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mPW1PW91 Calculated Structures and IR Spectra of the Conformational Stereoisomers of C-Cyanophenyl Pyrogallol[4]arene

  • Ahn, Sangdoo;Park, Tae Jung;Choe, Jong-In
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1323-1328
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    • 2014
  • Molecular structures of the various conformational stereoisomers of 2,8,14,20-cyanophenyl pyrogallol[4]arenes 1 were optimized using the mPW1PW91 (hybrid Hartree-Fock density functional) calculation method. The total electronic and Gibbs free energies and the normal vibrational frequencies of the different structures from three major conformations (CHAIR, TABLE, and 1,2-Alternate) of the four stereoisomers [1(rccc), 1(rcct), 1(rctt), and 1(rtct)] were analyzed. The mPW1PW91/6-31G(d,p) calculations suggested that $1(rcct)_{1,2-A}$, 1(rctt)CHAIR, and $1(rtct)_{CHAIR}$ were the more stable conformations of the respective stereoisomers. Hydrogen bonding is the primary factor for the relative stabilities of the various conformational isomers, and maximizing the ${\pi}-{\pi}$ interaction between the cyanophenyl rings is the secondary factor. The calculated IR spectra of the more stable conformers [$1(rctt)_{CHAIR}$, $1(rcct)_{1,2-A}$, $1(rtct)_{CHAIR}$] were compared with the experimental IR spectrum of $1(rtct)_{CHAIR}$.

Direct UV laser projection ablation to engrave 6㎛-wide patterns in a buildup film (빌드업 필름의 선폭 6㎛급 패턴 가공을 위한 직접식 UV 레이저 프로젝션 애블레이션)

  • Sohn, Hyonkee;Park, Jong-Sig;Jeong, Jeong-Su;Shin, Dong-Sig;Choi, Jiyeon
    • Laser Solutions
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    • v.17 no.3
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    • pp.19-23
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    • 2014
  • To directly engrave circuit-line patterns as wide as $6{\mu}m$ in a buildup film to be used as an IC substrate, we applied a projection ablation technique in which an 8 inch dielectric ($ZrO_2/SiO_2$) mask, a DPSS 355nm laser instead of an excimer laser, a ${\pi}$-shaper and a galvo scanner are used. With the ${\pi}$-shaper and a square aperture, the Gaussian beam from the laser is shaped into a square flap-top beam. The galvo scanner before the $f-{\theta}$ lens moves the flat-top beam ($115{\mu}m{\times}105{\mu}m$) across the 8 inch dielectric mask whose patterned area is $120mm{\times}120mm$. Based on the results of the previous research by the authors, the projection ratio was set at 3:1. Experiments showed that the average width and depth of the engraved patterns are $5.41{\mu}m$ and $7.30{\mu}m$, respectively.

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On Generalized Integral Operator Based on Salagean Operator

  • Al-Kharsani, Huda Abdullah
    • Kyungpook Mathematical Journal
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    • v.48 no.3
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    • pp.359-366
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    • 2008
  • Let A(p) be the class of functions $f\;:\;z^p\;+\;\sum\limits_{j=1}^{\infty}a_jz^{p+j}$ analytic in the open unit disc E. Let, for any integer n > -p, $f_{n+p-1}(z)\;=\;z^p+\sum\limits_{j=1}^{\infty}(p+j)^{n+p-1}z^{p+j}$. We define $f_{n+p-1}^{(-1)}(z)$ by using convolution * as $f_{n+p-1}\;*\;f_{n+p-1}^{-1}=\frac{z^p}{(1-z)^{n+p}$. A function p, analytic in E with p(0) = 1, is in the class $P_k(\rho)$ if ${\int}_0^{2\pi}\|\frac{Re\;p(z)-\rho}{p-\rho}\|\;d\theta\;\leq\;k{\pi}$, where $z=re^{i\theta}$, $k\;\geq\;2$ and $0\;{\leq}\;\rho\;{\leq}\;p$. We use the class $P_k(\rho)$ to introduce a new class of multivalent analytic functions and define an integral operator $L_{n+p-1}(f)\;\;=\;f_{n+p-1}^{-1}\;*\;f$ for f(z) belonging to this class. We derive some interesting properties of this generalized integral operator which include inclusion results and radius problems.

