• Title/Summary/Keyword: Physical stability

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The Study on the Structure and Energy State of Potassium-Graphite Intercalation Compounds (칼륨-흑연 층간화합물의 구조와 에너지 상태에 관한 연구)

  • 오원춘;백대진;고영신
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.3 no.1
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    • pp.66-74
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    • 1993
  • Potassium-Graphite Intercalation Compounds(K-GICs) have been prepared from purified natural graphite by transformed two-bulb method with variations of reaction temperature ($T_g:450^{\circ}C$, $400^{\circ}C$, $350^{\circ}C$, $300^{\circ}C$, $250^{\circ}C$).Prepared K-GICs were identified to stage transition process by X-ray diffraction data. At these results, d values of (00l) diffraction at 1 stage and 2 stage were corresponded to $5.35\AA$ and $8.73\AA$ respectively. The stage stability and energy states of K-GlCs were obtained by UV /VIS Spectrophotometric data. We found that the minimum value of reflectance was 2.67 eV(465nm) at $250^{\circ}C$and it's moved to higher energy than original graphite's. And X-ray diffraction and UV /VIS spectrophotometric datas suggest that K-GICs were formed lower stage and many charge carriers exist between C atoms of graphite. And then, these results also provide informations on the electrical and other physical properities of K-GICs.Especially, according to studied reports, d values differ from them of each author, but accurate values were established through this study.

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Measurement of an Isoelectric Point and Softness of a EO-PO Adducted Zwitterionic Surfactant (EO-PO가 부가된 양쪽성 계면활성제의 등전점 및 유연력 측정에 관한 연구)

  • Lim, JongChoo;Mo, DaHee;Lee, JinSun;Park, JunSeok;Han, DongSung
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.455-463
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    • 2012
  • In this study, the measurement of physical properties of ethylene oxide-propylene oxide adducted zwitterionic surfactants were measured such as critical micelle concentration, surface tension, interfacial tension, contact angle, viscosity and foam stability. Also, the dual function characteristics of a zwitterionic surfactant were investigated by determining an isoelectric point, which were obtained using zeta potential measurement and QCM (quartz crystal microbalance) experiments. The isoelectric point of DEP-OSA82-AO zwitterionic surfactant determined by zeta potential measurement was close to that obtained by QCM experiment and both results have shown almost the same trend as that determined by the frictional property measured using an automated mildness tester. In particular, it has been observed that DEP32-OSA82-AO and DEP34-OSA82-AO surfactants provide better softening effect at a pH of acidic or neutral condition than at an alkaline condition. This result indicates that both surfactants act as a cationic surfactant at a pH of acidic or neutral condition and thus provide good softening effect during a rinsing cycle in the detergency process.

Effects of pH and Temperature on the Adsorption of Cationic Dyes from Aqueous Suspension by Maghnia Montmorillonite (수용액으로부터 양이온 염료 흡수에 대한 pH 및 온도 효과)

  • Elaziouti, A.;Laouedj, N.
    • Journal of the Korean Chemical Society
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    • v.55 no.2
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    • pp.208-217
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    • 2011
  • The effects of pH and temperature on the removal of two dyes (neutral red; NR and malachite green oxalates; MG) from aqueous effluents using Maghnia montmorillonite clay in a batch adsorption process were investigated. The results showed the stability of the optical properties of MG in aqueous solution and adsorbed onto clay under wide range of pH 3-9. However, the interaction of NR dye with clay is accompanied by a red shift of the main absorption bands of monomer cations under pH range of 3-5, whereas, those of neutral form remains nearly constant over the pH range of 8-12. The optimal pH for favorable adsorption of the dyes, i.e. ${\geq}$90% has been achieved in aqueous solutions at 6 and 7 for NR and VM respectively. The most suitable adsorption temperatures were 298 and 318 K with maximum adsorption capacities of 465.13mg/g for NR and 459.89 mg/g for MG. The adsorption equilibrium results for both dyes follow Langmuir, Freundlich isotherms. The numerical values of the mean free energy $E_a$ of 4.472-5.559 kj/mol and 2.000-2.886 kj/mol for NR and MG respectively indicated physical adsorption. Various thermodynamic parameters, such as ${\Delta}H^{\circ}$, ${\Delta}S^{\circ}$, ${\Delta}G^{\circ}$ and Ea have been calculated. The data showed that the adsorption process is spontaneous and endothermic. The sticking probability model was further used to assess the potential feasibility of the clay mineral as an alternative adsorbent for organic ion pollutants in aqueous solution.

