• Title/Summary/Keyword: Polar low

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Studies in Browning Reaction in Dried Fish Lipid Oxidative Browning in Dried Conger eel and Properties of Browning Products (수산건제품의 갈변에 관한 연구 붕장어육 및 유의 산화, 갈변 물질의 성상)

  • SUH Jae-Soo;LEE Kang-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.27 no.5
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    • pp.454-461
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    • 1994
  • This studies was carried out in order to investigate the browning reaction of lipid originated compound with nitrogenous compound in dried conger eel. The major fatty acids were $C_{16:0},\;C_{16:1},\;C_{18:1},\;C_{20:5}\;and\;C_{22:6}$. The nonpolar lipid contained the highest percentage of $C_{16:0}$, while the polar lipid contained the highest percentage of $C_{22:6}$. The browning reaction there was a rapidly developed with the beginning of the decline in carbonyl value and remarkable decrease in polyunsaturated fatty acids such as $C_{20:5},\;C_{22:5},\;C_{22:6}$ compared with the other fatty acid, in the water soluble fraction of the browning product obtained from tile fish was detected some antioxidation activity but in the lipid soluble fraction which covers most of the browning reactions in the fish meat antioxidation activity was not detected. In the test of conger eel oil, the phosphatidylcholine was largest in quantity and browning products provided in this experiment showed very low reducing activity.

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The Analysis of Interference between IMT-2000 and GMPCS (IMT-2000 과 GMPCS간의 간섭 분석)

  • 배태경;차병규;최재훈;조영란
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.10 no.3
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    • pp.401-411
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    • 1999
  • IMT-2000 will provide worldwide mobile telecommunication services with the extended coverage areas such as polar regions and mountainous district. GMPCS also provides global telephony and paging services via satellite network at the altitude of 500~12,000 km. "Big LEO" which is one of the GMPCS systems using frequency above 1 GHz and IMT-2000 will share the frequency range of 1 to 3 GHz. Therefore, there exists possible interference between the two systems which can cause the performance degradation of both systems. In this paper, the radio-propagation modeling and interference analysis methods are presented and these methods are used to analyse the effect of the interference between IMT-2000 and GMPCS on system performance.rformance.

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Synthesis and Thermal Properties of Wholly Aromatic Poly(benzoxazole)s

  • Han, So Hee;Lee, Eung Jae;Choi, Jae Kon
    • Elastomers and Composites
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    • v.53 no.3
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    • pp.141-149
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    • 2018
  • A series of aromatic poly(o-hydroxyamide)s (PHAs) were synthesized by the direct polycondensation reaction of 4,4′-(2,3-quinoxalinedioxy) dibenzoic acid and/or 4,4′-(2,3-pyridinedioxy) dibenzoic acid with bis(o-aminophenol) including 2,2-bis-(amino-4-hydroxyphenyl)hexafluoropropane. The PHAs exhibited inherent viscosities in the range of 0.17-0.35 dL/g at $35^{\circ}C$ in a DMAc solution. These polymers showed low inherent viscosities and yielded brittle films. All the PHAs showed excellent solubility in aprotic solvents such as DMAc, DMSO, NMP, and DMF at room temperature and in less polar solvents such as pyridine and THF. However, all the PBOs were only partially soluble in $H_2SO_4$. The PBOs exhibited 10% weight loss at temperatures in the range of $537-551^{\circ}C$. The maximum weight loss temperature increased with an increase in the content of the quinoxaline-containing monomer. The residue of the PBOs showed a weight loss of 45.8-56.7% at $900^{\circ}C$ in a nitrogen atmosphere.

Dependence of Energetic Electron Precipitation on the Geomagnetic Index Kp and Electron Energy

  • Park, Mi-Young;Lee, Dae-Young;Shin, Dae-Kyu;Cho, Jung-Hee;Lee, Eun-Hee
    • Journal of Astronomy and Space Sciences
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    • v.30 no.4
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    • pp.247-253
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    • 2013
  • It has long been known that the magnetospheric particles can precipitate into the atmosphere of the Earth. In this paper we examine such precipitation of energetic electrons using the data obtained from low-altitude polar orbiting satellite observations. We analyze the precipitating electron flux data for many periods selected from a total of 84 storm events identified for 2001-2012. The analysis includes the dependence of precipitation on the Kp index and the electron energy, for which we use three energies E1 > 30 keV, E2 > 100 keV, E3 > 300 keV. We find that the precipitation is best correlated with Kp after a time delay of < 3 hours. Most importantly, the correlation with Kp is notably tighter for lower energy than for higher energy in the sense that the lower energy precipitation flux increases more rapidly with Kp than does the higher energy precipitation flux. Based on this we suggest that the Kp index reflects excitation of a wave that is responsible for scattering of preferably lower energy electrons. The role of waves of other types should become increasingly important for higher energy, for which we suggest to rely on other indicators than Kp if one can identify such an indicator.

