• Title/Summary/Keyword: Plastic crystal

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Molecular Simulation of Nano-Scale Waterjet Machining (나노스케일 워터젯 가공에 대한 분자시뮬레이션 연구)

  • Sang-Hoon Lee;Hyun-Joon Kim;Tae-Wook Kim
    • Tribology and Lubricants
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    • v.39 no.5
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    • pp.216-219
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    • 2023
  • This study employs molecular dynamics simulations to investigate the material behavior of workpieces in waterjet machining processes. To gain fundamental insights into waterjet machining, simulations were conducted using pure water, excluding abrasive particles. The simulation model comprised thousands of water molecules interacting with a single crystal metal workpiece. Water molecule clusters were imparted with various velocities to initiate collisions with the metal workpiece. The material behavior of the metal surface was analyzed with respect to the applied velocity conditions, considering the intricate interplay between water molecules and the workpiece at the atomic scale. The results demonstrated that the machining of the metal workpiece occurred only when water molecules were endowed with velocities above a certain threshold. In cases where energy was insufficient, the metal workpiece exhibited a slight increase in surface roughness due to mild plastic deformation, without undergoing substantial material removal. When machining occurred, the ejection of material revealed a 3-fold symmetric pattern, confirming that material removal in waterjet machining of the metal workpiece is primarily driven by plastic deformation-induced material ejection. This research provides crucial insights into the mechanisms underlying waterjet machining and enhances our understanding of material behavior during the process. The findings can be valuable in optimizing waterjet machining techniques.

Plastic LCDs Using Pixel Isolated LC mode

  • Jung, Jong-Wook;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1220-1222
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    • 2004
  • We developed a new device structure using anisotropic phase separation from liquid crystal (LC) and polymer composite materials using UV intensity variation and polymer wetting properties. In the device, the LC molecules are isolated in pixels where LCs are surrounded by the inter-pixel vertical polymer walls and the horizontal polymer films on the upper substrate. These devices show very good mechanical stability against external pressure. The electro-optic characteristics and the mechanical stability of the devices are discussed in view of the flexible display applications.

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Finite Element Analysis for Steady State Forming Process of Polycrystalline Metal Including Texture Development (집합조직의 발전을 반영하는 다결정재의 정상상태성형공정해석)

  • 김응주;이용신
    • Transactions of Materials Processing
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    • v.5 no.4
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    • pp.297-304
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    • 1996
  • A process model is formulated considering the effect of crystallographic texture developed in forming process. The deformation induced plastic anisotropy can be predicted by capturing the evolution of texture during large deformation in the polycrystalline aggregate. The anisotropic stiffness matrix for the aggregate is derived and implemented in Eulerian finite element code using a Consistent Penalty method. As an application the evolution of texture in rolling drawing and extrusion processes are simulated. The numerical results show good agreements with report-ed experimental textures.

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Fabrication and Characterization of a Fiber-Optic Alpha/Beta Detector for Nuclear Medicine Application (핵의학 적용을 위한 광섬유 기반의 알파/베타 검출기의 제작 및 특성분석)

  • Hong, Seung-Han;Yoo, Wook-Jae;Shin, Sang-Hun;Seo, Jeong-Ki;Han, Ki-Tek;Jeon, Da-Yeong;Cho, Seung-Hyun;Lee, Bong-Soo
    • Journal of Sensor Science and Technology
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    • v.21 no.5
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    • pp.367-373
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    • 2012
  • We fabricated a fiber-optic alpha/beta detector, which is composed of a sensing probe, a plastic optical fiber, a photomultiplier tube, and a multichannel analyzer, to obtain the energy spectra of radioactive isotopes. As inorganic scintillators of a sensing probe, a ZnS(Ag) film was coupled with a $CaF_2$(Eu) crystal for alpha and beta spectroscopy. In this study, $^{210}Po$ and $^{90}Sr$ were used as alpha and beta sources, respectively, and we measured the radiation energy spectra using a fiber-optic alpha/beta detector to identify alpha and beta emitting radionuclides for nuclear medicine application. Also, the variations of energy spectrum were obtained according to the length of plastic optical fiber.

