• Journal of Welding and Joining
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• 제17권5호
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• pp.89-96
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• 1999

The base metal and weld metal of alloy designed austenitic stainless steels were electrochemically tested in artificial sea water. Pitting resistance of 14 different stainless steels was evaluated by measuring pitting potential. The effect of alloy element to pitting potential was evaluated by changing chromium, nickel, sulfur content. The site of pitting initiation was observed by optical microscope. As a result of electrochemical test, pitting resistance of weld metal was higher than base metal, and rapidly cooled weld metal has higher pitting potential than slowly cooled weld metal. In case of primary δ-ferrite solidification, pitting potential was increased, but residual δ-ferrite was detrimental to pitting resistance. Chromium was more effective to pitting resistance than nickel, and sulfur was very detrimental element to pitting resistance.

• Corrosion Science and Technology
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• 제13권2호
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• pp.48-55
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• 2014

Influence of annealing temperature on the microstructure and resistance to pitting corrosion of the hyper duplex stainless steel was investigated in acid and neutral chloride environments. The pitting corrosion resistance is strongly dependent on the microstructure, especially the presence of chromium nitrides ($Cr_2N$), elemental partitioning behavior and volume fraction of ferrite phase and austenite phase. Precipitation of deleterious chromium nitrides reduces the resistance to pitting corrosion due to the formation of Cr-depleted zone. The difference of PREN (Pitting Resistance Equivalent Number) values between the ferrite and austenite phases was the smallest when solution heat-treated at $1060^{\circ}C$. Based on the results of electrochemical tests and critical crevice temperature tests, the optimal annealing temperature is determined as $1060^{\circ}C$.

• 한국표면공학회지
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• 제48권4호
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• pp.142-148
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• 2015

The effect of equal channel angular pressing (ECAP) on the pitting corrosion resistance of hard anodized Al5052 alloy was investigated. The degree of internal stress generated in anodic oxide films during hard anodization was also evaluated with a strain gauge method. The pitting corrosion resistance of hard anodized Al5052 alloy was greatly decreased by ECAP. Cracks occurred in the anodic oxide film during hard anodization and these cracks were larger and deeper in the alloy with ECAP than without. The pitting corrosion was accelerated by cracks. The internal stress present in the anodic oxide films was compressive and the stress was higher in the alloys with ECAP than without, resulting in an increased likelihood of cracks. The pitting corrosion resistance of hard anodized Al5052 alloy was improved by annealing at the range of 473-573K after ECAP processed at room temperature for four passes. The compressive internal stress gradually decreased with increasing annealing temperature. It is assumed that the improvement in the pitting corrosion resistance of hard anodized Al5052 alloy by annealing may be attributed to a decrease in the likelihood of cracks due to the decreased internal stresses in anodic oxide films.

• 한국표면공학회지
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• 제39권1호
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• pp.18-24
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• 2006

Although stainless steels have the excellent corrosion resistance by passive film, they are susceptible to pitting corrosion in the environment containing halogen elements such as chloride ions. The resistance to pitting corrosion can be evaluated by measuring the critical pitting temperature (CPT). CPT values can be obtained using immersion, potentiodynamic and potentiostatic polarization test methods. Results on duplex 2205 stainless steels showed that CPT values were measured as $50^{\circ}C,\;55^{\circ}C\;and\;61^{\circ}C$, respectively for immersion, potentiodynamic and potentiostatic polarization test methods, depending upon the different test methods, even though the difference between CPT values are not much.

• 한국표면공학회지
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• 제36권3호
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• pp.277-283
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• 2003

Electrochemical techniques were used to study the surface treatment for improving the pitting corrosion resistance of 304L stainless steel by inhibitors in chloride medium. Sodium molybdate (in concentration range : 0.005-80 g/l) , sodium nitrite (in concentration range : 0.001-50 g/l) and their mixture were used for this study. It was found that, molybdate and nitrite were good passivators for 304L stainless steel, but molybdate was not able to prohibit the pitting ; nitrite prevented pitting corrosion of 304L stainless steel only at the concentration more than 25 g/l. The relationship between pitting potentials and concentrations of inhibitors in the logarithm expression obeyed the linear function. It was found that the surface treatment by mixture of two inhibitors enables stainless steel to have increased the corrosion resistance , the pitting corrosion of 304L stainless steel was completely prohibited by the mixtures of molybdate and nitrite in ratio min, with $m\;\geq\;3\;and\;n\;\geq\;10$. The interesting cases on electrochemical measurement of threshold of inhibitors concentration combination for optimum surface treatment were described.

