• Current Photovoltaic Research
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• v.3 no.3
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• pp.80-84
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• 2015

We suggest new emitter formation method using solid-phase epitaxy (SPE); solid-phase epitaxy emitter (SEE). This method expect simplification and cost reduction of process compared with furnace process (POCl3 or BBr3). The solid-phase epitaxy emitter (SEE) deposited a-Si:H layer by radio-frequency plasma-enhanced chemical vapor deposition (RF-PECVD) on substrate (c-Si), then thin layer growth solid-phase epitaxy (SPE) using rapid thermal process (RTP). This is possible in various emitter profile formation through dopant gas ($PH_3$) control at deposited a-Si:H layer. We fabricated solar cell to apply solid-phase epitaxy emitter (SEE). Its performance have an effect on crystallinity of phase transition layer (a-Si to c-Si). We confirmed crystallinity of this with a-Si:H layer thickness and annealing temperature by using raman spectroscopy, spectroscopic ellipsometry and transmission electron microscope. The crystallinity is excellent as the thickness of a-Si layer is thin (~50 nm) and annealing temperature is high (<$900^{\circ}C$). We fabricated a 16.7% solid-phase epitaxy emitter (SEE) cell. We anticipate its performance improvement applying thin tunnel oxide (<2nm).

• Korean Journal of Materials Research
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• v.29 no.9
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• pp.553-558
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• 2019

$Cu_2ZnSn(S,Se)_4(CZTSSe)$ thin film solar cells areone of the most promising candidates for photovoltaic devices due to their earth-abundant composition, high absorption coefficient and appropriate band gap. The sputtering process is the main challenge to achieving high efficiency of CZTSSe solar cells for industrialization. In this study, we fabricated CZTSSe absorbers on Mo coated soda lime glass using different pressures during the annealing process. As an environmental strategy, the annealing process is performed with S and Se powder, without any toxic $H_2Se$ and/or $H_2S$ gases. Because CZTSSe thin films have a very narrow stable phase region, it is important to control the condition of the annealing process to achieve high efficiency of the solar cell. To identify the effect of process pressure during the sulfo-selenization, we experiment with varying initial pressure from 600 Torr to 800 Torr. We fabricate a CZTSSe thin film solar cell with 8.24 % efficiency, with 435 mV for open circuit voltage($V_{OC}$) and $36.98mA/cm^2$ for short circuit current density($J_{SC}$), under a highest process pressure of 800 Torr.

• Current Photovoltaic Research
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• v.2 no.3
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• pp.95-102
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• 2014

Light trapping techniques can change the propagation direction of incident light and keep the light longer in the absorption layers of solar cells to enhance the power conversion efficiency. In thin film silicon (Si) solar cells, the thickness of absorption layer is generally not enough to absorb entire available photons because of short carrier life time, and light induced degradation effect, which can be compensated by the light trapping techniques. These techniques have been adopted as textured transparent conduction oxide (TCO) layers randomly or periodically textured, intermediate reflection layers of tandem and triple junction, and glass substrates etched by various patterning methods. We reviewed the light trapping techniques for thin film Si solar cells and mainly focused on the commercially available techniques applicable to textured TCO on patterned glass substrates. We described the characterization methods representing the light trapping effects, texturing of TCO and showed the results of multi-scale textured TCO on etched glass substrates. These methods can be used tandem and triple thin film Si solar cells to enhance photo-current and power conversion efficiency of long term stability.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.17 no.5
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• pp.1187-1195
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• 2013

Photovoltaic inverters should always track the maximum power of solar cell arrays in operation. Also, they should be irrespective of the maximum power point voltage of a wide range of solar cells in tracking the maximum power point. If the current ripple of solar cells occurs, the function of maximum power point tracking drops, and normal tracking is difficult when solar radiation or the maximum power point changes. To solve this problem, this paper proposed a new maximum power point tracking algorithm with high efficiency and an algorithm to reduce the current ripple of solar cells. According to the results from the test on 4KW grid-connected PV inverter, the efficiency of maximum power point tracking and inverter output and the total harmonic distortion of inverter output current showed 99.97%, 97.5% and 1.05% respectively. So, the inverter showed excellent performance, and made possible stable maximum power point tracking operation when the solar radiation rapidly changed from 100% to 10% and from 10% to 100% for 0.5 seconds.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.249.2-249.2
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• 2015

Connecting two or more sub-cells is a simple and effective way of improving power conversion efficiency (PCE) of solar cells, and the theoretical efficiency of this tandem cell is known to reach 85~88% of the sum of the sub-cell's efficiencies. There are two ways of connecting sub-cells in the tandem structure, i.e. parallel and series connection. The parallel connection can increase the short circuit current (Jsc) and the series connection can increase the open circuit voltage (Voc). Although various tandem structures have been studied, the full use of incident light and optimization of cell efficiency is still limited. In this work, we designed series tandem solar cells consisting of lead sulfide (PbS) quantum dots/zinc oxide-based QDSC and zinc phthalocyanine (ZnPc)/C60-based small molecule OSCs. It is expected that the loss of the incident light is minimized because the absorption range of the PbS quantum dots and ZnPc is significantly different, and the Voc increases according to the Kirchhoff's law.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.23 no.1
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• pp.162-168
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• 2009

