• Title/Summary/Keyword: Polarized absorption

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Electrical Conductivity and Optical Properties of Elongated Conducting Polymer (연신도전성고분자의 전기전도와 광학적 특성)

  • 박대희;강성화;임기조
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.59-62
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    • 1994
  • Tact Electrical conductivity. optical absorption spectra of poly(p-phenylene vinylene) and their dependence on stretching are discussed in detail. The conductivity in the parallel direction to the stretching is higher over one order in magnitude than that in the perpendicular direction to the stretching is higher over one order in magnitude than that in the perpendicular direction to the stretching. The photocurrent spectrum for the ligh polarized parallel to the chain direction is much enhanced in lower photon energy compared with that for the light polarized perpendicular to that direction. The result may be originated in the difference of energies which is needed to photogenerate carriers wi th the light polarized parallel and perpendicular to the chain stretched direction.

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Production of Hyperpolarized 129Xe Using Spin Exchange Optical Pumping

  • Kavtanyuk, Vladimir Vladimirovich;Kim, Wooyoung;Ando, Yu;Chebotaryov, Sergey;Seon, Yonggeun;Tan, Joshua Artem
    • Journal of the Korean Physical Society
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    • v.73 no.10
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    • pp.1458-1465
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    • 2018
  • We present a constructed setup for polarizing $^{129}Xe$ noble gas. Hyperpolarized $^{129}Xe$ has been obtained via spin exchange with an optically pumped rubidium vapor. Optical pumping is based on polarizing the valence electron of rubidium by the resonant absorption of a circularly polarized laser light. The magnetic field of 30 G was used for obtaining $^{129}Xe$ polarization. The apparatus for detecting polarization is a nuclear magnetic resonance spectrometer. The highest $^{129}Xe$ polarization of 54% has been obtained using 60 W circularly polarized laser light with wavelength of 794.7 nm. The measured longitudinal relaxation time of the hyperpolarized $^{129}Xe$ was 72.3 minutes.

Environment-dependent Broadband Perfect Absorption of Metal-insulator-metal Metamaterial Systems

  • Feng Li;Yulong Tang;Qingsong Peng;Guosheng Hu
    • Current Optics and Photonics
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    • v.7 no.2
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    • pp.136-146
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    • 2023
  • Based on calculations using the macroscopic Maxwell's equations with mesoscopic boundary conditions, light absorption by a layered metal-insulator-metal (MIM) metamaterial system embedded in three different environments is investigated. Increasing the top metal thickness shifts the broad absorption band to lower dielectric-constant regions and longer wavelengths, for either TM or TE waves. Boosting the dielectric-layer thickness redshifts the broadband absorption to regions of larger dielectric constant. In air, for the dielectric-constant range of 0.86-3.40, the absorption of the system exceeds 98% across 680-1,033 nm. In seawater with optimized dielectric constant, ≥94% light absorption over 400-1,200 nm can be achieved; particularly in the wavelength range of 480-960 nm and dielectric-constant range of 0.82-3.50, the absorption is greater than 98%. In an environment with even higher refractive index (1.74), ≥98% light absorption over 400-1,200 nm can be achieved, giving better performance. The influence of angle of incidence on light absorption of the MIM system is also analyzed, and the angle tolerance for ≥90% broadband absorption of a TM wave is up to 40° in an environment with large refractive index. While the incident-angle dependence of the absorption of a TE wave is nearly the same for different circumstances, the situation is different for a TM wave.

A Study on the Molecular Orientation of Po1yamic Acid Alkylamine Salt Langmuir-Blodgett Films (Polyamic Acid 알킬아민 염 랭뮤어-블로젯막의 분자 배향에 관한 연구)

  • 정순욱;임현성
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2000.11a
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    • pp.53.1-56
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    • 2000
  • Langmuir-Blodgett(LB) technique is the best candidate for the future molecular electronic devices. But, these molecular thin film devices require the bulk properties that are influenced by the molecular orientations. So, this is of current interest in molecular electronic device fabrications of new materials. In this study, quantitative evaluation of molecular orientation in LB films of PAAS was performed by comparing the absorption intensities of the FT-IR transmission and reflection-absorption spectra and the polarized UV/visible absorption spectra. It was found that the polar angle($\theta$) of the dipole moment is about 68$^{\circ}$and the tilting angle of the alkyl chain is about $11.5^{\circ}$ .

