• Title/Summary/Keyword: Polar low

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Relation between the Dipole Orientation and the Degree of Polymerization in Low Viscous Silicone Oils (저점도 실리콘유의 쌍극자 배향과 중합도의 관계)

  • Cho, Kyung-Soon;Kim, Kyung-Hwan;Kim, Wang-Kon;Hong, Jin-Woong
    • Proceedings of the KIEE Conference
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    • 1993.11a
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    • pp.234-236
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    • 1993
  • Dielectric properties of low viscous silicone oils have been investigated as a function of frequency and The increase of polymerization degree was attributed to presence of Si-O-Si bonds and their increased dissociation factor. The application of the Clausius-Mosotti equation on the low viscous silicone oils, it has been previously assumed that the oils were dilute solutions of polar molecules. In the silicone oil the Si-o and O-Si bonds give dipole polarization. Simple relations have been found which dipole moment and activation energy as a function of number of Si atoms in the low viscous silicone oils.

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Remarkable impact of steam temperature on ginsenosides transformation from fresh ginseng to red ginseng

  • Xu, Xin-Fang;Gao, Yan;Xu, Shu-Ya;Liu, Huan;Xue, Xue;Zhang, Ying;Zhang, Hui;Liu, Meng-Nan;Xiong, Hui;Lin, Rui-Chao;Li, Xiang-Ri
    • Journal of Ginseng Research
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    • v.42 no.3
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    • pp.277-287
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    • 2018
  • Background: Temperature is an essential condition in red ginseng processing. The pharmacological activities of red ginseng under different steam temperatures are significantly different. Methods: In this study, an ultrahigh-performance liquid chromatography quadrupole time-of-flight tandem mass spectrometry was developed to distinguish the red ginseng products that were steamed at high and low temperatures. Multivariate statistical analyses such as principal component analysis and supervised orthogonal partial least squared discrimination analysis were used to determine the influential components of the different samples. Results: The results showed that different steamed red ginseng samples can be identified, and the characteristic components were 20-gluco-ginsenoside Rf, ginsenoside Re, ginsenoside Rg1, and malonyl-ginsenoside Rb1 in red ginseng steamed at low temperature. Meanwhile, the characteristic components in red ginseng steamed at high temperature were 20R-ginsenoside Rs3 and ginsenoside Rs4. Polar ginsenosides were abundant in red ginseng steamed at low temperature, whereas higher levels of less polar ginsenosides were detected in red ginseng steamed at high temperature. Conclusion: This study makes the first time that differences between red ginseng steamed under different temperatures and their ginsenosides transformation have been observed systematically at the chemistry level. The results suggested that the identified chemical markers can be used to illustrate the transformation of ginsenosides in red ginseng processing.

Synthesis and Application of Sorbic Acid Grafted Hydrogenated Dicyclopentadiene Hydrocarbon Resin (소르빅산 변성 수소첨가 DCPD계 석유수지의 합성 및 응용)

  • Kong, Won Suk;Park, Jun Hyo;Yoon, Ho Gyu;Lee, Jae Wook
    • Journal of Adhesion and Interface
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    • v.16 no.1
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    • pp.29-34
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    • 2015
  • Hydrocarbon resins, which are defined as low molecular weight, amorphous, and thermoplastic polymers, are widely used as tackifier for various types of adhesives, as processing aids in rubber compounds, and as modifiers for plastics polymers such as isotactic polypropylene. Typically, hydrocarbon resins are non-polar, and thus highly compatible with non-polar rubbers and polymer. However, they are poorly compatible with polar system, such as acrylic copolymer, polyurethanes, and polyamides. Moreover, recently the raw materials of hydrocarbon resin from naphtha cracking had been decreased because of light feed cracking such as gas cracking. To overcome this problem, in this study, novel hydrocarbon resins were designed to have a highly polar chemical structure which material is sustainable. And, it was successfully synthesized by Diels-Alder reaction of dicyclopentadiene monomer and sorbic acid from blueberry as renewable resources. Acrylic resins were formulated with various tackifiers solution including sorbic acid grafted hydrogenated dicyclopentadiene hydrocarbon resins in acrylic adhesive and rolling ball tack, loop tack, $180^{\circ}$ peel adhesion strength, and shear adhesion strength were measured. The properties depend on the softening point and polar content of tackifiers.

