• Title/Summary/Keyword: Physical separation

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토양 유기물 분리 처리 방법이 비친수성 오염물질 흡착에 미치는 영향

  • Jeong Sang-Jo
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.42-45
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    • 2005
  • Accurate prediction of the fate and transport of contaminants in soils and sediments is very Important to environmental risk assessment and effective remediation of contaminated soils and sediments. The fate and transport of contaminants in subsurface are affected by geosorbents, especially carbonaceous materials including black carbon. Various physical and chemical treatment methods have been developed to separate different kinds of carbonaceous materials from soils and sediments. However, the effects of these separation methods on the properties of remaining carbonaceous materials including sorption capacity and linearity are unclear. The objective of this study is to determine if the chemical and thermal treatment methods previously used to separate different carbonaceous material fractions affect the properties of carbonaceous materials including longer term sorption capacity of hydrophobic organic contaminants. The results indicate that treatments with hydrochloric acid (HCl)/hydrofluoric acid (HF), trifluoroacetic acid (TFA), sodium hydroxide (NaOH) may not affect the sorption capacity of black carbon reference materials such as char and soot, however, treatments with acid dichromate $(K_2Cr_2O_7/H_2SO_4)$ and heat $(375^{\circ}C)$ for 24 hours in sufficient of oxygen) decrease the sorption capacity of them. The results of longer term sorption isotherm indicate that 2 days might be enough for trichloroethene (TCE) to equilibrate apparently with treated black carbon reference materials. The results suggest that acid dichromate and heat treatments may not appropriate method to investigate sorption properties of black carbon in soils and sediments.

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Effect of Dissolved and Colloidal Contaminants of Newsprint Machine White Water on Water Surface Tension and Paper Physical Properties

  • Consultant, Seika-Tay
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.61-69
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    • 1999
  • Contaminants such as fatty acids, triglycerides, resin acids and foam collected from a high yield sulfite weak liquor storage tank lowered the water surface tension and reduced inter-fibre bonding but also tended to benefit sheet opacity. Some common wet end additives such as defoamers and dispersants gave similar results. Lignosulfonate and naphthalene sulfonate showed little if any negative effect on both surface tension and sheet strength properties. Among the natural wood extractives. fatty acids were identified to be most detrimental followed by triglycerides and then resin acids. In order to alleviate the detrimental impact of these contaminants, membrane separation, air floatation and ozone treatment were carried out on paper machine white water samples. The effect of these treatments on removal of fatty and resin acids was quantified by a GC-Mass analysis. Reverse osmosis with a 1000 molecular weight cut off membrane failed to totally reject fatty and resin acids, but markedly reduced losses of sheet properties due to contaminants. Ozone treatment resulted in a significant increase of the surface tension and air floatation was considered to be a practical and useful method for removing fatty and resin acids from the machine white water.

Flow-induced Vibration(FIV) Analysis of a 3D Axial Compressor Blade (3차원 축류압축기 블레이드의 유체유발진동 해석)

  • Kim, Dong-Hyun;Kim, Yu-Sung;Yang, Guo Wei;Jung, Kyu-Kang;Kim, Kyung-Hee;Min, Dae-Gee
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.19 no.6
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    • pp.551-559
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    • 2009
  • In this study, flow-induced vibration(FIV) analyses have been conducted for a 3D compressor blade model. Advanced computational analysis system based on computational fluid dynamics(CFD) and computational structural dynamics(CSD) has been developed in order to investigate detailed dynamic responses of designed compressor blades. Fluid domains are modeled using the computational grid system with local grid deforming and remeshing techniques. Reynolds-averaged Navier-Stokes equations with $\kappa-\epsilon$ turbulence model are solved for unsteady flow problems of the rotating compressor model. A fully implicit time marching scheme based on the Newmark direct integration method is used for computing the coupled aeroelastic governing equations of the 3D compressor blade for fluid-structure interaction(FSI) problems. Detailed dynamic responses and instantaneous pressure contours on the blade surfaces considering flow-separation effects are presented to show the multi-physical phenomenon of the rotating compressor blade.

