• Applied Chemistry for Engineering
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• v.24 no.4
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• pp.402-406
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• 2013

In this study, a pitch for melt-electrospinning was prepared from naphtha cracking bottom (NCB) oil by the modification with heat treatment. The softening point and property of the modified pitch was influenced by modification conditions such as nitrogen flow rate, heat treatment temperature, and reaction time. Among these, the heat treatment temperature had a very strong influence on the distribution of molecular weight and softening point of the pitch. The C/H mole ratio and average molecular weight increased with increasing the heat treatment temperature due the decomposition and cyclization reaction of surface-functional groups. In addition, the values of benzene insoluble and quinoline insoluble also tends to decrease, and the width of molecular weight distribution seems to get more narrow. The carbon fiber with a diameter of $4.8{\mu}m$ was prepared from a modified pitch at the softening point of $155^{\circ}C$ by melt-electrospinning. It is believed that the melt-electro spinning method is much more convenient to get the thinner fiber than the conventional melt spinning method.

• The Journal of the Acoustical Society of Korea
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• v.30 no.7
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• pp.390-395
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• 2011

This paper covers the studies on common voice parameters through the voice analysis of female main news anchors on weekday evening by the station, and differences of relative voices and sounds among stations. To examine voice characteristics, 6 voice parameters were analyzed and it showed anchors of each station had distinctive characteristics of voices and phonations over all fields except the speech rate, and there were also differences in sound systems. As major analysis parameters, basic pitch, tone of the 1st formant and pitch ratio, level of closeness by pitch bandwidth, type of sentence closing through average pitch position within pitch bandwidth, average speech rate, and acoustic tone analysis by energy distribution by frequency band were used. Analyzed values and results could be referred to and utilized in the criteria of phonation characteristics for domestic female news anchors.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.35 no.11
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• pp.964-972
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• 2007

Wind turbine experiment was carried out for the horizontal axis wind turbine with the aerodynamically optimized blade. From the comparison of aerodynamic performance between upwind and downwind type wind turbine rotor, the measured torque fluctuation of the latter is larger than that of the former. This phenomenon is owing to the interaction of wake generated from support column and blades. The wind turbine model satisfies the design condition in that the measured result of the power coefficient at zero pitch angle shows maximum peak at the designed tip speed ratio, λ = 6. It also shows that the decrease in aerodynamic power due to negative pitch change is more sensitive than that of the same positive pitch change.

• Korean Chemical Engineering Research
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• v.58 no.1
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• pp.142-149
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• 2020

In this study, the electrochemical performance of Graphite/Silicon/Pitch composites as anode material was investigated to improve the low theoretical capacity of artificial graphite. Spherical artificial graphite surface was coated with polyvinylpyrrolidone (PVP) amphiphiles material to synthesize Graphite/Silica material by silica islands growth. The Graphite/Silicon/Pitch composites were prepared by petroleum pitch coating and magnesiothermic reduction. The Graphite/Silicon/Pitch composite electrodes manufactured using poly(vinylidene fluoride) (PVDF), carboxymethyl cellulose (CMC) and polyacrylic acid (PAA) binders. The coin type half cell was assembled using various electrolytes and additives. The Graphite/Silicon/Pitch composites were analysed by X-ray diffraction (XRD), scanning electron microscope (SEM) and a thermogravimetric analyzer (TGA). The electrochemical characteristics of Graphite/Silicon/Pitch composite were investigated by constant current charge/discharge, rate performance, cyclic voltammetry and electrochemical impedance spectroscopy. The Graphite/Silicon/Pitch composites showed high cycle stability at a graphite/silica/pitch ratio (1:4:8 wt%). When the electrode is prepared using PAA binder, the high capacity and stability is obtained. The coin type half cell assembled using EC: DMC: EMC electrolyte showed high initial capacity (719 mAh/g) and excellent cycle stability. The rate performance has an capacity retention (77%) at 2 C/0.1 C and an capacity recovery (88%) at 0.1 C / 0.1 C when the vinylene carbonate (VC) was added.

• Journal of Korean Society of Forest Science
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• v.18 no.1
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• pp.1-7
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• 1973

This survey was estimated under the ratio estimate such as single class method, simple random sampling method, compound ratio sampling method, separate ratio sampling method and average tree sampling method artificial forest pitch pine volume. The following results were realized by the ratio estimates. At the above table simple random sampling method and compound ratio sampling method are the only ones which is included the actual stand volume in the ratio estimatedstand volume. It is thought that the sampling was in a such good result was because of stand structual stands were simple forest. The most simple measurement and calcuation on the stand volume estimates, in order, would be (1) single class method, (2) simple random sampling method (3) average tree method (4) separate ratio sampling method and compound ratio sampling method, and at the planted evenaged forest the method has realized the best results in obtaining good accuracy and the measure stand volume with least time, expenses and labor in considerably.

