• Title/Summary/Keyword: Physical characterization

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Synthesis and Characterization of Nonlinear Optical Polymers Having Quinoline-based Chromophores

  • Kim, Min-Ho;Jin, Jung-Il;Lee, Chul-Joo;Kim, Nak-Joong;Park, Ki-Hong
    • Bulletin of the Korean Chemical Society
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    • v.23 no.7
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    • pp.964-970
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    • 2002
  • We synthesized three kinds of chromophores incorporating aromatic quinoline unit as a $\pi-conjugated$ bridge in order to prepare more thermally stable nonlinear optical (NLO) chromophores than general stilbene unit. The NLO poly(methylmethacrylate) copolymer, polyimides, and polyester were successfully synthesized by these corresponding quinoline-based monomers. Their physical and optical properties were investigated by thermogravimetry, gel permeation chromatography, ultraviolet-visible spectroscopy, second harmonic generation (SHG) and electro-optic (EO) measurement. All the polymers exhibited better thermal stability,however their NLO activity was a little lower than that of general stilbene-based NLO polymers. Among three kinds of polymers, the PMMA copolymer with quinoline chromophores had the largest SHG coefficient d33 value of 27 pm/V (at 1.064 $\mu\textrm{m})$ and EO coefficient r33 value of 6.8 pm/V (at 1.3 $\mu\textrm{m}$).

Chitin Nanofibers Characterization for Flexible/Transparent Films (유연/투명 필름을 위한 키틴 나노파이버 특성)

  • Hwang, Joong-Kook;Seo, Eung-soo;Chang, Sang-Mok;Shin, Hoon-Kyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.12
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    • pp.797-801
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    • 2015
  • In this study ensuring a filming technology is attempted through dispersion technologies and mixing polymer scaffolds in order to produce films based on the nanowaires obtained from chitin. In addition this study proposes technologies in measuring and improving characteristics of films produced using nanowires and for applying electric conductivity to the films as a chemical and physical manner. Also, a possibility in applications of mass productive films or substrates to producing flexible and transparent films is proposed. In the experiment implemented in this study, it is verified that developments of high strength, high transparency, and high flexibility films can be developed through combining it with producing flexible and transparent films.

Synthesis and Characterization of Substituted Pyridine Complexes of Molybdenum (III). Pyridinium and 3,5-Lutidine Complexes of Oxomolybdenum(V) (몰리브덴의 피리딘계 착물합성과 그 성질 (제3보) 몰리브덴(V)의 피리딘 및 3,5-루티딘착물)

  • Sang Oh Oh;Chang Su Kim
    • Journal of the Korean Chemical Society
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    • v.26 no.2
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    • pp.73-80
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    • 1982
  • The pyridine and 3,5-lutidine complexes of quinquevalent molybdenum have been prepared. The infrared, electronic and reflectance spectra and magnetic susceptibility data of the complexes are reported. It is found that the binuclear complexes contain the di-${\mu}$-oxo-dimolybdenum(V) group, $MoO_2Mo$, and the possible structures are proposed on the basis of elemental analysis and physical measurements.

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Physico-chemical characterization of individual particles emitted from the air pollution point sources (대기 점오염원에서 배출되는 개별입자상물질의 물리화학적 특성)

  • Park Jeong-Ho;Suh Jeong-Min
    • Journal of Environmental Science International
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    • v.14 no.8
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    • pp.761-770
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    • 2005
  • Scanning electron microscopy / energy dispersive X-ray analyzer(SEM/EDX) has played an important role for evaluation the source of atmospheric particle because it is a powerful tool for characterizing individual particles. The SEM/EDX system provides various physical parameters like optical diameter, as well as chemical information for a particle-by-particle basis. The purpose of the study was to classify individual particle emitted from the point sources based on clustering analysis and physico-chemical analysis by SEM/EDX. The total of 490 individual particle were analyzed at 8 point sources including coal-fired power plant, incinerator, H-C oil boiler, and metal manufacturing industry. The main components were Si and AI in the coal-fired power plant, Cl and Na in the domestic waste Incinerator, S in the H-C oil boiler and S and Fe in the metal manufactory industry, respectively.

Morphological Characterization and Classification of Anuran Tadpoles in Korea

  • Park, Dae-Sik;Cheong, Seo-Kwan;Sung, Ha-Cheol
    • Journal of Ecology and Environment
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    • v.29 no.5
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    • pp.425-432
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    • 2006
  • The tadpoles of 12 Korean anuran species, including Bombina orientalis, Bufo gargarizans, B. stejnegeri, Hyla japonica, Kaloula borealis, Rana dybowskii, R. huanrenensis, R. coreana, R. nigromaculata, R. chosenica, R. rugosa, and R. catesbeiana, were classified based on their morphological characteristics. We collected eggs or tadpoles of the 12 Korean anuran species from Gangwon, Incheon, Chungcheong, and Gyeonggi districts in 2005 and 2006 breeding seasons. When the tadpoles reached at $27{\sim}37$ Gosner's developmental stages, we described morphological characteristics of the tadpoles of each anuran species and measured their physical parameters such as total length, body length, and body mass. After that, we chose 12 morphological characteristics to identify each species and to use them as classification keys such as eye location, caudal musculature pattern, spiracle location, oral disc morphology, and labial tooth row formula. In this paper, we presented classification keys, morphological characteristics, and drawings for the tadpoles of 12 anuran species.

