• Title/Summary/Keyword: Phase potential

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One step facile synthesis of Au nanoparticle-cyclized polyacrylonitrile composite films and their use in organic nano-floating gate memory applications

  • Jang, Seok-Jae;Jo, Se-Bin;Jo, Hae-Na;Lee, Sang-A;Bae, Su-Gang;Lee, Sang-Hyeon;Hwang, Jun-Yeon;Jo, Han-Ik;Wang, Geon-Uk;Kim, Tae-Uk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.307.2-307.2
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    • 2016
  • In this study, we synthesized Au nanoparticles (AuNPs) in polyacrylonitrile (PAN) thin films using a simple annealing process in the solid phase. The synthetic conditions were systematically controlled and optimized by varying the concentration of the Au salt solution and the annealing temperature. X-ray photoelectron spectroscopy (XPS) confirmed their chemical state, and transmission electron microscopy (TEM) verified the successful synthesis, size, and density of AuNPs. Au nanoparticles were generated from the thermal decomposition of the Au salt and stabilized during the cyclization of the PAN matrix. For actual device applications, previous synthetic techniques have required the synthesis of AuNPs in a liquid phase and an additional process to form the thin film layer, such as spin-coating, dip-coating, Langmuir-Blodgett, or high vacuum deposition. In contrast, our one-step synthesis could produce gold nanoparticles from the Au salt contained in a solid matrix with an easy heat treatment. The PAN:AuNPs composite was used as the charge trap layer of an organic nano-floating gate memory (ONFGM). The memory devices exhibited a high on/off ratio (over $10^6$), large hysteresis windows (76.7 V), and a stable endurance performance (>3000 cycles), indicating that our stabilized PAN:AuNPs composite film is a potential charge trap medium for next generation organic nano-floating gate memory transistors.

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A Plant Modeling Case Based on SysML Domain Specific Language (SysML DSL 기반 플랜트 모델링 케이스)

  • Lee, Taekyong;Cha, Jae-Min;Kim, Jun-Young;Shin, Junguk;Kim, Jinil;Yeom, Choongsub
    • Journal of the Korean Society of Systems Engineering
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    • v.13 no.2
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    • pp.49-56
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    • 2017
  • Implementation of Model-based Systems Engineering(MBSE) depends on a model supporting efficient communication among engineers from various domains. And SysML is designed to create models supporting MBSE but unfortunately, SysML itself is not practical enough to be used in real-world engineering projects. SysML is designed to express generic systems and requires specialized knowledge, so a model written in SysML is less capable of supporting communication between a systems engineer and a sub-system engineer. Domain Specific Languages(DSL) can be a great solution to overcome the weakness of the standard SysML. A SysML based DSL means a customized SysML for a specific engineering domain. Unfortunately, current researches on SysML Domain Specific Language(DSL) for the plant engineering industry are still on the early stage. So as the first step, we have developed our own SysML based Piping & Instrumentation Diagram (P&ID) creation environment and P&ID itself of a specific plant system, using a widely used SysML authoring tool called MagicDraw. P&ID is one of the most critical output during the plant design phase, which contains all information required for the plant construction phase. So a SysML based P&ID has a great potential to enhance the communication among plant engineers of various disciplines.

Effect of n-type Dopants on CoSb3 Skutterudite Thermoelectrics Sintered by Spark Plasma Sintering (Spark Plasma Sintering 법으로 제조한 CoSb3 Skutterudite계 열전소재의 n형 첨가제 효과)

