• 제목/요약/키워드: Planar-type structures

검색결과 57건 처리시간 0.026초

Structural and Bonding Trends among the B7C11-,B6C2, and B5C31+

  • Park, Sung-Soo
    • Bulletin of the Korean Chemical Society
    • /
    • 제26권1호
    • /
    • pp.63-71
    • /
    • 2005
  • Equilibrium geometries, electronic structures, and energies of borocarbon clusters (binary compounds of carbon and boron), an unexplored class of molecules with highly unusual characteristics and potential for further development, have been investigated by means of B3LYP/6-311+G$^*$ density functional theory computations. A large number of B$_7$C${_1}^{1-}$, B$_6C_2$, and B$_5C_{3}\,^{1+}$ clusters with planar and non-planar monocyclic and polycyclic rings, as well as cage structures, have been systematically studied. Unexpectedly, planar forms are predicted not only to be the most stable structures, but also, in many cases, to have unprecedented planar heptacoordinate boron (p-heptaB) and planar heptacoordinate carbon (p-heptaC) arrangements. All these pheptaB and p-heptaC have 6π electrons and are aromatic according to the nucleus independent chemical shift (NICS). This novel bonding pattern is analyzed in terms of natural bond orbital (NBO) analysis. For virtually all possible B$_7$C${_1}^{1-}$, B$_6C_2$, and B$_5C_{3}\,^{1+}$ combinations, the p-heptaB arrangements are the more stable than other type structures.

평판형 연료전지 스택의 제조를 위한 매니폴드 형상별 압력분포 시뮬레이션 (Pressure Distribution Simulation on Geometrical Manifolds Structure for Fabrication of a Planar-type Fuel-Cell Stack)

  • 박세준;최용성;이경섭
    • 전기학회논문지P
    • /
    • 제58권4호
    • /
    • pp.609-614
    • /
    • 2009
  • A fuel-cell power system among various alternative power sources has many advantages such as comparatively independable circumstances, high-efficient, and heat-recyclable, thus it is now able to be up to hundreds MWh-scaled through improving feasibility and longevity of it. During the last few decades, numerous research results has been investigated to expand interest in fuel-cell technology. This study presents pressure distribution on the geometrical manifold structures, which are U-type and Z-type, of a planar-type fuel-cell stack by simulated with computational fluid dynamics(CFD). Then, electrical performance of a 200W fuel-cell stack, which is U-type, was diagnosed after pre-conditioning operation. The stack has electrical characteristics ; 22V, 10A, 220W, and current density $200mA/cm^2$.

불화물 게이트 절연막을 이용한 반전형 GaAs MISFET (The GaAs Inversion-type MISFET using Fluoride Gate Insulator)

  • KWang Ho Kim
    • 전자공학회논문지A
    • /
    • 제30A권3호
    • /
    • pp.61-66
    • /
    • 1993
  • The interface properties of Fluoride/GaAs structures were investigated. It was foung that rapid thermal annealing(RTA) typically 800-850$^{\circ}C$for 1 min, was useful for improving the interface properties of that structures. The analysis by means of SIMS indicated that interdiffusion of each constitutional atom through the interface was negligible. The interfacial atom bonding model for RTA treatment was proposed. Bases on these results, inversion-type GaAs MISFET was fabricated using standard planar technologies.

  • PDF

600 V급 Planar Field Stop IGBT 최적 설계 및 전기적 특성 분석에 관한 연구 (A Study on Optimal Design and Electrical Characteristics of 600 V Planar Field Stop IGBT)

  • 남태진;정은식;강이구
    • 한국전기전자재료학회논문지
    • /
    • 제25권4호
    • /
    • pp.261-265
    • /
    • 2012
  • IGBT(insulated gate bipolar transistor) is outstanding device for current conduction capabilities. IGBT design to control the large power switching device for power supply, converter, solar converter, electric home appliances, etc. like this IGBT device can be used in many places so to increase the efficiency of the various structures are coming. in this paper optimization design of planar type IGBT and planar field stop IGBT, and both devices have a comparative analysis and reflection of the electrical characteristics.

일반적인 전원을 포함하는 평판구조에 대한 정확한 Closed-form 그린함수 (An Accurate Closed-form Green's Function for the Planar Structure with General Sources)

  • 강연덕;이택경
    • 대한전자공학회논문지TC
    • /
    • 제41권6호
    • /
    • pp.79-86
    • /
    • 2004
  • 정확한 closed-form 근린함수 계산방법은 공간영역 그린함수에 포함된 Sommerfeld 적분의 계산시간을 줄이기 위해 기존에 이용되어온 복소 영상법(Complex image method)과 2단계 근사화법(Two-level approach)에 비해 훨씬 적은 오차를 갖는다. 본 논문에서는 정확한 closed-form 그린함수 계산방법을 일반적인 전원을 포함하는 평판구조에 적용하는 방법을 제안하였다.

미끄럼 관절 콤플라이언스를 활용한 평면형 3 자유도 RCC 메카니즘의 해석 (Analysis of a Planar 3 DOF RCC Mechanism using Prismatic Joint Compliances)

  • 김희구;김동국;이병주
    • 한국정밀공학회:학술대회논문집
    • /
    • 한국정밀공학회 1994년도 추계학술대회 논문집
    • /
    • pp.611-616
    • /
    • 1994
  • Most of Commercial Remote Center Compliance(RCC) devices have been designed using deforma ble structures. In this work, we propose another type of assembly devices which generate the compliance effec ts by attaching the compliances (or spring) at the prismatic joints of the griven mechainsm. First, the kinematic analysis for a parallel-type planar 3-degree-of-freedom mechanism is performed using modified transfer method of generalized coordinate. Then, compliance characteristics for the mechanism using prismatic joint compliances are investigated. In particular, when the system maintains its symmetric configuration, the mechanism is show n to have RCC points at the center of the workspace. Finally, sensitivity analysis around RCC points is perfor med.

  • PDF

사면체 및 사각형 $[M(II)N_2S_2]$ 형태 착물의 쌍극자 모멘트의 계산 [M(II) = Ni(II), Co(II), Cu(II) 또는 Zn(II)] (Calculation of the Dipole Moments for Tetrahedral and Square Planar $[M(II)N_2S_2]$ Type Complexes [M(Ⅱ) = Ni(Ⅱ), Co(Ⅱ), Cu(Ⅱ) or Zn(Ⅱ)])

  • 안상운
    • 대한화학회지
    • /
    • 제23권1호
    • /
    • pp.1-6
    • /
    • 1979
  • 사각형 및 사면체 $[M(II)N_2S_2]$형태 착물의 쌍극자모멘트를 spherical harmonics의 전개방법에 의하여 계산하였다. [M(II) = Co(II), Ni(II), Cu(II) 또는 Zn(II)]. 이들 착물에 대한 쌍극자모멘트의 계산치가 실험치 범위안에 들었다. 계산한 쌍극자모멘트와 자기적 성질을 기초로하여 벤젠용액에서 이들 착물에 대한 가능한 구조를 고찰하였다.

  • PDF