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A Study on the Molecular Orientation of Polyamic Acid Alkylamine Salt Langmuir-Blodgett Films (Polyamic Acid 알킬아민 염 랭뮤어-블로젯막의 분자 배향에 관한 연구)

  • 정순욱;임현성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.53-56
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    • 2000
  • Langmuir-Blodgett(LB) technique is the best candidate for the future molecular electronic devices. But, these molecular thin film devices require the bulk properties that are influenced by the molecular orientations. So, this is of current interest in molecular electronic device fabrications of new materials. In this study, quantitative evaluation of molecular orientation in LB films of PAAS was performed by comparing the absorption intensities of the FT-IR transmission and reflection-absorption spectra and the polarized UV/visible absorption spectra. It was found that the polar angle( $\theta$ ) of the dipole moment is about 68$^{\circ}$ and the tilting angle of the alkyl chain is about 11.5$^{\circ}$

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Study on the realtionship between phthalic and naphthalenic polyimide structures and the photo-induced molecular orientaion of liquid crystals on polyimides

  • Cho, Ki-Yun;Sung, Shi-Joon;Hah, Hyun-Dae;Park, Jung-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1167-1168
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    • 2004
  • Polarized ultraviolet irradiation techniques have been developed recently to produce alignment of liquid crystals (LC). Because of the excellent thermal stability and the alignment ablility of polyimides, polyimides has attracted considerable research interest for the photoinduced alignment layer. Hasegawa and Taira confirmed homogeneous alignment of LC by the decompostion of a polyimide induced by lineraly ultra-violet polarized light. It was reported that ultraviolet visible absorption spectra of a polyimide alignment film showed a remarkable change upon irradiation. In this study, we synthesized phthalic polyimide and a naphthalenic polyimide in order to investigate the effect of the polyimide structure. Some difference in terms of the photo-induced molecular orientaion of liquid crystals were observed with the polyimide structure.

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The Characteristics of Photo-alignment with Photo-crosslinkable Polyimide (광 가교성 폴리이미드의 광배향 특성)

  • Shin, Dong-Muyng;Cho, Sun-Ju;Shon, Byoung-Choung;Choi, Jeong-Woo;Yi, Mi-Hie;Choi, Kil-Yeoung
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.1
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    • pp.15-20
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    • 1999
  • Photo-crosslinkable polyimide(PI) which contains CF3 moiety was synthesized. Polarized UV light transformed ketone group of PI to hydroxyl group, which was confirmed by IR and UV-visible spectroscopy. We investigated the dichroic UV-absorption before and after photo-reaction with linearly polarized light. In particular we have attempted to clarify the relationship between the anisotropy of surface region and surface azimuthal anchoring energy and knew that the anchoring energy of photo-alignment PI is comparable with that of mechanical rubbing.

