• 제목/요약/키워드: Phase transformation.

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불평형 전원시스템을 고려한 3상 능동전력 필터에 관한 연구 (A Study on a 3-phase Active Power Filter Under Unbalanced Input Voltage)

  • 이승요;조준석;최규하;목형수;박영길;신우석
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 1997년도 전력전자학술대회 논문집
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    • pp.233-238
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    • 1997
  • An important assumption for the active power filter design using instantaneous power theory and the d-q transformation method in a 3-phase power system is based on balanced 3-phase system. However, under pratical conditions, the 3-phase power system can not be continuously balanced due to unbalanced loading. In this paper, a method to control the 3-phase active power filer using instantaneous power theory and the d-q transformation under unbalanced power system is presented and the theoretical results are verified by simulated results.

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알루미나 여과막의 상전이와 미세구조 변화: I. 지지체의 기공율에 의한 영향 (Change of Phase Transformation and Microstructure of Alumina Membrane: I. Effect by Porosity of Support)

  • 정훈;황광택;최덕균;정덕수
    • 한국재료학회지
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    • 제12권3호
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    • pp.205-210
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    • 2002
  • The HPS(High Porosity Support, 39.3%) and the LPS( Low Porosity Support, 18.7%) were fabricated to investigate the phase transformation and the chance of microstructure with porosity of alumina support. Alumina sol was made using aluminum tri-sec $butoxide(ATSB,\; Al(O-Bu)_3)$, the membrane on porous support with different porosity and the membrane without support were fabricated. The $\theta$-to ${\alpha}-A1_2O_3$ phase transformation in the membranes was investigated using thin film X-ray diffraction (XRD), and the change of microstructure was observed using scanning electron microscopy(SEM). XRD patterns showed that the membrane on LPS and HPS had 10$0^{\circ}C$, 5$0^{\circ}C$ higher $\theta$-to ${\alpha}-A1_2O_3$ transformation temperature compared to the unsupported membrane. A similar effect was also observed in microstructure of the membranes, theoritical temperature difference were 97$^{\circ}C$ and 44$^{\circ}C$ by Crapeyron equation.

기계적 합금화로 제조한 N형 β의 상변화 및 열전 특성 (Phase Transformation and Thermoelectric Properties of N-tyre β Processed by Mechanical Alloying)

  • 어순철
    • 한국재료학회지
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    • 제12권5호
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    • pp.375-381
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    • 2002
  • N-type ${\beta}-FeSi_2$ with a nominal composition of $Fe_{0.98}Co_{0.02}Si_2$ powders has been produced by mechanical alloying process and consolidated by vacuum hot pressing. As-milled powders were of metastable state and fully transformed to ${\beta}-FeSi_2$ phase by subsequent isothermal annealing. However, as-consolidated $Fe_{0.98}Co_{0.02}Si_2$ consisted of untransformed mixture of ${\alpha}-Fe_2Si_ 5$ and $\varepsilon$-FeSi phases. Isothermal annealing has been carried out to induce the transformation to a thermoelectric semiconducting ${\beta}-FeSi_2$ phase. The transformation behavior of ${\beta}-FeSi_2$ was investigated by utilizing DTA, a modified TGA under magnetic field, SEM, and XRD analyses. Isothermal annealing at $830^{\circ}C$ in vacuum led to the thermoelectric semiconducting ${\beta}-FeSi_2$ phase transformation, but some residual metallic $\alpha$ and $\varepsilon$ phases were unavoidable even after prolonged annealing. Thermoelectric properties were remarkably improved by isothermal annealing due to the transformation from metallic $\alpha$ and $\varepsilon$ phases to semiconducting phases.

분말야금법으로 제작한 NiAl합금의 기계적성질 및 형상기억특성 (Mechanical Properties and Shape Memory Characteristics of NiAl Alloys by Powder Metallurgy)

  • 한창석;진성윤;권혁구
    • 한국재료학회지
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    • 제30권5호
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    • pp.231-238
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    • 2020
  • The composition of martensite transformation in NiAl alloy is determined using pure nickel and aluminum powder by vacuum hot press powder metallurgy, which is a composition of martensitic transformation, and the characteristics of martensitic transformation and microstructure of sintered NiAl alloys are investigated. The produced sintered alloys are presintered and hot pressed in vacuum; after homogenizing heat treatment at 1,273 K for 86.4 ks, they are water-cooled to produce NiAl sintered alloys having relative density of 99 % or more. As a result of observations of the microstructure of the sintered NiAl alloy specimens quenched in ice water after homogenization treatment at 1,273 K, it is found that specimens of all compositions consisted of two phases and voids. In addition, it is found that martensite transformation did not occur because surface fluctuation shapes did not appear inside the crystal grains with quenching at 1,273 K. As a result of examining the relationship between the density and composition after martensitic transformation of the sintered alloys, the density after transformation is found to have increased by about 1 % compared to before the transformation. As a result of examining the relationship between the hardness (Hv) at room temperature and the composition of the matrix phase and the martensite phase, the hardness of the martensite phase is found to be smaller than that of the matrix phase. As a result of examining the relationship between the temperature at which the shape recovery is completed by heating and the composition, the shape recovery temperature is found to decrease almost linearly as the Al concentration increases, and the gradient is about -160 K/at% Al. After quenching the sintered NiAl alloys of the 37 at%Al into martensite, specimens fractured by three-point bending at room temperature are observed by SEM and, as a result, some grain boundary fractures are observed on the fracture surface, and mainly intergranular cleavage fractures.

