• International Journal of Highway Engineering
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• v.17 no.5
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• pp.67-73
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• 2015

PURPOSES : This study was conducted to derive the optimum mixing ratio of phosphorescent pigment for the development of phosphorescent line marking. METHODS: In this study, we utilized a literature review and case study methodology, to describe the domestic and foreign state of practice for the production and mixing of phosphorescent pigment for use in line marking. The optimal mixing ratio was derived by comparing the reduction in luminance over time for the various phosphorescent pigment mixing ratios identified in the literature. In addition, performance and construction characteristics were analyzed using field testing techniques. RESULTS : The results were as follows: 1) the results of the luminance performance standards tests showed that all of the phosphorescence test specimens satisfied the phosphorescent fire protection standard. As the phosphorescent pigment mixing ratio increased, the luminance value increased, 2) the luminance reduction rate was minimum at the mixing ratio of 50%. However, when compared to a mixing ratio 40%, a small difference was recorded, the luminance reduction rate from the mixing ratio of 40% is judged as being converged. Therefore, in view of the economic efficiency, it was determined that the optimal mixing ratio was 40%, 3) as a result of construction on the field, a mixing ratio of 40% was found to have a higher luminance value than the general line marking for up to three hours after sunset, 4) it was found that the phosphorescent line markings without glass beads spraying had a higher luminance value than the phosphorescent line markings with glass beads spraying. CONCLUSIONS : Through the results of the basic experiments of the line markings obtained by blending a phosphorescent pigment, the results could be applied to play an important role in the development of phosphorescent line marking paint technology and in establishing application planning for on-site construction characteristics.

• Journal of the Korean institute of surface engineering
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• v.56 no.2
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• pp.152-159
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• 2023

The night visibility of pavement is being considered as a global issue in the field of traffic safety. Although the spreading glass beads on the lane paints has been mainly used to secure night-visibility by utilizing the effect of retroreflection, obvious shortcoming of this method is that retroflection does not occur in the range where the headlights do not reach the glass beads. The use of functional paints including phosphorescent constituents could be a solution for overcoming fore-mentioned problem. SrAl₂O₄ based chemicals have not only good phosphorescent property, but also are chemically stable compared to existing ZnS based materials. However, this chemicals also need the improvement due to slightly reduced luminous effect in time. Herein, we developed novel paints showing enhanced phosphorescent properties by putting rare earth elements such as Eu, Dy and Y into SrAl₂O₄. These prepared phosphorescent pigments have displayed improved properties in terms of durability and long afterglow. For instance, the property of afterglow has been persisted after 5 hours with luminace of 20.6 mcd/m².

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.12
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• pp.7380-7384
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• 2014

Evacuation fire doors were manufactured by applying phosphorescent paint to the whole fire door whose performance was already recognized, and applying heat sensitive paint around the grip. The facility was improved by the evacuation and safety functions on the fire door, which has been used as only a fire facility, and the fire door is also used as an evacuation facility. The brilliance of the evacuation safety fire door manufactured in this study passed the brilliance test of Korea Fire Institute with a performance more than the brilliance (7mcd after 60 minutes) of the existing inducement sign. During a fire, the visible area is larger than the evacuation door inducement, etc. and light preventive status in the lower part of the fire door was observed during the descent of smoke. Therefore, it is considered to extend the evacuation effective time of evacuators. In heat sensitive paint applied around the grip, a color change is observed on the fire door when approaching a certain temperature ($70^{\circ}C$). Therefore, the first disaster that evacuators can encounter on the grip of a fire door during a fire can be prevented and should be helpful in recognizing the backfiring possibility and preventing safety accidents for firefighters who must enter a fire space.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.36 no.4
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• pp.685-694
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• 2016

Visibility of lane marking is impaired at night, or in case of rain, and thereby threatens traffic safety. Recently, various studies and technology have been developed to improve lane marking visibility, such as the extension of lane marking life expectancy (up to 1.5 times), improvement of lane marking equipment, improvement of lane marking visibility (32.7%) by applying phosphorescent material mixed paint, and expressway lane design standards alternative (length 6m, gap 12m, width 13cm: 27.8% of painted surface are reduced) adoption with ergonomic analysis. In this study, a set of cost-benefit analyses was performed for the cases where such techniques were applied. Based on the literature review, 26.9% of traffic accidents would be prevented by improving lane marking visibility by 32.7%; accident reduction benefit was calculated as much as 12.5 billion KRW. Meanwhile, total increased cost when introducing phosphorescent material mixed paint and lane design standards alternative is calculated as 30.6 billion KRW. However, economic feasibility could not be secured with 0.41 of cost-benefit ratio when applied to the expressway network as a whole. Additionally, cost-benefit (B/C) analysis was applied to each of the top 20 night accident hot spots and the results of B/C ratios were between 0.67 and 4.20, showing that 11 out of 20 spot sections of expressway can have economic feasibility. This results indicate, with this kind of pavement marking applied to accident hot spots in rural expressway, better visibility and economic feasibility can be guaranteed through traffic accident reduction. Some limitations and future research agenda have also been discussed.

