• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 추계학술발표대회
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• pp.31.1-31.1
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• 2009

In an approach to acclimate ourselves torecent ecological consciousness trend, a lead-free piezoelectric material, bismuth sodium titanate (abbreviated as BNT) based bismuth sodium barium titanate (abbreviated as BNT-BT), was considered as an environment-friendly alternative for a lead based piezoelectric system. Ceramic specimens of0.94[(BixNa0.5)TiO3]-0.06[BaTiO3] (x = 0.500~0.515) compositions were prepared by a modified mixed oxide method. To increase the chemical homogeneity andre action activity, high energy mechanical milling machine and pre-milled nanosized powder has been used. In this method (BixNa0.5)TiO3 (x=0.500~0.515) andBaTiO3 were prepared separately from pre-milled constituent materials at low calcination temperature and then separately prepared BNTX (X=1, 2, 3 and 4) and BT were mixed by high energy mechanical milling machine. Without further calcination step the mixed powders were pressed into disk shape and sintered at $1110^{\circ}C$. Microstructures, phase structures and electrical properties of the ceramic specimens were systematically investigated. Highly dense ceramic specimens with homogenous grains were prepared in spite of relatively low sintering temperature. Phase structures were not significantly influenced by the excess amount Bi. Large variation on the piezoelectric and dielectric properties was detected at relative high excess Bi amounts. When $x{\leq}0.505$, the specimens exhibit insignificant variation in piezoelectric and dielectric constant though depolarization temperature is found to be decreased. Considerable amount of decrease in piezoelectric and dielectric properties are observed with higher excess of Bi amounts ($x{\geq}0.505$). This research indicates the advantages of high energy mechanical milling and importance of proper maintenance of Bi stoichiometry.

• 한국전기전자재료학회논문지
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• 제24권7호
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• pp.543-546
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• 2011

We studied sintering temperature to enhance the piezoelectric properties of $0.98(Na_{0.5}K_{0.5})NbO_3-0.02Li(Sb_{0.17}Ta_{0.83})O_3$+0.01wt%ZnO (hereafter NKN-LST+ZnO) lead free piezoelectric ceramics. The synthesis and sintering method were the conventional solid state reaction method and sintering was executed at $1,080\sim1,120^{\circ}C$. We found that NKN-LST+ZnO ceramics at optimal sintering temperature showed the improved piezoelectric properties at the optimal sintering temperature. The NKN-LST+ZnO ceramics show good performance with piezoelectric constant $d_{33}$= 153 pC/N sintered at $1,090^{\circ}C$. The results reveal that NKN-LST+ZnO ceramics are promising candidate materials for lead-free piezoelectric application.

• 대한기계학회논문집
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• 제17권1호
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• pp.90-100
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• 1993

본 연구에서는 압전 감지기/작동기를 이용한 복합적층판의 진동제어해석을 위 하여 판요소를 사용한 능률적인 유한요소코드 개발에 있다. 운동방정식은 고전 적층 판이론과 Hamilton의 법칙을 이용하여 유도하며 압전방정식으로부터 전기적-기계적 연 계를 고려한 감지식과 작동식을 구한다.각식들은 유한요소 보간함수에 의하여 절점 변위에 대한 행렬방정식으로 변환된다. 요소마다 하나의 전기적 자유도를 가진 4-절 점 12-자유도 판요소를 사용하여 효율적인 계산을 가능하게 하였다. 압전 감지기/작 동기를 도입함에 있어 하나의 전극에 대해 압전 감지기/작동기는 하나의 감지/작동전 압을 갖는다. 각 요소에 전극번호를 부가함으로써 다양한 형상의 전극을 쉽게 모델 링하였으며 전극의 특성도 충분히 고려하였다. 전기적 하중에 의한 압전보의 변형과 변형에 대한 감지전압에 대한 계산을 수행하여 기존의 연구와 비교함으로써 본 프로그 램의 타당성을 확인하였다. 나아가 여러가지 전극형상에 대한 복합재료 평판의 시간 영역과 주파수영역에서 응답을 계산하였다.