Development of a Supported Emulsion Liquid Membrane System for Propionic Acid Separation in a Microgravity Environment

  • Li, Jin;Hu, Shih-Yao B.;Wiencek, John M.
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.6
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    • pp.426-432
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    • 2001
  • Perstractive fermentation is a good way to increase the productivity of bioreactors. Us-ing Propionibacteria as the model system, the feasibility of using supported emulsion liquid mem-brane(SELM) fro perstractive fermentation is assessed in this study. Five industrial solvents were considered as the solvent for perparing the SELM. The more polar a solvent, is the higher the par-tition coefficeint However, toxicity of a solvent also increases with its polarity. CO-1055(indus-trial decanol/octanol blend)has the highest partition coefficient toward propionic acid among the solvents that has no molecular toxicity toward Propionibacteria, A preliminary extraction study was conducted using tetradecane as solvent in a hydrophobic hollow fiber contactor. The results confirmed that SELM eliminates the equilibrium limitation of conventional liquid-liquid extrac-tion and allows the use of a non-toxic solvent with low partition coefficient.

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Morphology and Surface Magnetism of Ultrathin Fe Films on Pd(111)

  • Park, Jae-Hoon;Kim, Wookje;Kim, Wondong;Kim, Jae-Young;Hoon Koh;S.J. Oh
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.141-141
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    • 2000
  • In situ surface magneto-optic Kerr effect(SMOKE), X-ray photoelectron spectroscopy(XPS) and low energy electron diffraction(LEED) were used to study magnetic and structural properties of ultrathin Fe films grown on the Pd(111) surface. The SMOKE measurement showed strong enhancement of ferromagnetism after proper annealing process. Simultaneous changes in morphology was checked by LEED and XPS. After room temperature Fe deposition. longitudinal magnetization appeared above a critical thickness between 2.0 and 2.5 monolayers. When annealed at 450K, 2.0 monolayer Fe film exhibited boty longitudinal and polar magnetizations while 3.0 and 5.5 monolayer films showed little changes. After annealing at 600K, both magnetizations were totally destroyed in 2.0 monolayer film, but longitudinal magnetization was enhanced in 3.0 monolayer film. In the case of 5.5 monolayer film, it was only after 660K annealing that the enhancement of the longitudinal magnetization was observed. It was concluded that the surface flatness and the amount of intermixing were critical in the development of surface magnetism of this system.

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The Influence of Mixed Solvents Volatility on Charge State Distribution of Peptides During Positive Electrospray Ionization Mass Spectrometry

  • Nielsen, Birthe V.;Abaye, Daniel A.;Nguyen, Minh T.L.
    • Mass Spectrometry Letters
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    • v.8 no.2
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    • pp.29-33
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    • 2017
  • Understanding the mechanisms that control and concentrate the observed electrospray ionisation (ESI) response from peptides is important. Controlling these mechanisms can improve signal-to-noise ratio in the mass spectrum, and enhances the generation of intact ions, and thus, improves the detection of peptides when analysing mixtures. The effects of different mixtures of aqueous: organic solvents (25, 50, 75%; v/v): formic acid solution (at pH 3.26) compositions on the ESI response and charge-state distribution (CSD) during mass spectrometry (MS) were determined in a group of biologically active peptides (molecular wt range 1.3 - 3.3 kDa). The ESI response is dependent on type of organic solvent in the mobile phase mixture and therefore, solvent choice affects optimal ion intensities. As expected, intact peptide ions gave a more intense ESI signal in polar protic solvent mixtures than in the low polarity solvent. However, for four out of the five analysed peptides, neither the ESI response nor the CSD were affected by the volatility of the solvent mixture. Therefore, in solvent mixtures, as the composition changes during the evaporation processes, the $pK_b$ of the amino acid composition is a better predictor of multiple charging of the peptides.