• Korean Journal of Materials Research
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• v.26 no.10
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• pp.561-569
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• 2016

$SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphorescent phosphors were synthesized using the polymerized complex method. Generally, phosphorescent phosphors synthesized by conventional solid state reaction show a micro-sized particle diameter; thus, this process is restricted to applications such as phosphorescent ink and paint. However, it is possible to synthesize homogeneous multi-component powders with fine particle diameter by wet process such as the polymerized complex method. The characteristics of $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ powders prepared by polymerized complex method with one and two step calcination processes were comparatively analyzed. Temperatures of organic material removal and crystallization were observed through TG-DTA analysis. The crystalline phase and crystallite size of the $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphorescent phosphors were analyzed by XRD. Microstructures and afterglow characteristics of the $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphors were measured by SEM and spectrofluorometry, respectively.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.37 no.5
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• pp.815-825
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• 2017

Visibility of lane marking is impaired at night or in the rain, which thereby threatens traffic safety. Recently, various studies and technologies have been developed to improve lane marking visibility, such as the extension of lane marking life expectancy (up to 1.5 times), improvement of lane marking equipment productivity, improvement of lane marking visibility by applying phosphorescent material mixed paint. Cost-benefit analysis was performed with considering various benefit items that can be expected. About 45% of traffic accidents would be prevented by improving lane marking visibility. Additionally, accident reduction benefit and traffic congestion reduction benefit were calculated as much as 246 billion KRW per year and 12 billion KRW per year, respectively, by reducing repaint cycle due to enhanced durability. 45 billion KRW per year is expected to reduced with improved lane detection performance of autonomous vehicle. Meanwhile, total increased cost when introducing phosphorescent material mixed paint to 91,195km of nationwide road is identified as 1922 billion KRW per year. However, economic feasibility could not be secured with 0.16 of cost-benefit ratio when applied to the road network as a whole. In case of "Accident Hot Spot" analyzing section window (400m), one or more fatality or two or more injured (one or more injured in case of less than 2 lanes per direction) per year were caused by pavement marking related accident, economic feasibility was secured. In detail, 3.91 of cost-benefit ratio is estimated with comparison of the installation cost for 5,697 of accident hot spot and accident reduction benefit. Some limitations and future research agenda have also been discussed.

• Journal of Adhesion and Interface
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• v.17 no.3
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• pp.110-116
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• 2016

A decrease in the retro-reflectivity of glass-bead-covered road paint because of a rainwater film significantly reduces the visibility of drivers at night, and has been considered as a critical cause of traffic accidents. For enhanced visibility, the microencapsulation of hydrophobically modified $SrAl_2O_4:Eu^{2+}$,$Dy^{3+}$ phosphorescent phosphor was carried out via suspension polymerization of methyl methacrylate (MMA). The effects of surface modification agent and radical initiator types, loading amount of phosphorescent phosphor, and microcapsule size on the phosphor content ($W_{TGA}$) in the luminous poly(methyl methacrylate) (PMMA) microcapsules were investigated by thermogravimetric analyses (TGA). It was found that the $W_{TGA}$ value was ranged from 7 wt% to 81 wt%, which suggests suspension polymerization is suitable for the preparation of luminous microcapsules with a wide range of phosphor content. At a lower loading amount of phosphor, the $W_{TGA}$ value obviously increased as the microcapsule size decreased; however, the $W_{TGA}$ values with a higher loading amount of phosphor were less affected by the microcapsule size. The luminous microcapsules with the size range of $425{\sim}710{\mu}m$ were collected and tested as a luminous road lanes. It was found that luminance intensities of the microcapsule-coated plates remained higher than $300mcd/m^2$ for up to 100 s in darkness after 20 min of light emitting diode lamp irradiation. The results suggest that the luminous microcapsules can be a candidate for the replacement of glass beads for enhanced visibility of drivers.