• Title/Summary/Keyword: Polarization Direction

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AN ELECTROCHEMICAL STUDY BY USING A POTENTIOSTAT ON THE CORROSION OF AMALGAMS IN SALIVA (Potentiostat를 이용한 타액에서의 아말감부식에 대한 전기화학적 연구)

  • Son, Yoon-Hee;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.19 no.2
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    • pp.534-548
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    • 1994
  • The purpose of this study is to observe the corrosion characteristics of seven dental amalgams (CAULK FINE CUT, CAULK SPHERICAL, OPTALLOY II, DISPERSALLOY, HI VERALOY, TYTIN, VALIANT) through the anodic polarization curve obtained by using a potentiostat. After each amalgam alloy and Hg being triturated, the triturated mass was inserted into the cylindrical metal mold, and condensed by hydrolic pressure(160 kg/$cm^2$). Each specimen was removed from the metal mold. 24 hours after condensation, specimens were polished with the emery paper and stored at room temperature for 1 week. The anodic polarization curves were employed to compare the corrosion behaviours of the amalgam in 0.9% saline solution, Fusayama's artificial saliva, and stimulated parotid saliva at $37^{\circ}C$ with 3-electrode potentiostat. After the immersion of specimen in electrolyte for 1 hour, the potential scan was begun. The potential scan range was. -1700m V ~ + 400m V(vs. S. C. E) in the working electrode and the scan rate was 50m V /sec. The results were as follows, 1. The corrosion potential, the potential of anodic current peak, and transpassive potential in the stimulated parotid saliva shifted to more anodic direction than those in saline solution, and the current density in the stimulated parotid saliva was lower than that in saline solution. Those in Fusayama's artificial saliva was similar to those in stimulated parotid saliva. 2. The anodic polarization profiles in Fusayama's artificial saliva and stimulated parotid saliva indicated a region of slow slope current density, which is extending from the corrosion potential to the potential of anodic current peak, but that in 0.9% saline solution indicated no region of slow slope. 3. The corrosion potentials for CAULK FINE CUT, CAULK SPHERICAL, and OPT ALLOY II had the similarity in 0.9% saline solution, Fusayama's artificial saliva and stimulated parotid saliva, but those for high coper amalgam and VALIANT had no similarity. 4. The current density for TYTIN amalgam in stimulated parotid saliva was the lowest among the others. 5. As for current density, there was no significant difference between palladium enriched VALINAT and other high copper amalgams.

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A STUDY ON THE CORROSION BEHAVIOUR OF AMALGAMS BY USING OF POTENTIOSTATIC POLARIZATION METHOD (정전압 분극곡선법에 의한 아말감의 부식 거동에 관한 연구)

  • Shin, Dong-Hoon;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.12 no.1
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    • pp.39-49
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    • 1986
  • The purpose of this study was to observe characteristic properties through the polarization curves and SEM images from 4 different types of amalgam obtained by using the potentiostats (Princeton EG & G) & SEM (Jeol/35), and to investigate the degree of corrosion on the oxidation peak of the each phase of amalgam. After each amalgam alloy and Hg was triturated as the direction of the manufacturer by means of the mechanical amalgamator (Shofu Co.), the triturated mass was inserted into the cylindrical metal mold which was 12mm in diameter and 10.0mm in height and was condensed by using routine manner. The specimen was removed from the mold and stored at room temperature for about 24 hours. The standard surface preparation was routinely carried out. Anodic polarization measurement was employed to confirm the corrosion behaviour of the amalgams in a 0.9% saline solution (P.H: 6.8-7.0) at $37^{\circ}C$. The initial rest potential (corrosion potential) was determined after 30 minutes of immersion of specimen in electrolyte, and the potential scan was begun at the point of 100mV cathodic from the corrosion potential. The scan rate was 0.17mV/sec. in the study to observe the degree of corrosion of each phase. SEI and EPMA images on the determined oxidation peaks of each amalgam were observed. The results were as follows: 1. In the four anodic polarization curves, low copper amalgams have three oxidation peaks and high copper amalgams have two oxidation peaks, -270mV, +26mV and +179mV(SEC) in the low copper lathe cut, and -300mV, +39mV and +163mV(SEC) in the low copper spherical. -4mV and +154mV(SEC) in the Dispersalloy, and +17mV and +180mV(SEC) in the Tytin as high copper amalgams. 2. ${\gamma}_2$ phase in the low copper amalgam and ${\eta}$ phase in the high copper amalgam were the most corrodible phases and Ag-Cu eutectic in high copper amalgam was the most slowly corroded phase. 3. Low copper amalgam was more susceptible in corrosion than high copper amalgam.

