• Korean Journal of Materials Research
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• v.30 no.11
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• pp.621-626
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• 2020

This study is aimed at preparing and evaluating the plasma resistance of YAS (Y₂O₃-Al₂O₃-SiO₂) coating layer with crystalline YAG phase contents. For this purpose, YAS frits with controlled phase contents are prepared and melt-coated on sintered Al₂O₃ ceramics. Then, the results of phase analysis of crystalline YAS coating layer are compared to that of YAS frits, and discussed with regard to the plasma resistance of the YAS coating layer. The phase contents of the YAS frit change in a manner different from that of the prepared YAS coating layer, presumably owing to the composition change of YAS frit during the melt-coating process. The plasma resistance of the YAS coating layer is shown to increase with the YAG phase contents in the coating layer. Comparing the weight loss of YAS coating layer with those of commercial Y₂O₃, Al₂O₃, and quartz ceramics, the plasma resistance of the prepared YAS coating layer is 8 times higher than that of quartz and 3 times higher than that of Al₂O₃; this layer shows 70 % of the resistance of Y₂O₃.

• Journal of Powder Materials
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• v.18 no.3
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• pp.226-237
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• 2011

W-ZrC and W-HfC composite powders were fabricated by the Plasma Alloying & Spheroidization (PAS) method and the powders were sprayed into hybrid coating layers by using Low Vacuum Plasma Spray (LVPS) process, respectively. Microstructure, mechanical properties, and ablation characteristics of the fabricated coating layers were investigated. The LVPS process led to successful production of W-Carbide hybrid coatings, approximately 400 ${\mu}M$ or above in thickness. As the substrate preheating temperature increased from $870^{\circ}C$ to $917^{\circ}C$, the hardness of the W-ZrC coating layer increased due to decreased porosity. Vickers hardness showed higher value (about 108.4 HV) in W-ZrC hybrid coating material compared to that of W-HfC while adhesive strength was found to be similar in both coating layers. The plasma torch test revealed good ablation resistance of the W-Carbide hybrid coating layers. The relatively high performance W-ZrC coating layer at the elevated temperature is thought to be attributed to both the strengthening effect of ZrC particle remained in the layer and the formation of ZrO2 phase with high temperature stability.

• Journal of the Korean Ceramic Society
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• v.53 no.6
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• pp.628-634
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• 2016

The 8 wt% yttria($Y_2O_3$) stabilized zirconia ($ZrO_2$), 8YSZ, a typical thermal barrier coating (TBC) for turbine systems, was fabricated under different starting powder conditions and coating parameters by atmospheric plasma spray (APS) coating process. Four different starting powders were prepared by conventional spray dry method with different additive and process parameter conditions. As a result, large- and small-size spherical-type particles and Donut-type particles were obtained. Dense structure of 8YSZ coating was produced when small size spherical-type or Donut-type particles were used. On the other hand, 8YSZ coating with a porous structure was formed from large-size spherical-type particles. Furthermore, a segmented coating structure with vertical cracks was observed after post heat treatment on the surface of dense structured coating by argon plasma flame at an appropriate gun distance and power condition.

• Korean Journal of Materials Research
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• v.14 no.8
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• pp.558-564
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• 2004

In order to improve the low hardness and low wear resistance of Ti-6Al-4V alloy, plasma carburization treatment and CrN film coating were carried out. Effects of the plasma carburization and CrN coating were analyzed and compared with the non-treated alloy by mechanical and creep tests. After plasma carburization and CrN coating treatments, the carburized layer was about 150 ${\mu}m$ in depth and CrN coated layer was about 7.5 ${\mu}m$ in thickness. Hardness value of about $H_{v}$ 402 of the non-treated alloy was improved to $H_{v}$ 1600 and 1390 by plasma carburization and CrN thin film coating, respectively. Stress exponent(n) was decreased from 9.10 in CrN coating specimen to 8.95 in carburized specimen. However, the activation energy(Q) was increased from 242 to 250 kJ/mol. It can be concluded that the static creep deformation for Ti-6Al-4V alloy is controlled by the dislocation climb over the ranges of the experimental conditions.

