• Korean Chemical Engineering Research
• /
• 제54권6호
• /
• pp.863-870
• /
• 2016

본 논문의 목적은 소듐냉각고속로(sodium cooled fast reactor, SFR)와 초임계 $CO_2$ Brayton cycle의 연계 시, 원자로 열수송 계통과 동력변환 계통의 압력 경계를 형성하는 회로인쇄형 열교환기의 경계면에 균열이 발생해 고압(약 200 bar)의 $CO_2$가 상압 수준의 액체소듐유로 측에 유입되었을 때의 물리/화학적 현상을 파악하여 열교환기 설계에 활용 가능한 실험 자료를 생산하는 것이다. 열교환기의 소듐-$CO_2$ 경계면 균열 현상은 경계면의 균열 크기에 따라 미세 균열에 의한 소듐유로막힘(plugging) 현상과 상대적으로 큰 균열에 의한 열교환기 재료손상(wastage) 현상으로 나뉜다. Plugging 실험결과, 소듐유로 직경이 3mm일 때 $CO_2$ 주입 즉시 소듐 흐름이 정지한 반면 소듐유로 직경이 5 mm일 때는 유량이 감소되기 시작하는 시점은 3 mm의 경우와 유사하게 $CO_2$ 주입 즉시 나타났지만 소듐의 흐름이 완전히 정지할 때까지는 상대적으로 오랜 시간이 소요되었다. 이러한 실험결과는 실제 열교환기의 소듐-$CO_2$ 경계면에서 미세균열이 발생했을 때, 소듐유로 직경이 3 mm로 좁을 경우 균열 발생과 동시에 해당 소듐유로가 반응생성물에 의해 막혀 해당 유로 외의 유로들로 지속적인 열교환기 운전이 가능하지만, 소듐유로의 직경이 5 mm로 넓어질 경우 소듐유로가 고체생성물에 의해 즉시 막히지 않고 생성물이 소듐유로를 따라 계통 내부를 이동하다 일정 농도 이상이 되어야 소듐유로를 막게 할 것으로 예상할 수 있는 결과이다. Wastage 실험결과, 열교환의 재질(STS316, Inconel600, G91 합금강), 운전온도($400{\sim}500^{\circ}C$), 노즐직경(0.2~0.8 mm), 시편-노즐 거리(2~6 mm)와 무관하게 고압(약 200~250 bar)의 $CO_2$ 분사에 의한 시편의 물리적 손상(erosion) 현상은 발생하지 않았다. 노즐에서의 분사되는 $CO_2$의 분사속도는 마하 0.4~0.7인 것으로 확인되었다. 본 연구의 실험결과는 열교환기 파손 대처 설계에 배경 실험 자료로 활용될 것으로 기대된다.

• 한국가스학회지
• /
• 제6권1호
• /
• pp.38-45
• /
• 2002

가스 하이드레이트는 메탄, 에탄, 프로판, 부탄 등과 같은 천연가스-성분이 물에 의해 포획된 얼움형태의 고체연료로서, 세계적으로 가스 하이드레이트 추정 매장량은 기존 화석연료 매장량에 비해 약 2배 이상인 것으로 예측되어 미래의 신 에너지 자원으로 기대되고 있다. 그러나 이러한 에너지 자원측면과는 반대로 파이프라인을 통한 가스 수송과정에서 형성된 하이드레이트는 유동저해나 배관손상을 유발 할 수 있는 요인으로 영구동토지연인 시베리아는 물론이고 북해와 멕시코만 등의 여러 유전이나 가스전에서 심각한 문제를 발생시키고 있다. 해저 가스 파이프라인이나 동토지역을 통과하는 가스 파이프라인에서는 관내 압력과 온도에 따라 하이드레이트가 생성될 수 있으며, 특히 송출압력을 높게 할 경우에는 파이프라인 안에 하이드레이트가 생성될 가능성은 더욱 높아져, 플러깅 형성에 의한 유동저해 및 배관손상이 예상된다. 본 연구에서는 실제 파이프라인 내부에서 하이드레이트로 인한 플러깅 생성 메카니즘을 규명하고 이에 대한 형성조건을 측정함으로써, 그 방지기준 및 방지책을 선정하는데 활용하고자 실험실 규모의 환상형 파이프라인 실험장치를 개발하려다. 개발된 실험장치를 통해 파이프라인에서의 하이드레이트 평형조건을 도출하고, 다양한 속도 및 압력 조건하에서 하이드레이트 플러깅 형성온도를 측정하였다 이를 통해 유통속도 및 압력, 온도에 관한 상관관계를 파악하고 그 경향을 도출함으로써 실제 가스 파이프라인에의 하이드레이트 플러깅 형성조건을 파악할 수 있었다.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2003년도 추계학술대회
• /
• pp.1186-1191
• /
• 2003

