• Bulletin of the Korean Chemical Society
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• v.32 no.7
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• pp.2267-2273
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• 2011

A novel energetic material, 1-amino-1-(2,4-dinitrophenylhydrazinyl)-2,2-dinitroethylene (APHDNE), was synthesized by the reaction of 1,1-diamino-2,2-dinitroethylene (FOX-7) and 2,4-dinitrophenylhydrazine in N-methyl pyrrolidone (NMP) at 110 $^{\circ}C$. The theoretical investigation on APHDNE was curried out by B3LYP/6-311+$G^*$ method. The IR frequencies analysis and NMR chemical shifts were performed and compared with the experimental results. The thermal behavior of APHDNE was studied by DSC and TG/DTG methods, and can be divided into two crystal phase transition processes and three exothermic decomposition processes. The enthalpy, apparent activation energy and pre-exponential factor of the first exothermic decomposition reaction were obtained as -525.3 kJ $mol^{-1}$, 276.85 kJ $mol^{-1}$ and $10^{26.22}s^{-1}$, respectively. The critical temperature of thermal explosion of APHDNE is 237.7 $^{\circ}C$. The specific heat capacity of APHDNE was determined with micro-DSC method and theoretical calculation method, and the molar heat capacity is 363.67 J $mol^{-1}K^{-1}$ at 298.15 K. The adiabatic time-to-explosion of APHDNE was also calculated to be a certain value between 253.2-309.4 s. APHDNE has higher thermal stability than FOX-7.

• Journal of the Society of Naval Architects of Korea
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• v.58 no.6
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• pp.400-406
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• 2021

The primary effect of the far-field underwater explosion (UNDEX) is the whipping of the ship hull girder. This paper aims to verify why inelastic effects should be considered in the whipping response estimations from the UNDEX simulations. A navy ship was modeled using Timoshenko beam elements over the ship length uniformly keeping the constant midship section modulus. The transient UNDEX pressure was produced using two types of the Geers-Hunter doubly-asymptotic models: compressible and incompressible fluids. Because the UNDEX model based on incompressible fluid assumption provided more increased fluid volume acceleration in the bubble phase, the incompressible fluid-based UNDEX model was adopted for the inelastic whipping response analyses. The non-linear hull girder bending moment-curvature curve was used to embed inelastic effects in the UNDEX analyses where the Smith method was applied to derive the non-linear stiffness. We assumed two stand-off distances to see more apparent inelastic effects: 40.5 m and 35.5 m. In the case of the 35.5 m stand-off distance, there was a statistically significant inelastic effect in terms of the average of peak moments and the average exceeding proportional limit moments. For the conservative design of a naval ship under UNDEX, it is recommended to use incompressible fluid. In the viewpoint of cost-effective naval ship design, the inelastic effects should be taken into account.

• Journal of KIISE:Software and Applications
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• v.37 no.9
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• pp.669-675
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• 2010

For detecting requirement errors in early system development phase, the behaviors of a system should be described in formal methods and be analyzed with analysis techniques such as reachability analysis and cycle detection. However, since they are usually based on explicit exploration of system state space, state explosion problem may be occurred when a system becomes complex. That is, the memory and execution time for exploration exponentially increase due to a huge state space. In this paper, we analyze the fundamental causes of this problem in concurrent systems and explore the state space without composing concurrent state spaces for reducing the memory requirement for exploration. Also our new technique keeps a visited history minimally for reducing execution time. Finally we represent experimental results which show the efficiency of our technique.

• Journal of the Korean Society of Safety
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• v.16 no.4
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• pp.103-108
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• 2001

Explosive limit is one of the major physical properties used to determine the fire and explosion hazards of the flammable substances. Explosive limits are used to classify flammable liquids according to their relative flammability. Such a classification is important for the safe handling of flammable liquids which constitute the solvent mixtures. Explosive limits of all compounds and solvent mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Dalton, Le Chatelier and activity coefficient models. In this paper, Raoult,s law and van Laar equation(activity coefficient model) are shown to be applicable for the prediction of the explosive limits in the flammable ethylacetate-toluene system. The values calculated by the proposed equations were a good agreement with literature data within a given percent. From a given results, by the use of the proposed equations, it is possible to predict explosive limits of the other flammable mixtures. It is hoped eventually that this method will permit the estimation of the explosive Properties of flammable mixtures with improved accuracy and the broader application for other flammable stances.

• Journal of the Korean Ceramic Society
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• v.33 no.11
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• pp.1209-1216
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• 1996

MoSi2-Al2O3 composites were prepared by thermal explosion mode of self-propagating high temperature syn-thesis (SHS) using element powders of MoO3 Mo Si and Al. The combustion products of MoSi2 which have 10, 20, 30 and 40 wt% Al2O3 showed the molten state in the range of Mo to MoO3 6:1-9.5:1, 2:1-8:1, 1:1-5:1, and 1:1-3:1 (molar ratio) respectively. The combustion products which made least seperation the molten phase from the slag phase were in Mo/MoO3=9, 5:1, 8:1, 5:1 and 3:1 (molar ratio) respectively. Particles size of MoSi2 and Al2O3 in the combustion product were decreased as the molar ratio of Mo to MoO3 increase. By XRD analysis only MoSi2 and $\alpha$-Al2O3 peaks were identified in the combusion products, In case of MoSi2 containing 20wt% Al2O3 5.1wt% Al existed into MoSi2 grains and 30.7wt% Si and 7.7wt% Mo existed into Al2O3 grains. The relative density of MoSi2 containing 10, 20, 30 and 40 wt% Al2O3 were 82.7, 85.2, and 81.9% respectively. The fracture strength of MoSi2-Al2O3 composites increased with increasing Al2O3 and that of MoSi2-20wt% Al2O3 composite was 195 MPa.