Sea Ice Drift Tracking from SAR Images and GPS Tracker (SAR 영상과 GPS 추적기를 이용한 여름철 해빙 이동 궤적 추적)

  • Jeong-Won Park;Hyun-Cheol Kim;Minji Seo;Ji-Eun Park;Jinku Park
    • Korean Journal of Remote Sensing
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    • v.39 no.3
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    • pp.257-268
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    • 2023
  • Sea ice plays an important role in Earth's climate by regulating the amount of solar energy absorbed and controlling the exchange of heat and material across the air-sea interface. Its growth, drift, and melting are monitored on a regular basis by satellite observations. However, low-resolution products with passive microwave radiometer have reduced accuracy during summer to autumn when the ice surface changes rapidly. Synthetic aperture radar (SAR) observations are emerging as a powerful complementary, but previous researches have mainly focused on winter ice. In this study, sea ice drift tracking was evaluated and analyzed using SAR images and tracker with global positioning system (GPS) during late summer-early autumn period when ice surface condition changes a lot. The results showed that observational uncertainty increases compared to winter period, however, the correlation coefficient with GPS measurements was excellent at 0.98, and the performance of the ice tracking algorithm was proportional to the sea ice concentration with a correlation coefficient of 0.59 for ice concentrations above 50%.

Ultrasonic Effect on the Extraction of Ash-free coal from Low Rank Coal (저등급 석탄으로부터 초청정석탄의 추출과 초음파의 영향)

  • Lee, Sihyun;Kim, Sangdo;Jeong, Soonkwan;Rhim, Youngjun;Kim, Daehun;Woo, Kwangjae
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.555-560
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    • 2008
  • Extraction was performed to prepare ash-free coal from low rank coal under the temperature of $200-430^{\circ}C$ and initial pressure of 0.1MPa. Three kinds of coal samples with different rank were used and N-methyl-2-pyrrolidinone(NMP, polar), 1-methyl naphthalene(I-MN, non-polar), Light Cycle Oil(LCO, non-polar) were used as solvents. Results showed that higher extraction yield could be obtained with NMP than with 1-MN and LCO, but the ash concentration shows minimun in the case of 1-MN. Three operation modes were compared, that is, idle, agitation and ultrasonic extraction mode. From the results, it was found that the extraction yield and ash concentration were 70.09% and 1.03% under the agitation mode, 80.7% and 0.76% under the ultrasonic operation mode respectively in the case of NMP used at the temperature of $350^{\circ}C$. Similar results were obtained with 1-MN. Effect of ultrasonic on the extraction was estimated as 15-20% increase in the yields and 26% reduction in the ash concentration.

Surface Modification of Polypropylene by Low Temperature Plasma Polymerization( I ) ―hydrophilicity― (저온 Plasma 중합에 의한 Polypropylene의 표면 개질 (I) -친수성-)

  • Chang, Du Sang;Cho, In Sul
    • Textile Coloration and Finishing
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    • v.8 no.2
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    • pp.8-15
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    • 1996
  • This research was attempted to improve the hydrophilicity of polypropylene(PP) by using low temperature plasma polymerization of acrylic acid(AA) as a starting material. The results of the present study were as follows: The PP films deposited with AA plasma polymer showed excellent hydrophilicity, that the polar parts were about 20 dyn/cm, and also that the surface tensions were about 55 dyn/cm, whereas the disperse parts were not changed. Work of adhesions of the PP films deposited with AA plasma polymer were above 100 erg/ $cm^{2}$. AA plasma polymer formed by low temperature plasma polymerization of acrylic acid(AA) was even thin layer which contained many -OH groups.

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Radio iodination (II) Radio iodination of various aromatic derivatives in organic solvent at low temperature (放射性 요오드化 反應 (第 II 報) 有機容媒 中에서의 各種 芳香誘導體의 低溫 요오드化 反應)

  • Kim, You-Sun;Kim, Chong-Doo
    • Journal of the Korean Chemical Society
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    • v.12 no.1
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    • pp.35-38
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    • 1968
  • Radio iodination of various aromatic derivatives (aniline, toluene, iodobenzene, acetanilide, benzene, benzoic acid) were achieved at low temperature by a chloroamine-T procedures in presence of polar solvent(dioxane). Organic base (piperidine) was used as the catalyst. Iodine replacement reaction had occured on the aromatic or alicyclic ring by this reaction, and the kind and ratio of iodinated products were proved to be different from those of usual iodide reaction in organic solvent at low temperature. The reactivity of various aromatic or alicyclic compounds towards the present iodination system was evaluated and the scope and limitation of the present procedures in the preparation of radio pharmaceuticals were discussed.