Calcium pyrophosphate dihydrate deposition disease in the temporomandibular joint: diagnosis and treatment

  • Kwon, Kwang-Jun;Seok, Hyun;Lee, Jang-Ha;Kim, Min-Keun;Kim, Seong-Gon;Park, Hyung-Ki;Choi, Hang-Moon
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.40
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    • pp.19.1-19.6
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    • 2018
  • Background: Calcium pyrophosphate dihydrate deposition disease (CPDD) is a rare disease in the temporomandibular joint (TMJ) space. It forms a calcified crystal mass and induces a limitation of joint movement. Case presentation: The calcified mass in our case was occupied in the left TMJ area and extended to the infratemporal and middle cranial fossa. For a complete excision of this mass, we performed a vertical ramus osteotomy and resected the mass around the mandibular condyle. The calcified mass in the infratemporal fossa was carefully excised, and the segmented mandible was anatomically repositioned. Scanning electronic microscopy (SEM)/energy-dispersive X-ray spectroscopy (EDS) microanalysis was performed to evaluate the calcified mass. The result of SEM/EDS showed that the crystal mass was completely composed of calcium pyrophosphate dihydrate. This result strongly suggested that the calcified mass was CPDD in the TMJ area. Conclusions: CPDD in the TMJ is a rare disease and is difficult to differentially diagnose from other neoplasms. A histological examination and quantitative microanalysis are required to confirm the diagnosis. In our patient, CPDD in the TMJ was successfully removed via the extracorporeal approach. SEM/EDS microanalysis was used for the differential diagnosis.

Coordination Modes and Properties of Ag(I) Complex with N,N,N',N',N''-Pentamethyldiethylenetriamine

  • Chun, In-Sung;Kwon, Jung-Ah;Bae, Myung-Nam;Lee, Sim-Seong;Jung, Ok-Sang
    • Bulletin of the Korean Chemical Society
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    • v.27 no.7
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    • pp.1005-1008
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    • 2006
  • The reaction of $AgClO_{4}$ with acyclic potential tridentate N,N,N',N',N''-pentamethyldiethylenetriamine (pmdeta) has given colorless crystals suitable for X-ray crystallography. The crystal structure ($P2_{1}$/n, a = 14.413(1) $\AA$, b = 25.270(2) $\AA$, c = 16.130(1) $\AA$, b = $103.012(1){^{\circ}}$, V = 5723.7(8) A$\AA^{3}$, Z = 4, R = 0.0349) has been solved and refined. Three silver(I) ions connect four pmdeta ligands to produce discrete complex of $[Ag_3(pmdeta)_4](ClO_4)_3$. A pmdeta ligand is bridged to three silver(I) ions, and three other pmdeta ligands are chelated to each silver(I) center in a tridentate mode. Thus, the product is a rare tri-nuclear silver(I) complex with two different chemical environments. $^{13}C$ NMR and $MAS\;^{13}$C NMR indicate that the tri-nuclear silver(I) complex is not rigid in solution. The contact angles and thermal analyses of the complex are measured and discussed.

High Quality Nano Structured Single Gas Barrier Layer by Neutral Beam Assisted Sputtering (NBAS) Process

  • Jang, Yun-Sung;Lee, You-Jong;Hong, Mun-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.251-252
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    • 2012
  • Recently, the growing interest in organic microelectronic devices including OLEDs has led to an increasing amount of research into their many potential applications in the area of flexible electronic devices based on plastic substrates. However, these organic devices require a gas barrier coating to prevent the permeation of water and oxygen because organic materials are highly susceptible to water and oxygen. In particular, high efficiency OLEDs require an extremely low Water Vapor Transition Rate (WVTR) of $1{\times}10^{-6}g/m^2$/day. The Key factor in high quality inorganic gas barrier formation for achieving the very low WVTR required ($1{\times}10^{-6}g/m^2$/day) is the suppression of defect sites and gas diffusion pathways between grain boundaries. In this study, we developed an $Al_2O_3$ nano-crystal structure single gas barrier layer using a Neutral Beam Assisted Sputtering (NBAS) process. The NBAS system is based on the conventional RF magnetron sputtering and neutral beam source. The neutral beam source consists of an electron cyclotron Resonance (ECR) plasma source and metal reflector. The Ar+ ions in the ECR plasma are accelerated in the plasma sheath between the plasma and reflector, which are then neutralized by Auger neutralization. The neutral beam energies were possible to estimate indirectly through previous experiments and binary collision model. The accelerating potential is the sum of the plasma potential and reflector bias. In previous experiments, while adjusting the reflector bias, changes in the plasma density and the plasma potential were not observed. The neutral beam energy is controlled by the metal reflector bias. The NBAS process can continuously change crystalline structures from an amorphous phase to nano-crystal phase of various grain sizes within a single inorganic thin film. These NBAS process effects can lead to the formation of a nano-crystal structure barrier layer which effectively limits gas diffusion through the pathways between grain boundaries. Our results verify the nano-crystal structure of the NBAS processed $Al_2O_3$ single gas barrier layer through dielectric constant measurement, break down field measurement, and TEM analysis. Finally, the WVTR of $Al_2O_3$ nano-crystal structure single gas barrier layer was measured to be under $5{\times}10^{-6}g/m^2$/day therefore we can confirm that NBAS processed $Al_2O_3$ nano-crystal structure single gas barrier layer is suitable for OLED application.

