• 제목/요약/키워드: Phase transformation.

검색결과 1,432건 처리시간 0.03초

Heat Treatment Effects on the Phase Evolutions of Partially Stabilized Grade Zirconia Plasma Sprayed Coatings

  • Park, Han-Shin;Kim, Hyung-Jun;Lee, Chang-Hee
    • 한국표면공학회지
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    • 제34권5호
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    • pp.486-493
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    • 2001
  • Partially stabilized zirconia (PSZ) is an attractive material for thermal barrier coating. Zirconia exists in three crystallographic phases: cubic, tetragonal and monoclinic. Especially, the phase transformation of tetragonal phase to monoclinic phase accompanies significant volume expansion, so this transition generally results in cracking and contributes to the failure of the TBC system. Both the plasma sprayed ZrO$_2$-8Y$_2$O$_3$ (YSZ) coat and the ZrO$_2$,-25CeO$_2$,-2.5Y$_2$O$_3$ (CYSZ) coat are isothermally heat -treated at 130$0^{\circ}C$ and 150$0^{\circ}C$ for 100hr and cooled at different cooling rates. The monoclinic phase is not discovered in all the CYSZ annealed at 130$0^{\circ}C$ and 150$0^{\circ}C$. In the 150$0^{\circ}C$ heat-treated specimens, the YSZ contains some monoclinic phase while none exists in the 130$0^{\circ}C$ heat-treated YSZ coat. For the YSZ, the different phase transformation behaviors at the two temperatures are due to the stabilizer concentration of high temperature phases and grain growth. For the YSZ with 150$0^{\circ}C$-100hr annealing, the amount of monoclinic phase increased with the slower cooling rate. The extra oxygen vacancy, thermal stress, and c to t'phase transformation might suppress the t to m martensitic phase transformation.

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기계적 합금화 Iron Silicide의 열간성형 및 열처리에 의한 상변화 (Phase Transformation During Hot Consolidation and Heat Treatments in Mechanically Alloyed Iron Silicide)

  • 어순철;김일호;황승준;조경원;최재화
    • 한국재료학회지
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    • 제11권12호
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    • pp.1068-1073
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    • 2001
  • An n-type iron$silicide(Fe_{0.98}Co_{0.02}Si_2)$has been produced by mechanical alloying process and consolidated by vacuum hot pressing. Although as-milled powders after 120 hours of milling did not show an alloying progress,${\beta}-FeSi_2$phase transformation was induced by isothermal annealing at$830{\circ}C$for 1 hour, and the fully transformed${\beta}-FeSi_2$phase was obtained after 4 hours of annealing. Near fully dense specimen was obtained after vacuum hot pressing at$ 1100{\circ}C$with a stress of 60MPa. However, as-consolidated iron silicides were consisted of untransformed mixture of ${\Alpha}-Fe_2Si_5$and ${\varepsilon-FeSi$phases. Thus, isothermal annealing has been carried out to induce the transformation to a thermoelectric semiconducting${\beta}-FeSi_2$phase. The condition for${\beta}-FeSi_2$transformation was investigated by utilizing DTA, SEM, and XRD analysis. The phase transformation was shown to be taken place by a vacuum isothermal annealing at$830{\circ}C$and the transformation behaviour was investigated as a function of annealing time. The mechanical properties of${\beta}-FeSi_2$materials before and after isothermal annealing were characterized in this study.

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Analysis of 3-phase Induction Motor considering Current Regulator using DQ Transformation with Matrix Vector

  • Hong, Sun-Ki;Na, Yoo-Chung
    • Journal of international Conference on Electrical Machines and Systems
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    • 제3권2호
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    • pp.116-120
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    • 2014
  • 3-phase Induction machines are being used in industry and dq transformation from 3 phase of a, b, c is commonly used to analyze these machines. The equivalent circuits of d and q axis are however generally cross coupled and not simple to analyze. In this study, an analysis method of 3ph induction motor considering current regulator using dq transformation and matrix vector is proposed and it can explain the 3ph induction motor physically. This model does not need the separating process of d and q components. With this technique, the model becomes simple, is easy to understand in physical, and can get the same results with those from the other dq models. These simulation results of the proposed model are compared with those of other models for the conformation of the proposed method.

PZT 박막의 급속열처리시 Pb 함량이 상변태에 미치는 영향 (Effect of Pb Content on the Phase Transformation of Sputter-Deposited PZT Thin Film During RTA)

  • 주재현;길덕신;주승기
    • 한국세라믹학회지
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    • 제30권10호
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    • pp.803-810
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    • 1993
  • PbxZr0.4Ti0.6O3 thin films were prepared by reactive co-sputtering and annealed by RTA(Rapid Thermal Annealing) process. Effect of Pb content in PbxZr0.4Ti0.6O3 films on the phase transformation was intensively studied. It has been found out that depending on the Pb content as well as RTA temperature, crystal structure of PbxZr0.4Ti0.6O3 films change greatly. It turned out that transformation temperature for perovskite can be lowered and the width of transition temperature region was reduced by increasing Pb content in the film. And the lattice was expanded with increasing Pb content. With increasing RTA temperature, as-deposited phase was transformed into perovskite through three different transformation paths depending on Pb content. It was confirmed that activation energies for nucleation of perovskite structure are much larger than those of its growth.