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Secure sharing method for a secret binary image and its reconstruction system

  • Lee, Sang-Su;Han, Jong-Wook
    • 제어로봇시스템학회:학술대회논문집
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    • 2003.10a
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    • pp.1240-1243
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    • 2003
  • In this paper, an encryption method to share a secret binary image is proposed. It divides the image to be encrypted into an arbitrary number of images and encrypts them using XOR process with different binary random images which was prepared by the means of the XOR process, too. Each encrypted slice image can be distributed to the authenticated ones. However, we transfer the encrypted images to the binary phase masks to strengthen the security power, that means phase masks can not be copied with general light-intensity sensitive tools such as CCDs or cameras. For decryption, we used the Mach-Zehnder interferometer in which linearly polarized two light beams in orthogonal direction, respectively. The experimental result proved the efficiency of the proposed method.

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Crevice Corrosion Resistance of Stainless Steels in Natural Sea Water with different Post Welding Treatment

  • Lee, Y.H.;Kim, Y.H.;Kim, H.
    • Corrosion Science and Technology
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    • v.2 no.5
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    • pp.219-224
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    • 2003
  • Crevice corrosion of stainless steels in natural seawater was investigated for several post weld treatments; as-annealed, as-welded, pickled, and ground. The results confirmed the effect of the biofilm on the cathodic reaction leading to an ennoblement of the rest potential. The degree of ennoblement of corrosion potential depends on the surface finish. As-annealed and pickled samples show stable corrosion potential approaching to 200 ~ 300 mV (SCE) while as-welded and ground samples show the fluctuating corrosion potential. This points to a situation where there are conflicting effects determining the trend in free corrosion potential. Crevice corrosion initiation will tend to pull the free corrosion potential in the active direction, whereas the presence of biofilm will tend to ennoble corrosion potential. There was no visible attack on UNS S31803, S32550, and 2205W. Therefore, those stainless steel grades appeared to be resistant to crevice corrosion in natural seawater on condition of weld metal.

Dimerization Behavior of Cinnamate Group attached to Flexible Polymer Backbone and Its Application to Liquid Crystal Alignment

  • Sung, Shi-Joon;Cho, Ki-Yun;Hah, Hyun-Dae;Kim, Won-Sun;Jeong, Yong-Cheol;Park, Jung-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1163-1166
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    • 2004
  • Cinnamate group is well-known for the dimerization reaction by ultra-violet irradiation and cinnamate polymers are studied for photo-alignment materials. The cinnamate groups of flexible polymer are found to produce LC alignment parallel to polarization direction of ultra-violet light, which is contrary to the LC orientation on conventional cinnamate polymers. The un-reacted cinnamate groups in the flexible polymer are also found to participate in cycloadducts formation by additional thermal reaction that preserves the orientation of cycloadducts, leading to the enhancement of thermal stability of LC alignment.

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Growth and Characterization of ZnO Thin Films on R-plane Sapphire Substrates by Plasma Assisted Molecular Beam Epitaxy (R-면 사파이어 기판 위에 플라즈마 분자선 에피탁시법을 이용한 산화아연 박막의 성장 및 특성평가)

  • Han Seok-Kyu;Hong Soon-Ku;Lee Jae-Wook;Lee Jeong-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.10
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    • pp.923-929
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    • 2006
  • Single crystalline ZnO films were successfully grown on R-plane sapphire substrates by plasma-assisted molecular beam epitaxy. Epitaxial relationship between the ZnO film and the R-plane sapphire was determined to be $[-1101]Al_2O_3{\parallel}[0001]ZnO,\;[11-20]Al_2O_2{\parallel}[-1100]ZnO$ based on the in-situ reflection high-energy electron diffraction analysis and confirmed again by high-resolution X-ray diffraction measurements. Grown (11-20) ZnO films surface showed mound-like morphology along the <0001>ZnO direction and the RMS roughness was about 4 nm for $2{\mu}m{\times}2{\mu}m$ area.

