• Title/Summary/Keyword: Photocurable resin

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Fabrication and characterization of photocurable inorganic-organic hybrid materials using organically modified colloidal-silica nanoparticles and acryl resin

  • Kang, Dong-Jun;Han, Dong-Hee;Kang, Young-Taec;Kang, Dong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.422-422
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    • 2009
  • Photocurable inorganic-organic hybrid materials were prepared from colloidal-silica nanoparticles synthesized through the solgel process and using acryl resin. The synthesized colloidal-silica nanoparticles had uniform diameters of around 20 nm, and they were organically modified, using methyl and methacryl functional silanes, for efficient hybridization with acryl resin. The organically modified and stabilized colloidal-silica nanoparticles could be homogeneously hybridized with aeryl resin without phase separation. The successfully fabricated hybrid materials exhibit efficient photocurability and simple film formation due to the photopolymerization of the organically modified colloidal-silica nanoparticles and acryl resin upon UV exposure. The fabricated hybrid films exhibit an excellent optical transmission of above 90% in the visible region as well as an enhanced surface smoothness of around 1 nm RMS roughness. In addition, the hybrid films exhibit improved thermal and mechanical characteristics, much better than those of acryl resin. More importantly, these photocurable hybrid materials fabricated through the synergistic combination of colloidal-silica nanoparticles with acryl resin are candidates for optical and electrical applications.

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Curing characteristics of the Photocurable Resin for Fabrication of Micro-structures with overhang shape (돌출 형상을 가진 마이크로 구조물 가공을 위한 광경화성 수지의 경화 특성)

  • Jeoung M.G.;Choi J.W.;Ha Y.M.;Lee S.H.;Kim H.C.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.491-492
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    • 2006
  • In the microstereolithography which can make 3-D microstructures, curing depth is different according to exposure energy. Curing depth has to be controlled to fabricate complex 3-D microstructures with overhang shape. It becomes increases when the exposure energy increases. And photocurable resin is cured when the exposure energy is bigger than critical energy. So optimal exposure energy has to be found to fabricate overhang structures without being gel. To make thinner layer, UV absorber is used and exposure pattern is changed. In this paper, we find curing characteristics according to exposure energy, and fabricate microstructures with overhang shape.

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Modification of the curing characteristics of the photocurable resin FA1260T for 3D microfabrication using microstereolithography (삼차원 마이크로광조형 기술 응용을 위한 광경화 수지 EA1260T의 경화특성 조절에 대한 연구)

  • Kim Sung-Hoon;Jung Dae-Jun;Joo Jae-Young;Jeong Sung-Ho
    • Journal of the Korean Society for Precision Engineering
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    • v.23 no.6 s.183
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    • pp.174-179
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    • 2006
  • The curing characteristics of a photocurable resin are critical factors that often decide the ultimate resolution and structural sharpness of a final product fabricated by microstereolithography$(\mu-STL)$. In this study, we investigated the curing characteristics of the FA1260T photopolymer under a visible laser light of 42nm wavelength. Modification of the curing property of the FA1260T is attempted to reduce the cure depth $(D_c)$ by adding a radical quencher to the resin. Also, an organic solvent was used to reduce the resin viscosity for an improvement of the flatness of the liquid surface during layer-by-layer curing. As a result, the minimum $D_c$ has been reduced over a factor of 3 with no abrupt increase. Samples of three dimensional microstructures fabricated using the modified FA1260T are presented.

A study on color characteristics of Multi-color functional Rapid Prototypes Using laser stereolithography (광조형을 이용한 다색 기능성 시작품의 색상특성에 관한 연구)

  • 조진구;정해도;손재혁;임용관
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.05a
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    • pp.824-828
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    • 2000
  • As production cycle has become more and more shorter, the demand of rapid prototyping technology has increased largely. There are many methods for rapid prototyping technology, such as SLA. SLS, FDM. INK JET, LOM and so on. Of all methods, SLA has been most widely used for fabricating precision parts. But products manufactured by this method have limitation of single color and single material. So the principal purpose of this study is to overcome the limit of single color product. If the internal structure of manufactured product is visible with multi-color characteristic, it is possible to check easily the designed model with reality. In order to give multi-color characteristic to the product, photocurable resin mixed with pigment is used in this study. First, transparency of photocurable resin without pigment is evaluated, and then color characteristic and curing characteristic of the mixture is evaluated changing mixing ratio. Through the basic experiments, it becomes possible to fabricate multi-color 3D prototype without assembly.

