• Title/Summary/Keyword: Point electrode method

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Performance Change according to the Catalyst Intrusion Rate in the MEA for the PEM Water Electrolysis (고분자전해질 수전해용 MEA의 촉매침투도에 따른 성능변화)

  • Kim, Hong-Youl;Lee, Ji-Jung;Lee, Jae-Young;Lee, Hong-Ki
    • New & Renewable Energy
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    • v.5 no.4
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    • pp.75-78
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    • 2009
  • The performances of proton exchange membrane (PEM) water electrolysis depend on many factors such as materials, geometries, fabrication methods, operating conditions, and so forth. The fabrication method is concerned, membrane electrode assemblies (MEA) are a most important part to show different performances by different fabrication methods. The performance change of PEM water electrolysis was experimentally measured according to the fabrication differences of the anode electrodes. One point of view is the catalyst intrusion rate to the anode gas diffusion layer (GDL), and the other point of view is the catalyst loading distribution in depth of the anode GDL. Results show that the performances of MEA with deep intrusion of the catalysts are better in the range of low current densities but worse at higher current densities. The catalyst loading distribution does not affect significantly to the performance of PEM water electrolyser.

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Development of Tight-Fitting Garments with a Portable ECG Monitor to Measure Vital Signs (휴대용 심전도 기기와 직물형 전극을 이용한 생체정보 측정용 밀착 의복 개발)

  • Jeong, Yeon-Hee; Kim, Seung-Hwan;Yang, Young-Mo
    • Journal of the Korean Society of Clothing and Textiles
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    • v.34 no.1
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    • pp.112-125
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    • 2010
  • A Holter monitor is used for ECG monitoring of ambulatory daily life in hospital. However, the use of this apparatus causes skin allergies and discomfort in patients because of the attachment gel and tapes used to attach disposable electrodes to the skin. In this study, the development of tight-fitting clothing connected to a portable Holter monitor was proposed. In addition, the use of conductive fabrics as electrodes was proposed; this will enable the use of garments in u-health care for measuring ECG signals. The male subjects were university students in the ages of 20 to 24. Subjective wear sensations of the experimental garments were rated using seven Likert scales. A Likert type scale was used for the evaluation and a 7 point score indicates that it provided the best fit as a tight-fitting upper clothing. Clothing pressure was measured using an air-pack-type pressure sensor (model AMI 3037-2) at 4 locations (the conductive fabric electrode) As results, a male basic sloper for upper clothing was developed and that pattern was manipulated to the tight fit pattern by considering the reduction rate of the percentage stretch in the fabric. The developed tight-fitting garment was superior in terms of subjective sensation and 6t. The mean pressure of the garment with reduction rates of 40% in width and of 50% in length was 8.45gf/$cm^2$. A conductive fabric electrode was developed by considering the sewing method and the developed electrode was detected well. The ECG data were recorded for 13 hr 19 min 44 sec and the artifacts in the ECG signals were recorded for 9 hr 3 min 46 sec (total time: 22 hr 23 min 23 sec). The artifacts data were obtained during heavy activities.

Electrochemical Properties of Organic Ultra Thin Films of Fatty Acid and Phospholipid Mixture (지방산과 인지질 혼합 유가초박막의 전기화학적 특성)

  • Park, Keun-Ho;Choi, Sung-Hyun;Son, Tae-Churl;Song, Ju-Yeong
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.2
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    • pp.137-146
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    • 2006
  • We investigated the electrochemical properties for Langmuir-Blodgett (LB) films mixed with fatty acid (8A5H) and phospholipid (DLPE, DMPC, and DPPA). LB films of 8A5H monolayer and 8A5H-phospholipid mixture were deposited using the Langmuir-Blodgett method on the indium tin oxide(ITO) glass. The electrochemical properties measured using cyclic voltammetry with three-electrode system, an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode at various concentrations(0.1, 0.5, and 1.0 mol/L) of $NaClO_4$ solution. A measuring range was reduced from initial potential to -1350 mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate was 50, 100, 150 and 200 mV/s, respectively. As a result, LB films of fatty acid and phospholipid (8A5H/DLPE and DPPA) appeared irreversible process were caused by only the reduction current from the cyclic voltammogram and LB film of 8A5H-DMPC mixture was found to be caused by a reversible oxidation-reduction process.