• Structural Engineering and Mechanics
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• 제75권6호
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• pp.747-769
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• 2020

This paper provides a semi-analytical approach to investigate the variations of 3D displacement components, electric potential, stresses, electric displacements and transverse vibration frequencies in laminated piezoelectric composite plates based on the scaled boundary finite element method (SBFEM) and the precise integration algorithm (PIA). The proposed approach can analyze the static and dynamic responses of multilayered piezoelectric plates with any number of laminae, various geometrical shapes, boundary conditions, thickness-to-length ratios and stacking sequences. Only a longitudinal surface of the plate is discretized into 2D elements, which helps to improve the computational efficiency. Comparing with plate theories and other numerical methods, only three displacement components and the electric potential are set as the basic unknown variables and can be represented analytically through the transverse direction. The whole derivation is built upon the three dimensional key equations of elasticity for the piezoelectric materials and no assumptions on the plate kinematics have been taken. By virtue of the equilibrium equations, the constitutive relations and the introduced set of scaled boundary coordinates, three-dimensional governing partial differential equations are converted into the second order ordinary differential matrix equation. Furthermore, aided by the introduced internal nodal force, a first order ordinary differential equation is obtained with its general solution in the form of a matrix exponent. To further improve the accuracy of the matrix exponent in the SBFEM, the PIA is employed to make sure any desired accuracy of the mechanical and electric variables. By virtue of the kinetic energy technique, the global mass matrix of the composite plates constituted by piezoelectric laminae is constructed for the first time based on the SBFEM. Finally, comparisons with the exact solutions and available results are made to confirm the accuracy and effectiveness of the developed methodology. What's more, the effect of boundary conditions, thickness-to-length ratios and stacking sequences of laminae on the distributions of natural frequencies, mechanical and electric fields in laminated piezoelectric composite plates is evaluated.

• 한국세라믹학회지
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• 제52권1호
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• pp.77-82
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• 2015

The effect of the electrode type on the dielectric and piezoelectric properties of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbZrO_3-PbTiO_3$ (PMN-PZT) single crystals was investigated in an effort to improve their properties for various piezoelectric applications. First, three different types of PMN-PZT single crystals [PMN-PZT-A (piezoelectrically soft type; dielectric constant ~ 10,000), PMN-PZT-B (piezoelectrically soft type; phase-transition temperature between the rhombohedral and tetragonal phases ($T_{RT}$) ~ $145^{\circ}C$), PMN-PZT-C (piezoelectrically hard type; high mechanical quality factor ($Q_m$) ~ 1,000)] were fabricated using the solid-state single crystal growth (SSCG) method. Then, four different types of electrodes [sputtered Au, sputtered Cr/Au, sputtered Ti/Au, and fired Ag] were formed on the single crystals, and their dielectric and piezoelectric properties were measured. The single crystals with a sputtered Ti/Au electrode showed the highest dielectric and piezoelectric constants but the lowest coercive electric field ($E_C$). The single crystals with a fired Ag electrode showed the lowest dielectric and piezoelectric constants but the highest coercive electric field ($E_C$). This dependence on the type of electrode was most significant in the piezoelectrically hard PMN-PZT-C single crystals. However, the effects of the electrode type on the phase transition temperatures ($T_C$, $T_{RT}$) and dielectric loss were negligible. These results clearly demonstrate that it is important to select an appropriate electrode so as to maximize the dielectric and piezoelectric properties of single crystals in each type of piezoelectric application.

• 센서학회지
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• 제31권5호
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• pp.312-317
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• 2022

