• International Journal of Highway Engineering
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• v.15 no.6
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• pp.1-9
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• 2013

PURPOSES : About 35% of air pollutant is occurred from road transport. NOx is the primary pollutant. Recently, the importance of NOx removal has arisen in the world. $TiO_2$ is very efficient for removing NOx by photocatalytic reaction. The mechanism of removing NOx is the reaction of photocatalysis and solar energy. Therefore, $TiO_2$ in concrete need to be contacted with solar radiation to be activated. In general, $TiO_2$ concrete are produced by substitute $TiO_2$ as a part of concrete binder. However, 90% of $TiO_2$ in the photocatalysis can not contacted with the pollutant in the air and solar radiation. Coating and penetration method are attempted as the alternative of mixing method in order to locate $TiO_2$ to the surface of structure. METHODS : The goal of this study was to attempt to locate $TiO_2$ to the surface of concrete, so we can use the concrete in pavement construction. The distribution of $TiO_2$ along the depth were confirmed by basing on the comparison of $TiO_2$ compare by using the EDAX(Energy Dispersive X-ray Spectroscopy). RESULTS : $TiO_2$ were distributed within 3mm from concrete surface. This distribution of $TiO_2$ is desirable, since the $TiO_2$ induce photocatalysis are located to where they can be contacted with the air pollutant and solar radiation. CONCLUSIONS : Nano size $TiO_2$ is easily penetration in the top 3mm of concrete surface. By the penetration $TiO_2$ concrete can be produced with the use of only 10% of $TiO_2$, by comparing the mixing types.

• Journal of Sensor Science and Technology
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• v.31 no.2
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• pp.102-106
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• 2022

Currently, the demand for real-time monitoring of water quality has increased dramatically. Total organic carbon (TOC) analysis is a suitable method for real-time analysis compared with conventional biochemical oxygen demand (BOD) and chemical oxygen demand (COD) methods in terms of analysis time. However, this method is expensive because of the complicated internal processes involved. The photocatalytic titanium dioxide (TiO2)-based TOC method is simpler as it omits more than three preprocessing steps. This is because it reacts only with organic carbon (OC) without extra processes. We optimized the rate between the TiO2 photocatalyst and binder solution and the TiO2 concentration. The efficiency was investigated under 365 nm UV exposure onto a TiO2 coated substrate. The optimized conditions were sufficient to apply a real-time monitoring system for water quality with a short reaction time (within 10 min). We expect that it can be applied in a wide range of water quality monitoring industries.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.6
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• pp.120-127
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• 2022

Nitrogen oxide(NOx) is a major cause of air pollution, exists in the form of nitrogen monoxide and nitrogen dioxide, and is harmful to the human body. Recently, a number of studies to reduce NOx in the atmosphere have been conducted, and these efforts have been the same in the field of construction materials. It is known that NOx can be efficiently removed by using a photocatalytic reaction. In this study, the NOx removal performance of the foam composite using activated carbon(AC) and titanium dioxide(TiO₂) was investigated. AC was used to enhance the photocatalytic reaction of TiO₂ by increasing the internal specific surface area of the foam composite. In this study, foam composites were prepared using the substitution rate of AC as the main variable. The NOx removal performance of specimen was evaluated according to the test method presented in ISO-22197-1. The specific surface area of the foam composite showed a tendency to increase according to the AC content, but decreased at 15% or more. Also, when the AC substitution rate was 15%, the NOx removal efficiency was the highest.

• Clean Technology
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• v.23 no.1
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• pp.54-63
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• 2017

Volatile organic compounds (VOCs) are widely used in both industrial and domestic activities. VOCs are one of the most unpleasant, frequently complaint-rousing factors of pollution around the world. It is now necessary to research and develop an alternative technology that could overcome the problems of the existing odor-control and VOC-eliminating techniques. In this study, essential oil and photocatalytic process was applied in the removal of benzene and toluene, typical VOCs in petrochemistry plant. therefore, this study conducted experiments on the selection of appropriate essential oil, photodegradation, hydroxyl radical generation capacity. The removal efficiency and reaction rate were performed to selecte the type and concentration of essential oil. As a result, removal efficiency of Hinoki Cypress oil was approximately 70% and reaction rate of Hinoki Cypress was high. The results of photolysis experiment, photocatalytic oxidation process showed that the decomposition efficiency of VOCs increased considerably with increasing UV lamp power. In addition, the conversion of VOCs was increased up to $0.1gL^{-1}$ photocatalysts. The hydroxyl radicals measure was performed to determine the ability to generate hydroxyl radicals. The analytical result showed that high $TiO_2$ concentration and lamp power was produced many hydroxyl radical. Experiments of the removal efficiency and reaction rate were performed using essential oil and photooxidation. As a result, the removal efficiency showed that the removal efficiency was increased high temperature and reaction time. The activation energy was calculated from the reaction rate equation at various temperature condition. Activation energy was approximately $18kJmol^{-1}$.

• Particle and aerosol research
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• v.4 no.2
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• pp.69-75
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• 2008

Nanosize ZnO particles were prepared by oxidation of zinc vapor and the particle growth was modeled by a coagulation model by assuming that the characteristic time for reaction was much shorter than coagulation time and residence time (${\tau}_{reaction}{\ll}{\tau}_{coagulation}{\ll}{\tau}_{residence}$). Experimental measurement of zinc oxide particles diameter was consistent with the predicted result from the coagulation model. For practical purpose of predicting zinc oxide size in areosol reactor, the constant kernel solution is concluded to be sufficient, Uniqueness of nano-scale property of zinc oxide was confirmed by the higher photocatalytic activity of zinc oxide than nanosize titania particles.

