• Journal of Environmental Health Sciences
• /
• v.34 no.1
• /
• pp.62-69
• /
• 2008

The life cycle assessment method for environmental impact assessment was used, in this study, to assess the production process of wheat flour which is the most important material in the food industry. Environmental impact assessments were compared between that of the Ministry of Environment, Republic of Korea (method I) with that of the Ministry of Commerce, Industry and Energy (method II). Life cycle inventories (LCI) was performed using internal and external databases and the production statistics database of company S. The procedure of life cycle impact assessment (LCIA) was followed in terms of classification, characterization, normalization and weighting to identify the key issues. The impact categories of method I were divided into 8 categories with consideration of : abiotic resources depletion, global warming, ozone depletion, photochemical oxidant creation, acidification and eutrophication. The impact categories of method II were divided into 10 categories with consideration of: abiotic resources depletion, global warming, ozone depletion, photochemical oxidant creation, acidification, eutrophication, human toxicity, freshwater aquatic ecotoxicity, marine aquatic ecotoxicity and terrestrial ecotoxicity.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
• /
• v.4 no.1
• /
• pp.11-23
• /
• 2000

Photochemical air quality models are essential tools in predicting future air quality and assessing air pollution control strategies. To evaluate air quality using a photochemical air quality model, emission inventories are important inputs to these models. Since most emission inventories are provided at a county-level, these emission inventories need to be geographically allocated to the computational grid cells of the model prior to running the model. The conventional method for the spatial allocation of these emissions uses "spatial surrogate indicators", such as population for mobile source emissions and county area for biogenic source emissions. In order to examine the applicability of such approximations, more detailed spatial surrogate indicators were developed using Geographic Information System(GIS) tools to improve the spatial allocation of mobile and boigenic source emissions, The proposed spatial surrogate indicators appear to be more appropriate than conventional spatial surrogate indicators in allocating mobile and biogenic source emissions. However, they did not provide a substantial improvement in predicting ground-level ozone(O3) concentrations. As for the carbon monoxide(CO) concentration predictions, certain differences between the conventional and new spatial allocation methods were found, yet a detailed model performance evaluation was prevented due to a lack of sufficient observed data. The use of the developed spatial surrogate indicators led to higher O3 and CO concentration estimates in the biogenic source emission allocation than in the mobile source emission allocation.llocation.

• Journal of Korean Society for Atmospheric Environment
• /
• v.24 no.2
• /
• pp.206-219
• /
• 2008

The purpose of this study is to evaluate concentrations of carbonyl compounds during summer season in Seoul metropolitan area. The air samples were collected at 7 sites in this area from June 2001 to June 2003. The carbonyl compounds were analyzed by DNPH/HPLC method. The analytical method applied in this study showed good repeatability, linearity, and sensitivity. The most abundant carbonyl was formaldehyde (average 4.48 ppb), and followed by acetone, acetaldehyde, methyl ethyl ketone, butyraldehyde, propionaldehyde and benzaldehyde, respectively. Concentrations of carbonyl compounds in June were higher than those in August. There was not only higher solar radiation but also higher ozone concentration in June than in August. As a result o photochemical reactions, carbonyl compounds from both primary and secondary sources are likely to contribute to the formation of ozone. The contributions to photochemical ozone creation of two carbonyl compounds such as formaldehyde and acetaldehyde were estimated to be about 70%. Ratios of formaldehyde to acetaldehyde in this study ranged from 1.13 to 4.26, which are generally equivalent levels to those of other urban areas in domestic and foreign countries.

• Journal of Korean Society for Atmospheric Environment
• /
• v.16 no.4
• /
• pp.317-326
• /
• 2000

Carbonyl compounds have been measured in downtown Seoul for September 1998 using 2-series impinger method. Average concentration (ppbv) of carbonyl compounds were 12.66$\pm$5.77 HCHO, 12.05$\pm$4.86 CH3CHO and 7.92$\pm$2.63 CH3CHCH3 These compounds were the most abundant carbonyl,. They showed maximum concentration during the daytime when photochemical activity was very strong minimum concentration were usually showed during the night and early morning. Comparison of diurnal variation of carbonyl compounds with the concentration of O3, NMHC, CO and meteorological data indicated that primary and secondary sources contributed the observed carbonyl compounds. Photochemical Formation Rate(PFR) of carbonyl compounds dur-ing the sampling periods were 61% HCHO, 85% CH3CHO, 85% CH3CHO, 71% CH3COCH3.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2005.06a
• /
• pp.1277-1280
• /
• 2005

A high-aspect-ratio and high-resolution stainless steel shadow mask for organic thin-film transistors (OTFTs) circuit has been fabricated by a new method which combines photochemical machining, micro-electrical discharge machining (micro-EDM), and electrochemical etching (ECE). First, connection lines and source-drain holes are roughly machined by photochemical etching, and then the part of source and drain holes is finished by the combination of micro-EDM and ECE processes. Using this method a $100\;\mu{m}$ thick stainless steel (AISI 304) shadow mask for inverter can be fabricated with the channel length of $30\;\mu{m}\;and\;10\;\mu{m}\;respectively.\;The\;width\;of\;connection line\;is\;150\;\mu{m}$. The aspect ratio of the wall is about 5 and 15, respectively. Metal lines and source-drain electrodes of OTFTs were successfully deposited through the fabricated shadow mask.