The 40% of wall criterion, which is generally used for the plugging of steam generator tubes, may be applied only to a single crack. In the previous study, a total of 9 failure models were introduced to estimate the local failure of the ligament between cracks and the optimum coalescence model of multiple collinear cracks was determined among these models. It is, however, known that parallel axial cracks are more frequently detected during an in-service inspection than collinear axial cracks. The objective of this study is to determine the plastic collapse model which can be applied to the steam generator tube containing two parallel axial through-wall cracks. Nine previously proposed local failure models were selected as the candidates. Subsequently interaction effects between two adjacent cracks were evaluated to screen them. Plastic collapse tests for the plate with two parallel through-wall cracks and finite element analyses were performed for the determination of the optimum plastic collapse model. By comparing the test results with the prediction results obtained from the candidate models, a plastic zone contact model was selected as an optimum model.

• Nuclear Engineering and Technology
• /
• 제36권4호
• /
• pp.316-326
• /
• 2004

The $40\%$ of wall criterion, which is generally used for the plugging of steam generator tubes, is applied only to a single crack. In a previous study, a total number of 9 failure models were proposed to estimate the local failure of the ligament between cracks, and the optimum coalescence model of multiple collinear cracks was determined among these models. It is, however known that parallel axial cracks are more frequently detected than collinear axial cracks during an in-service inspection. The objective of this study is to determine the plastic collapse model that can be applied to steam generator tubes containing two parallel axial through-wall cracks. Three previously proposed local failure models were selected as the candidates. Subsequently, the interaction effects between two adjacent cracks were evaluated to screen them. Plastic collapse tests for the plate with two parallel through-wall cracks and finite element analyses were performed to determine the optimum plastic collapse model. By comparing the test results with the prediction results obtained from the candidate models, a COD base model was selected as an optimum model.

• Nuclear Engineering and Technology
• /
• 제36권4호
• /
• pp.327-337
• /
• 2004

It is commonly required that tubes with defects exceeding $40\%$ of wall thickness in depth should be plugged; however, this criterion is too conservative for some locations and for some types of defects. Many studies have been done with the aim of developing an alternative plugging criteria, and these studies have shown that steam generator tubes with a certain range of axial through-wall cracks could remain in service without any safety or reliability problems. However, these studies have been limited, thus far, to consideration of single cracked tubes, necessitating a study on multiple cracks, which are commonly found. A crack coalescence model applicable to steam generator tubes with two collinear axial through-wall cracks was proposed in the previous study. In this paper, the investigation is extended to the parallel axial cracks spaced in a circumferential direction, because parallel axial cracks are more frequently detected during in-service inspections than collinear axial cracks. Interaction effects between two parallel cracks are evaluated by performing elastic and elastic-plastic finite element analyses.

