effects of poling strength and thermal aging on the temperature characteristics of eletromechanical coupling factor k31 of the specimens, which were poled with the DC electric fields, 1.5, 2.5 and 3.5 kV/mm respectively and thermally aged for an hour at $200^{\circ}C$. The eletromechanical coupling factor k31 of the specimen with the composition Zr/Ti= 53/47, nearest to the morphotropic phase boundary decreased the most greatly, irrelevant to the intensity of poling field, due to 1st thermal aging. And the temperature coefficient of eletromechanical coupling factor k31 was (-) in the tetragonal phase composition and (+) in the rhombohedral phase composition, which is reverse in the temperature coefficient of resonance frequency. It is interesting that eletromechanical coupling factor k31 of PZT ceramics is shown to be able to increase as temperature increase in the interval $-20{\sim}80^{\circ}C$.

• 한국전기전자재료학회논문지
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• 제23권6호
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• pp.491-496
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• 2010

The relaxation behavior of aligned electric dipoles in a mixed polymer of P2ANS with P(VDF-TrFE) is studied with optical second harmonic generation (SHG). In this work, a macroscopic noncentrosymmetry of the spin coated film was achieved by an electrical poling. The relaxation of induced polar order of nonlinear optic(NLO) chromophores after poling leads to an insufficient long-term stability of NLO properties. In this work, we develop a new technique to suppress such kind of dipole relaxation in a poled polymer. We found that the poled dipoles in a NLO polymer were effectively immobilized by the internal electric field created by a thermally annealed ferroelectric polymer. The long-term stability in a mixed system of NLO polymer/ferroelectric polymer was successively accomplished by a series of thermal treatments applied to the mixed polymer system at a temperature of $140^{\circ}C$ for at least 1hour after poling.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2005년도 추계학술대회 논문집 전기물성,응용부문
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• pp.157-159
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• 2005

In this study, in order to develop Pb-free piezoelectric ceramics, $[Li_{0.04}(Na_{0.44}K_{0.52)-(Nb_{0.86}Ta_{0.10}Sb_{0.04})]O_3$ ceramics were fabricated by conventional mixed oxide method and their piezoelectric characteristics were investigated according to the poling condition. The transition temperature from orthorhombic phase to tetragonal phase observed at $93[^{\circ}C]$ and Curie temperature was $346[^{\circ}C]$. At $50[^{\circ}C]$ poling temperature, dielectric constant, electromecha nical coupling factor kp, piezoelectric $d_{33}$ const ant, coercive field Ec, remanant polarization Pr and mechanical quality factor Qm showed the optimum value of 737, 0.45, 209[pC/N], 1l.34[kV/cm], $7.14[{\mu}C/cm^2]$ and 205, respectively.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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• pp.309-312
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• 2002

Ferroelectric $Sr_{0.3}Ba_{0.7}Nb_{2}O_{6}$ (SBN30) thin films were deposited on Pt/Ti/$SiO_{2}$/Si(100) substrates by ion beam sputtering. During annealing treatment at $750^{\circ}C$, poling was attempted by applying dc voltage bias across polished surfaces. Phase relation, microstructure and crystallization behavior were examined using XRD and FE-SEM. Ferroelectric hysteresis characteristics were also determined where both remanent polarization and coercive values decreased with the increase of bias voltage. The measured remanent polarization and coercive field values at 5 V and 10 V bias were $36{\mu}C/cm^2$, $10{\mu}C/cm^2$ and 100kV /cm, 80kV /cm, respectively.

• 한국세라믹학회지
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• 제36권12호
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• pp.1374-1380
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• 1999

The cause of Scond Harmonic Generation (SHG) in thermally poled silica glass is suggested basedon the electrical and dielectric relaxation measurements. The absorption currents as functions of time were measured for various types of silica glasses and analyzed by the theory of Space Charge Polarization. Space charge polarization occurs when an ionic conducting material is subjected to dc electric field with blocking electrode. Thermal poling performed to induce SHG in silica glass is basically identical to the process generating space charge polarization. Hence it was found that gene-ration removal reproduction and temperature dependence of SHG in poled silica is directly related to those of space charge polarization. It turned out that the fundamental parameters governing the SHG in poled silica are charge carrier concentration and mobility. Based on the theory of space charge polarization and experimental results of electrical rela-xation the method to increase the intensity of SHG is proposed.

• 한국재료학회지
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• 제33권12호
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• pp.517-524
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• 2023

BaTiO₃-Poly vinylidene fluoride (PVDF) solution was prepared by adding 0~25 wt% BaTiO₃ nanopowder and 10 wt% PVDF powder in solvent. BaTiO₃-PVDF film was fabricated by spreading the solution on a glass with a doctor blade. The output performance increased with increasing BaTiO₃ concentration. When the BaTiO₃ concentration was 20 wt%, the output voltage and current were 4.98 V and 1.03 ㎂ at an applied force of 100 N. However, they decreased when the over 20 wt% BaTiO₃ powder was added, due to the aggregation of particles. To enhance the output performance, the generator was poled with an electric field of 150~250 kV/cm at 100 ℃ for 12 h. The output performance increased with increasing electric field. The output voltage and current were 7.87 V and 2.5 ㎂ when poled with a 200 kV/cm electric field. This result seems likely to be caused by the c-axis alignment of the BaTiO₃ after poling treatment. XRD patterns of the poled BaTiO₃-PVDF films showed that the intensity of the (002) peak increased under high electric field. However, when the generator was poled with 250 kV/cm, the output performance of the generator degraded due to breakdown of the BaTiO₃-PVDF film. When the generator was matched with 800 Ω resistance, the power density of the generator reached 1.74 mW/m². The generator was able to charge a 10 ㎌ capacitor up to 1.11 V and turn on 10 red LEDs.

• 한국전기전자재료학회논문지
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• 제19권7호
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• pp.644-649
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• 2006

This paper presents a new disk-type piezoelectric transformer. The input side of the transformer has a crescent-shaped electrode and the output side has a focused poling direction. The piezoelectric transformers operated in each transformer's resonance vibration mode. The electrodes and poling directions on commercially available piezoelectric ceramic disks were designed so that the planar or shear mode coupling factor $(k_p\;k_{15})$ becomes effective rather than the transverse mode coupling factor $(k_{31})$. ANSYS finite element code was used to analyze transformer behavior and to optimize electrode and poling configurations. The voltage step-up ratio of the proposed transformer has been markedly improved in comparison with that of the equivalent rectangular(Rosen) type. A single layer prototype transformer, $20\sim30mm$ in diameter and $1.0\sim3.5mm$ thick, was fabricated, such as step-up ratio, power transformation efficiency, and temperature were measured. While the transformer was driving a Cold Cathode Fluorescent Lamp(CCFL), the temperature field of the transformer was also observed.

• 한국광학회지
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• 제16권4호
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• pp.366-375
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• 2005

Ti 확산 리튬나오베이트 채널 광도파로의 z-축 분극을 주기적으로 $180^{\circ}$ 위상 변화시키는 Ti:PPLN 제작 공정을 검토하고, 개선하였다. 분극반전 공정에 적합한 지그와 Labview 프로그램을 이용하여 전하량 제어시스템을 고안하였다. 분극반전에 필요한 전하량으로부터 분극에 적절한 고전압 펄스와 duty-cycle을 조절하였으며, 분극에 필요한 임계 전압 보다 작은 전압을 인가한 상태에서 누설전류의 변화를 관찰하여 절연파괴 현상을 또한 최소화하였다.