• Elastomers and Composites
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• v.49 no.4
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• pp.313-322
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• 2014

Among many types of flame retardants, the most available halogen-containing flame retardants were put under environmental restrictions in their use, so non-halogen type phosphorus-based flame retardants have come into the spotlight. When added to resins, flame retardants commonly bring about thermal degradation and decrease in mechanical properties of resins. Studies of new flame retardants were carried out in an attempt to minimize degradation of physical properties and require enough flame retardancy. In this study, three types of non-halogen phosphorus-based flame retardants were synthesized with diaryl alkyl phosphate esters, aromatic phosphate esters and phosphonium nitron flame retardants, which were then identified for the synthesis and thermal properties by gas chromatography (GC), IR and thermal gravimetric analysis (TGA).

• ETRI Journal
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• v.38 no.1
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• pp.70-80
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• 2016

This paper addresses the problem of robust waveform design for distributed multiple-radar systems (DMRSs) based on low probability of intercept (LPI), where signal-to-interference-plus-noise ratio (SINR) and mutual information (MI) are utilized as the metrics for target detection and information extraction, respectively. Recognizing that a precise characterization of a target spectrum is impossible to capture in practice, we consider that a target spectrum lies in an uncertainty class bounded by known upper and lower bounds. Based on this model, robust waveform design approaches for the DMRS are developed based on LPI-SINR and LPI-MI criteria, where the total transmitting energy is minimized for a given system performance. Numerical results show the effectiveness of the proposed approaches.

• Proceedings of the International Microelectronics And Packaging Society Conference
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• 2002.11a
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• pp.115-121
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• 2002

In this research we have investigated the characteristics of ultra thin $HfO_2 /SiON$stack structure films using several analytical techniques. SiON layer was thermally grown on standard SCI cleaned silicon wafer at $825^{\circ}C$ for 12sec under $N_2$O ambient. $HfO_2 /SiON$$_4$/$H_2O$ as precursors and $N_2$as a carrier/purge gas. Solid HfCl$_4$was volatilized in a canister kept at $200^{\circ}C$ and carried into the reaction chamber with pure $N_2$carrier gas. $H_2O$ canister was kept at $12^{\circ}C$ and carrier gas was not used. The films were grown on 8-inch (100) p-type Silicon wafer at the $300^{\circ}C$ temperature after standard SCI cleaning, Spectroscopic ellipsometer and TEM were used to investigate the initial growth mechanism, microstructure and thickness. The electrical properties of the film were measured and compared with the physical/chemical properties. The effects of heat treatment was discussed.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.22 no.6
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• pp.265-268
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• 2012

The growth of AlN single crystals of large size and good quality is of prime importance for UV LEDs and power devices applications. However, the crystals having the size of more than 1 inch and high quality have not been reported in the world. In the PVT growth of AlN, the crystal morphology of as grown were important because the preferred orientation of growth of it was evaluated for growth rate increase. In the present study, the AlN single crystals grown by PVT process were evaluated by the side of the growth morphology. Optical microscopic characterization was carried out to observe the shape of the crystals and the growth facets. Furthermore the growth habit of it were discussed by observation of the surface of AlN crystals.

• Macromolecular Research
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• v.12 no.3
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• pp.263-268
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• 2004

We have synthesized a water-soluble polyimide precursor, poly(amic acid) amine salt (PAD), from pyromellitic dianhydride (PMDA), 4,4'-oxydianiline, and N,N -dimethylethanolamine (DMEA) and have investigated in detail its properties with respect to the degree of salt formation (D$\_$sf/). The maximum value of D$\_$sf/ we obtained upon precipitation of the precursor solution into acetone was 79%. We synthesized a PAD having a D$\_$sf/ of 100% (PAD100) by the solid state drying of an organic solution. The precursors showed different solubility depending on the D$\_$sf/ to make up to 4 wt% solutions in water containing a small amount of DMEA. PAD100 is completely soluble in pure water. We investigated the imidization behavior of PAD in aqueous solution using various spectroscopic methods, which revealed that PAD 100 has faster imidization kinetics relative to that of the poly(amic acid)-type precursors. The resulting polyimide films prepared from an aqueous precursor solution possess almost similar physical and thermal properties as those prepared from N-methyl-2-pyrrolidone(NMP) solution. Therefore, we have demonstrated that PAD can be used as a water-based precursor of polyimide; this procedure avoids the use of toxic organic solvents, such as NMP.

