• Title/Summary/Keyword: Phase retardation

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Temperature Effect on Effective Diffusion Coefficients of Zn and Cd through Column Diffusion Tests (칼럼 확산 실험을 통한 아연 및 카드뮴의 유효확산계수에 미치는 온도영향)

  • Dho, Nam-Young;Lee, Seung-Rae
    • Journal of the Korean GEO-environmental Society
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    • v.3 no.1
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    • pp.13-26
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    • 2002
  • In this study, column diffusion tests for Cd and Zn were conducted at $15^{\circ}C$ and $55^{\circ}C$ to investigate a temperature effect on effective diffusion coefficient. An increase in temperature from $15^{\circ}C$ to $55^{\circ}C$ caused up to ten times larger diffusion coefficient for each heavy metal. Besides, it caused the increased retardation of heavy metals, and hence the effective diffusion coefficient should be overestimated as we use an overestimated retardation factor to calibrate the coefficient. The results of sequential extraction analyses showed that Zn was occluded in carbonate phase and this trend was getting prominent with the increase in temperature. As for Cd, it was partitioned mainly in the exchangeable phase(over 60%) at any temperature.

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Birefringence Analysis of a Uniaxially Anisotropic Substrate Based on the Trajectory of the Transmission Ellipsometric Pseudoconstant in Polar Coordinates (유사 투과타원상수의 극좌표상 자취에 기반한 단축 이방성 기층의 복굴절 해석)

  • Yang, Sung Mo;Kim, Sang Youl
    • Korean Journal of Optics and Photonics
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    • v.30 no.4
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    • pp.159-166
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    • 2019
  • The trajectory of the transmission ellipsometric pseudoconstant ${\rho}=tan{\psi}_{\mu}e^{i{\Delta}_{\mu}}$ of a uniaxially anisotropic substrate like PET forms a circle in polar coordinates, as the phase-retardation angle is varied at a fixed azimuthal angle. The radius as well as the center's position of this circle are functions of the azimuthal angle only. This circle passes through the point (1,0), and the center of this circle is located on the real axis. These characteristics of the circle are examined analytically, and are utilized to derive simple expressions for the azimuthal angle and the phase-retardation angle of the uniaxially anisotropic substrate using the measured transmission ellipsometric constant. Finally, we confirm that the derived expressions are well applied to the analysis of the optical anisotropy of a PET film.

Effect of Microstructure on Fracture Behavior of Multi-phase Low-density Steel (다상계 저비중강의 파괴거동에 미치는 미세조직의 영향)

  • Shin, Sun-Kyoung;Park, Seong-Jun;Cho, Kyung Mox
    • Journal of the Korean Society for Heat Treatment
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    • v.26 no.6
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    • pp.306-316
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    • 2013
  • Microstructure and fracture behavior of a multi-phase low-density steel were investigated. After hot-rolling and heat treatment, the microstructure of low-density steel was composed of coarse ferrite grains and elongated bands which include second phases such as austenite, martensite and ${\kappa}$-carbide depending on holding time during isothermal heat treatment. After tensile test, microcracks were observed at martensite or ${\kappa}$-carbide interface in the elongated bands. Coarse ferrite grains showed cleavage fracture behavior regardless of second phase. The cleavage fracture of ferrite could be attributed to their coarse grain size and solute atoms that increase ductile-to-brittle transition temperature of ferrite. Despite of the tendency of cleavage fracture in coarse ferrite grains, a specimen having coarse spheroidized ${\kappa}$-carbide particles in the elongated bands showed high total elongation of 30%. Thus, the easiness of plastic deformation in the elongated band seems to play an important role in retardation of cleavage crack formation in coarse ferrite grains.

Preparation of Silicon Carbide with Sialon (시알론을 첨가한 탄화규소 세라믹스의 제조)

  • Lee, J.K.;Park, J.G.;Lee, E.G.;Kim, H.
    • Journal of the Korean Ceramic Society
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    • v.37 no.3
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    • pp.247-255
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    • 2000
  • Silicon carbide with sialon was prepared by hot pressing and transient liquid-phase sintering, and the effects of sintering atmosphere and starting phases on their microstructural characteristics were investigated. The sintered SiC with Sialon composition(Y2O3, AlN, Si3N4) in argon atmosphere had high sintered density and large aspect ratio. But sintered specimens in nitrogen atmosphere showed low aspect ratio and small grian size, becuase of the retardation of phase transformation and grain growth. Addition of Y-Sialon powder to SiC also retarded the phase transformation to ${\alpha}$-SiC from ${\beta}$-SiC and densification. The SiC specimen prepared from the starting ${\beta}$-SiC powder with Sialon composition(Y2O3, AlN, Si3N4) showed the highest fracture toughness about 6.0 MPa$.$m1/2.

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The Effect of Mn on Microstructural Change in 93W-5.6Ni-1.4Fe Heavy Alloy (텅스텐 중합금에 Mn 첨가에 따른 미세조직)

  • 김은표
    • Journal of Powder Materials
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    • v.5 no.1
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    • pp.35-41
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    • 1998
  • The effect of Mn on the densification and the microstructural change in W heavy alley was investigated with adopting the improved Mn-adding method. In order to avoid the pore formation problems associated with Mn powder mixing to the other constituent powders, Mn was added afterwards to the sintered heavy alloy; Mn powder was spread homogeneously on the surface of the sintered heavy alloy compact, and this Mn powder contained specimen was resintered at the same sintering temperature. As expected, the resintered specimen showed the pore free microstructure because Mn was reduced separately from the other constituent elements. It was also founded that W grains grew rapidly at the initial stage of resintering treatment due to the activated reprecipitation of the excess W atoms substituted by Mn atoms, but the growth rate of W grains was slowly lowered with the prolonged sintering time, especially, compared to the Mn free heavy alloy. Such a retardation of grain growth should be attributed to the decreased W solubility in the Mn contented matrix phase. Furthermore, Mn addition resulted in the decrease of contiguity by improving the wetting between matrix phase and W grain.