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Optimization of Physical Factor for amylase Production by Arthrobacter sp. by Response Surface Methodology (반응표면분석법을 통한 Arthrobacter sp.의 amylase 생산 최적화)

  • Kim, Hyun-do;Im, Young-kum;Choi, Jong-il;Han, Se Jong
    • Korean Chemical Engineering Research
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    • v.54 no.1
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    • pp.140-144
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    • 2016
  • In this study, the physical factors for amylase production by Arthrobacter sp. were optimized using response surface methodology(RSM). Antarctic microorganism Arthrobacter sp. PAMC 27388 was obtained from the Polar and Alpine Microbial Collection(PAMC) at the Korea Polar Research Institute. This microorganism was confirmed for the excretion of amylase with Lugol's solution. The amylase activity was after flask culture was as low as 1.66 mU/L before optimization. The physical factors including the inoculum volume, the initial culture pH, and the medium volume were chosen to be optimized for the enhanced amylase production. The calculated results using RSM indicate that the optimal physical factors were 2.49 mL inoculum volume, 6.85 pH and 42.87 mL medium volume with a predicted amylase production of 2.84 mU/L. The experimentally obtained amylase activity was 2.50 mU/L, which was a 150% increase compared to the level before optimization.

Paleomagnetism of Three Seamounts Northwest of the Marshall Islands from Magnetic Inversion (자기이상 역산에 의한 마샬제도 북서쪽 세 해저산의 고지자기 해석)

  • Lee, Tae-Gook;Moon, Jai-Woon;Ko, Young-Tak;Jung, Mee-Sook;Kim, Hyun-Sub;Lee, Kie-Hwa
    • Ocean and Polar Research
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    • v.26 no.4
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    • pp.559-565
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    • 2004
  • Total magnetic field measurements were performed to study paleomagnetism of three seamounts (OSM7, OSM8-1, and OSM8-2) to the northwest of the Marshall Islands in the western Pacific. The study area is located at the Ogasawara Fracture Zone which is a boundary between the Pigafetta and East Mariana basins. The magnetic parameters and paleopoles of three seamounts were derived from inversion of the measured magnetic field. The goodness-of-fit ratio of OSM7 is too low to be included to the estimation of parameters. The complex magnetic anomalies of center, scarcity of flank rift zones and steep slope at OSM7 suggest that the multiple intrusions of magma converge into the center of volcanic edifice. Inclination calculated from the magnetic anomalies of OSM8-1 and OSM8-2 is $-41.2^{\circ}$, and the paleolatitude calculated from the inclination is $23.6^{\circ}S$. The corresponding paleopoles for OSM8-1 and OSM8-2 are $(24^{\circ}42'W,\;48^{\circ}54'N)\;and\;(18^{\circ}18'W,\;48^{\circ}30'N)$, respectively. In comparison with the apparent polar wander path (APWP) of the Pacific plate, the paleopoles are close to 129-Ma pole. The paleopoles and paleolatitudes of OSM8-1 and OSM8-2 suggest that they were formed at similar time and location. The seamounts have drifted northward about $41^{\circ}$ from the paleolatitude to present latitude of seamounts.

Phylogenetic Analysis of Culturable Arctic Bacteria

  • Lee, Yoo-Kyung;Kim, Hyo-Won;Cho, Kyeung-Hee;Kang, Sung-Ho;Lee, Hong-Kum;Kim, Yea-Dong
    • Ocean and Polar Research
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    • v.26 no.1
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    • pp.51-58
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    • 2004
  • We isolated and identified culturable Arctic bacteria that had inhabited soils around the Korean Arctic Research Station Dasan located at Ny-Alsund, Svalbard, Norway $(79^{\circ}N,\;12^{\circ}E)$. The collected soils were diluted in distilled water; the diluted soil-water was spread on 3M petri-films at Dasan Station. The petri-films were transported to the laboratory at KORDI, and cultured at $4^{\circ}C$. Colonies grown on the petri-films were subsequently cultured on nutrient agar plates at $4^{\circ}C$ every 7 days. The pure colonies were inoculated into nutrient liquid media, genomic DNA was extracted, and phylogenetic analysis was performed on the basis of 165 rDNA sequences. A total of 227 strains of bacteria were isolated. Among them, 16S rDNA sequences of 185 strains were identical with those of known strains isolated in this study, and 42 strains were finally identified. Phylogenetic analysis using 16S rDNA indicated that the 30 strains belonged to Pseudomonas, 7 strains to Arthrobacter, two strains to Flavobacterium, and the remaining to Achromobacter, Pedobacter, and Psychrobacter. Among the 42 strains, 14 bacteria produced protease: they were 6 strains of Pseudomonax, 4 strains of Arthrobater, an Achromobacter strain, 2 strains of Flavobacterium, and a Pedohacter strain. We expect these Arctic bacteria can be used for screening to develop new industrial enzymes that are active at low temperatures.