Photoinduced Anisotropy and Reorientation of Anisotropic Axis in Amorphous $As_2S_3$ Thin Film (비정질 $As_2S_3$ 박막의 광유도 비등방성과 비등방축의 가역성)

  • 김향균
    • Proceedings of the Optical Society of Korea Conference
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    • 1990.02a
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    • pp.162-166
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    • 1990
  • Photoinduced anisotropy (PIA) in amorphous As2S3 (a-As2S3 ) thin film, deposited by vacuum evaporation, is investigated. PIA is induced by linearly polarized Ar+ laser beam (λ=514.5nm) and probed by weak Ar+ laser (λ=514.5nm) and He-Ne laser (λ=632.8nm) beam through the crossed analyzer. Keeping pump beam intensity constantly, rotation of pump beam polarization direction induces reorientation phenomina of anisotropic axis. Introducing directional factor into simplified 3-level system, which is used to analyze photodarkening phenomina, an analytical expression of PIA is derived. Temporal behavior of PIAand its reorientation phenomina are investigated andcompared with theory. In the experiment pump beam intensity is 100mW/$\textrm{cm}^2$ and thickness of a-As2S3 thin film is 3${\mu}{\textrm}{m}$. In those condition, time constant of photoinduced anisotropy obtained by method of least square curve fitting is 4.0$\times$10-2sec-1. The time constant of PIA we obtained is larger than that of photodarkening, 2.8$\times$10-2sec-1.

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Directional Radiation of Surface Plasmon Polaritons at Visible Wavelengths through a Nanohole Dimer Optical Antenna Milled in a Gold Film

  • Janipour, Mohsen;Hodjat-Kashani, Farrokh
    • Journal of the Optical Society of Korea
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    • v.18 no.6
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    • pp.799-808
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    • 2014
  • The mechanism of optical interaction of two nanoholes, milled in an opaque gold film, by means of surface plasmon polariton (SPP) propagation is investigated. The interaction depends on the polarization direction of the incident light when the nanohole pair is illuminated through uniform single antenna excitations. It is shown that by illuminating one of the nanoholes, under single antenna excitation, the other nanohole can be excited indirectly via propagated SPPs from the excited nanohole. In addition, it is found that the spectrum of electromagnetic power above the surface of the metallic film at an arbitrary point along the axis of the nanohole pair presents two resonant peaks. These peaks are due to the optical interaction between nanoholes, where the short- and long-wavelength peaks can be assigned to in-phase and antiphase interactions of magnetic dipoles relative to each nanohole, respectively. The magnetic coupled dipole approximation (MCDA) method confirms the simulation results.

Optical Compensation in a Vertical Alignment Liquid Crystal Cell for Elimination of the Off-Axis Light Leakage

  • Ji, Seung-Hoon;Choi, Jung-Min;Lee, Gi-Dong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1580-1583
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    • 2008
  • We propose an optical configuration for a vertical alignment (VA) liquid crystal (LC) cell to eliminate the off-axis light leakage in the dark state. The proposed compensation configuration consists of a positive A-film, a positive C-film and a negative C-film. The optical design is performed on a Poincar$\acute{e}$ sphere. This configuration has a better tolerance to the wavelength dispersion, as the polarization trace could self-compensate it. From calculations, we show that the proposed VA LC cell can improve the viewing angle characteristics by compensating for the light leakage in the diagonal direction.

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A Study on the Inspection of Orthotropy Composite Laminate plates Using Ultrasonics (직교이방성 복합적층판의 초음파 탐사에 관한 연구)

  • 나승우;임광희;양인영
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.11a
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    • pp.583-586
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    • 2000
  • This work ethibits how susceptive the shear ultrasonic waves are to a little misoriented plies according to the angle variation of shear ultrasoic waves $0^\circ$ , $45^\circ$ and $90^\circ$. Also, it is shown that shear waves, particularly the transmission mode with the transmitter and receiver perpendicular to each other, have high sensitivity for detecting anomalies in fiber orientation and ply layup sequence that may occur in the manufacturing of composite laminates. Experimental results are agreed with modeling solutions which were based on decomposition of shear wave polarization vector as it propagates through the composite laminates. This wave appeared considerably to be sensitive to CFRP composites to the thickness direction along in-plane fibers.

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