• Journal of Ocean Engineering and Technology
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• v.15 no.4
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• pp.60-65
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• 2001

Thermal spray coating is formed by a process in which melted particles flying with high speed towards substrate, then crash and spread on the substrate surface cooled and solidified in a very short time, Stacking of the particles makes coating. In this study, the exfoliation of $Al_2$O$_3$ and Ni-4.5wt.%Al thermally sprayed coating which were deposited by an atmospheric plasma spray apparatus are investigated using an AE method. A tensile test is conducted on notch specimens in a stress range below the elastic limit of substrate. The wave forms of AE generated from the three coating specimens can be classified by FFT analysis into two types which low frequency(type I waveform is considered to corresponds exfoliation of coating layers and type II waveform corresponds the plastic deformation of notch tip or the resultant fracture of coating. The fracture of the coating layers can estimate by AE event and amplitude, because AE features increase when the deformation generates.

• Archives of Metallurgy and Materials
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• v.67 no.4
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• pp.1521-1524
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• 2022

Fe-Cr-B-based metamorphic alloy coating layers were manufactured by plasma spray with a Fe-Cr-B-Mo-Nb composition (hereinafter, M+) powder. The microstructure and wear properties of the coating layers were investigated and compared with a metamorphic alloy coating layer fabricated with commercial M material. XRD analysis revealed that the M and M+ coating layers were composed of α-Fe, (Cr, Fe)₂B, and some metallic glass phases. Wear test results showed that M+ coating layers had a superior wear resistance which had 1.48 times lower wear volume than M coating layers. Observations of the worn-out surfaces and cross-sections of the coating layers showed that M+ coating layer had relatively low oxides along the particle boundaries and it suppress a delamination behavior by the oxides.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.05a
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• pp.248-254
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• 2002

The most controversial topics in plasma sprayed ceramic coating system are recently mechanical properties such as bond strength, cohesive strength, toughness and so on. Determination of bond strength of coatings is one of the most important problems. In the industry, the bond strength of coating system has been estimated by Pull-off test(ASTM standard C633-79). But, without a fixed jig and specimen, it is impossible to obtain the bond strength. Therefore, it is necessary to study the critical fracture load on interface of the coating by indentation test. Because the critical fracture load plays an important role in evaluating the bond strength for plasma sprayed ceramic coating system. So, we have estimated critical fracture load in plasma sprayed ceramic coating system, and it was shown that inverse relationship between the cross-section hardness of coating and the critical fracture load(Pc). In case of the high load(1kgf, 2kgf) in $Al_{2}O_{3}+13%TiO_{2}$, it was found that the critical point(Pco), which the coating was broken on.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2000.11a
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• pp.80-88
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• 2000

The plasma spray technics has known as one of the surface modification methods to improve the mechenical properties or the functional charactristics of materials. This paper has been aimed to investigate the effects of plasma sprayed conditions, such as spray distance and arc power level, on sliding wear properties of plasma sprayed $Al_2$O$_3$-40%TiO$_2$coating layer. The sliding wear test using pin-on-disc type wear machine, has been conducted in several sliding speed for coating layer sparyed under different conditions. The result of this paper is that the wear resistance of plasma sprayed $Al_2$O$_3$-40%TiO$_2$coating layer is fluctuated with tile spray distance and the arc power level. The wear resiatance could be improved with decreasing the spray distance and with increasing the arc power level.

• Journal of Surface Science and Engineering
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• v.40 no.4
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• pp.159-164
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• 2007

Transparent aluminum oxide films were deposited on polycarbonate (PC) substrates by inductively coupled plasma (ICP) assisted reactive sputtering. the oxygen flow rate was regulated by controlling the target voltage with a proportional integrate derivative controller. The PC substrate was treated with plasma prior to the deposition in order to the enhance the adhesive strength of the $Al_2O_3$ film. The characteristics of hardness, structure, density, transmittance, deposition rate, surface roughness and residual stress were investigated to estimate the possibility for the hard coating.

• Journal of Power System Engineering
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• v.2 no.3
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• pp.49-54
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• 1998

This paper is investigated of hardness and adhesiveness of plasma sprayed coating steels by AE(Acoustic Emission) testing when loading a tensile. AE Parameters used are Event, Count, Energy and Amplitude. Test specimens are carbon steel(S45C) with sprayed coating layers of Ni-4.5wt.%Al(bond coating) and $TiO_2$(top coating), and carry out heat treatment at $800^{\circ}C\;and\;1000^{\circ}C$, respectively. The micro-hardness of the heat treatment specimen have been improved more than that of non-heat treatment. On the tensile test, the process and occurence of the exfoliation of the sprayed coating layer can be estimated by AE Characteristics of AE parameters, such as event, count, amplitude and energy, on the layer exfoliation are shown the similar aspects. The exfoliation of bond coating occure at about 20% of strain and top coating is about 5% of strain.