Characterization of Nylon 6-Based Polypyrrole Composite Fabrics for EMI Shielding (전자파 차폐용 나일론 6-폴리피롤 복합직물의 특성)

  • Jang, Soon-Ho;Jeong, Sung-Hoon;Byun, Sung-Weon;Lee, Jun-Young;Joo, Jin-Soo;Kim, Seong-Hun
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.191-194
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    • 2001
  • Among the many electrically conducting materials, Polypyrrole (PPy) is one of the most promising, intrinsically conducting polymers (ICP) due to its high conductivity, oxygen resistant and good environmental stability. To enhance the mechanical properties, the researchers have studied the polymer-textile composites. These composites can provide the both excellent physical properties and electrical conductivity. (omitted)

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Syntheses and Thermal Properties of 5,10-Disubstituted-2,3,7,8-tetracyano-5,10-dihydrodipyrazino [2,3-b:2′,3′-el pyrazines and Polymeric Porphyrazines Derived from 2,3-Dichloro-5,6-dicyanopyrazine

  • Jaung, Jae-yun;Kim, Sung-Dong
    • Fibers and Polymers
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    • v.1 no.2
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    • pp.71-75
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    • 2000
  • Intermolecular cyclization of 2-alkylamino-3-chloro-5,6-dicyanopyrazine 2 in the presence of tributylamine in N,N-dimethylformamide (DMF) gave 5,10-disubstituted-2,3,7,8-tetracyano -5,10-dihydrodipyrazino〔2,3-b:2',3'-e]pyrazines 3, which showed strong mesomorphic property and were anticipated as new chromophoric system for functional dye materials. Absorption spectra, fluorescent properties and other physical properties were correlated with their chemical structures. Vanadyl oligomeric porphyrazine with long alkyl groups synthesized from 3 had satisfactory solubility in tetrahydrofuran (THF), diethyl ether and dimethylsulfoxide (DMSO). The syntheses and characterization of vanadyl polymeric porphyrazines derived from 3 with long alkyl groups are reported.

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Characterization of Glasses by Ion-Exchange(II) : Behavior of Mechanical Properties (이온교환에 따른 비정질 고체재료의 특성화(II) : 기계적 물성 거동)

  • 이동인;이용근;이희수
    • Journal of the Korean Ceramic Society
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    • v.25 no.6
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    • pp.665-670
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    • 1988
  • The behavior of mechanical properties of ion exchanged glasses was investigated in this study. The used glasses were soda-lime-silica glasses that were produced by float process. The maximum values of the bending strength and the curvature depth are 45Kg/$\textrm{mm}^2$ and 8.6mm respectively treated at 45$0^{\circ}C$ for 6h, which are 4.4 times and 3.3 times higher than parent glass. In the case, the thermalshock resistance ΔT is 335$^{\circ}C$ that is 205$^{\circ}C$ higher than parent glass, which is the maximum values in this study. The maximum values of the surface microhardness is 490Kg/$\textrm{mm}^2$ in case of 43$0^{\circ}C$ for 4h. It is also found out that annealing points are increased linearly with increasing the amount of K+ ion exchange independent of treatment temperature. Furthermore, the present work shows that the ion exchange strengthened glasses are more effective than the physical tempering glasses ; the bending strength and the curvature depth are 1.8 times and twice higher respectively.

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Characterization of Tribological Properties of DLC Films Prepared by Different Deposition Method (증착방법에 따른 DLC 막의 마찰-마모 특성평가)

  • Oh, Yoon-Suk
    • Journal of the Korean Ceramic Society
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    • v.46 no.5
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    • pp.497-504
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    • 2009
  • DLC is considered as the candidate material for application of moving parts in automotive components relatively in high pressure and temperature operating conditions for its high hardness with self lubrication and chemical inertness. Different deposition method such as arc plating, ion gun plating and PECVD were used for comparing mechanical and tribological properties of each DLCs deposited on stainless steel with 1 um thick respectively. Among these 3 types of DLCs, the arc plated DLC film showed highest value for wear resistance in dry condition. From the results of analysis for physical properties of DLC films, it seems that the adhesion force and crack initiation modes were more important factors than intrinsic mechanical properties such as hardness, elastic modulus and/or roughness to the wear resistance of DLC films. Raman spectroscopy was used for understanding chemical bonding natures of each type of DLC films. Typical D and G peaks were identified based on the deposition method. Hardness of the coating layers were identified by nanoindentation method and the adhesions were checked by scratch method.

Electric Arc furnaces: Chaotic Load Models and Transient Analysis

  • Jang, Gil-Soo;Venkata, S.S.;Kwon, Sae-Hyuk
    • Proceedings of the KIEE Conference
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    • 1998.07c
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    • pp.923-925
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    • 1998
  • Electric arc furnaces (EAFs) are a main cause of voltage flicker due to the interaction of the high demand currents of the load with the supply system impedance. The stochastic models have described the physical phenomena of EAFs. An alternative approach is to include deterministic chaos in the characterization of the arc currents. In this paper, a chaotic approach to such modeling is described and justified. At the same time, a DLL (Dynamic Link Library) module, which is a FORTRAN interface with TACS (Transient Analysis of Control Systems), is developed to implement the chaotic load model in the Electromagnetic Transients Program (EMTP). The details of the module and the results of tests performed on the module to verify the model and to illustrate its capabilities are presented in this paper.

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