Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
권호 표지

Synthesis and Characterization of Substituted Pyridine Complexes of Molybdenum (III). Pyridinium and 3,5-Lutidine Complexes of Oxomolybdenum(V)

몰리브덴의 피리딘계 착물합성과 그 성질 (제3보) 몰리브덴(V)의 피리딘 및 3,5-루티딘착물

  • Sang Oh Oh (Department of Chemistry, Kyungpook National University) ;
  • Chang Su Kim (Department of Chemistry College of Education, Daegu University)
  • 오상오 (경북대학교 자연과학대학 화학과) ;
  • 김창수 (대구대학교 사범대학 화학과)
  • Published : 1982.04.30
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Abstract

The pyridine and 3,5-lutidine complexes of quinquevalent molybdenum have been prepared. The infrared, electronic and reflectance spectra and magnetic susceptibility data of the complexes are reported. It is found that the binuclear complexes contain the di-${\mu}$-oxo-dimolybdenum(V) group, $MoO_2Mo$, and the possible structures are proposed on the basis of elemental analysis and physical measurements.

몰리브덴(V)의 피리딘 및 3,5-루티딘 착물을 합성하고 이들 착물의 적외선 스펙트럼, 전자 흡수스펙트럼, reflectance 스펙트럼 및 자화율을 측정하였다. 이들 착물의 분석과 물리적 측정결과를 기초로 이들 착물은 두 산소로 브리지된 이핵착물임을 확인하고 가능한 구조를 제안하였다.

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