• 제목/요약/키워드: Plateau pressure

검색결과 52건 처리시간 0.028초

Mg8Ti2-(10, 20 wt.%)Ni 수소저장합금의 제조 및 수소화 특성 평가 (Fabrication and Evaluation of Hydorgenation Propeties on Mg8Ti2-(10, 20 wt.%)Ni Composites)

  • 김경일;홍태환
    • 한국재료학회지
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    • 제20권10호
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    • pp.543-549
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    • 2010
  • The hydrogen energy had recognized clean and high efficiency energy source. The research field of hydrogen energy was production, storage, application and transport. The commercial storage method was using high pressure tanks but it was not safety. However metal hydride was very safety due to high chemical stability. Mg and Mg alloys are attractive as hydrogen storage materials because of their lightweight and high absorption capacity (about 7.6 wt%). Their range of applications could be further extended if their hydrogenation properties and degradation behavior could be improved. The main emphasis of this study was to find an economical manufacturing method for Mg-Ti-Ni-H systems, and to investigate their hydrogenation properties. In order to examine their hydrogenation behavior, a Sievert's type automatic pressure-compositionisotherm (PCI) apparatus was used and experiments were performed at 423, 473, 523, 573, 623 and 673 K. The results of the thermogravimetric analysis (TGA) revealed that the absorbed hydrogen contents were around 2.5wt.% for (Mg8Ti2)-10 wt.%Ni. With an increasing Ni content, the absorbed hydrogen content decreased to 1.7 wt%, whereas the dehydriding starting temperatures were lowered by some 70-100 K. The results of PCI on (Mg8Ti2)-20 wt.%Ni showed that its hydrogen capacity was around 5.5 wt% and its reversible capacity and plateau pressure were also excellent at 623 K and 673 K.

기체분무형 공정으로 제조된 Zr계 금속수소화물의 수소화반응 및 Ni-MH 2차전지 전극 특성에 관한 연구 (Hydrogneation and Electrochemical Characteristics of Gas-atomized Zr-based $AB_2$ Hydride for Ni-MH Secondary Battery)

  • 김진호;황광택;김병관;한정섭
    • 한국수소및신에너지학회논문집
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    • 제20권6호
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    • pp.505-511
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    • 2009
  • The hydriding and electrochemical characteristics of Zr-based $AB_2$ alloy produced by gas atomization have been extensively examined. For the particle morphology of the as-cast and gas-atomized powders, it can be seen that the mechanically crushed powders are irregular, while the atomized powder particles are spherical. The increase of jet pressure of gas atomization process results in the decrease of hydrogen storage capacity and the slope of plateau pressure significantly increases. TEM and EDS studies showed the increase of jet pressure in the atomization process accelerated the phase separation within grain of the gas-atomized alloy, which brought about a poor hydrogenation property. However, the gas-atomized $AB_2$ alloy powders produced by jet pressure of 50 bar kept up the reversible $H_2$ storage capacity and discharge capacity similar to the mechanically crushed particles. In addition, the electrode of gas-atomized Zr-based $AB_2$ alloy of 50 bar showed improved cyclic stability over that of the cast and crushed particulate, which is attributed to the restriction of crack propagation by grain boundary and dislocation with ch/discharging cycling.

소양(Cow's Rumen-reticulum)영양성의 가열조리시 분과 맛성분의 용출에 관한 연구 (Studies on the Contents of the Nutrients and the Nucleotides in Soup Stock During Cooking of Cow's Rumen-Reticulum)