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Solid Phase Crystallizations of Sputtered and Chemical Vapor Deposited Amorphous Hydrogenated Silicon (a-Si:H) Thin Film (스퍼터링 및 화학기상 증착 비정질 수소화 실리콘박막의 고상결정화)

  • 김형택
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.4
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    • pp.255-260
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    • 1998
  • Behavior of solid phase crystallizations (SPC) of RF sputtered and LPCVD amorphous hydrogenated silicon film were investigated. LPCVD films showed the higher degree of crystallinity and larger grain size than sputtered films. The applicable degree of crystallinity was also obtained from sputtered films. The deposition method of amorphous silicon film influenced the behavior of post annealing SPC. Observed degree of crystallinity of sputtered films strongly depended on the partial pressure of hydrogen in deposition. The higher deposition temperature of sputtering provided the better crystallinity after SPC. Due to the high degree of poly-crystallinity, the retardation of larger grain growth was observed on sputtering film.

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Design of High Repetition Nd:YAG Laser Transmitter Module for Rangefinder (거리측정용 고반복 Nd:YAG 레이저 발진부 설계)

  • Park, Y.C.;Choi, Y.S.;Kim, H.K.;Kwon, W.G.;Kang, E.C.
    • Proceedings of the KIEE Conference
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    • 1993.07a
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    • pp.460-463
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    • 1993
  • In this paper, The laser transmitter module is designed as the subsystem of the high repetitive laser rangefinder. The module consists of high voltage power supply, high voltage control circuits, high voltage discharger, electro-optic Q-switch driver, and laser resonator. The high voltage power supply is composed of 2-phase flyback converter. And it has 220W power level and 78% conversion efficiency. From the Q-switch driver of the crossed porro resonator, the phase retardation voltage is switched from 600V to -1500V with 200ns falling time. The module can be operated up to 15Hz. And it generates the laser pulse which has 20ns width and 80mJ.

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Low temperature solid phase crystallization of amorphous silicon thin film by crystalline activation

  • Kim, Hyung-Taek;Kim, Young-Kwan
    • Journal of Korean Vacuum Science & Technology
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    • v.2 no.2
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    • pp.97-100
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    • 1998
  • We have investigated the effects of crystalline activation on solid phase crystallization (SPC) of amorphous silicon (a-Si) thin films. Wet blasting and self ion implantation were employed as the activation treatments to induce macro or micro crystalline damages on deposited a-Si films. Low temperature and larger grain crystallization were obtained by the applied two-step activation. High degree of crystallinity was also observed on both furnace and rapid SPC. crystalline activations showed the promotion of nucleation on the activated regions and the retardation of growth in an amorphous matrix in SPC. The observed behavior of two-step SPC was strongly dependent on the applied activation and annealing processes. It was also found that the diversified effects by macro and micro activations on the SPC were virtually diminished as the annealing temperature increased.

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One dimensional inhomogeneous phase modulation effects on the MTF of an optical system (일차원적 비균일 위상변조가 광학계의 MTF에 미치는 영향)

  • 홍경희
    • Korean Journal of Optics and Photonics
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    • v.10 no.1
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    • pp.10-14
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    • 1999
  • One dimensional inhomogeneous phase modulation effects on the MTF of optical system was investigated. The lens under test was a doublet made in Korea. It was 36 mm effective diameter, 128.04 mm effective focal length. The ray-fans and spot diagrams were calculated and presented on the picture for on-axis and off-axis (field of view, $1^{\circ}$ and $2^{\circ}$). Phase modulation was carried out by positioning a phase modulator close contacted with the lens under test. One was linear type that had linearly increasing phase retardation and the other was stepped type which had phase difference $\pi$ for each step. The MTFs were measured on the Gaussian image plane and were compared with one another. The MTFs of linear type phase modulated apertures had a little lower values than the MTF of unmodulated aperture for on-axis but most of all the MTFs of one dimensional phase modulated aperture are improved than the MTF of unmodulated aperture.

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Study on the Flame Retardation and Thermal Resistance for CPE Rubber Material Added Etching By-product of Aluminum (알루미늄 엣칭부산물을 첨가한 CPE 고무재료의 난연성 및 내열성 연구)

  • Kim, Kyung Hwan;Lee, Chang Seop
    • Journal of the Korean Chemical Society
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    • v.45 no.4
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    • pp.341-350
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    • 2001
  • Aluminum Hydroxide was employed as a thermal retardent and flame retardent for Chloropolyethylene (CPE) rubbery materials which is the construction material of automotive oil cooler hose. and then cure characteristics, physical properties, thermal resistance and flame retardation of compounded rubber were investigated, and optimum mixing conditions of rubber and flame retarding agent were deduced from the experimental results. CPE rubber material which has excellent properties of chemical corrosion resistance and cold resistance and inexpensive in price was used to prepare rubber specimen. The by-product of ething, produced from the process of surface treatment of aluminum was processed to aluminum hydroxide via crushing and purification, which is characterized by XRD, PSA, SEM and ICP-AES techniques in terms of phase, size, distribution, morphology and components of particles and then mixed to CPE rubber materials in the range of 0~80 phr. Hardness, tensile strength, elongation and thermal properties of compounded rubber specimens were tested. The optimum mixing ratio of rubber to additives to give maximum effect on thermal resistance and flame retardation, within the range of tolerable specification for rubber materials, was determined to be 40 phr. The flame retardation of CPE rubber materials was found to be increased by 5 times at this mixing ratio.

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