Research and Development Trend of Pertraction Process using Membrane (분리막을 이용한 투과추출공정의 연구와 개발 동향)

  • Kim, Deuk Ju;Choi, Whee Moon;Nam, Sang Yong
    • Membrane Journal
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    • v.22 no.6
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    • pp.381-394
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    • 2012
  • Recently, a variety of chemical and physical methods are employed to separate ionic materials from complex aqueous. Most of all, membrane pertraction using contactor has been considered as alternative recovery and separation system in field of chemical, petrochemical and medicines because heavy metals, hydrocarbon based materials in contaminants like wastewater can be recovered by pertraction system. Also, pertraction process has characteristics such as ease of operation, lower energy consumption and operational cost, higher selectivity. This work investigates some example of developed membrane and their performance for the application of pertraction process.

IMPURITY SEGREGATION ON CRACKED GRAIN BOUNDARIES IN LLCC SOLDER JOINTS DURING THERMAL CYCLING (온도 변화에 지배되는 LLCC Solder접합부에서 균열이 일어난 계면에 대한 불순물 편석)

  • Lee, Seong-Min
    • Korean Journal of Materials Research
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    • v.4 no.3
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    • pp.329-333
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    • 1994
  • A large number of grain boundaries were seen to crack in near-eutectic solder joints of leadless ceramic chip carriers (LLCC's) during thermal cycling at temperature ranges from -$35^{\circ}C$ to +$125^{\circ}C$ with lhr time period. One potential explanation for this type of cracking might be the presence of embrittling species on the boundary. Although there do not appear to be any instances reported in the literature of solders being embrittled by small amounts of contaminating species, the possibility of such an occurrence exists. The potential presence of impurities located at crack surfaces was inspected using Scanning Auger Microprobe(SAM) and it was found that intergranular cracking could be accomplished by the oxidation of the grain boundary. A physical model for fatigue crack growth was introduced, in which grain boundary separation took place under oxidation facilitated by sliding.

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Effect of Soft Segment Length on the Dispersion and Physical Properties of Polyurethane Ionomer (Soft Segment 길이가 Polyurethane Ionomer의 분산특성 및 물리적 특성에 미치는 영향)

  • Kim, Byung Kyu
    • Textile Coloration and Finishing
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    • v.5 no.4
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    • pp.60-66
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    • 1993
  • Aqueous polyurethane(PU) anionomer dispersions were prepared from isophorone diisocyanate (IPDI), polytetramethylene adipate glycol(PTAd) and dimethylol propionic acid(DMPA) as potential anionic centers. The effects of polyol molecular weight(Mn) on the state of dispersion, thermal, mechanical, and viscoelastic properties and swelling of emulsion cast film were determined. With increasing Mn of PTAd, particle size of emulsion and soft segment T$_{g}$ decreased, and solvent swell, emulsion viscosity, and hard segment $T_{g}$ increased. Tensile strength showed minimum with PTAd 1000, and elongation at break generally increased with the Mn of PTAd. These results were possibly nterpreted in terms of soft segment-hard segment phase separation and crystallization of high molecular weight PTAd.

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Skeletal Changes Following Application of RME at Different Maturation Stages (골격적 성숙도의 차이에 따라 RME 사용시 나타나는 상악골 복합체의 변화)

  • Han, Soon-Ki;Chung, Dong-Hwa;Cha, Kyung-Suk
    • Journal of Dental Rehabilitation and Applied Science
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    • v.23 no.4
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    • pp.373-384
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    • 2007
  • The purpose of this study was to analyse the stress distribution on the craniofacial suture and cranium after application of RME. Twelve years and six months old boy and twenty years old adult male were chosen for taking computed-tomography for FEM. From DICOM visual information, it was processed by 3-dimensional image construction program Mimics 10.01. Hounsfield unit(HU) which shows gray scale of CT image is picked for revealing mechanical properties of each model. The models have been accomplished with various range of physical properties. After applying 5.0 mm expansion, the maxillary complex model was obeserved for analyzing displacement and stress distribution of the model. The amount of transverse expansion of child and adult maxilla is different according to its location. It appears that it decreases gradually with the distance from separation site. In child, maximum compressive stress located broad area in zygomatic buttress department and the ends of frontal process of maxilla, pterygoid plate, and bones surrounding orbit. However, in adult maximum compressive stress was located smaller area and the stres was higher than child.