  • 이연숙;박동연;박정숙
    • 한국식생활문화학회지
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    • 제4권3호
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    • pp.245-251
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    • 1989
  • 우리나라 고유 식품인 소양의 영양적 가치와 최적조리 조건을 제시하기 위해서, 소양 조직의 일반 영양성분과 조리방법(가열처리, 압력처리, 양과 물의 첨가비)에 따른 질소성분과 미네랄성분의 용출, 핵산관련 맛성분의 용출 및 관능검사 결과를 요약하면 다음과 같다. 1. 소양의 제 1위와 제 2위의 영양성분은 거의 차이가 없었으며 수분 약 83%, 회분 $0.4{\sim}0.5%$, 지방 약 3%, 단백질 약 13%, 칼슘 $50{\sim}56mg%$, ${\alpha}-amino$ N $75{\sim}76mg%$, 인 $75{\sim}76mg%$였다. 소양의 상피세포층의 중량은 제 1위에서 35%, 제 2위에서 29%를 차지하였으며, 회분과 칼슘을 제외한 모든 영양성분은 상피세포층과 근육층에 균일하게 분포되어 있었으나 칼슘은 총함량의 80% 이상이 상피세포층에 함유되어 있었다. 2. 소양을 2, 4, 8, 12, 24시간 가열한 후 질소성분(총질소와 ${\alpha}-amino$ N)과 미네랄성분(칼슘과인)은 각각 8시간과 4시간 가열에 의해 plateau에 달하였으며, 맛성분인 5'-IMP는 8시간 가열에 의해 plateau에 달하였다. 관능검사 결과는 8-12시간 가열시 좋은 성적을 얻었다. 3. 소양을 압력솥에서 30분, 1, 2, 3, 4시간 가열조리한 후 질소성분과 미네랄성분은 각각 2시간과 1시간 가열에 의해 plateau에 달하였으며 5'-IMP는 2시간의 압력가열로 최대값을 나타냈다. 관능검사 결과는 1시간 이상 가열시 좋은 성적을 나타내었다. 4. 소양의 중량별 용출액 중의 영양성분을 보면, 양에 대한 물의 첨가량이 10배 이상일 때 용출량은 증가하고, 특히 칼슘은 10배 이하에서는 20배에서의 용출량의 50%로 감소되었다. 맛성분의 용출은 20배에서 가장 효과적이었으며, 관능검사 결과에는 차이가 없었다. 이상의 실험 성적에서 소양은 단백질과 칼슘의 급원 식품으로서 조리시 상피세포층을 제거하였을 때 영양적 손실이 크며, 특히 칼슘의 손실이 컸다. 영양성분의 충분한 용출과 맛을 위해서는 상압가열 조리에 있어서는 8시간의, 압력조리에 있어서는 $1{\sim}2%$시간의 조리시간, 양에 대한 물의 첨가량은 10배 이상이 필요하였다. 이것은 소양의 조리시 충분량의 물을 넣어 장시간 가열하는 우리나라 재래식 조리방법이 영양적, 미각적 측면에서 매우 합리적임을 시사한 것으로 본다.

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열-나노임프린트 공정의 점탄성 유한요소해석 (A Viscoelasitc Finite Element Analysis of Thermal Nanoimprint Lithography Process)

  • 김남웅;김국원;신효철
    • 마이크로전자및패키징학회지
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    • 제14권4호
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    • pp.1-7
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    • 2007
  • 최근 나노임프린트 리소그래피 공정이 마이크로/나노스케일의 소자 개발에 있어서 경제적으로 대량 생산할 수 있는 기술로 주목 받고 있다. 나노 스케일의 패턴을 성공적으로 전사하기 위해서는 폴리머의 기계적 거동에 대한 이해를 바탕으로, 적절한 공정 조건 즉, 압력, 온도, 시간 등의 선택이 필요하다. 본 연구에서는 열-나노임프린트 공정에서의 충전과정을 해석하기 위하여 비선형 유한요소법을 이용하였으며, 폴리머의 거동을 점탄성으로 가정하여 재료의 응력완화 효과를 고려하였다. 해석을 통하여 온도 및 몰드의 패턴형상이 열-나노임프린트 공정에 미치는 영향을 살펴보았다.

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정지기상위성의 밝기온도로 분석한 2004년 동아시아지역에서 발생한 여름철 대류 시스템의 특성과 그 예측 가능성 (The Characteristics and Predictability of Convective System Based on GOES-9 Observations during the Summer of 2004 over East Asia)

  • 백선균;최영진;정주용;조천호
    • 대기
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    • 제16권3호
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    • pp.225-234
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    • 2006
  • Convective systems propagate eastward with a persistent pattern in the longitude-time space. The characteristic structure and fluctuation of convective system is helpful in determining its predictability. In this study, convective index (CI) was defined as a difference between GOES-9 window and water vapor channel brightness temperatures following Mosher (2001). Then the temporal-spatial scales and variational characteristics of the summer convective systems in the East Asia were analyzed. It is found that the average moving speed of the convective system is about 14 m/s which is much faster than the low pressure system in the summer. Their average duration is about 12 hours and the average length of the cloud streak is about 750km. These characteristics are consistent with results from other studies. Although the convective systems are forced by the synoptic system and are mostly developed in the eastern edge of the Tibetan Plateau, they have a persistent pattern, i.e., appearance of the maximum intensity of convective systems, as they approach the Korean Peninsula. The consistency of the convective systems, i.e., the eastward propagation, suggests that there exists an intrinsic predictability.