  • Lee, Jae-Ki;Choi, Soon-Mok;Lee, Hong-Lim;Seo, Won-Seon
    • Korean Journal of Materials Research
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    • v.20 no.6
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    • pp.326-330
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    • 2010
  • $CoSb_3$ Skutterudites materials have high potential for thermoelectric application at mid-temperature range because of their superior thermoelectric properties via control of charge carrier density and substitution of foreign atoms. Improvement of thermoelectric properties is expected for the ternary solid solution developed by substitution of foreign atoms having different valances into the $CoSb_3$ matrix. In this study, ternary solid solutions with a stoichiometry of $Co_{1-x}Ni_xSb_3$ x = 0.01, 0.05, 0.1, 0.2, $CoSb_{3-y}Te_y$, y = 0.1, 0.2, 0.3 were prepared by the Spark Plasma Sintering (SPS) system. Before the SPS synthesis, the ingots were synthesized by vacuum induction melting and followed by annealing. For phase analysis X-ray powder diffraction patterns were checked. All the samples were confirmed as single phase; however, with samples that were more doped than the solubility limit some secondary phases were detected. All the samples doped with Ni and Te atoms showed a negative Seebeck coefficient and their electrical conductivities increased with the doping amount up to the solubility limit. For the samples prepared by SPS the maximum value for dimensionless figure of merit reached 0.26, 0.42 for $Co_{0.9}Ni_{0.1}Sb_3$, $CoSb_{2.8}Te_{0.2}$ at 690 K, respectively. These results show that the SPS method is effective in this system and Ni/Te dopants are also effective for increasing thermoelectric properties of this system.

A High Power 60 GHz Push-Push Oscillator Using Metamorphic HEMT Technology (Metamorphic HEMT를 이 용한 60 GHz 대역 고출력 Push-Push 발진기)

  • Lee Jong-Wook
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.17 no.7 s.110
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    • pp.659-664
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    • 2006
  • This paper reports a high power 60 GHz push-push oscillator fabricated using $0.12{\mu}m$ metamorphic high electron-mobility transistors(mHEMTs). The devices with a $0.12{\mu}m$ gate-length exhibited good DC and RF characteristics such as a maximum drain current of 700 mA/mm, a peak gm of 660 mS/mm, an $f_T$ of 170 GHz, and an $f_{MAX}$ of more than 300 GHz. By combining two sub-oscillators having $6{\times}50{\mu}m$ periphery mHEMT, the push-push oscillator achieved a 6.3 dBm of output power at 59.5 GHz with more than - 35 dBc fundamental suppression. The phase noise of - 81.5 dBc/Hz at 1 MHz offset was measured. This is one of the highest output power obtained using mHEMT technology without buffer amplifier, and demonstrates the potential of mHEMT technology for cost effective millimeter-wave commercial applications.

Spatio-Spectral Coherence Analysis of ERP signals for Attentional Visual Stimulus (시각 자극의 집중에 따른 뇌유발전위의 공간-주파수 상관 분석)

  • Lee, ByuckJin;Yoo, SunKook
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.10
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    • pp.217-228
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    • 2013
  • In this paper, the brain function in relation with human's visual attention was investigated by means of coherence and bicoherence methods. Throughout experimentation with attentional visual stimulus ERP (Event Related Potential) data and synthesized simulated data with different combinations of parameters, it is demonstrated that bicoherence and coherence can be useful to reveal the phase synchronies between different frequency bands at fixed scalp location, and between different scalp locations at fixed frequency band, respectively. Both methods are also affected by time interval from the onset, and the level of white noise added. The phase coupled relationships among ${\Theta}$, ${\delta}$, and ${\alpha}$ bands, and between frontal and central lobes were observed for attentional tasks, while those were little observable for inattentional tasks, which can show brain's functional spatio-spectral differences associated with human's attention.

Comparison of the ICT Adoption Pattern;In the Case of Korea and the U.S.