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Prediction of Cured Cross-sectional Image in Projection Microstereolithography (전사방식 마이크로광조형의 경화 단면형상 예측)

  • Kim, Sung-Hyun;Park, In-Baek;Ha, Young-Myoung;Lee, Seok-Hee
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.4
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    • pp.102-108
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    • 2010
  • Projection microstereolithography is a process of fabricating a micro-structure by using dynamic mask such as digital micromirror device(DMD). DMD shapes the beam into cross-sectional image of structure. Photocurable resin is cured by the beam and stacked layer on top of layer. It is difficult to deliver the beam from the DMD to the photocurable resin without any distortions. We assume that the beam exposed to the resin by 1 pixel of DMD has Gaussian distribution, so the shaped beam reflected by the DMD affects its neighboring area. Curing pattern corresponding to a cross-sectional images is predicted by superposition of pixels of Gaussian distribution and it is similar to cured shape.

Dielectric Property Analysis of BaTiO3 Capacitor Manufactured by Inkjet Printing Process (잉크젯 프린팅 공정을 통해 제작된 BaTiO3 Capacitor의 유전특성 분석)

  • Kim, Yu-Jin;Lee, Gyeong-Yeong;Lee, In-Gon;Hong, Ic-Pyo;Kim, Ji-Hoon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.6
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    • pp.610-615
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    • 2022
  • BaTiO3 is one of the ferroelectric materials with excellent dielectric properties such as high dielectric constant, low dielectric loss, and is widely used for the manufacturing of capacitors, piezoelectric converters, microsensors, and ferroelectric memories. Inkjet printing is a technology which uses digital and contactless methods which significantly improves flexibility associated with material and structural design, reducing manufacturing costs. Therefore, the top and bottom electrodes, BaTiO3 ink, and photocurable resin were all printed by an inkjet to produce a BaTiO3 capacitor. The properties of the printed thin film were analyzed. It was confirmed that the photocurable resin ink was well-infiltrated between the BaTiO3 powder particles printed by inkjet. The dielectric properties of the capacitor such as dielectric constant which varies in accordance with frequency, polarization and tunability that changes with voltage, were measured.

Improvement of Mechanical Properties of UV-curable Resin for High-aspect Ratio Microstructures Fabricated in Microstereolithography (마이크로광조형에서 고 세장비 구조물 집적화 가공을 위한 UV 경화성 수지의 물성 개선)

  • Lee, Su-Do;Choi, Jae-Won;Park, In-Beak;Ha, Chang-Sik;Lee, Seok-Hee
    • Journal of the Korean Society for Precision Engineering
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    • v.24 no.12
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    • pp.119-127
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    • 2007
  • Recently, microstructures fabricated using microstereolithography technology have been used in the biological, medical and mechanical fields. Microstereolithography can fabricate real 3D microstructures with fine features, although there is presently a limited number of materials available for use in the process. Deformation of the fine features on a fabricated microstructure remains a critical issue for successful part fabrication, and part deformation can occur during rinsing or during fabrication as a result of fluid flow forces that occur during movement of mechanical parts of the system. Deformation can result in failure to fabricate a particular feature by breaking the feature completely, spatial deflection of the feature, or attaching the feature to neighboring microstructures. To improve mechanical strength of fabricated microstructures, a clay nanocomposite can be used. In particular, a high-aspect ratio microstructure can be fabricated without distortion using photocurable liquid resin containing a clay nanocomposite. In this paper, a clay nanocomposite was blended with a photocurable liquid resin to solve the deformation problem that occurs during fabrication and rinsing. An optimal mixture ratio of a clay nanocomposite was found through tensile testing and the minimal allowable distance between microstructures was found through fabrication experimentation. Finally, using these results, high-aspect ratio microstructures were fabricated using a clay nanocomposite resin without distortion.

A Study on Resin flow Analysis and Free Surface forming at Micro-stereolithography using a Dynamic Pattern Generator (동적 패턴 생성기를 이용한 마이크로 광 조형 시스템에서 수지 유동 해석 및 자유표면 형성에 관한 연구)

  • Won M.H.;Choi J.W.;Ha Y.M.;Lee S.H.;Kim H.C.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.878-881
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    • 2005
  • A Stereolithography technology is based on stacking of sliced layer from STL file that is converted from 3-dimensional CAD data. A microstereolithography technology is evolved from conventional stereolithography to fabricate microstructures. In this technology, we have to consider influence of resin flow to make refresh surface. To generate new resin surface, stage has to be moved downward deeply and upward to desired position. At this time, resin flow affects to refresh surface of resin. And resin viscosity is the key factor in simulation of resin flow. By setting optimal refresh time for resin surface, total fabrication time is reduced and there is no damage to fabricated layers. In this research, we simulate resin flow using CFD software and derive optimal stage moving time and dwelling time.

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