외부의 물과 Er:YAG Laser의 작용에 의한 Dental Hard Tissue에서의 열과 역학적 효과: Free-running 방식 (Exogenous-Water-Induced Thermal and Mechanical Effects on Dental Hard Tissue by the Er:YAG Laser: Free-running Mode)

  • 권용훈
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1997년도 추계학술대회
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    • pp.380-384
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    • 1997
  • This study was performed to understand the exogenous-water-drop induced thermomechanical effect on the tooth in the free-running Er:YAG laser mode for the proper use of water as a laser energy absorber and coolant in dentistry. The ree-running Er:YAG laser was used in the dental hard tissue ablation study. A Microjet system was employed to dispense precise water drops. Ablation rate, recoil momentum, and temperature rise in the pulp cavity were measured with and without an exogenous water drop on the tooth surface. Exogenous water enhanced ablation rate in the thick tooth in which the ablation rate on the dry surface does not increase linearly but shows plateau. Optimal exogenous water volume was shifted from 2 nl to 4 nl as the laser energy was increased from 48 mJ to 145 mJ. The magnitude of the recoil momentum was increased as the volume of exogenous water increased. The results of this study suggest that we must pay attention to the recoil momentum or recoil pressure study or the optimal and safe usage of water in the dental treatment because these mechanical effects depend on the volume of exogenous water on the tooth surface.

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원판(圓板)의 열판건조(熱板乾燥)에서 컴퓨터 시뮬레이션에 의한 내부온도(內部溫度)와 함수율(含水率) 분포모형(分布模型) (Distribution Model Based on Computer Simulation for Internal Temperature and Moisture Content in Press Drying of Tree Disks)

  • 여환명;정희석
    • Journal of the Korean Wood Science and Technology
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    • 제22권2호
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    • pp.61-70
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    • 1994
  • This study was executed to find the applicability of press drying of tree disk by investigating the shrinkage and drying defect and to form appropriate model by comparing the actual moisture content(MC) and internal temperature in respect of drying time with calculated values based computer simulation to which was applied finite difference method. In press drying disk, heating period, constant drying rate period maintained plateau temperature at 100$^{\circ}C$ and falling drying rate period were significantly distinguished. Actual MC and internal temperature were analogous to those calculated at comparing points. Heat transfer model formed by Fourier's law using specific heat of moist wood and conduction coefficient considering fractional volume of each element of wood cell wall, bound water, free water and air showed applicability as basic data to developing heat expansion, shrinkage and drying stress during press drying. Also mass transfer model formed by Fick's diffusion law using water vapor diffusion coefficient showed applicability. Longitudinal shrinkage was developed by pressure of hot press and tangential shrinkage was restrained by hygrothermal recovery. The heart check, surface check and ring failure were occurred differently in species, but V-shaped crack didn't develop.

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DEM study on effects of fabric and aspect ratio on small strain stiffness of granular soils

  • Gong, Jian;Li, Liang;Zhao, Lianheng;Zou, Jinfeng;Nie, Zhihong
    • Geomechanics and Engineering
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    • 제24권1호
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    • pp.57-65
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    • 2021
  • The effects of initial soil fabric and aspect ratio (AR) on the small-strain stiffness (G0) of granular soils are studied by employing discrete element method (DEM) numerical analysis. Elongated clumps composed of subspheres were adopted, and the G0 values were obtained by DEM simulations of drained triaxial tests under different densities and initial confining pressure (p0). The DEM simulations indicate that the initial soil fabric has an insignificant effect on G0. The effect of the AR on G0 is related to the initial density. Namely, for dense specimens, G0 first increases with increasing AR, reaching a plateau value when the AR ≥ 1.5. However, for loose specimens, G0 gradually increases as the AR increases. Microscopic examination reveals that G0 uniquely depends on the coordination number of the particles (CN-particle) rather than the subspheres (CN-sphere) at the particulate level for the effects of initial soil fabric and AR. Finally, Poisson's ratio ν0 is also determined by CN-particle. In addition, based on data in literature and this study, ν0 can be fitted as ν0 = 5.920(G0/(p0)1/3)-0.99, which can be used to predict ν0 of granular soils based on the measured G0.