• Particle and aerosol research
• /
• v.7 no.1
• /
• pp.31-44
• /
• 2011

The hourly volatile organic compounds(VOCs) concentrations between 2005 and 2008 at Bulgwang photochemical assessment monitoring station were investigated to establish a method for quality assurance and quality control(QA/QC) procedure. Systematic error, erratic error, and random error, which was manifested by outlier and highly fluctuated data, were checked and removed. About 17.3% of the raw data were excluded according to the proposed QA/QC procedure. After QA/QC, relative standard deviation for representing 15 species concentrations decreased from 94.7-548.0% to 63.4-125.8%, implying the QA/QC procedure is proper. For further evaluation about the adequacy of QA/QC procedure, principal components analysis(PCA) was carried out. When the data after QA/QC procedure was used for PCA, the extracted principal components were different from the result from the raw data and could logically explain the major emission sources(gasoline vapor, vehicle exhaust, and solvent usage). The QA/QC procedure based on the concept of errors is inferred to proper to be applied on VOCs. However, an additional QA/QC step considering the relationship between species in the atmosphere needs to be further considered.

• Asian Journal of Atmospheric Environment
• /
• v.11 no.4
• /
• pp.235-253
• /
• 2017

This study was conducted for analyzing the contribution factors on ozone concentrations and its long term trends in each major city and province in Korea through several statistical methods such as simple linear regression, generalized linear model, KZ-filer, correlation matrix, Kringing method, and cluster analysis. The overall ozone levels in South Korea have been consistently increasing over the past 10 years. The ozone concentrations in Seoul, the biggest city in Korea, are the lowest in all areas with the highest increasing ratio for $95^{th}%$ ozone. It is thought that the active photochemical reaction could affect the higher ozone concentration increase. On the other hand, the ozone concentrations in Jeju are the highest in Korea with the highest increasing ratio for $5^{th}%$, $33^{th}%$, and $50^{th}%$ ozone. It is also thought that the weak $NO_x$ titration could be the reason of higher ozone concentrations in Jeju. In case of Jeju, transport related factors is the major factor affecting the ozone trend. Thus, it is assumed that the variation of ozone trend of Asian region affecting the ozone trend in Jeju, where domestic ozone photochemical reaction is less active than urban area. It is thought that the photochemical reaction plays the role of increasing of ozone concentrations in the urban area, even though the LRT affected on the increase of ozone concentrations in non-urban area.

• Journal of the Microelectronics and Packaging Society
• /
• v.27 no.1
• /
• pp.25-29
• /
• 2020

This study demonstrates direct-patternable amorphous TiO_x resistive switching (RS) device and the fabrication method using photochemical metal-organic deposition (PMOD). For making photosensitive stock solutions, Ti(IV) 2-ethylhexanoate was used as starting precursor. Photochemical reaction by UV exposure was observed and analyzed by Fourier transform infrared spectroscopy and the reaction was completed within 10 minutes. Uniformly formed 20 nm thick amorphous TiO_x film was confirmed by atomic force microscopy. Amorphous TiO_x RS device, formed as 6 × 6 ㎛ square on 4 ㎛ width electrode, showed forming-less RS behavior in ±4 V and on/off ratio ≈ 20 at 0.1 V. This result shows PMOD process could be applied for low temperature processed ReRAM device and/or low cost, flexible memory device.

• Korean Journal of Remote Sensing
• /
• v.33 no.5_1
• /
• pp.507-519
• /
• 2017

The applications of NDVI (Normalized Difference Vegetation Index) as a vegetation index has been widely used to understand vegetation biomass and physiological activities. However, NDVI is not suitable way for monitoring vegetation stress because it is less sensitive to change in physiological state than biomass. PRI (Photochemical Reflectance Index) is well developed to present physiological activities of vegetation, particularly high-light-stress condition, and it has been adopted in several satellites to be launched in the future. Thus, the understanding of PRI performance and the development of analysis method will be necessary. This study aims to interpret the characteristics of light-stress-sensitive PRI in shadow areas and to evaluate the PRI calculated by other wavelengths (i.e., 488.9 nm, 553.6 nm, 646.9 nm, and 668.4 nm) instead of 570 nm that used in original PRI. Using airborne-based hyperspectral image, we found that PRI values were increased in shadow detection due to the reduction of high light induced physiological stress. However, the qualities of both PRI and NDVI data were dramatically decreased when the shadow index (SI) exceeded the threshold (SI<25). In addition, the PRI calculated using by 553.6 nm had best correlation with original PRI. This relationship was improved by multiple regression analysis including reflectances of RED and NIR. These results will be helpful to the understanding of physiological meaning on the application of PRI.

• Journal of the Korean Society for Precision Engineering
• /
• v.21 no.12
• /
• pp.13-20
• /
• 2004

Manufacturing process for the microfluidic device can include such sequential steps as master fabrication, electroforming, and injection molding. The laser ablation using masks has been applied to the fabrication of channels in microfluidic devices. In this study, manufacturing of polymer master and mold insert for micro injection molding was investigated. Ablation of PET (polyethylene terephthalate) by the excimer laser radiation could be used successfully to make three dimensional master fur nickel mold insert. The mechanism fur ablative decomposition of PET with KrF excimer laser $({\lambda}: 248 nm, pulse duration: 5 ns)$ was explained by photochemical process, while ablation mechanism of PMMA (polymethyl methacrylate) is dominated by photothermal process, the .eaction between PC (polycarbonate) and KrF excimer laser beam generate too much su.face debris. Thus, PET was adopted in polymer master for nickel mold insert. Nickel electroforming using laser ablated PET master was preferable for replication method. Finally, it was shown that excimer laser ablation can substitute for X-ray lithography of LIGA process in microstructuring.