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Characterization of interfacial chemistry on the coal bottom ash (저회의 계면 화학적 특성 규명)

  • Lee, Ki-Gang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.2
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    • pp.92-97
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    • 2011
  • Landfill is the main treatment method for bottom-ash because it has not only an irregular particle size and ingredients but also not proper recycling treatment. The aim of this study is to raise recycling rate of bottom-ash(nonplasticity pulverulent) and for the purpose of alternatives of clay to investigate the properties of Bottom-ash (B/A)-Hard Clay (H/C) bodies with controlled interfacial chemistry properties. After investigating the sedimentation height of suspensions with controlled pH, it was discovered that there was no hetero-polar aggregation for mixed slips because hard clay and bottom-ash had similar interfacial chemistry properties. Also, bulk density, water absorption, and microstructure properties of each pellet was observed that made by silp casting method and manufactured at $50^{\circ}C$ intervals between $1000{\sim}1250^{\circ}C$. As a result, dispersed slip of clay and bottom ash are possible for slip casting and plastic forming process because they exhibit Bingham plastic behavior. Products that made by slip with dispersed clay and bottom ash are not only suitable for KS L 4201 and KS L 1001 at $1250^{\circ}C$ but it is also possible to apply for ceramic and sanitary ware because specific gravity was about 15 % lighter than general ceramic materials.

Separation of 2,6-dimethylnaphthalene in Dimethylnaphthalene Isomers Mixture by Crystallization Operation (결정화 조작에 의한 Dimethylnaphthalene 이성체 혼합물 중의 2,6-dimethylnaphthalene의 분리)

  • Kang, Ho-Cheol;Kim, Su Jin
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.116-120
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    • 2014
  • Light cycle oil (LCO), one of the by-products of the catalytic cracking gasoline manufacturing process, contains a lot of valuable aromatics. In particular, 2,6-dimethylnaphthalene (2,6-DMN) contained in LCO has been becoming important as the basic material of polyethylene naphthalate plastic and liquid crystal polymer, etc. If it were possible to separate and purify the valuable aromatic hydrocarbons (such as 2,6-DMN) from LCO, which have only been used as fuel mixed with heavy oil, it would be very meaningful in terms of the efficient use of resources. We investigated the high-purity purification of 2,6-DMN by the combined method of melt crystallization (MC) and solute crystallization (SC). The enriched DMN isomer mixtures (concentration of 2,6-DMN : 10.43%) recovered from LCO by distillation-extraction combination and the crystal recovered by MC used as raw materials of MC and SC, respectively. The solvent of SC used was a mixture of methanol and acetone (60 : 40 wt%). The crystal of 2,6-DMN with a high-purity of 99.5% was recovered by MC-SC combination. We confirmed that the MC-SC combination was one of the very useful combinations for the high-purity purification of 2,6-DMN contained in the enriched DMN isomer mixtures.

A study on the cold forging die geometry optimal design for forging load reduction (성형하중 감소를 위한 냉간단조금형 최적설계에 관한 연구)

  • Hwang, Joon;Lee, Seung-Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.6
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    • pp.251-261
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    • 2022
  • This paper describes the finite element analysis and die design change of spring retainer forging process to reduce the cold forging load and plastic forming stress concentration. Plastic deformation analysis was carried out in order to understand the forming process of workpieces and elastic stress analysis of the die set was performed in order to get basic data for the die fatigue life estimation. Cold forging die design was set up to each process with different four types analysis progressing, the upper and lower dies shapes with combination of fillets and chamfers shapes of cold forging dies. This study suggested optimal cold forging die geometry to reduce cold forging load. The design parameters of fillets and chamfers are selected geometry were selected to apply optimization with the DoE (design of experiment) and Taguchi method. DoE and Taguchi method was performed to optimize the workpiece preform shape for spring retainer forging process, it was possible to expect an increase in cold forging die life due to the 20 percentage forging load reduction.