Dependence of Phase Stability of Tetragonal Zirconia Polycrystal on Dopants

  • Chon, Uong
    • The Korean Journal of Ceramics
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    • 제4권4호
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    • pp.297-303
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    • 1998
  • The effect of aliovalent dopants, $ Nb_2O_5$ and MnO, on the phase stability of 12 mol% ceria partially-stabilized zirconia (Ce-TZP) polycrystals was studied. Both dopants (MnO and $ Nb_2O_5$) significantly increased the stability of the tetragonal zirconia phase (Mb temperature lower than liquid nitrogen temperature). The enhancement of the stability of the tetragonal phase in Ce-TZP doped with 1 mol% of Mno(Ce-TZP/MnO) andCe-TZP doped with 1 mol% of $ Nb_2O_5$(Ce-TZP/$ Nb_2O_5$) were explained by the significant reduction of the driving force, -${\Delta}$Gchem, for the tetragonal-to-mono-clinic phase transformation caused by the addition of MnO and $ Nb_2O_5$. The enhanced stability of the tetragonal phase in the Ce-TZP and Al2O3 composite (Ce-TZP/$Al_2O_3$) is believed to be caused by smaller grain size, moderate reduction in the chemical driving force and increase in the strain energy barrier to the transformation. Mechanical properties of the Ce-TZP and the Ce-TZP/$Al_2O_3$ with (i) the same grain size and (ii) the same Mb temperature were examined by measuring stress-strain behavior in 3 point bending. The Ce-TZP/$Al_2O_3$ composite doped with 1.3w% MnO (Ce-TZP/$Al_2O_3$/MnO), which had the same grain size as the Ce-TZP and De-TZP/$Al_2O_3$ showed more transformation plasticity than either the Ce-TZP or the Ce-TZP/$Al_2O_3$ composite. The Ce-TZP wihch had the same Mb temperature as that of the Ce-TZP/$Al_2O_3$/MnO did not show any transformation plasticity.

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상전이가 섭입 슬랩의 좌굴에 미치는 영향과 지체구조적 암시 (Effect of phase transformations on buckling behavior of subducting slab and tectonic implication)

  • 이창열
    • 지질학회지
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    • 제54권6호
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    • pp.657-675
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    • 2018
  • 하부 맨틀의 상부에서 관찰되는 섭입된 해양판의 겉보기 두꺼워짐은 과거 연구를 통해 슬랩 좌굴에 의한 것으로 제안되었다. 그러나, 맨틀의 상전이가 슬랩 좌굴에 미치는 영향을 정량적으로 평가하고 이를 규모 법칙으로 검증한 연구는 거의 이루어지지 못하였다. 이 연구에서는 상전이를 고려한 2차원 컴퓨터 섭입 모델링을 수행하여 상전이가 슬랩 좌굴에 미치는 영향에 대해 정량적으로 평가하고 규모 법칙으로 검증하였다. 실험 결과는 410 km 깊이에서 발생하는 감람석-와드슬레이아이트 상전이가 슬랩 좌굴의 발달에 중요한 영향을 미친다는 것을 보였다. 흡열 상전이는 상부 맨틀에서 섭입 슬랩의 침강을 가속시켜 660 km 깊이에 존재하는 불연속면에 빠르게 도달하게 한다. 그러나 660 km 깊이에 존재하는 링우다이트-페로브스카이트+마그네시오우스타이트 상전이는 슬랩 좌굴의 발달에 상대적으로 작은 영향을 미치는데 그 상전이가 섭입 슬랩의 하부 맨틀 침강을 지연시켜 전이대에 섭입한 슬랩을 누적시키기 때문이다. 그럼에도 불구하고 슬랩 좌굴은 규모 법칙을 20% 이내의 오차에서 잘 만족한다. 이처럼 슬랩 좌굴은 맨틀에서 발생하는 보편적인 현상으로써 자바-순다 및 동북 일본 섭입대에서 관찰되는 하부 맨틀의 상부와 전이대에서의 슬랩 좌굴을 잘 설명한다. 또한 백악기 시기 경상 분지가 겪은 주기적인 압축 및 인장이 슬랩 좌굴에 의한 가능성을 암시한다.