Rectangular prism pressure coherence by modified Morlet continuous wavelet transform

  • Le, Thai-Hoa;Caracoglia, Luca
    • Wind and Structures
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    • v.20 no.5
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    • pp.661-682
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    • 2015
  • This study investigates the use of time-frequency coherence analysis for detecting and evaluating coherent "structures" of surface pressures and wind turbulence components, simultaneously on the time-frequency plane. The continuous wavelet transform-based coherence is employed in this time-frequency examination since it enables multi-resolution analysis of non-stationary signals. The wavelet coherence quantity is used to identify highly coherent "events" and the "coherent structure" of both wind turbulence components and surface pressures on rectangular prisms, which are measured experimentally. The study also examines, by proposing a "modified" complex Morlet wavelet function, the influence of the time-frequency resolution and wavelet parameters (i.e., central frequency and bandwidth) on the wavelet coherence of the surface pressures. It is found that the time-frequency resolution may significantly affect the accuracy of the time-frequency coherence; the selection of the central frequency in the modified complex Morlet wavelet is the key parameter for the time-frequency resolution analysis. Furthermore, the concepts of time-averaged wavelet coherence and wavelet coherence ridge are used to better investigate the time-frequency coherence, the coherently dominant events and the time-varying coherence distribution. Experimental data derived from physical measurements of turbulent flow and surface pressures on rectangular prisms with slenderness ratios B/D=1:1 and B/D=5:1, are analyzed.

INVESTIGATION ON EFFECTS OF ENLARGED PIPE RUPTURE SIZE AND AIR PENETRATION TIMING IN REAL-SCALE EXPERIMENT OF SIPHON BREAKER

  • Kang, Soon Ho;Lee, Kwon-Yeong;Lee, Gi Cheol;Kim, Seong Hoon;Chi, Dae Young;Seo, Kyoungwoo;Yoon, Juhyeon;Kim, Moo Hwan;Park, Hyun Sun
    • Nuclear Engineering and Technology
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    • v.46 no.6
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    • pp.817-824
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    • 2014
  • To ensure the safety of research reactors, the water level must be maintained above the required height. When a pipe ruptures, the siphon phenomenon causes continuous loss of coolant until the hydraulic head is removed. To protect the reactor core from this kind of accident, a siphon breaker has been suggested as a passive safety device. This study mainly focused on two variables: the size of the pipe rupture and the timing of air entrainment. In this study, the size of the pipe rupture was increased to the guillotine break case. There was a region in which a larger pipe rupture did not need a larger siphon breaker, and the water flow rate was related to the size of the pipe rupture and affected the residual water quantity. The timing of air entrainment was predicted to influence residual water level. However, the residual water level was not affected by the timing of air entrainment. The experimental cases, which showed the characteristic of partical sweep-out mode in the separation of siphon breaking phenomenon [2], showed almost same trend of physical properties.

Preparation of Silicone Polymeric Membrane and Removal of Chlorinated Organic Compounds by Pervaporation (실리콘계 고분자막의 제조와 투과증발법에 의한 유기염소계 화합물 제거)

  • 백귀찬;이용택;김용옥
    • Membrane Journal
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    • v.9 no.2
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    • pp.114-125
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    • 1999
  • Dense polymer membranes were made from vanous silicone polymers such as poly(1-trimethylsilyl-1-propyneHPTMSP), poly(dimethylsiloxaneHPDMS), PTMSP- g-PDMS. These membranes were evaluated in terms of the removal of chlorinated organic hydrocarbons such as chloroform, trichloroethylene(TCE), perchloroethylene(PCE) from water by pervaporation. It was possible for membranes used in this study to remove PCE selectively which is dissolved small quantity in water among other separable solutes. PTMSP membranes exhibited a remarkable decay in permeability with time because of the free volume decreases. However, PTMSP-g-PDMS membrane underwent no physical aging and showed the stable flux behavior. From the results of the contact angle measurement, polymeric membranes used in this study showed affinity with solutes for separation and no affinity with water. The relative swelling degree was directly related to the selectivity, while it has no influence on the flux.

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