Backstepping Control for Multi-Machine Web Winding System

  • Bouchiba, Bousmaha;Hazzab, Abdeldjebar;Glaoui, Hachemi;Med-Karim, Fellah;Bousserhane, Ismail Khalil;Sicard, Pierre
    • Journal of Electrical Engineering and Technology
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    • v.6 no.1
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    • pp.59-66
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    • 2011
  • This work treat the modeling and simulation of non-linear dynamic behavior of a web winding process during traction. We designate by a winding process any system applying the cycles of unwinding, transport, treatment, and winding to various flat products. This system knows several constraints, such as the thermal effects caused by the frictions, and the mechanical effects provoked by metal elongation, that generates dysfunctions due to the influence of the process conditions. Several controllers are considered, including Proportional-integral (PI) and Backstepping control. This paper presents the study of Backstepping controls strategy of the winding system. Our winding system is simulated in MATLAB SIMULINK environment, the results obtained illustrate the efficiency of the proposed control with no overshoot, and the rising time is improved with good disturbances rejections comparing with the classical control law.

Complex Vector Current Control of Grid Connected Inverter Robust for Inductance Variation (인덕턴스 변화에 강인한 계통연계형 인버터의 복소 벡터 전류제어기)

  • Lee, Taejin;Jo, Jongmin;Shin, Changhoon;Cha, Hanju
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.10
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    • pp.1648-1654
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    • 2016
  • This paper analyzes complex vector current control for the enhanced cross-coupling compensation in accordance with parameter variation in grid-connected inverter system, and verifies through simulation and experiment. Complex vector current control is performed in the synchronous reference frame through d-q transformation. It generates cross-coupling components with rotating nominal angular frequency. In general, cross-coupling elements are compensated by decoupling terms added to output of conventional decoupling PI controller. But, it is impossible to compensate them perfectly which transient response is especially deteriorated such as large overshoot and slow tracking, when variation of grid impedance or measurement error occurs. However, complex vector current control can improve stability and response characteristic of current control regardless of the situation as before. Decoupling controller and complex vector controller are represented through complex forms, and these controllers are analyzed by using frequency response in s-domain, respectively. It is verified that complex vector controller has more superior response characteristic than decoupling controller through MATALB, PSIM and experimental in 5kW grid-connected inverter when L filter parameter is varied from 1.1mH to increase double, 2.2mH.

A Study on 120Hz Output Voltage Ripple Reduction of LLC Converter using Resonant Controller (공진 제어기를 이용한 LLC 컨버터의 출력전압 120Hz 맥동저감에 관한 연구)

  • So, Byong-Chul;Lee, Sang-Ri;Kim, Hag-Wone;Cho, Kwan-Yuhl;Hwang, Soon-Sang;Choi, Eun-Seok
    • The Transactions of the Korean Institute of Power Electronics
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    • v.17 no.4
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    • pp.345-352
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    • 2012
  • This paper proposes a new method to reduce 120Hz output voltage ripple of LLC converter using resonant voltage controller. This method can reduce the 120Hz output voltage ripple with very high gain at this frequency by the resonant controller with previous PI voltage controller. The reason why the voltage ripple can be reduced is explained by the Bode diagram comparing with the previous PI controller. The simulation with Matlab/Simulink is carried out for this resonant controller and the simulation results show that resonant controller can reduce the 120Hz output voltage ripple. Experiments with DSP controller also carried out and the experimental results also show that the usefulness of the proposed voltage controller.