Holographic phase gratings in back- and frontlights for LCD's

  • Bastiaansen, C.W.M.;Heesch, C. van;Broer, D.J.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.421-421
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    • 2006
  • The light and energy-efficiency of classical liquid crystal displays is notoriously poor due to the use of absorption-based linear polarisers and colour filters. For instance, the light efficiency of PVAL polarisers is typically between 40 and 45 % and the colour filters have a typical efficiency below 35 % which results in a total light and energy-efficiency of the display below 10 %. In the past, a variety of polarizers were developed with an enhanced efficiency in generating linearly polarized light. Typically, these polarizers are based on the polarisationselective reflection, scattering or refraction of light i.e. one polarisation direction of light is directly transmitted to the LCD/viewer and the other polarization direction of light is depolarised and recycled which results in a typical efficiency for generating linearly polarized light of 70-85 %. Also, special colour filters have been proposed based on chiral-nematic reactive mesogens which increase the efficiency of generating colour. Despite the enormous progress in this field, a need persists for improved methods for generating polarized light and colour based on low cost optical components with a high efficiency. Here, the use of holographic phase gratings is reported for the generation of polarized light and colour. The phase grating are recorded in a photopolymer which is coated onto a backor frontlight for LCDs. Typically the recording is performed in the transmisson mode or in the waveguiding mode and slanted phase gratings are generated with their refractive index modulation at an angle between 20o and 45o with the normal of the substrate. It is shown that phase gratings with a high refractive index modulation and a high efficiency can be generated by a proper selection of the photopolymer and illumination conditions. These phase gratings coupleout linearly polarized light with a high contrast (> 100) and the light is directed directly to the LCD/viewer without the need for redirection foils. Dependent on the type of phase grating, the different colours are coupled-out at a slightly different angle which potentially increases the efficiency of classical colour filters. Moreover, the phase gratings are completely transparent in direct view which opens the possibility to use them in frontlights for LCDs. Holographic polarization gratings posses a periodic pattern in the polarization state of light (and not in the intensity of light). A periodic pattern in the polarization direction of linearly polarized light is obtained upon interference of two circularly polarized laser beams. In the second part of the lecture, it is shown that these periodic polarization patterns can be recorded in a linear photo-polymerizable polymer (LPP) and that such an alignment layer induces a period rotation in the director of (reactive and non-reactive) liquid crystals. By a proper design, optical components can be produced with only first order diffraction and with a very high efficiency (>0.98). It is shown that these diffraction gratings are potentially useful in projection displays with a high brightness and energy efficiency

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Polyamic Acid Alkylamine Salts(PAAS) (Langmuir-Blodgett(LB) Films의 광학적 및 전기적 특성)

  • 이승엽;강도열;김태완
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.277-280
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    • 1997
  • It is important to investigate the molecular arrangement and the orientational distribution in the study of LB films. Polarized UV/visible absorption spectra make it possible to reveal the molecular arrangement and the orientational distribution. It is clarified that the PAAS LB films have specific directions in the molecular arrangement and the orientational distribution, which art different in intensity corresponding to the surface pressure. Unpolarized UV/visible absorption spectra reveal that the surface pressure is proportional to the finn thickness and is related to the molecular orientation. Current-Voltage(I-V) measurements provide that the current decreases as the surface pressure increases and there are certain phenomena called switching phenomena. Switching effort indicates that the current flows in high conductivity during on-state and suddenly decreases into low conductivity during off-state.

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Mass constraints of coronal mass ejection plasmas observed in EUV and X-ray passbands

  • Lee, Jin-Yi;Raymond, John C.
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.1
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    • pp.39.1-39.1
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    • 2011
  • Coronal mass ejection (CME) plasmas have been observed in EUV and X-ray passbands as well as in white light. Mass of CME has been determined using polarized brightness observed by the Large Angle and Spectrometric Coronagraph Experiment (LASCO) on board Solar and Heliospheric Observatory (SOHO). Therefore, this mass obtained from the LASCO observation indicates the total CME mass. However, the mass of CME plasma in different temperatures can be determined in EUV and X-ray passbands using observations by SOHO/EIT, STEREO/EUVI, and Hinode/XRT. Prominence/CME plasmas have been observed as absorption or emission features in EUV and X-ray passbands. The absorption features provide a lower limit to cold mass. In addition, the emission features provide an upper limit to the mass of plasmas in temperature ranges of EUV and X-ray. We determine the mass constraints using the emission measure obtained by assuming the prominence/CME structures. This work will address the mass constraints of hot and cold plasmas in CMEs, comparing to total CME mass.

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