Thermal Analysis of Vegetable Insulation Oil for Hermetically Sealed Wind Turbine Transformer (풍력발전기용 밀폐형 변압기의 식물성 절연유에 대한 열적특성 연구)

  • Lee, Sung-Won;Lee, Joon-Yeob;Kim, Jun-Su;Woo, Jae-Hi;Kim, Dong-Hae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.1
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    • pp.97-102
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    • 2012
  • A hermetically sealed oil transformer is designed by applying expanding function of the tank due to the volume changes of the insulation oil according to the temperature rises. When the insulation oil expands, an increase in the volume of the corrugated fin prevents a pressure rise of the transformer. For a wind turbine transformer, a vegetable-oil-immersed transformer has the advantages of excellent biodegradation and fire-resistant properties like an exceptionally high fire point. When vegetable oil is substituted for mineral oil, however, the maximum winding temperature rises because of the decrease in the internal circulation flow rate resulting from the variations of the oil's physical characteristics, such as density and viscosity. The purpose of this study is to develop a hermetically sealed vegetable oil transformer that can be applied in a wind turbine and to analyze the thermal stability of the active part of the transformer to deal with pressure variations due to the temperature changes. In addition, thermal tests for the vegetable oil transformer have been performed, and the measured values are compared with the analysis results.

Three Dimensional Implementation of Intelligent Transportation System Radio Frequency Module Packages with Pad Area Array (PAA(Pad Area Array)을 이용한 ITS RF 모듈의 3차원적 패키지 구현)

  • Jee, Yong;Park, Sung-Joo;Kim, Dong-Yong
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.38 no.1
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    • pp.13-22
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    • 2001
  • This paper presents three dimensional structure of RF packages and the improvement effect of its electrical characteristics when implementing RF transceivers. We divided RF modules into several subunits following each subunit function based on the partitioning algorithm which suggests a method of three dimension stacking interconnection, PAA(pad area array) interconnection and stacking of three dimensional RF package structures. 224MHz ITS(Intelligent Transportation System) RF module subdivided into subunits of functional blocks of a receiver(RX), a transmitter(TX), a phase locked loop(PLL) and power(PWR) unit, simultaneously meeting the requirements of impedance characteristic and system stability. Each sub­functional unit has its own frequency region of 224MHz, 21.4MHz, and 450KHz~DC. The signal gain of receiver and transmitter unit showed 18.9㏈, 23.9㏈. PLL and PWR modules also provided stable phase locking, constant voltages which agree with design specifications and maximize their characteristics. The RF module of three dimension stacking structure showed $48cm^3$, 76.9% reduction in volume and 4.8cm, 28.4% in net length, 41.8$^{\circ}C$, 37% in maximum operating temperature, respectively. We have found that three dimensional PAA package structure is able to produce high speed, high density, low power characteristics and to improve its functional characteristics by subdividing RF modules according to the subunit function and the operating frequency, and the features of physical volume, electrical characteristics, and thermal conditions compared to two dimensional RF circuit modules.

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Study of Mechanical Characteristics of Electric Cupping Apparatus in Korea for Suggestion of its Assessment Guideline (국내 평가 가이드 라인 제시를 위한 전동식 부항기의 특성 조사에 관한 연구)

