• Title/Summary/Keyword: Polarization of water

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Electrochemical Characteristics under Cavitation-Erosion Environment of STS 304 and Hot-Dip Aluminized STS 304 in Sea Water Solution (천연해수 용액에서 STS 304와 용융 알루미늄 도금된 STS 304의 캐비테이션-침식 환경 하에서의 전기화학적 특성)

  • Chong, Sang-Ok;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.49 no.1
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    • pp.26-31
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    • 2016
  • In this paper, the characteristics of a cavitation-erosion damage behavior on the STS 304 and hot-dip aluminized STS 304 under cavitation environment in sea water solution was investigated. The electrochemical experiments were carried out by potential measurement, anodic/cathodic polarization test, Tafel analysis, and also galvanostatic experiment in current density variables for the samples. The apparatus of cavitation-electrochemical experiment was manufactured in compliance with modified ASTM G-32 standard, with the conditions of sea water temperature of $25^{\circ}C$ and the measurement, amplitude of $30{\mu}m$. The damage behavior was analyzed by an observation of surface mophologies and a measurement of damage depth by a scanning electron microscope(SEM) and a 3D microscope, respectively, after electrochemical test. After polarization experiment under cavitation environment, much higher damage depths for the hot-dip aluminized STS 304 were observed comparing to the untreated STS 304. In addition, higher corrosion current density in hot-dip aluminized STS 304 presented than that of untreated STS 304 as a result of Tafel analysis.

A study on induced polarization characteristics of sand and clay for alluvium investigation (충적층 조사를 위한 모래와 점토의 유도분극 특성 고찰)

  • Choi, Sang-Hyuk;Kim, Hyoung-Soo;Kim, Ji-Soo
    • 한국지구물리탐사학회:학술대회논문집
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    • 2008.10a
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    • pp.179-184
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    • 2008
  • Silt or clay alluvium fully saturated with water generally shows low resistivity. Sometimes it is believe that the low resistivity layer is considered as good aquifer but this makes problems in the development of groundwater. To overcome this problem, we adopted induced-polarization(IP) method with resistivity method. Laboratory experiments and resistivity/IP field surveys with non-polarization electrodes were conducted for the study. Laboratory experiments shows that the increase of clay contents in the sample mixed with sand and clay give low resistivity and high chargeability. We used this experiment results in the interpretation of resistivity/IP field data which were obtained in riverbank filtration. Finally, the layer which has low resistivity and chargeabilty would be regarded as a good aquifer for the development of groundwater intake.

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The Effect of Corrosion Inhibitors Influencing on the Corrosion of Reinforced Steel in Mortar Specimen Immersed in Sea Water for Seven Years (해수중 7년간 침지된 몰탈시험편의 철근부식에 미치는 부식억제제의 효과)

  • 정진아;남진각;문경만;이명훈;김기준
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10c
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    • pp.211-216
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    • 1998
  • Recently the shortage of good aggregate has encouraged the use of sea sand in construction field, and the corrosion damage of the reinforced steel in concrete structures has been increased due to chlorides from sea sand and deicing salt. Therefore, a number of researchs are proceeding to prevent the corrosion of the reinforced steel in concrete, especially in marine environments. This study focused on the effect of corrosion inhibitors to evaluate protection characteristics for mortar specimens containing clorides. Corrosion behaviors have been investigated by half-cell potential measurement, linear polarization method, AC impedance method, and cyclic polarization test after immersing in sea water for 7 years. A possitive effect of a corrosion inhibitor has been obtained.

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Polarization Behaviors of SnCu Pb-Free Solder Depending on the P, Ni, Addition (SnCu계 무연솔더의 Ni, P 첨가에 따른 분극거동)

  • Hong Won Sik;Kim Whee Sung;Park Sung Hun;Kim Kwang-Bae
    • Korean Journal of Materials Research
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    • v.15 no.8
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    • pp.528-535
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    • 2005
  • It is inclined to increase that use of hazardous substances such as lead(Pb), mercury (Hg), cadmium(Cd) etc. are prohibited in the electronics according to environmental friendly policies of an advanced nation for protecting environment of earth. As this reasons, many researches for ensuring the reliability were proceeding in Pb free soldering process. n the flux remains on the PCB(printed circuit board) in the soldering process or the electronics exposed to corrosive environment, it becomes the reasons of breakdown or malfunction of the electronics caused by corrosion. Therefore in this studies we researched the polarization and Tafel properties of Sn40Pb and SnCu system solders based on the electrochemical theory. The experimental polarization curves were measured in distilled ionized water and 1 mole $3.5 wt\%$ NaCl electrolyte of $40^{\circ}C$, pH 7.5. Ag/AgCl and graphite were utilized by reference and counter electrodes, respectively. To observe the electrochemical reaction, polarization test was conducted from -250mV to +250mV. From the polarization curves composed of anodic and cathodic curves, we obtained Tafel slop, reversible electrode potential(Ecorr) and exchange current density((cow). In these results, we compared the corrosion rate of SnPb and SnCu solders.