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유한요소법을 이용한 용접부의 열전달 및 잔류응력 해석에 관한 연구 (A Study on Analysis of Heat Transfer and Residual Stress on the Weld Zone using FEM)

  • 김일수
    • 한국생산제조학회지
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    • 제9권5호
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    • pp.96-104
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    • 2000
  • This paper represents to develop a computer software system which is capable to analyze the phase transformation of high strength steel(BV-AH32) and to predict heat transfer and welding residual stress due to phase transformation during Gas Metal Arc(GMA) welding. The developed model was considered temperature dependent properties such as young's modules, coefficient of thermal expansion and yield stress as well as the double ellipsoidal heat distribution by the moving arc. From the results, it was found that the longitudinal and transverse residual stresses calculated by the coupled analysis of heat transfer, residual stress and phase transformation showed good agreement with the experimental data. In addition, the temperature distribution as well as longitudinal and transverse residual stresses of weldment by the 1-pass and 2-pass of welding were also determined.

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Ferromagnetic Resonance Observation of Martensitic Phase Transformation in Ni-Mn-Ga Ferromagnetic Shape Memory Films

  • Dubowik, J.;Kudryavtsev, Y.V.;Lee, Y.P
    • Journal of Magnetics
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    • 제9권2호
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    • pp.37-39
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    • 2004
  • Polycrystalline Ni-Mn-Ga films have been deposited onto mica substrates held at 720 K by flash-evaporation method. At room temperature the films have a tetragonal structure with a = b = 0.598 and c = 0.576 nm typical for bulk $Ni_2MnGa$ below a martensitic transformation. Temperature measurements of ferromagnetic resonance reveal a martensitic phase transformation at 310 K. The transformation brings about a substantial decrease in the effective magnetization and a drastic increase in the ferromagnetic resonance linewidth due to a strong increase in the magnetic anisotropy in the martensitic phase.

복소 벡터와 dq 변환을 이용한 교류기 모델링에 관한 연구 (A Study on AC Machine Modeling using Complex Vector and dq Transformation)

  • 홍선기;박진호
    • 전기학회논문지
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    • 제61권11호
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    • pp.1601-1605
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    • 2012
  • Three-phase voltage and current is applied to the three-phase alternating current motors which are commonly used in industry. Three phase variables of a, b, c are converted into d, q, 0 axis and the AC machines are modeled and analyzed. Basically the coordinate transformation or d-q transformation is used for convenience, a few steps are needed to analyze the motor performances - separating d and q components, establishing each equivalent circuit, and solving the differential equations of the circuits. In this study, a modeling technique of induction motor using complex vector is proposed and it can explain the induction motor physically. This method does not need the separating process of d and q components. With this technique, the model becomes simple, is easy to understand in physical, and can get the same results with those from the other models. These simulation results of the proposed model are compared with them for the conformation of the proposed method.

열간압연 고강도강의 온도 및 재질제어 (Temperature and Property Control of High Strength Steel in Hot Strip Mills)

  • 박철재
    • 한국생산제조학회지
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    • 제20권6호
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    • pp.817-823
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    • 2011
  • This paper proposes a cooling stop temperature control(CST) and a phase transformation control(PTR) which aim at obtaining the uniform temperature and quality along the longitudinal direction of the high strength steel on the run-out table(ROT) process. The problems of the temperature control are analyzed for the conventional steel and the new control concepts are derived from a time-temperature transformation(TTT) diagram. The proposed control technologies are verified from the simulation results under the temperature prediction model by the heat transfer governing equation, and the temperature estimation simulator. It is shown through the field test of the hot strip mills that the phase transformation ratio of the high strength steel is considerably improved by the proposed temperature controls.

Change of Phase Transformation Temperature at Fabricated Membrane using Sol-gel Method

  • Cheong, Hun;Choi, Duck-Kyun;Cheong, Deock-Soo
    • 한국세라믹학회지
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    • 제38권10호
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    • pp.876-880
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    • 2001
  • The supported and unsupported boehmite ($\gamma$-AlOOH) membranes were prepared using a boehmite sol. The supported membrane was consisted of a porcelain support, two intermediate $\alpha-{Al_2}{O_3}$ layers, and a top boehmite membrane. XRD patterns showed that the supported top membrane had a higher $\theta-$ to $\alpha-{Al_2}{O_3}$ transformation temperature compared to the unsupported membrane. This result was also confirmed from microstructural study of the membrane. The shift in the phase transformation temperature should be explained by difference of a stress generated in the supported top membrane due to interaction between the support layers and the top membrane.

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TSMG법에 의한 RE-123계 초전도 단결정 제조에 미치는 seed의 영향 (Effect of seed on the TSMG processing of RE-123 superconductor)

  • 오용택;신동찬;한상철;성태현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.59-62
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    • 2003
  • This study investigated the phase transformation of the $REBa_2Cu_3O_{7-x}$ (RE=Nd, Gd, By) superconductor, and CCT (Continuous-Cooling-Transformation) along with the TTT (Time-Temperature-Transformation) diagrams are suggested according to the isothermal and continuous cooling heat-treatments. According to result of fabricated single crystal of RE-123 superconductor through TSMG method based on phase transformation neted among heat treatment process, when the ionic radius elements was decreased, RE-211 phase was well-distributed. According to result that examine about seed of pretreatment effect of TSMG method, magnetic hysteresis improved when preprocess among oxygen atmosphere in same seed. and used after. Effect of miscut expressed good superconducting special quality in case miscut uses big seed.

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