  • Yi, Seung-Ho;Kim, Eun-Jung;Shin, Kyung-Hoon;Nam, Dong-Woo;Kang, Jung-Won;Lee, Seung-Deok;Lee, Hye-Jung;Lee, Jae-Dong;Kim, Kap-Sung
    • Journal of Acupuncture Research
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    • v.27 no.1
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    • pp.1-10
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    • 2010
  • Objectives : The mechanical properties of Korean electric cupping systems are studied via experimental measurements. The study aimed at establishing the fundamentals of industrialization and systemization of oriental medicine device industry, as well as improving the quality of life for many Koreans. Methods : We reviewed the studies on traditional cupping as well as modern one to fine necessary factors for electric cupping systems. To characterize the mechanical properties of Korean electric cupping systems, we measured the pressure characteristics of commercially available electric cupping system by using an automatic pressure acquisition system and a standard cup. The pumping capability was checked at 40 seconds, and the stability of the suction cup was checked at 600 seconds. We also acquired the noise level of each system in clinical setting. To check the portability of each system, we also measured its physical dimensions. We scrutinized system manuals provided by the system manufacturers. Results : It took less than 5 second to reach the pressure if the connection between the air hose and the vacuum valve of the cupping system was secure. Pressure diminished to no more than 10% for 600s for all systems. Noise levels were 55~70 dB. Increase in pressure was too fast to control for a designated vacuum level except for one product. Conclusions : The Pumping ability of the systems is impressive and reliable. Pressure retention ability of each cup is quite reliable and reproducible. Therefore, their mechanical performances were worthy of recommendation. Some of them had noise level higher than 60 dB and they were bothersome. It was also suggested that the control for low to middle pressure needed to be accomplished by the cupping system.

Direct Growth of CNT on Cu Foils for Conductivity Enhancement and Their Field Emission Property Characterization (전도성 향상을 위한 구리호일 위 CNT의 직접성장 및 전계방출 특성 평가)

  • Kim, J.J.;Lim, S.T.;Kim, G.H.;Jeong, G.H.
    • Journal of the Korean Vacuum Society
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    • v.20 no.2
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    • pp.155-163
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    • 2011
  • Carbon nanotubes (CNT) have been attracted much attention since they have been expected to be used in various areas by virtue of their outstanding physical, electrical, and chemical properties. In order to make full use of their prominent electric conductivity in some areas such as electron emission sources, device interconnects, and electrodes in energy storage devices, direct growth of CNT with vertical alignment is definitely beneficial issue because they can maintain mechanical stability and high conductivity at the interface between substrates. Here, we report direct growth of vertically aligned CNT (VCNT) on Cu foils using thermal chemical vapor deposition and characterize the field emission property of the VCNT. The VCNT's height was controlled by changing the growth temperature, growth time, and catalytic layer thickness. Optimum growth condition was found to be $800^{\circ}C$ for 20 min with acetylene and hydrogen mixtures on Fe catalytic layer of 1 nm thick. The diameter of VCNT grown was smaller than that of usual multi walled CNT. Based on the result of field emission characterization, we concluded that the VCNT on Cu foils can be useful in various potential applications where high conductivity through the interface between CNT and substrate is required.

Synthesis and Characterization of PPC/Organo-Clay Nanohybrid: Influence of Organically Modified Layered Silicates on Thermal and Water Absorption Properties (PPC와 Organo-Clay 나노 조성물의 합성과 실리카층의 수분흡수와 열적특성에 대한 영향)

  • Han, Hak-Soo;Khan, Sher Bahadar;Seo, Jong-Chul;Jang, Eui-Sung;Choi, Joon-Suk;Choi, Seung-Hyuk
    • Membrane Journal
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    • v.19 no.4
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    • pp.341-347
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    • 2009
  • Nanohybrid based on environmentally friendly and biodegradable polymer, poly propylene carbonate (PPC) and cloisite 20B (PPC/C-20B) have been synthesized by solution blending method and their morphology, thermal and water absorption properties have been evaluated. The structure of PPC/C-20B nanohybrid was confirmed by X-ray diffraction (XRD). The thermal property of PPC and PPC/C-20B nanohybrid were investigated by thermal gravimetric analysis (TGA) and differential scanning calorimetric (DSC). The experimental results demonstrated that nanohybrid showed the highest thermal stability in TGA and DSC. TGA tests revealed that the thermal decomposition temperature ($T_{d50%}$) of the nanohybrid increased significantly, being $23^{\circ}C$ higher than that of pure PPC while DSC measurements indicated that the introduction of 5 mass% of clay increased the glass transition temperature from 21 to $30^{\circ}C$. Further the water absorption capacity of the PPC was significantly decreased by the incorporation of clay. Water absorption cause degradation of the coating by the moistures and affect the physical and mechanical performance. This result indicates that organic modifiers have effect on thermal and water absorption capacity of PPC and are of importance for the practical process and application of PPC.