• 한국재료학회지
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• 제25권12호
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• pp.666-671
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• 2015

In this study, we investigated the effect of the residual carbides and tempered carbides precipitated by tempering treatment after quenching on the pitting corrosion of mod. 440A martensitic stainless steel. In quenched specimens and tempered specimens after quenching of mod. 440A martensitic stainless steel, the volume fraction of the residual carbides and total carbides decreased with the increase of the austenitizing temperature. Pitting resistance increased with the increase of austenitizing temperature. With the increase of the volume fraction of the residual and total carbides, the pitting resistance of mod. 440A martensitic stainless steel was decreased. The pitting resistance of mod. 0.5C-17Cr-0.5Ni 440A martensitic stainless steel had stronger affected by residual carbides than precipitated carbides produced by tempering.

• Corrosion Science and Technology
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• 제22권5호
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• pp.305-313
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• 2023

The objective of this study was to investigate the effectiveness of sodium dodecyl benzene sulfonate (SDBS) as a corrosion inhibitor on the pitting corrosion behavior of aluminum alloys used in electric vehicle battery cooling systems within a mixture of ethylene glycol and water (EG-W) coolant. Potentiodynamic polarization testing revealed unstable passive film formation on the aluminum alloys in the absence of SDBS. However, the addition of SDBS resulted in a robust passive film, enhancing the pitting corrosion resistance across all examined alloys. Pitting corrosion was predominantly observed near intermetallic compounds in the presence of Cl? ions, which was attributed to galvanic interactions. Among tested alloys, A1040 demonstrated superior resistance due to its lower areal fraction of precipitates and donor density. The incorporation of SDBS inhibitors mitigated the overall pitting corrosion process by hindering Cl? ion penetration. These findings suggest that SDBS can significantly improve pitting corrosion resistance in aluminum alloys employed in battery coolant environments.

• 열처리공학회지
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• 제14권3호
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• pp.145-150
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• 2001

The effect of laser welding and surface treatment, developed as a method of repairing steam generator tubes, on the pitting corrosion resistance of alloy 690 was examined. The surfaces of some heat-treated Alloy 690 materials were melt-treated using the Nd-YAG laser beam, and then examined to characterize the microstructures. The resistance to pitting corrosion was evaluated by measuring of Ep(pitting potential) through the electrochemical tests and also by measuring the degree of pit generation through the immersion tests. The pit formation characteristics were investigated by observing microstructural changes and pit morphologies. The results show that the resistance to pitting corrosion increases in the order of the following list; solution annealed Alloy 690, thermally treated Alloy 690, and laser surface melt-treated Alloy 690. The melted region was found to have a cellular structure and fine precipitates. It was confirmed that the resistance of Alloy 690 to pit initiation and also to pit propagation was higher when it was laser treated than treated otherwise.

• 한국가스학회지
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• 제9권4호
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• pp.6-10
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• 2005

이 논문은 비저항에 따른 가스보일러용 오스테나이트계 스테인리스강(STS304)재의 손상거동에 관해 연구하기 위하여, 비저항에 따른 전기화학적 분극시험을 수행하였다. 그리고 비저항에 따른 가스보일러용 STS304강의 양극분극특성 및 손상거동인 공식양상을 고찰하였다. 비저항이 감소할수록 STS304강의 부동태유지전류밀도는 증가하고 부동태영역은 작아지고 있으며, 관통전위는 낮아지고 있다 또한 비저항이 가장 높은 $74{\Omega}{\cdot}m$중에서 손상거동인 공식양상은 거의 나타나지 않고, 비저항이 낮아질수록 손상거동인 공식양상은 더욱 성장되고, 공식수가 점점 증가하는 경향을 보이고 있다.

• Corrosion Science and Technology
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• 제16권6호
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• pp.278-284
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• 2017

The effects of TIG welding and post-treatment procedures on the microstructure and the pitting corrosion resistance of welded lean duplex stainless steel S82441 were investigated. Autogenous TIG welding was used with different amounts of heat input and shielding gases such as Ar, and mixtures of $Ar-N_2$ and Ar-He. The addition of 5% to 15% of nitrogen to argon practically did not affect the level of the pitting corrosion resistance. However, the application of gas mixtures (50% Ar + 50% He) resulted in a significant decrease in pitting corrosion resistance. We found that increased current (200 A and 250 A) led to lower values of CPT of welds compared with welds obtained with 50 A, 100 A and 150 A. In addition, the removal of the weld surface layer (0.2 ~ 0.3 mm thickness) in most cases not only resulted in a significant increase in resistance to the pitting corrosion but also post-treatment of weld, implying that corrosion resistance depended on factors such as surface roughness or the presence of undesirable oxides.