Evaluation on the Rlationship between Wear Ratio and Polarization Characteristics of Anti-Fouling Paint (방오도료 도막의 마모율과 분극특성의 상관관계에 관한 평가)

  • Jeong, Jae-Hun;Moon, Kyung-Man;Won, Jong-Pil;Park, Dong-Hyun;Kim, Yun-Hae;Kim, Hyun-Myung;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Corrosion Science and Technology
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    • v.13 no.1
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    • pp.15-19
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    • 2014
  • Recently, anti-fouling paints which does not include the poison components such as tin(Sn), copper(Cu) have been increasingly developed in order to inhibit the environmental contamination of the sea water. Moreover, the wear ratios of these anti-fouling paints are very important problem to prolong their life time in economical point of view. In this study, five types of anti-fouling paints as self polishing type were investigated on the relationship between their polarization characteristics and wear ratios. It was verified that there was apparently a good relationship between the wear ratio and polarization characteristics, for example, the wear ratio increased with increasing the impedance ratio, and increased or decreased with the corrosion potential shifting in the negative or positive direction respectively. In addition, the wear ratio decreased with decreasing the corrosion current density. Consequently, it is suggested that we can qualitatively expect the wear ratio by only measuring the polarization characteristics. Therefore, before the examination of the wear ratio was actually carried out in the field, the evaluation of polarization property in the laboratory may give a available reference data for their developments.

Diffusion Coefficients of CdSe/CdS Quantum Rods in Water Measured Using Polarized Fluorescence Correlation Spectroscopy

  • Lee, Jaeran;Pack, Chan-Gi;Kim, Soo Yong;Kim, Sok Won
    • Journal of the Optical Society of Korea
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    • v.18 no.5
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    • pp.598-604
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    • 2014
  • A polarization fluorescence correlation spectroscopy system based on a confocal microscope was built to study the rotational and translational diffusion of CdSe/CdS quantum rods (Q-rods), with the same and different polarization states between the polarizer and the analyzer (i.e. the XXX and XYY states). The rotational diffusion amplitude showed the dependences on polarization of $0.75{\pm}0.05$ in the XXX state and $0.26{\pm}0.03$ in the XYY state, when the translational diffusion amplitude was 1. The diffusion coefficients of the Q-rods were found based on their translational and rotational diffusion times in the two polarization states, in solutions with viscosity ranging from 0.9 to 6.9 cP. The translational and rotational diffusion coefficients ranged from $1.5{\times}10^{-11}$ to $2.6{\times}10^{-12}m^2s^{-1}$ and from $2.9{\times}10^5$ to $5.6{\times}10^4s^{-1}$, respectively.

Effect of Seawater Temperature on the Cyclic Potentiodynamic Polarization Characteristics and Microscopic Analysis on Damage Behavior of Super Austenitic Stainless Steel (슈퍼오스테나이트 스테인리스강의 순환동전위 분극특성에 미치는 해수온도의 영향과 손상 거동에 관한 미시적 분석)

  • Hwang, Hyun-Kyu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.412-425
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    • 2021
  • Because austenitic stainless steel causes localized corrosion such as pitting and crevice corrosion in environments containing chlorine, corrosion resistance is improved by surface treatment or changes of the alloy element content. Accordingly, research using cyclic potentiodynamic polarization experiment to evaluate the properties of the passivation film of super austenitic stainless steel that improved corrosion resistance is being actively conducted. In this investigation, the electrochemical properties of austenitic stainless steel and super austenitic stainless steel were compared and analyzed through cyclic potentiodynamic polarization experiment with varying temperatures. Repassivation properties were not observed in austenitic stainless steels at all temperature conditions, but super austenitic stainless steels exhibited repassivation behaviors at all temperatures. This is expressed as α values using a relational formula comparing the localized corrosion rate and general corrosion rate. As the α values of UNS S31603 decreased with temperature, the tendency of general corrosion was expected to be higher, and the α value of UNS N08367 increased with increasing temperatures, so it is considered that the tendency of localized corrosion was dominant.

Concentration Polarization Phenomena in Ion-Exchange Membranes (이온교환막에서의 농도분극 현상)

  • 최재환;문승현
    • Membrane Journal
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    • v.12 no.3
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    • pp.143-150
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    • 2002
  • Electrodialysis(ED) is a reliable and effective process for the separation and concentration of ionic compounds. However, commercial uses of ED are often hindered by the cost of the stack that mainly resulted from the ion-exchange membrane cost. In order to minimize the membrane cost, it is desired to operate ED at the highest practicable current density. In an actual ED system the high current operation is limited by the concentration polarization phenomenon. This article illustrates the transport phenomena of ions through ion exchange membranes using current-voltage relations as a characterizing method. Also recent studies on electroconvection and water-spitting phenomena caused by concentration polarization were reviewed.

A Study on Electrode Array for Measurement of Induced Polarization of Rock Samples (암석 시료의 유도분극 측정을 위한 전극배열 비교)

  • Man-ho Han;Jung-hwan Lee;Keun-Soo Lee;Myeong-Jong Yi
    • Tunnel and Underground Space
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    • v.33 no.6
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    • pp.483-494
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    • 2023
  • Measurement of the physical properties of rocks or minerals is an important factor in determining the distribution of the underground medium as well as mineral resource investigations. Resistivity and induced polarization, which are widely used in Korea, are methods for measuring electrical properties, which are representative properties of obtaining subsurface information. In order to precisely analyze the exploration data obtained from various sites, it is important to accurately measure the material properties. Electrical properties of rock is measured using two-electrode or four-electrode method. Compared to the four-electrode method, the two-electrode method is generally used because it is very easy to contact the sample and the electrode, but there is a problem in that the impedance of the electrode and the sample is measured together. In this study, the time-domain the induced polarization effects were measured using the 2-electrode method and the 4-electrode method for artificial samples mixed with graphite and cement having induced polarization characteristics, and the results were compared. Although the 4-electrode method has difficulties in installing potential electrodes, it was confirmed that it is effective in measuring electrical properties because it can reduce the problem caused by the impedance of potential electrodes compared to the 2-electrode method.