• Korean Chemical Engineering Research
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• v.59 no.4
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• pp.487-492
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• 2021

In this study, the electrochemical properties of pitch coated silicon sheets/graphite anode materials were investigated. Using NaCl as a template, silicon sheets were prepared through the stöber method and the magnesiothermic reduction methode. In order to synthesize the anode composite, the silicon sheets and graphite were combined with SDBS. The pitch coated silicon sheets/graphite was synthesized using THF as a solvent for the anode material composite. The physical properties of the prepared anode composites were analysed by XRD, SEM, EDS and TGA. The electrochemical performances of the prepared anode composites were performed by the current charge/discharge, rate performance, cyclic voltammetry and EIS tests in the electrolyte LiPF₆ dissolved solvents (EC:DMC:EMC=1:1:1 vol%). As the silicon composition of silicon sheets/graphite composite material increased, the discharge capacity also increased, but the cycle stability tended to decrease. The anode material of pitch coated silicon sheets/graphite composite (silicon sheets:graphite=3:7 weight ratio) showed the initial discharge capacity of 1228.8 mAh/g and the capacity retention ratio of 77% after 50 cycles. From these results, it was found that the cycle stability of pitch coated silicon sheets/graphite was improved.

• Journal of the Korean Society of Marine Environment & Safety
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• v.26 no.5
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• pp.561-568
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• 2020

A performance analysis was conducted according to changes in inflow velocity and the tip speed ratio of a portable horizontal-axis hydro turbine that can be used for marine leisure sports and outdoor activities by using the commercial computational fluid dynamics software ANSYS CFX. By using the analysis result and flow field analysis, the design was reviewed and the performance of the device was confirmed. In addition, data necessary to improve the performance of the hydro turbine were acquired by performing an additional performance analysis according to the variable blade pitch angle. The results among the numerical analysis cases show that the highest performance at all inflow velocities and blade pitch angles if achieved at a tip speed ratio of 4. The output power was found to be 30 W even under some conditions below the design flow rate. Among the numerical analysis cases, the highest output power (~ 85 W) and power coefficient (~ 0.30) were observed at an inlet flow rate of 1.5 m/s, a blade pitch angle of 3°, and a tip speed ratio of 4.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.7
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• pp.879-886
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• 2004

A numerical optimization has been carried out to determine the shape of the three-dimensional channel with oblique ribs attached on both walls to enhance turbulent heat transfer. The response surface based optimization is used as an optimization technique with Reynolds-averaged Navier-Stokes analysis of fluid flow and heat transfer. Shear stress transport (SST) turbulence model is used as a turbulence closure. Numerical results fur heat transfer rate show good agreements with experimental data. four dimensionless variables such as, rib pitch-to-rib height ratio, rib height-to-channel height ratio, streamwise rib distance on opposite wall to rib pitch ratio, and the attack angle of the rib are chosen as design variables. The objective function is defined as a linear combination of heat-transfer and friction-loss related coefficients with a weighting factor. D-optimal method is used to determine the training points as a means of design of experiment. Sensitivity of the objective parameters to each design variable has been analyzed. And, optimal values of the design variables have been obtained in a range of the weighting factor.

• The Transactions of the Korean Institute of Electrical Engineers B
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• v.53 no.8
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• pp.477-487
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• 2004

Helical magneto-cumulative generators(MCGs) are devices which convert explosive energy into electromagnetic energy. The electromagnetic energy supplied from an external circuit is amplified by an explosively driven metal conductor mounted at the center of a helical coil compressing magnetic flux between the conductor and the coil. To optimize the coil design, output properties of small-size helical MCGs were measured while varying design parameters; the number of coil sections, length of the sections, pitch in the sections, and type of copper wire. Dimensions of the coil were kept constant, 50 mm in diameter and 200 mm in length. The coil was fabricated by using enamel-coated copper wire of 1 mm in diameter. The highest energy amplification ratio and figure of merit were 52.5 and 0.81, respectively. from an helical MCG with initial inductance of 63.7 $\mu$H at initial energy of 0.152 kJ Based on the experimental and calculated results, empirical formulas capable of optimizing coil designs were derived. By using these formulas, pitch in each coil section can be obtained at an arbitrary inductive load for high energy amplification ratio and figure of merit.

• Korean Journal of Materials Research
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• v.26 no.4
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• pp.173-181
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• 2016

In order to use coal tar pitch (CTP) as a raw material for carbon fibers, it should have suitable properties such as a narrow range of softening point, suitable viscosity and uniform optical properties. In this study, raw CTP was modified by heat treatment with three types of polymer additives (PS, PET, and PVC) to make a spinnable pitch for carbon fibers. The yield, softening point, C/H ratio, insoluble yield, and meso-phase content of various modified CTPs with polymer additives were analyzed by changing the type of polymer additive and the heat treatment temperature. The purpose of this study was to compare the properties of CTPs modified by polymer addition with those of a commercial CTP. After the pitch spinning, the obtained green fibers were stabilized and carbonized. The properties of the respective fibers were analyzed to compare their uniformity, diameter change, and mechanical properties. Among three polymer additives, PS220 and PET261 pitches were found to be spinnable, but the carbon fibers from PET261 showed mechanical properties comparable with those of a commercial CTP produced by an air-blowing method (OCI284). The CTPs modified with polymer additive had higher ${\beta}$-resin fractions than the CTP with only thermal treatment indicating a beneficial effect of carbon fiber application.