Electrochemical Properties of Langmuir-Blodgett(LB) Films of Fatty Acid Containing Azobenzene and $L-{\alpha}-dimyristoylphosphatidylcholine$ Mixture (아조벤젠기를 가진 지방산과 $L-{\alpha}-dimyristoylphosphatidylcholine$ 혼합 LB막의 전기화학적 특성)

  • Park, Keun-Ho;Choi, Sung-Hyun;Song, Ju-Yeong
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.4
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    • pp.315-322
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    • 2005
  • We investigated the electrochemical properties for Langmuir-Blodgett (LB) films mixed with 4-octyl-4'-(5-carboxylpentamethyleneoxy)azobenzene (denoted as 8A5H) and $phospholipid(L-{\alpha}-dimyristoylphosphatidylcholine$, denoted as DMPC). LB films of 8A5H monolayer and 8A5H-DMPC were deposited by using the Langmuir-Blodgett method on the indium tin oxide(ITO) glass. The electrochemical properties measured by using cyclic voltammetry with a three_electrode system, an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode at various concentrations(0.1, 0.5, and 1.0mol/L) of $NaClO_4$ solution. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650mV and measured to the initial point. The scan rates were 50, 100, 150 and 200mV/s, respectively. As a result, LB films of 8A5H monolayer appeared irreversible process caused by only the oxidation current from the cyclic voltammogram and LB films of 8A5H-DMPC mixture were found to be caused by a reversible oxidation-reduction process.

Effect of Welding method and Welding Material to Corrosion Property of Repair Weld Zone for Exhaust Valve in 5% H2SO4 Solution -1 (5% 황산용액에서 배기밸브 보수 용접부의 부식 특성에 미치는 용접방법과 용접봉의 영향-1)

  • Kim, Jin-Gyeong;Cho, Hwang-Rae;Lee, Myung-Hoon;Kim, Yun-Hae;Moon, Kyung-Man
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.6
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    • pp.744-752
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    • 2007
  • Recently a fuel oil of the diesel engine in the ship is being changed with low quality as the oil price is higher more and more. Therefore the wear and corrosion in all parts of the engine like cylinder liner ring groove of piston crown, spindle and seat ring of exhaust valve are increased with using of heavy oil of low quality In particular the degree of wear and corrosion in between valve spindle and seat ring are more serious compared to the other parts of the engine due to operating in severe environment such as the high temperature of exhaust gas and repeating impact. Thus the repair weld to the valve spindle and seat ring is a unique method to prolong the life of the exhaust valve in an economical point of view In this study. corrosion property of both weld metal zone and base metal was investigated with some electrochemical methods such as measurement of corrosion potential, cathodic and anodic polarization curves, cyclic voltammogram and polarization resistance etc. in 5% $H_2SO_4$ solution. in the case of being welded with some welding methods and welding materials to the exhaust valve specimen as the base metal. In all cases. the values of hardness of the weld metal zone were more high than that of the base metal. And their corrosion resistance were also superior to the base metal. The weld metal of A2F(AC SMAW: 2 pass welding with foreign electrode) showed a relatively good results to the corrosion resistance as well as the hardness compared to the ether welding methods and welding materials. Moreover it indicated that hardness of the weld metal by the domestic electrode was considerably high compared to that of the foreign electrode.

Experimental Verification on Factors Affecting Core Resistivity Measurements (II)-Characteristics of Time Series Data and Determination Method of Resistivity (코어비저항 측정에 미치는 영향요소에 대한 실험적 고찰(Ⅱ) - 시계열자료의 특성과 대표비저항 값의 결정)

  • Kim, Yeong Hwa;Choe, Ye Gwon
    • Journal of the Korean Geophysical Society
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    • v.2 no.4
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    • pp.269-276
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    • 1999
  • As a part of trying to get the resistivity values correctly from laboratory core resistivity measurement, the effect of sample holders in resistivity measurement was analyzed and a better way to determine the representative resistivity value from the time series resistivity data was searched. Modified GS type and modified two-electrode type sample holders were devised and their effects have been compared with those of GS and two-electrode type sample holders. The modified two-electrode type sample holder has benefits both in repetition and simplicity in data acquisition. The analysis of distribution trend of the time series resistivity data obtained with different kind of sample holders and source frequencies shows that the maximum curvature point method gives the best result in determining representative resistivity value.

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On-site Water Nitrate Monitoring System based on Automatic Sampling and Direct Measurement with Ion-Selective Electrodes