• 한국지반공학회논문집
• /
• 제18권4호
• /
• pp.189-197
• /
• 2002

개단말뚝의 지지력은 말뚝의 폐색정도에 영향을 받으며, 이러한 폐색정도는 관내토증분비인 IFR에 의하여 정량화 될 수 있다. 그러나 말뚝의 폐색정도가 말뚝의 지지력에 미치는 영향을 정확하게 고려하는 개단말뚝의 지지력 산정기준이 현재까지 없는 실정이다. 따라서 말뚝의 폐색정도가 지지력에 미치는 영향을 조사하기 위하여 계측기가 부착된 모형 개단말뚝과 가압토조를 이용해서 모형말뚝시험을 수행하였다. 시험결과 개단말뚝의 IFR은 말뚝의 관입깊이에 대한 관내토길이의 비로 정의되는 관내토길이비(PLR)로부터 예측이 가능함을 알 수 있었다. 그리고 개단말뚝의 선단 지지력과 주면마찰력은 말뚝의 IFR이 증가함에 따라 감소하는 경향을 보였다. 또한 이와 같은 모형말뚝시험의 결과에 근거하여 개단말뚝의 선단지지력과 주면마찰력을 산정할 수 있는 새로운 지지력산정식이 제안되었다.

• 펄프종이기술
• /
• 제31권1호
• /
• pp.52-60
• /
• 1999

Drainage rate in wet-end, which has significant influences on the production capacity, product quality and process economics in papermaking, becomes an important factor in the modern high speed papermaking processes owing to increased level of fines contained in today's pulp materials and increased papermaking system closure. A study was carred out to investigate the influence of beating and fines content on natural and vacuum dewatering using a vacuum drainage tester. Increase in beating and accumulation of fines in the stock decreased natural dewatering, Vacuum dewatering effect, however, increased substantially as beating and fines content were increased. But this increase in vacuum dewatering decreased again when a stock is severely beaten or fines content is greater than 35%. Above this level of fines content, mobile fines migrates to the interstices of the forming web to cause sealing or plugging which restrict fluid movement through the web.

• Corrosion Science and Technology
• /
• 제16권4호
• /
• pp.167-174
• /
• 2017

Bicarbonate/carbonate and molybdate anions have been characterized for their inhibitive effect on pitting corrosion of carbon steel in simulated concrete pore solution by using electrochemical tests such as electrochemical impedance (EIS) and linear polarization (LP). It was revealed that bicarbonate/carbonate has a weak inhibitive effect on pitting corrosion that is approximately one order of magnitude lower compared to hydroxide. Molybdate is effective against pitting corrosion induced by the concentration of chloride as low as 113 mM and can increase the pitting potential of a previously pitted sample to the oxygen evolution potential by the concentration of molybdate as much as 14.6 mM only. The formation of a $CaMoO_4$ film on the surface hinders the reduction of dissolved oxygen on the steel surface, reducing corrosion potential and increasing the safety margin between corrosion potential and pitting potential further. In addition, pore-plugging by $FeMoO_4$ as a type of salt film within pits increases the likelihood of repassivation.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2005년도 춘계학술대회
• /
• pp.618-621
• /
• 2005

In this study, the phenomena of hydrate formation and inhibition were investigated according to varying the concentrations using methanol and ethylene glycol as chemical additives. The results reveal that the used additives display better inhibition effects compared to pure water by decreasing the formation temperature and the inhibition performance of methanol is superior to that of ethylene glycol. As a conclusion, the plugging phenomena of flowline in natural gas product ion. subsea and frozen field pipelines can be predicted by examining the hydrate formation and inhibition conditions. Specifically, the results of this study can be applied to the selection of the prevention criteria and method of hydrate formation.

• Journal of Advanced Marine Engineering and Technology
• /
• 제13권2호
• /
• pp.64-77
• /
• 1989

In this study, the experiments were carried out for the purpose of establishment of aluminium cementation to steel surface by diffusible heat treatment after making the coated film onto the substrate by arc spray method. Also, the microstructure and mechanical properties of the cementation layer produced by this study were inspected for various heat treatment and spraying conditions. Main results obtained are as follow ; 1. The coating film characteristics which have excellent errosion-resistance, high temperature oxidation-resistance are obtained by aluminium penetration heat treatment after making the sprayed aluminum coating film onto the steel substrate. 2. Aluminium diffusion penetration takes place at higher temperature than 660.deg.C, and the more heat treatment time and the higher heat treatment temperature adopted, the deeper diffusion layer obtained. 3. Insert gas arc spraying using argon gas as the carrier gas higher improvement of mechanical property than that of compressed air environment. 4. The coating film characteristics appeared to be improvement of adhesive property, porosity plugging effect by heat treatment in air environment.