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.93-94
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• 2007

An essential step for SERGI is to show the TRANSFORMER PROTECTOR (TP) efficacy for all transformers and all types of rupture of insulation. Its research program philosophy is thus to maintain a strong connection between experiments and the theoretical developments. Up to now, two TP test campaigns have been performed, both under the worst conditions by creating low impedance faults leading to electrical arcs inside the transformer tank dielectric oil. In 2002, Electricite de France performed 28 TP tests. Then, in 2004, a second campaign of 34 TP tests was carried out by CEPEL, the Brazilian independent High Voltage Laboratory. For the 62 tests, each transformer was equipped with the TP, which reacts directly to the moving dynamic pressure peak, shock wave, caused by the low impedance fault. When an electrical arc occurs, only one pressure peak is generated. The initial energy transfer is almost instantaneous, and so is the phase change. Because of the oil inertia, the gas is very quickly pressurised. As it is more difficult to vaporise a liquid than to crack oil-vapour into smaller molecules, the arc location would mainly remain in the gaseous phase after and less gas will be produced. As a result, when comparing tests for which pressure peaks are respectively equal to 8 bar (116 psi) and 8.8 bar (127 psi), the corresponding arc energies vary by an order 10 of magnitude (0.1 MJ and 1 MJ respectively). The correlation of the results obtained between arc energy and dynamic pressure demonstrates that the arc energy is not the key parameter during transformer tank explosion, which is in opposition with the common electrical engineers belief.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2006.11a
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• pp.299-302
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• 2006

We present an innovative means of numerically treating interfaces associated with chemically active energetic materials. Recent advances in wave tracking technique based on the Ghost Fluid Concept is extended to handle multi-material multi-phase interfaces associated with chemical environment associated with explosion. We show several work-in-progress applications of our code, including the impact problems involving both energetic and inert elements. Accurate modeling of the equation of state and the constitutive relations are also discussed

• Journal of The Korean Astronomical Society
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• v.26 no.1
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• pp.1-12
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• 1993

In order to explore the time dependence of the closure parameters of the two-fluid calculations for supernova remnants and the terminal shocks of stellar winds, we have considered a simple model in which the time evolution of the cosmic-ray distribution function was followed in the test-particle limit using the Bohm diffusion model. The particles are mostly accelerated to relativistic energy either in the free expansion phase of the SNRs or in the early phase of the stellar winds, so the evolution of the closure parameters during these early stages is substantial and should be followed correctly. We have also calculated the maximum momentum which is limited by either the age or the curvature of these spherical shocks. We found that SNRs expanding into the medium where the gas density decreases with the distance from the explosion center might be necessary to explain the observed power-law distribution of the galactic cosmic rays. The energy loss due to the escaping energetic particles has been estimated for the terminal shocks of the stellar winds.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.28 no.2
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• pp.187-195
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• 2015

The gas explosions in offshore installations are known to be very severe according to its geometry and environmental conditions such as leak locations and wind directions, and a dynamic response of structures due to blast loads depends on the load profile. Therefore, a parametric study has to be conducted to investigate the effects of the dynamic response of structural members subjected to various types of load shapes. To do so, a series of CFD analyses was performed using a full-scale FPSO topside model including detail parts of pipes and equipments, and the time history data of the blast loads at monitor points and panels were obtained by the analyses. In this paper, we focus on a structural dynamic response subjected to blast loads changing the magnitude of positive/negative phase pressure and time duration. From the results of linear/nonlinear transient analyses using single degree of freedom(SDOF) and multi-degree-of freedom(MDOF) systems, it was observed that dynamic responses of structures were significantly influenced by the magnitude of positive and negative phase pressures and negative time duration.

• Applied Microscopy
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• v.43 no.3
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• pp.127-131
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• 2013

The crystallization behavior in the $Al_{87}Ni_3Y_{10}$ and $Al_{88}Ni_3Y_9$amorphous alloys has been investigated. As-quenched $Al_{87}Ni_3Y_{10}$ amorphous phase decomposes by simultaneous formation of Al and intermetallic phase at the first crystallization step, while as-quenched $Al_{88}Ni_3Y_9$ amorphous phase decomposes by forming Al nanocrystals in the amorphous matrix. The density of Al nanocrystals is extremely high and the size distribution is homogeneous. Such a microstructure can result from rapid explosion of the nucleation event in the amorphous matrix or growth of the preexisting nuclei embedded in the as-quenched amorphous matrix. The final equilibrium crystalline phases and their distribution at 873 K are exactly same in both $Al_{87}Ni_3Y_{10}$ and $Al_{88}Ni_3Y_9$ alloys.