유한요소해석을 이용한 핫스탬핑 공정시 발생하는 온도 이력 및 상변태 해석 (Analysis of Phase Transformation and Temperature History during Hot Stamping Using the Finite Element Method)

  • 윤승채;김도형
    • 소성∙가공
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    • 제22권3호
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    • pp.123-132
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    • 2013
  • Hot stamping, which is the hot pressing of special steel sheet using a cold die, can combine ease of shaping with high strength mechanical properties due to the hardening effect of rapid quenching. In this paper, a thermo-mechanical analysis of hot stamping using the finite element method in conjunction with phase transformations was performed in order to investigate the plastic deformation behavior, temperature history, and mechanical properties of the stamped car part. We also conducted a fully coupled thermo-mechanical analysis during the stamping and rapid quenching process to obtain the mechanical properties with the consideration of the effects of plastic deformation and phase transformation on the temperature histories at each point in the part. The finite element analysis could provide key information concerning the temperature histories and the sheet mechanical properties when the phase transformation is properly considered. Such an analysis can also be used to determine the effect of cyclic cooling on the tooling.

고온열전재료 $FeSi_2$의 변태거동 (Transformation Behaviour of High Temperature Thermoelectric $FeSi_2$)

  • 은영효;민병규;이동희
    • Applied Microscopy
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    • 제25권3호
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    • pp.90-98
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    • 1995
  • In the Fe-Si system, a mixture of a($Fe_{2}Si_5$) - and ${\epsilon}$(FeSi)-composition powders was sintered and heat-treated subsequently at various temperatures and time to get thermoelectric ${\beta}$-phase($FeSi_2$) compacts. The different transformational sequences depending on the heat treating temperature were found through the investigation into phase transformation and microstructural development. That is, a rapid eutectoid decomposition of ${\alpha}{\to}{\beta}+Si$ occurred together with a accompanying slow reaction between the dispersed Si formed by above decomposition and the preexisted ${\epsilon}$ phase at temperatures below $830^{\circ}C$. The unreacted Si and the micropores formed due to the density change upon the transformation coarsened as heat treating time elapsed. At temperatures above $880^{\circ}C$, however, transformation was proceeded by a peritectoid reaction of ${\alpha}+{\epsilon}{\to}{\beta}$. It took at least 200min. to achieve 90% volume fracion of transformed ${\beta}$ phase, and the growth of micro-pores was also observed in this transformational sequence with prolonged heat treating time.

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원전 밸브용 경면처리 합금의 캐비테이션 에로젼 (cavitation erosion) 거동에 관한 연구 (The Study on the Cavitation Erosion Behavior of Hardfacing Alloys for Nuclear Power Plants)

  • 오영민;김윤갑;김선진
    • 한국재료학회지
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    • 제12권4호
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    • pp.308-316
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    • 2002
  • The cavitation erosion behavior of wear-resistant hardfacing alloys such as Co-base Stellite 6, Fe-base Norem 02 and new Fe-base alloy were investigated up to 50 hours by using a 20kHz vibratory cavitation erosion test equipment. The crack, initiated easily at the interfaces between matrix and hard second phase, was repressed effectively in Stellite 6 because the matrix was hardened by phase transformation. For this reason, Stellite 6 showed an excellent cavitation erosion resistance compared to Norem 02. The phase transformation also occurred in Norem 02, but the increase of volume fraction of the interfaces caused the crack to be initiated frequently, thus resulting in a 1arge material loss. The matrix of NewAlloy was hardened effectively by vlongrightarrow$\alpha$' phase transformation and the volume fraction of the interfaces was very small compared to Norem 02. This caused the propagation of crack to the matrix to be repressed effectively. Therefore, NewAlloy showed a very excellent cavitation erosion resistance. It wasn't considered that the cavitation erosion resistance of NewAlloy was influenced the temperature of the bath filled with a distilled water up to $80^{\circ}C$.

CuAlNi 형상기억합금의 결정립 미세화에 따른 시효효과 (The Effect of Ageing on Grain Refinement of CuAlNi Shape Memory Alloy)

  • 양권승;박창선;장우양
    • 열처리공학회지
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    • 제8권1호
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    • pp.65-74
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    • 1995
  • This research was performed to investigate the effect of ageing on grain refinement of 82wt%Cu-13.5wt%Al-4.5wt%Ni-0.1wt% misch metal alloy with ageing temperature and time. The results obtained in this study are as follows; The variation of transformation temperature with ageing temperature had very influence on ageing time at $300^{\circ}C$. But it had not influence on ageing time at $100^{\circ}C$. The variation of transformation temperature after second reversed transformation cycle was not occured in martensitic phase ageing, but $M_s$ point was appeared equally with third reversed transformation cycle in parent phase ageing. The variation of $M_s$ point was not nearly with ageing time at $100^{\circ}C$ ageing temperature. But it was decreasing with ageing time at $300^{\circ}C$ ageing temperature and $A_s$ point was increasing with ageing time. Structure of parent phase ageing was being M18R martensitic and N2H martensitic phase. It was found that ${\alpha}$ and ${\gamma}_2$ phase were created by ageing of long time at $300^{\circ}C$ ageing temperature.

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