• Clean Technology
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• v.24 no.1
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• pp.50-54
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• 2018

In this work, N-methyl-2-pyrrolidone (NMP) was added into diethylenetriamine (DETA) aqueous solution for high $CO_2$ loading via phase splitting of absorbents during $CO_2$ absorption. Immiscible two phases were formed in the range of more than 30 wt% of NMP in 2 M DETA + NMP + water absorbents because of low solubility of DETA-carbamate in NMP solution. As the composition of NMP in the absorbents increased, the difference of $CO_2$ loading between each phase increased and the volume of bottom phase decreased. In $CO_2$ absorption in packed column by 2 M DETA + NMP + water absorbents, the absorption rate decreased in the range of more than 40 wt% of NMP. It is due to the increasing of mass transfer resistance in liquid film of absorbents at the high concentration of NMP. DETA + NMP + water absorbent is expected as the promising one for reducing the regeneration energy of absorbents according to volume reduction of $CO_2-rich$ phase.

• Clean Technology
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• v.21 no.2
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• pp.124-129
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• 2015

The constant-volume method was used to determine the solubility of CO₂ in various physical absorbents such as DMPEG (dimethyl ether of polyethylene glycol), DEC (diethyl carbonate), DMC (dimethyl carbonate), and TAT (triacetin) in the total pressure range from 5 to 30 bar. The Peng-Robinson equation of state has been used to describe the equilibrium behavior of these mixtures. It was found that the solubility of absorbents was in the of DMPEG250 > TAT > DEC > DMC at the same temperature. Futhermore, the solubiity of blended absorbent of DMPEG250 and DEC is higher than that of DMPEG 250 alone. Therefore, blended absorbent of DMPEG250 and DEC is expected to be an effective and low cost absorbent for physical absorption in precombustion CO₂ capture.

• Membrane Journal
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• v.26 no.2
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• pp.126-134
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• 2016

To produce renewable biomethane from biogas, the properties of physical absorbents such as water, methanol, 1-methyl-2-pyrrolidone (NMP), poly(ethylene glycol) dimethylether (PEGDME), and propylene carbonate (PC) were studied, and PC was applied to membrane contactor systems. Among physical absorbents, PC exhibited a high contact angle of $58.3^{\circ}$ on polypropylene surface, and a PC/water mixture (5 wt%) increased the contact angle to $90^{\circ}$. Furthermore, the PC/water mixture presented higher $CO_2$ absorption capacities (0.148-0.157 mmol/g) than that of water (0.121 mmol/g), demonstrating a good property as an absorbent for membrane contactors. Actual operations in membrane contactors using the PC/water mixture resulted in $CO_2$ removal of 98.0-97.8% with biomethane purities of 98.5-98.3%, presenting a strong potential for biogas treatment. However, the PC/water mixture yielded moderate improved in $CO_2$ removal and methane recovery, as compared with water in the membrane contactor operation. This is originated from insufficient desorption processes to reuse absorbent and low $CO_2$ flux of the PC/water absorbent. Thus, it is requiring optimizations of membrane contactor technology including development of absorbent and improvement of operation process.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.11
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• pp.4643-4648
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• 2010

In this study, $CO_2$ absorption properties at high pressure condition that can apply pre-combustion $CO_2$ capture were investigated for physical sorbent such as PEG, DMSO, and Sulfone. The $CO_2$ Solubility, regeneration, and initial absorption rate with temperature and pressure were measured using batch type stirred cell contactor. The PEG showed the highest $CO_2$ solubility and initial absorption rate. It can be found that all the physical sorbents used in this experiments were almost completely regenerated at various temperature and pressure.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.4
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• pp.334-339
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• 2013

In this study, as a candidate of the carbon dioxide ($CO_2$) absorbents, the mixture solution of polyethylene glycol dimethyl ether (PEGDME) and tetrahydrofuran (THF) were investigated. $CO_2$ absorption rate was measured by using high pressure $CO_2$ screening equipment in the range of 1 - 10wt% THF. Absorption capacity of the mixture solution was also estimated. Based on the results, we found that mixture solution containing THF had higher absorption rate and $CO_2$ loading capacity compared to PEGDME at $25^{\circ}C$.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.4
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• pp.584-591
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• 2017

Metal removal from water has not been explained clearly by either adsorption onto the surface of absorbents or precipitation as metal hydroxides because those occur simultaneously to a certain extent. For a better understanding of the metal removal mechanisms, batch experiments were performed using soil calcined at $850^{\circ}C$ under various pH conditions for Cu, Pb, Zn, Cd, and Cr. The results showed that the metal removal efficiency with the exception of Cr decreased abruptly, even within 5 min, showing more than 90% removal. The pH of each reactant increased gradually from around 7 to 9 with time. The increases in metal removal at higher pH appear to be associated with metal hydroxides precipitation. Comparative experiments, which were carried out changing the pH by reacting with commercial activated carbon (CAC), natural yellow soil (NYS), and calcined yellow soil (CYS), showed that the pH of the CYS only increased with time. Calcination processes might lead to a change in the physical properties of the soil matrix resulting in a high pH when reacted with water. Apart from adsorption onto the surface of the absorbents, these results show that the adsorption and/or precipitation of hydroxides onto the surface of adsorbents also play important roles in regulating the dissolved metals under alkaline conditions.