• Proceedings of the Membrane Society of Korea Conference
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• 2003.07a
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• pp.91-94
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• 2003

In this work, the physicochemical properties for permeant molecules and polyion complex membrane prepared by complexation between SA and chitosan were determined by using molecular modeling methods, and the permeation behaviors of water and alcohol molecules through the PIC membrane have been investigated. In the case of penetrant molecule, the experimental results showed that the prepared membrane was excellent pervaporation performance result in most solution, and the selectivity and permeability of the membrane were dependent on the molecular size, the polarity and the hydrophilic surface of permeant organics. However, the separation behavior of methanol aqueous solution exhibited other permeation tendency with other feed solutions and contradictory result. That is, the membrane were preferentially permeable to methanol over water despite water molecule has stronger polarity and small molecular size than methanol molecule. In this study, the results were discussed from the viewpoint of chemical and physical properties between permeant molecules and membrane in the diffusion state.

• Journal of Advanced Research in Ocean Engineering
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• v.2 no.4
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• pp.169-178
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• 2016

Recently, artificial reefs (ARs) have been frequently used primarily owing to the development in AR materials and projects for relatively complicated, large ARs. Among several engineering issues of ARs, wake region of an AR has been characterized because these regions have a high probability of recruiting seaweed spores, providing an energy saving zone, and facilitating deposition of sediments, nutrients, and bio-deposits. To characterize an efficiency index of an AR wake region and its dependency on the prevailing water flow directions, this study proposes a so-called efficiency index diagram. This characterization is done by normalizing the wake volumes with respect to the real AR volume and illustrating how efficiency indices vary with respect to the inlet flow directions. As a result, according to the diagram characteristics such as an averaged efficiency index, fundamental symmetric angle, secure angles, and principal directions, we can easily figure out how a target AR should be aligned along the main water flows to maximize the wake region around the AR. In addition, six ARs are considered and their efficiency index diagrams are illustrated to pinpoint the physical characteristics.

• Journal of the Korean Ceramic Society
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• v.48 no.5
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• pp.454-457
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• 2011

We report the preparation of nanocrystalline cobalt ferrite, $CoFe_2O_4$, particles using recycled $Co_3O_4$ and their surface coating with silica using micro emulsion method. Firstly, the $Co_3O_4$ powders were separated from waste cemented carbide with acid-base chemical treatment. The cobalt ferrite nanoparticles with the size 10 nm are prepared by thermal decomposition method using recycled $Co_3O_4$. $SiO_2$ was coated onto the $CoFe_2O_4$ particles by the micro-emulsion method. The $SiO_2$-coated $CoFe_2O_4$ particles were studied their physical properties and characterized by X-ray diffraction (XRD), high resolution-transmission electron microscopy (TEM) analysis and CIE Lab value.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.21 no.11
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• pp.1029-1035
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• 2008

$LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ cathode materials prepared from different precursors in lithium rechargeable batteries were characterized by various analytical methods. $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ powders were synthesized by using solid-state reaction method and their physical and chemical properties were analyzed by XRD, SEM, particle size analyzer and TCP-AES. These materials showed different crystallinity, particle size, surface morphology and chemical composition. Also, the charge/discharge cycling of $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ electrodes was carried out under various cut-off voltages and it showed different behaviors. It was found that the electrochemical cyclability of $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ was strongly related to its crystallinity.

• Proceedings of the KIEE Conference
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• 2003.07c
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• pp.1592-1594
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• 2003

This paper presents the deposition and characterization of microcrystalline silicon(${\mu}c$-Si:H) films by HWCVD(Hot-wire Chemical Vapor Deposition) method at low substrate($300^{\circ}C$). The filament temperature, pressure and $SiH_4$ concentration were determined to be a critical parameter for the deposition of poly-Si films. Series A was deposited under the conditions of $1380^{\circ}C$(Tf), 100 mTorr and $2{\sim}10%\{SC:SiH_4/(SiH_4+H_2)\}$ for 60 min. Series B was deposited under the conditions of $1400{\sim}1450^{\circ}(T_f)$, 30 mTorr and $2{\sim}12%$(SC) for 60 min. The physical characteristics were measured by Raman and FTIR spectroscopy, dark and photoconductivity measurements under AM1.5 illumination.