  • Kim, Dong-Wook;Jung, Dae-Hyun;Cho, Woo-Jae;Sim, Kwang-Cheol;Kim, Hak-Jin
    • Journal of Biosystems Engineering
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    • v.42 no.4
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    • pp.350-357
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    • 2017
  • Purpose: In-situ monitoring of water quality is fundamental to most environmental applications. The high cost and long delays of conventional laboratory methods used to determine water quality, including on-site sampling and chemical analysis, have limited their use in efficiently managing water sources while preventing environmental pollution. The objective of this study was to develop an on-site water monitoring system consisting mainly of an Arduino board and a sensor array of multiple ion selective electrodes (ISEs) to measure the concentration of $NO_3$ ions. Methods: The developed system includes a combination of three ISEs, double-junction reference electrode, solution container, sampling system consisting of three pumps and solenoid valves, signal processing circuit, and an Arduino board for data acquisition and system control. Prior to each sample measurement, a two-point normalization method was applied for a sensitivity adjustment followed by an offset adjustment to minimize the potential drift that could occur during continuous measurement and standardize the response of multiple electrodes. To investigate its utility in on-site nitrate monitoring, the prototype was tested in a facility where drinking water was collected from a water supply source. Results: Differences in the electric potentials of the $NO_3$ ISEs between 10 and $100mg{\cdot}L^{-1}$ $NO_3$ concentration levels were nearly constant with negative sensitivities of 58 to 62 mV during the period of sample measurement, which is representative of a stable electrode response. The $NO_3$ concentrations determined by the ISEs were almost comparable to those obtained with standard instruments within 15% relative errors. Conclusions: The use of the developed on-site nitrate monitoring system based on automatic sampling and two-point normalization was feasible for detecting abrupt changes in nitrate concentration at various water supply sites, showing a maximum difference of $4.2mg{\cdot}L^{-1}$ from an actual concentration of $14mg{\cdot}L^{-1}$.

Improvement of Power Generation of Microbial Fuel Cells using Maximum Power Point Tracking (MPPT) and Automatic Load Control Algorithm (최대전력점추적방법과 외부저항 제어 알고리즘을 이용한 미생물연료 전지의 전력생산 최대화)

  • Song, Young Eun;Kim, Jung Rae
    • KSBB Journal
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    • v.29 no.4
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    • pp.225-231
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    • 2014
  • A microbial fuel cell (MFC) and bioelectrochemical systems are novel bioprocesses which employ exoelectrogenic biofilm on electrode as a biocatalyst for electricity generation and various useful chemical production. Previous reports show that electrogenic biofilms of MFCs are time varying systems and dynamically interactive with the electrically conductive media (carbon paper as terminal electron acceptor). It has been reported that maximum power point tracking (MPPT) method can automatically control load by algorithm so that increase power generation and columbic efficiency. In this study, we developed logic based control strategy for external load resistance by using $LabVIEW^{TM}$ which increases the power production with using flat-plate MFCs and MPPT circuit board. The flat-plate MFCs inoculated with anaerobic digester sludge were stabilized with fixed external resistance from $1000{\Omega}$ to $100{\Omega}$. Automatic load control with MPPT started load from $52{\Omega}$ during 120 hours of operation. MPPT control strategy increased approximately 2.7 times of power production and power density (1.95 mW and $13.02mW/m^3$) compared to the initial values before application of MPPT (0.72 mW and $4.79mW/m^3$).

Impulse Response Characteristics of the Grounding Systems with respect to the Common-Connection Position in Power Utility System (수변전설비에서 접지시스템의 공결점의 위치에 따른 임펄스 응답특성)

  • Lee, B.H.;Eom, J.H.;Kim, S.W.;Shim, P.S.;Lee, S.C.
    • Proceedings of the KIEE Conference
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    • 1999.07e
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    • pp.2149-2151
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    • 1999
  • This paper describes the impulse response characteristics of the grounding systems in power utility system. Several regulations regarding to electric power equipments, services and managements require that the groundings of class 1 ($E_1$) and class 2 ($E_2$) must be connected at the common point in grounding systems. In addition, the grounding for arrester ($E_{LA}$), which belongs to the grounding of class 1, should be connected at the same point. However, there is no method and position of common-connection at anywhere. In this work, when the impulse current was injected through the grounding conductor for arrester, the investigations measuring and analyzing potential rises induced at the common connection point and other grounding conductors were conducted. The experiments were carried out in the conditions of the grounding conductor of 25m long and the near or remote common connection from ground electrode. The lightning impulse current was applied so as to simulate the on-set of arrester due to lightning and/or switching surges.

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Implementation on the Portable Blood Gas Analyzer (휴대형 혈액가스 분석시스템의 구현)

  • Kang S.C.;Jeong D.U.;Bae J.W.;Shon J.M.;Shim Y.B.;Jeon G.R.
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2006.05a
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    • pp.1032-1036
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    • 2006
  • In this study, we implement the potable blood gas analyzer measuring pH, $pCO_2\;and\;pO_2$ of the arterial blood. The implemented system by this study is divided into hardware and software part and also the hardware portion is parted by mechanism and electronic circuit mit. The system program is composed of operating, washing, correcting and measuring program. And to correct the system, two-point calibration method is used, one-point calibration method is also added for more accuracy, and system program is coded. For verifying the implemented system, We examine to response property of each electrode. And evaluate accuracy of the system using standard reagent and was construed as statistical.

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