Tertiary Structure of Ganglioside $G_{A1}$ as Determined by NMR Spectroscopy

  • 이경익;이상원;전길자;김양미
    • Bulletin of the Korean Chemical Society
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    • v.19 no.5
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    • pp.569-575
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    • 1998
  • Investigation of the structure of the gangliosides has proven to be very important in the understanding of their biological roles. We have determined the tertiary structure of asialoganglioside GM1 $(GA_1)$ using NMR spectroscopy and distance geometry calculations. All of the structures are very similar except the glycosidic torsion angles in the ring IV and ring III linkages. There are two low-energy structures for GA1, G1 and G2. G1 differs from G2 only in the IV-III glycosidic linkages and the orientation of acetamido group in ring III. There is a stable intramolecular hydrogen bond between the third hydroxyl group in ring I and the ring oxygen atom in ring II. Also, there may be a weak hydrogen bond between the second hydroxyl group in ring IV and the acetamido group in ring III. Small coupling constants of $^3J_{IH3,IOH3}\; and\; ^3J_{IVH2,IVOH2}$ support this result. Overall structural features of $(GA_1)$ are very similar to those of $(GM_1)$. It implicates that specificities of the sugar moieties in GM1 are caused not by their tertiary foldings, but mainly by the electrostatic interactions between the polar sialic acid and its receptors. Since it is evident that $(GA_1)$ is more hydrophobic than $(GA_1)$, a receptor with a hydrophobic binding site can recognize the $(GA_1)$ better than $(GA_1)$. Studies on the conformational properties of $(GA_1)$ may lead to a better understanding of the molecular basis of its functions.

A Study on the Change of Heavy Snow Strength by SST in Influence of Continental Polar Air Mass

  • Park, Geon-Young;Ryu, Chan-Su
    • Journal of Integrative Natural Science
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    • v.7 no.1
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    • pp.39-44
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    • 2014
  • The results of the synoptic meteorological analysis showed that when the cold and dry continental high pressure was extended, heavy snow occurred at dawn when the upper atmosphere cooled. In particular, when the continental high pressure was extended and the upper pressure trough passed through, heavy snow occurred due to the convergence region formed in the west coast area, sometimes in the inland of the Honam area. In addition, it was verified that the changes in the humidity coefficients in the upper and lower layers are important data for the determination of the probability, start/end and intensity of heavy snow. However, when the area was influenced by the middle-latitude low pressure, the heavy snow was influenced by the wind in the lower layer (925 hPa and 850 hPa), the equivalent potential temperature, the convergence field, the moisture convergence and the topography. In Case 2010 (30 December 2010), OSTIA had the best numerical simulation with diverse atmospheric conditions, and the maximum difference in the numerically simulated snowfall between NCEP/NCAR SST and OSTIA was 20 cm. Although there was a regional difference in the snowfall according to the difference in the SST, OSTIA and RTG SST numerical tests, it was not as significant as in the previous results. A higher SST led to the numerical simulation of larger snowfall, and the difference was greatest near Buan in the west coast area.

Phytoplankton Community and Surrounding Water Conditions in the Youngsan River Estuary: Weekly Variation in the Saltwater Zone (영산강 하구의 식물플랑크톤 군집 및 수 환경: 해수역의 주별 변동)

  • Sin, Yongsik;Yu, Haengsun
    • Ocean and Polar Research
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    • v.40 no.4
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    • pp.191-202
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    • 2018
  • In this study we conducted a weekly monitoring exercise at a fixed station in the saltwater zone during the dry season (Jan-Mar, 2013) and wet season (Jun-Aug, 2013) to understand the fluctuations in phytoplankton communities and environmental factors in the Youngsan River estuary altered by a dike constructed in the coastal area. Phytoplankton communities displayed seasonality; diatoms were dominant during the dry season whereas dinoflagellates were dominant during the wet season. T-test analysis showed that water temperature was significantly different between the seasons whereas freshwater discharge from the dike was not significantly different. This suggests that seasonal variations of phytoplankton are more likely affected by water temperature than freshwater discharge. However, a short-term fluctuation was also observed in response to freshwater discharge; freshwater species appeared during or after the discharge in the dry and wet seasons and blooms of harmful species developed after the discharge. Phytoplankton communities may be affected by changes in physical factors such as turbidity and salinity and nutrient supply resulting from freshwater discharge. Especially, the nutrient supply may directly contribute to the harmful algal blooms (HABs) composed of dinoflagellates which can adapt to low salinity after freshwater discharge.