Piezoelectric energy harvesting has attracted increasing attention over the last decade as a means for generating sustainable and long-lasting energy from wasted mechanical energy. To develop self-powered wearable devices, piezoelectric materials should be flexible, stretchable, and bio-eco-friendly. This study proposed the fabrication of stretchable piezoelectric composites via dispersing perovskite-structured BaTiO₃ nanoparticles inside an Ecoflex polymeric matrix. In particular, the stretchable piezoelectric sensor array was fabricated via a simple and cost-effective spin-coating process by exploiting the piezoelectric composite comprising of BaTiO₃ nanoparticles, Ecoflex matrix, and stretchable Ag coated textile electrodes. The fabricated sensor generated an output voltage of ~4.3 V under repeated compressing deformations. Moreover, the piezoelectric sensor array exhibited robust mechanical stability during mechanical pushing of ~5,000 cycles. Finite element method with multiphysics COMSOL simulation program was employed to support the experimental output performance of the fabricated device. Finally, the stretchable piezoelectric sensor array can be used as a self-powered touch sensor that can effectively detect and distinguish mechanical stimuli, such as pressing by a human finger. The fabricated sensor demonstrated potential to be used in a stretchable, lead-free, and scalable piezoelectric sensor array.

• 한국전기전자재료학회논문지
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• 제36권3호
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• pp.214-225
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• 2023

Piezoelectric actuators, which utilize piezoelectric crystals or ceramics, are commonly used in precision positioning applications, offering high-speed response and precise control. However, the use of low-performance ceramics and expensive single crystals is limiting their versatile use in the actuator market, necessitating the development of both high-performance and cost-effective piezoelectric materials capable of delivering higher forces and displacements. The use of textured Pb (lead)-based piezoelectric ceramics formed by so-called templated grain growth method has been identified as a promising strategy to address the performance and cost issue. This review article provides insights into recent advances in texturing Pb-based piezoelectric ceramics for improved performance in actuation applications. We discussed the relevant issues in detail focusing on current challenges and emerging trends in the textured piezoelectric ceramics for their reliability and performance in actuator applications. We discussed in detail focusing on current challenges and emerging trends of textured piezoelectric ceramics for their reliability and performance in actuator applications. In conclusion, the article provides an outlook on the future direction of textured piezoelectric ceramics in actuator applications, highlighting the potential for further success in this field.

• Structural Monitoring and Maintenance
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• 제7권2호
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• pp.85-107
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• 2020

Dynamic responses of porous piezoelectric and metal foam nano-size plates have been examined via a four variables plate formulation. Diverse pore dispersions named uniform, symmetric and asymmetric have been selected. The piezoelectric nano-size plate is subjected to an external electrical voltage. Nonlocal strain gradient theory (NSGT) which includes two scale factors has been utilized to provide size-dependent model of foam nanoplate. The presented plate formulation verifies the shear deformations impacts and it gives fewer number of field components compared to first-order plate model. Hamilton's principle has been utilized for deriving the governing equations. Achieved results by differential quadrature (DQ) method have been verified with those reported in previous studies. The influences of nonlocal factor, strain gradients, electrical voltage, dynamical load frequency and pore type on forced responses of metal and piezoelectric foam nano-size plates have been researched.

• Journal of Mechanical Science and Technology
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• 제18권9호
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• pp.1582-1589
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• 2004

The dynamic response of an eccentric Griffith crack in functionally graded piezoelectric ceramic strip under anti-plane shear impact loading is ana lysed using integral transform method. Laplace transform and Fourier transform are used to reduce the problem to two pairs of dual integral equations, which are then expressed to Fredholm integral equations of the second kind. We assume that the properties of the functionally graded piezoelectric material vary continuously along the thickness. The impermeable crack boundary condition is adopted. Numerical values on the dynamic stress intensity factors are presented for the functionally graded piezoelectric material to show the dependence of the gradient of material properties and electric loadings.

• 전력전자학회논문지
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• 제8권2호
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• pp.180-191
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• 2003

본 논문에서는 압전 변압기와 CCFL 구동회로의 전기적 등가회로에 의한 PSPICE와 모델을 제시하였다. 램프모델은 최소 제곱근을 이용하여 모델의 파라미터들을 유도하였다 이 모델에 대한 확증을 위해 CCFL 구동회로의 단독모델을 가지고 시뮬레이션을 수행한 결과 정확한 모델링이 되었음을 확인하였으며, 압전변압기는 푸시풀 인버터와 부하로써 주로 PSPICE로 모델링한 CCFL을 사용하여 시뮬레이션을 수행한 결과 만족스러운 모델링이 이루어졌음을 알 수 있었다.