2010년 3월 20일 부산지역에 발생한 극심한 황사의 에어로솔 농도 분포 특성 (Characterization of Aerosol Concentration during Severe Asian Dust Period at Busan, Korea in 20 March 2010)

  • 정운선;박성화;이동인;강덕두;김동철
    • 한국환경과학회지
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    • 제23권2호
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    • pp.275-289
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    • 2014
  • Asian dust (or yellow sand) occurring mainly in spring in East Asia is affected by the distribution of weather systems. This study was performed to investigate the characteristics of suspended particulate for Asian dust at Busan, Korea in 20 March 2010, which was one of the extreme case for the last 10 years. There was used the data of weather chart, satellite, automatic weather system (AWS), $PM_{10}$, laser particle counter (LPC), and backward trajectories model. In synoptically, the high pressure was located in the northwestern part and low pressure was located in the northeastern part of Korea. The strong westerly winds from surface to upper layer makes it possible to move air masses rapidly. Air masses passing through Gobi Desert in Mongolia and Inner Mongolia plateau covered the entire Korean peninsula. As the results of aerosol analysis, $PM_{10}$ concentration at Gudeok mountain in Busan was recorded $2,344{\mu}g/m^3$ in 2300 LST 20 March 2010 and their concentration was markedly increased at coarse mode particle. In surface condition, westerly wind about 3 ~ 5 m/s was dominant and small particles of $0.3{\sim}0.5{\mu}m$ were distributed on the whole. In heavy metal components analysis, the elements from the land was predominated.

Volume-Controlled Mode의 기계환기시 동일환 I:E Ratio하에서 Inspiratory Pause가 기도압 몇 가스교환에 미치는 영향 (The Effects of Inspiratory Pause on Airway Pressure and Gas Exchange under Same I:E ratio in Volume-controlled Ventilation)

  • 최원준;정성한;이정아;최강현
    • Tuberculosis and Respiratory Diseases
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    • 제45권5호
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    • pp.1022-1030
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    • 1998
  • 연구배경: Volume controlled ventilation(VCV)시 inspiratory pause의 사용은 흡기시간을 연장하여 평균기도압을 상승시키고 가스교환을 호전시키는 것으로 알려져 있다. 그러나 같은 흡기시간을 유지하더라도 inspiratory pause를 사용하였을 경우 평균기도압과 가스교환의 변화에 대하여는 잘 알려지지 않았다. 방 법: 저자들은 VCV으로 기계호흡을 받는 12명의 환자를 대상으로 흡기산소농도, 상시호흡량, 호흡수 및 I : E ratio(1 : 3)는 변화시키지 않고 5%의 pause를 사용한 경우와 사용하지 않은 경우의 기도압 및 가스교환의 변화를 관찰하여 비교하였다. 결 과: 동맥혈 이산화탄소분압은 pause를 사용한 경우 $38.6{\pm}7.4$ mmHg로 시용하지 않은 경우의 $41.0{\pm}7.7$ mmHg보다 유의하게 낮았다 (p<0.01). 동맥혈 산소분압은 pause를 사용한 경우 $94.4{\pm}23.2$ mmHg로 사용하지 않은 경우의 $91.8{\pm}19.7$ mmHg보다 높은 경향이 있었으나 (p=0.054), 폐포-동맥혈 산소분압차$(P(A-a)O_2)$는 pause 유무에 따른 차이가 없었다 ($185.3{\pm}86.5$ mmHg vs. $184.9{\pm}84.9$ mmHg, P=0.766). 평균기도압은 pause를 사용한 경우 $9.7{\pm}4.0\;cmH_2O$로 사용하지 않은 경우의 $8.8{\pm}4.0\;cmH_2O$보다 유의하게 높았다 (p<0.01). Pause를 사용했을 때의 pause pressure와 pause를 사용하지 않을 때의 최고흡기압의 차이는 호흡기계의 저항과 역상관관계를 보였으나 (r=-0.777, p<0.01), pause가 없을 때의 최고흡기압에서 pause를 사용했을 때의 최고흡기압으로의 증가는 호흡기계의 저항과 정상관관계를 보여 (r=0.811, p<0.01), 평균기도압의 차이는 호흡기계의 저항과 유의한 정상관관계를 보였다(r=0.681, p<0.05). 평균기도압의 변화는 $PaCO_2$의 변화와 상관관계를 보이지 않았다. 결 론: Volume control ventilation시 동일한 1:3 의 I:E ratio하에서라도 5%의 inspiratory pause를 사용하는 것이 평균기도압을 더 높게 유지할 수 있으며 폐환기를 호전시킬 수 있는 것으로 사료되었다. 또한 호흡기계의 저항이 증가되어 있을수록 평균기도압의 상승이 많았으나 평균기도압의 상승 정도는 폐환기의 변화와 상관관계를 보이지 않았다.

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