• Analytical Science and Technology
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• v.11 no.1
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• pp.13-19
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• 1998

In the dye sensitization for the solar energy conversion with a photoelectrochemical cell containing allylthiourea, the time profile of the sensitized photocurrent showed a rise and fall with the irradiation time. The dye solution before and after irradiation was analyzed by means of spectroscopic methods. A new precipitation reaction between sensitizer and supersensitizer and photobleaching of the dye appeared to be involved in the decreased photocurrent.

• Nanomaterials
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• v.11 no.6
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• pp.1377-1384
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• 2021

Efficient visible-light photocatalysis was realized by exploring self-induced defect states, including the abundant surface states of TiO_2-δ nanobelts synthesized through metal-organic chemical vapor deposition (MOCVD). The TiO_2-δ nanobelts exhibited two strong defect-induced absorption peaks at 2.91 and 1.92 eV, overlapping with the conduction band states so that photoexcited carriers can contribute effectively for the photocatalysis reaction. To further enhance visible-light photocatalytic activity, carbon atoms, the by-product of the MOCVD reaction, were self-doped at the judiciously determined growth conditions. The resulting visible-light photocatalysis suggests that the large surface area and consequent high concentration of the surface states of the TiO_2-δ nanobelts can be effectively utilized in a wide range of photocatalysis applications.

• International Journal of Highway Engineering
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• v.16 no.5
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• pp.49-58
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• 2014

PURPOSES : In areas of high traffic volume, such as expressway across large cities, the amount of nitrogen oxides (NOx) emitted into the atmosphere as air pollution can be significant since NOx gases are the major cause of smog and acid rain. Recently, the importance of NOx removal has arisen in the world. Titanium dioxide ($TiO_2$), that is one of photocatalytic reaction material, is very efficient for removing NOx. The NOx removing mechanism of $TiO_2$ is the reaction of solar photocatalysis. Therefore, $TiO_2$ in road structure concrete need to be contacted with ultraviolet rays (UV) to be activated. In general, $TiO_2$ concretes are produced by replacement of $TiO_2$ as a part of concrete binder. However, considerable portion of $TiO_2$ in concrete cannot contact with the pollutant in the air and UV. Therefore, $TiO_2$ penetration method using the surface penetration agents is attempted as an alternative in order to locate $TiO_2$ to the surface of concrete structure. METHODS : This study aimed to evaluate the NOx removal efficiency of photocatalytic concrete due to various $TiO_2$ application method such as mix with $TiO_2$, surface spray($TiO_2$ penetration method) on hardened concrete and fresh concrete using surface penetration agents. The NOx removal efficiency of $TiO_2$ concrete was confirmed by NOx Analyzing System based on the specification of ISO 22197-1. RESULTS : The NOx removal efficiency of mix with $TiO_2$ increased from 11 to 25% with increasing of replacement ratio from 3 to 7%. In case of surface spray on hardened concrete, the NOx removal efficiency was about 50% due to application amount of $TiO_2$ with surface penetration agents as 300, 500 and 700g/m2. The NOx removal efficiency of surface spray on fresh concrete due to all experimental conditions, on the other hand, which was very low within 10%. CONCLUSIONS : It was known that the $TiO_2$ penetration method as surface spray on hardened concrete was a good alternative in order to remove the NOx gases for concrete road structures.

• Journal of Hydrogen and New Energy
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• v.18 no.3
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• pp.230-237
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• 2007

Titania nanotube(TiNT) and CdS sol were synthesized by hydrothermal reaction under strongly basic condition and by precipitation reaction of $Cd(N0_3)_2$ and $Na_2S$ aqueous solutions, respectively. After preparing a series of CdS-TiNT composite films on $F:SnO_2$ conducting glass with variation of the mole ratio (r) of TiNT/(CdS+TiNT), their visible light absorption, photocatalytic activities for hydrogen production, and the photocurrent generation were examined. In general, this CdS-TiNT series showed lower photocatalytic activities and photocurrent generation under Xe light irradiation compared to their counterparts, i.e., CdS-$TiO_2$ particulate series. It appeared that TiNTs are not so effective photocatalyic material in spite of their larger specific surface areas compared to $TiO_2$ nanoparticles, because they indicate a poor crystallinity and less intimate interaction or contact with CdS particles owing to the tubular morphology and an easy agglomeration among themselves.

• Journal of the Microelectronics and Packaging Society
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• v.11 no.4 s.33
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• pp.55-59
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• 2004

We fabricates the $TiO_2$ thin film from anatase phase $TiO_2$ powder having good photocatalytic property using aerosol deposition method at room temperature. Aerosol deposition method, which sprays an aerosol powder with ultrasonic velocity and deposits a thin film on substrate at low temperature, has the advantages of low thermal stress and low cost. To fabricate the $TiO_2$ thin film, the aerosol bath pressure and chamber pressure were 500 torr and 0.4 torr, respectively. The difference of aerosol bath pressure and chamber pressure accelerated the $TiO_2$ nano powder to ultrasonic velocity through the nozzle of $0.4 mm{\times}10 mm$ and $TiO_2$ thin film was finally formed. SS mesh with diameter of 50 mm was used as a substrate to apply the $TiO_2$ thin film to water quality purification. The raw powder was dehydrated for the good dispersion of $TiO_2$ powder. To suppress the formation of second particle, the powder was dispersed for 90 min in alcohol bath by ultrasonic treatment and desiccated. The grain size of $1 {\mu}m$ was observed in $TiO_2$ thin film deposited on SUS mesh by scanning electron microscopy (SEM). The anatase phase of $TiO_2$ thin film was also observed by X-ray diffraction (XRD) and the anatase phase of raw powder was nicely maintained after aerosol deposition. The results are applicable to water treatment filter having photocatalytic reaction.