  • Yang, Kyung-Hoon;Lee, Sang-Gun
    • 한국경영정보학회:학술대회논문집
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    • 2007.06a
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    • pp.545-550
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    • 2007
  • The aim of this paper is to find out whether there is a difference in adopting and/or diffusing the information and communication technology (ICT) between countries. If there is, what are the primary factors that keep some countries from adopting and diffusing ICT while others do? To analyze the above problem, we adopted the Unified Theory of Acceptance and Use of Technology (UTAUT) suggested by Venkatesh et al. (2003), which consists of effort expectancy, performance expectancy and social influence. We also use the innovation diffusion functions, which are known to have the S-shape and are made up of the introduction, growth, maturity and decline phases. We do not, however, consider the decline phase, because the ICT that we are considering is not believed to be in that phase. Therefore, we researched how the three factors affect adoption in the three phases. We selected the cellular phone as the ICT, because it is considered to be the most popularly used ICT and its technology has been developing rapidly. We surveyed the cellular phone adopters in Korea, and the U.S. for 15 years from 1989 to 2003. Korea, and the U.S. represent newly developed and developed countries, respectively. For the data analysis, a survival analysis was used, as it could explain the characteristics of the potential adopters or non-adopters. We found that the ICT diffusion patterns, as well as the ICT diffusion factors, of the two countries were different. Therefore, we believe that the results of our research can be used in building strategies on reducing the digital divide gaps between countries.

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A Feasibility Study of Using Diesel/Biodiesel-Pyrolysis Oil-Butanol Blends in a Diesel Engine (디젤유/바이오디젤유-열분해유-부탄올 혼합유의 디젤 엔진 적용 가능성에 관한 연구)

  • Kim, Hoseung;Jang, Youngun;Lee, Seokhwan;Kim, Taeyoung;Kang, Kernyong;Yoon, Junkyu
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.5
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    • pp.116-125
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    • 2014
  • Pyrolysis oil (PO), derived from biomass through fast pyrolysis process have the potential to displace significant amounts of petroleum fuels. The PO derived from wood has been regarded as an alternative fuel to be used in diesel engines. However, the use of PO in a diesel engine is very limited due to its poor properties like low energy density, low cetane number, high acidity and high viscosity of PO. Therefore, one of the easiest way to adopt PO to diesel engine without modifications is blended with other fuels that have high centane number. However, PO that has high amount of polar chemicals is immiscible with non polar hydrocarbons of diesel or biodiesel. Thus, to stabilize a homogeneous phase of diesel/biodiesel-PO blends, a proper surfactant should be used. Nevertheless, PO which was produced from different biomass type have varied characteristics and this complicates the selection of a suitable additive for a specific PO-diesel emulsion. In this regard, a more simple approach such as the use of a co-solvent like ethanol or butanol to induce a more stable phase of the PO-diesel mixture could be a promising alternative. In this study, a diesel engine operated with diesel/biodiesel-PO-butanol blends was experimentally investigated. Performance and gaseous & particle emission characteristics of a diesel engine were examined under the engine loads of IMEP 0.2 ~ 0.8MPa.

Dynamic Respiratory Measurements of Corynebacterium glutamicum using Membrane Mass Spectormetry

  • Wittmann.Christoph;Yang, Tae-Hoon;Irene Kochems;Elmar Heinzle
    • Journal of Microbiology and Biotechnology
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    • v.11 no.1
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    • pp.40-49
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    • 2001
  • The present work presents a novel approach for the dynamic quantification of respiration rates on a small scale by using lysine-producing Corynebacterium glutamicum ATCC 21253. Cells sampeld from batch cultures at different times were incubated ina 12-ml scale bioreactor equipped with a membrane mass spectrometer. Under dynamic conditions, gas exchange across the gas-liquid phase, specific respiration rates, and RQ values were precisely measured. For this purpose, suitable mass balances were formulated. The transport coefficients for $O_2$ and $CO_2$, crucial for calculating the respiration activity, were determined as $k_La_{O2}=9.18h^{-1}$ and $k_La_{CO2}=5.10h^{-1}$ at 400 rpm. The application of the proposed method to batch cultures of C. glutamicum ATCC 21253 revealed the maximum specific respiration rates of $q_{O2}=8.4\;mmol\;g^{-1}h^{-1}\;and\;q_{CO2}=8.7\;mmol\;g^{-1}h^{-1}$ in the middle of the exponential growth phase after 5 h of cultivation. When the cells changed from growth to lysine production due to the depletion of the essential amino acids theonine, methionine, and leucine, $q_{O2}\;and\;q_{CO2}$ decreased significantly and RQ increased. The respiration data exhibited an excellent agreement with previous cultivations of the strain [13]. This confirms the potential of the developed approach to realistically reflect the metabolic activities of cells at their point of sampling. The short-term influence of added threonine, methionine, and leucine was highest during the shift from growth to lysine production, where $q_{O2}\;and\;q_{CO2}$ increased 50% within one minute after the pulse addition of these compounds. Non-growing, yet lysine-producing cells taken from the end of the batch cultivation revealed no metabolic stimulation with the addition of threonine, methionine, and leucine.