This thesis is based on the research and experiment of the optimal efficiency generation of electric power. The research and experiment were conducted to search the optimal generation of electric power from a specific amount of solar energy from Photovoltaic Power System with a solar position tracker were used. The changes in the array angles and spacing of the PV Module were also taken into account as well. Here are the findings and the conclusions. First of all, based on experiment using the various anglers, the efficiency generation of electric power increased to a maximum of approximately $12{\sim}17$[%] more at the PV module inclination angle of 30[$^{\circ}$] than at the inclination angles of 20[$^{\circ}$] and 40[$^{\circ}$]. As a result, we have found that installing the PV module inclination at the angle of 30[$^{\circ}$] brought about the most efficient conversion effect of the Photovoltaic Power System. But, when the solar cell is installed on a roof or rooftop where snow builds up, it is the most appropriate to install the solar energy at an 35[$^{\circ}$] angle so that snow slides down and not build up on the module.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.62 no.3
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• pp.371-375
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• 2013

A new model about output power prediction of PV module with various tilted angles and cell to cell distances has been proposed in this paper. Light intensity arrived on a solar cell could be changed by characteristics of PV module materials. Refractive indices, thickness and absorption coefficients of glass, EVA, solar cell and Backsheet are used to predict output. Also, the incident angle of light is changed 0 to 90[$^{\circ}$] and cell to cell distances are 5, 10 15[mm]. Two types of light incident on a solar cell are considered which are direct to a solar cell and reflected from Backsheet. The intensity of the incident light directly into the solar cell is reduced through glass and EVA about 17.5[%] in theoretical way. It has an error of 2.26[%] compared with experimental result. The results for compare theoretical with experimental data is validated within the error of 6.3[%]. This paper would be a research material to predict output power when the PV module is installed outdoor or a building.

• Journal of the Korean Solar Energy Society
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• v.34 no.1
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• pp.98-104
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• 2014

Photovoltaic (PV) cell is considered as one of the finest ways to utilize the solar power. A study of improving solar cell's efficiency is important because the lifetime of solar cell is determined by photovoltaic module technology. Therefore, oxidation (and/or corrosion) of solder materials will be one of the primary yield and long-term reliability risk factor. Recently, the development of lead-free solder alloy has been done actively about lead-free solder alloys of the thermodynamic and mechanical properties. However, the oxidation behavior have rarely been investigated In this study, the oxidations of 60 wt% Sn-40 wt% Pb, 62 wt% Sn-36 wt% Pb -2 wt% Ag, 50wt% Sn-48 wt% Bi-2 wt% Ag alloys for the interconnect ribbon after exposure in atmosphere at $100^{\circ}C$ for several times were investigated. The wettability of 62 wt% Sn-36 wt% Pb-2 wt% Ag and 50 wt% Sn-48 wt% Bi-2 wt% Ag solders was also studied to compare with that of 60 wt% Sn-40 wt% Pb alloy. The results howed that the zero cross time and the wetting time of 50 wt% Sn-48 wt% Bi-2 wt% Ag solder were better than other two samples. The surface of tested samples was analyzed by XPS. The XPS result showed that in all samples, SnO grew first and then the mixture of SnO and $SnO_2$ was detected. $SnO_2$ grew predominantly for the long time aging. Moreover XPS depth profile analysis has found surface enrichment of tin oxide.

• Current Photovoltaic Research
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• v.1 no.1
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• pp.52-58
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• 2013

Two different window-structured $CuInGaSe_2$(CIGS) solar cells, i.e., CIGS/thin-CdS/ZnO:B(sample A) and CIGS/very thin-CdS/Zn(S/O)/ZnO:B(sample B), were prepared, and the diffusivity of Zn, Cd, S, and B atoms, respectively, in the CIGS, ZnO or Zn(S/O) layer was estimated by a theoretical fit to experimental secondary ion mass spectrometer data. Diffusivities of Zn, Cd, S, and B atoms in CIGS were $2.0{\times}10^{-13}(1.5{\times}10^{-13})$, $4.6{\times}10^{-13}(4.4{\times}10^{-13})$, $1.6{\times}10^{-13}(1.8{\times}10^{-13})$, and $1.2{\times}10^{-12}cm^2/s$ at 423K, respectively, where the values in parentheses were obtained from sample B and the others from sample A. The diffusivity of the B atom in a Zn(S/O) of sample B was $2.1{\times}10^{-14}cm^2/sec$. Moreover, the diffusivities of Cd and S atoms diffusing back into ZnO(sample A) or Zn(S/O)(sample A) layers were extremely low at 423K, and the estimated diffusion coefficients were $2.2{\times}10^{-15}cm^2/s$ for Cd and $3.0{\times}10^{-15}cm^2/s$ for S.

• Proceedings of the KIEE Conference
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• 1996.11a
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• pp.326-328
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• 1996

The 10kW or 1MW model of a photovoltaic array written in PSPICE is presented in this paper. A problem with this large scale centralized photovoltaic system is the decrease of power due to the resistance of cable connecting individual subarray with inverter. In this paper, we analyzed the relationship between the resistance of cable and subarray output power of 1MW photovoltaic system by the PSPICE modeling. As a result of simulation, we can proved that photovoltaic array output power is limitted by the resistance of cable.