• Journal of the Korean Society of Safety
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• v.21 no.1 s.73
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• pp.86-91
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• 2006

Oil spills caused by the accidents have been occurred from house and factory waste, grounded tanker, the rupture of storage tank and oil pipelines, the deterioration of various industrial facilities, etc. Many oil spills result in contamination of shorelines and workplace. Fire and explosion may happen from these spills. There are several technologies used for clean-up application, which include use of oil dispersing agents, absorbents, solidifiers, booms and skimmers by physical, chemical, and biological methods. Methods for oil spill clean-up operation are classified into the absorption type, gel type and self-swelling type. Porous materials with oil absorptive properties are classified into micropore, mesopore, and macropore depending on their pore sizes. Recently, new porous materials with smaller size have been developed, but the selective oil absorption in water-in-oil interface demonstrates the macro pore size. In this study oil absorption effects were evaluated using the organic porous materials with a complex function of gel type and swelling type. Samples were subjected to analysis by FT-IR spectroscopy and were characterized in terms of gel formation and morphologies. Oil sorption capacity, pressure retention force and gel strength were also measured. From these results, the physicochemical reactivity before and after gelation was verified and the industrial applications of clean-up operation were suggested.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.1
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• pp.55-62
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• 2012

The present paper investigates the performance of the KOH aqueous solution as an absorbent to capture carbon dioxide ($CO_2$). The chemical absorption was carried out according to consecutive reactions that are generated in the order of $K_2CO_3$ and $KHCO_3$. The overall absorption was completed with following the physical absorption. When the absorption was conducted with the KOH as the limiting reactants in batch a reactor, $K_2CO_3$ production rate was the 1st order reaction for $OH^-$. However, $KHCO_3$ generation reaction was independent of the $CO_3^{2-}$ concentration and the rate was calculated to be $0.18gCO_2/min$ for all KOH absorbents, which is the same value of the reaction rate using $K_2CO_3$ aqueous solution as the absorbents. The overall $CO_2$ capture ratio of the 5% KOH absorbent was estimated to be 19% and the individual value in section 1 and 2 was 57 and 12%, respectively. The amount of $CO_2$ absorbed in the solution was very slightly less than the theoretical value, which was ascribed to the side reaction that produces $K_2CO_3{\cdot}KHCO_3{\cdot}1.5H_2O$ during the reaction and the consequent diminish in $CO_2$ absorption in the KOH solution.

• Journal of Environmental Science International
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• v.16 no.3
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• pp.377-383
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• 2007

In this study, the relationship between the pore size distribution and the adsorption amount of adsorbates is investigated in detail. Adsorption amounts of non-polar adsorbates were greater than those of polar adsorbates because of slight negative charge on surfaces of adsorbents. The adsorption of benzene on the surface of absorbents was largely influenced by the specific pore size of $2{\sim}4$ times of benzene diameter. But in case of toluene, the adsorption of toluene was affected by pore sizes of $2{\sim}4$ times as well as $4{\sim}6$ times of the diameter of toluene. Both acetone and MEK were examined by the same method. The adsorption of acetone was influenced by pore sizes of $2{\sim}4$ times of the diameter of acetone. But acetone does not look to be built up multi-layer on those pore sizes. Since acetone molecule is small and its mobility is so fast, it is assumed that the adsorption and desorption of acetone is simultaneously occurred at the same time even at room temperature. In case of MEK, MEK was effected by pore sizes of $2{\sim}4$ times of the diameter of MEK.

• Clean Technology
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• v.23 no.3
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• pp.237-247
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• 2017

In the dimethyl ether (DME) synthesis and separation process, over 8% by mole of $CO_2$ is fed to the DME synthesis reactor which lowers DME productivity. Therefore, this work focused on the removal of $CO_2$ using three kinds of processes with physical absorbents by comparing the utility consumption through computer simulation of each process. Among the processes selected for comparison are Rectisol$^{(R)}$ process using methanol, Purisol$^{(R)}$ process using n-methyl pyrrolidone (NMP), and SelexolTM process using dimethyl ethers of polyethylene glycol (DEPG) as a solvent. As a result of this study, it was concluded that Purisol$^{(R)}$ process consumes the least energy followed by SelexolTM process. Therefore, it is considered that Purisol$^{(R)}$ process is the most suitable method to absorb $CO_2$ contained in the feed of DME synthesis reactor.