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Fabrication and Electrical Properties of Anodic Aluminum Oxide Membrane with Various Anodizing Temperatures for Biosensor (바이오센서로 응용을 위한 양극산화알루미늄의 양극산화 온도에 따른 제작 및 전기적 특성)

  • Yeo, Jin-Ho;Lee, Sung-Gap;Kim, Yong-Jun;Lee, Young-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.6
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    • pp.394-398
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    • 2014
  • We fabricated the electrolyte-dielectric-metal (EDM) sensor on the base of AAO (anodic aluminum oxide) template with variation of the anodizing temperature. When a surface is immersed or created in an aqueous solution, a discontinuity is formed at the interface where such physicochemical variables as electrical potential and electrolyte concentration change significantly from the aqueous phase to another phase. Because of the different chemical potentials between the two phases, charge separation often occurs at the interfacial region [1]. This interfacial region, togeter with the charged surface, is usually known as the electrical double layer (EDL) [2]. The structural and electrochemical properties of AAO sensor were investigated for applications in capacitive pH sensors. To change the thickness of the AAO template, the anodizing temperature was varied from $5^{\circ}C$ to $20^{\circ}C$, the thickness of the AAO template invreased from 300 nm to 477 nm. The pH sensitivity of sensors with the anodizing temperature of $20^{\circ}C$ showed the highest value of 56.4 mV/pH in the pH range of 3 to 11. The EDM sensor with the anodizing temperature of $20^{\circ}C$ exhibited the best long-term stability of 0.037 mV/h.

Identification of M-1, S-1 Cortex Using Combined Intraoperative SEP and Cortical Stimulation - A Case Report - (수술중 체성감각 유발전위 및 대뇌피질 자극을 이용한 일차 운동피질영역과 일차 감각피질영역의 확인 - 증례보고 -)

  • Lee, Jae-Uhn;Son, Byung-Chul;Kim, Moon-Chan;Kang, Joon-Ki
    • Journal of Korean Neurosurgical Society
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    • v.29 no.7
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    • pp.954-958
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    • 2000
  • In the removal of small subcortical lesion in the eloquent area like sensory-motor cortex, the prevention of neurologic deficit is important. We present our technique of identification of M-1, S-1 cortex in a case of subcortical granuloma located in sensorymotor cortex. To accurately localize mass, stereotactic craniotomy was planned. At the beginning of procedure, functional MRI of motor cortex was done with stereotactic headframe in place. Next, the stereotactic craniotomy about 4 cm was done under propofol anesthesia for cortical mapping. After reflection of dura, central sulcus was identified with phase-reversal response of intraoperative SEP(somatosensory evoked potential) of contralateral median nerve. Then the patient was awakened, and direct cortical stimulation was done. We observed the muscle contractions of elbow, hand and fingers and the paresthesia over forearm, hand, fingers on the M-1 and S-1 cortex. Through cortical mapping and stereotactic guidance, we concluded that the mass lie immediately posterior to central sulcus, then the mass was carefully removed through small transsulcal approach, opening about 1 cm of rolandic sulcus.

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