Evaluation of Deformation Characteristics and Vulnerable Parts according to Loading on Compound Behavior Connector (복합거동연결체의 하중재하에 따른 변형 특성 및 취약부위 산정)

  • Kim, Ki-Sung;Kim, Dong-wook;Ahn, Jun-hyuk
    • Journal of the Society of Disaster Information
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    • v.15 no.4
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    • pp.524-530
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    • 2019
  • Purpose: In this paper, we construct a detailed three-dimensional interface element using a three-dimensional analysis program, and evaluate the composite behavior stability of the connector by applying physical properties such as the characteristics of general members and those of reinforced members Method: The analytical model uses solid elements, including non-linear material behavior, to complete the modeling of beam structures, circular flanges, bolting systems, etc. to the same dimensions as the design drawing, with each member assembled into one composite behavior linkage. In order to more effectively control the uniformity and mesh generation of other element type contact surfaces, the partitioning was performed. Modeled with 50 carbon steel materials. Results: It shows the displacement, deformation, and stress state of each load stage by the contact adjoining part, load loading part, fixed end part, and vulnerable anticipated part by member, and after displacement, deformation, The effect of the stress distribution was verified and the validity of the design was verified. Conclusion: Therefore, if the design support of the micro pile is determined based on this result, it is possible to identify the Vulnerable Parts of the composite behavior connector and the degree of reinforcement.

A Fundamental Study on Village Planning in the Reclaimed Area -A Case Study of Farming Villages in Deuk Ryang Reclaimed Area- (간척지 농촌취락계획을 위한 기초연구 -전남 보성군 득량간척지 농촌취락의 사례연구-)

  • 최수영;이원철;한경수;황한철
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.35 no.2
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    • pp.33-42
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    • 1993
  • In order to obtain the basic information for the optimal settlement planning in the reclaimed area, various existing settlement conditions on reclaimed farming village were analysed through a case study of in-and-round farming villages in Deuk Ryang Reclaimed Area. By comparison study between in-and-around villages, the allocation policy of farming settlement in the samll and medium scale area was proposed. The results obtained in this study were as follows ; 1.The population structure of the inner village(Ansim village) had become worse than the around village during 1976~1981 period from the viewpoint of total and female emigration ratios. Especially, the originally unbalanced sex ratio of Ansim village had worsen to the unacceptable ratio of 1.5 : 1(male : female). Therefore, the structural stability of the population should be carefully improved in the newly reclaimed farming villages by the systematic long-term controlling machanism.2.The farming status of Ansim village was much lower than the around villages viewing of the cultivated acreage and agricultural machinery stock Therefore, the continuous and intensive governmental support different from the existing farming area should be required for the settling of reclaimed farming. 3. The regularity of the village site as a planned village, though pursed in the first phase of village construction, had been severely disturbed inflowing of squatters. Recently, there are increasing vaccant houses in the village, and the level of living amenities and personal mobility of Ansim village are much lower than the around village. So, now, the physical structure of the village should be improved to the level of village reconstruction or new village construction. 4. The cultivated area of Ansim village leans to the south side which would be unfavoured by the farmers of the around villages, while its distributing pattern should be concentric around the village site. This phenomenon disturbs the central fuction of the planned farming village. In this respect, role assignment, relationship and balance of competence in farming activities should be planned between in-and-around villages in the reclaimed area from the initial stage. 5. Putting together the above results in this study, the farming and living conditions of Ansim village threaten its existence as a planned new farming village in the reclaimed area. And, so, the full scale reconstruction of village structure, including moving to the new site, should be designed as soon as possible. Although further many studies should be carried out, it would be sure that the new village planning should be reconsidered in the small and-medium scale reclamation works.

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