Anaysis of the photoelastic of CR lens using circular polariscope (원편광기를 이용한 CR 렌즈의 광 탄성 해석 연구)

  • Kim, Yong-Geun
    • Journal of Korean Ophthalmic Optics Society
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    • v.6 no.2
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    • pp.11-16
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    • 2001
  • The polariscope to measure :he stress in lens was made up quarter-wave plate polarizer and we analyzed two components of light's wave $E_1$ and $E_2$ following the steps. It is clear that the principal-stress difference ${\sigma}_1-{\sigma}_2$ can be determined in 2-D model if fringe order N is measured each point in sample moreover. the optical axes of sample coincide with the principal-stress directions. The birefringence acted to a light wave and a phase retardation were in proportioned to the principal-stressed difference (${\sigma}_1-{\sigma}_2$) and the intensity of final light wave was proportioned to $sin^2({\Delta}/2)$, when ${\Delta}/2=n^{\pi}$ (n=0, 1, 2, ...) and the extinction occurs. As a experimental result, the extinction band shifted owing to a magnitude of lens' external stress.

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Load compensation and Speed Controller for Hydraulic Inverter-fed Elevator (유압 인버터 엘리베이터를 위한 부하 보상 및 속도 제어기)

  • Han, Sang-Soo
    • Journal of the Institute of Electronics and Information Engineers
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    • v.51 no.2
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    • pp.163-167
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    • 2014
  • To prove the vibration and speed error problems caused by the nonlinear friction characteristics and load variation of the hydraulic system, a PID speed controller and a load compensation controller for the hydraulic inverter-fed elevator are proposed. The load compensation controller is composed by the PI controller and the speed controller is composed by the PID controller. The P,I and D gains of the control parameters are obtained by the frequency response of system transfer function. The Effectiveness of the proposed controller are shown by experimental results, which the proposed controller yields robustness with load variations and stable and good speed and acceleration responses with less oscillations.

Physicochyemical Properties of $ZrF_4-Based$ Fluoride Glasses Containing Rare-Earth Ions

  • Ishioka, Noriyuki;Ogawa, Kouji;Arakawa, Tsuyoshi
    • The Korean Journal of Ceramics
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    • v.5 no.4
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    • pp.375-378
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    • 1999
  • In tho XRD study of $56ZrF_4 \cdot34BaF_2 \cdot4AIF_3 \cdot(6-x)LaF_3 \cdotxLnF_3$ glassdLn=Ce, Nd, Gd, Th), halo pattern charactarktic fo an amorphous sample appeared. When the halo peak angle ($\theta_p$) was converted into a wavenumber with $Qp=4\pi sinG\pi/\lambda(\lambda$ is the wavolongth of the radialion used), it was found that the Qp values varied almost liuearly with the concentration 01 $LnF_3$. The emissiou spect1.a of $Ce^{3-}$-containing fluoride glasses nnder 273 nm excitation had a peak maximum at ea. 300 nm $(Ce^{3+}$ 5d-4f- transition). The maximal intensity of the fluorescence was observed when the $CeF_3$, content was extremely low (ca. 1 mol%j. DTA measurement revealed tbat these fluoride glasses had two crystallization temperatures. In $56ZrF_4. 34BaF_2. 4NF_3. (6-x)LaF_3 .xNdF_3$ glasses, the actmation energies of crystallization obtained from a Kssinger plot were 1.7 and 5.0 eV for the glass with x=2, and 1.9 and 5.6 eV for the glass with x=4.

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High Speed and Robust Control System with Deadbeat Disturbance Observer for 3D Eye Imaging Equipment (망막의 3차원 영상화를 위한 데드비트 외란 관측기를 가진 고속, 고강성 제어 시스템)

  • 고종선;이태훈;김영일
    • The Transactions of the Korean Institute of Power Electronics
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    • v.8 no.5
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    • pp.418-426
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    • 2003
  • To show a retina shape and thickness on the computer monitor, a laser has been used in Scanning Laser Ophthalmoscope(SLO) equipment using the traveling difference. This method requires exact synchronous control of laser traveling in optic system to show a clear 3-dimensional image of retina To obtain this image, this exact synchronism is very important for making the perfect plane scanning. In this study, a high speed and synchronous control of the galvanometer to make 3-dimensional retina image is presented. For the more, deadbeat load torque observer is added to the PI controller for compensation of the position error arisen in the high speed control. As a result, the proposed control system has a robust and precise response against the load torque variation appeared in high speed control. A stability and usefulness are verified by the computer simulation and the experiment.