• Title/Summary/Keyword: Phase potential

Search Result 1,934, Processing Time 0.028 seconds

Reconfigurable Intelligent Surface assisted massive MIMO systems based on phase shift optimization

  • Xuemei Bai;Congcong Hou;Chenjie Zhang;Hanping Hu
    • KSII Transactions on Internet and Information Systems (TIIS)
    • /
    • v.18 no.7
    • /
    • pp.2027-2046
    • /
    • 2024
  • Reconfigurable Intelligent Surface (RIS) is an innovative technique to precisely control the phase of incident signals with the help of low-cost passive reflective elements. It shows excellent potential in the sixth generation of mobile communication systems, which not only extends wireless coverage but also boosts channel capacity. Considering that multipath propagation and a high number of antennas are involved in RIS in assisted mega multiple-input multiple-output (MIMO) systems, it suffers from severe channel fading and multipath effects, which in turn lead to signal instability and degradation of transmission performance. To overcome this obstacle, this essay suggests an improved gradient optimization algorithm to dynamically and optimally adjust the phase of the reflective elements to counteract channel fading and multipath effects as a strategy. In order to overcome the optimization problem of falling into local minima, this paper proposes an adaptive learning rate algorithm based on Adagrad improvement, which searches for the global optimal solution more efficiently and improves the robustness of the optimization algorithm. The suggested technique helps to enhance the estimate of channel efficiency of RIS-assisted large MIMO systems, according to simulation results.

Variation of Oxygen Nonstoichiometry of Porous $La_{0.6}Ca_{0.4}MnO_{3-{\delta}}$ SOFC-Cathode under Polarization

  • Mizusaki, Junichiro;Harita, Hideki;Mori, Naoya;Dokiya, Masayuki;Tagawa, Hiroaki
    • The Korean Journal of Ceramics
    • /
    • v.6 no.2
    • /
    • pp.177-182
    • /
    • 2000
  • At the porous $La_{0.6}Ca_{0.4}MnO_{3-{\delta}}$(LCM)/YSZ electrodes of solid oxide fuel cells (SOFC), the electrochemical redox reaction of oxygen proceeds via the triple boundary (TPB) of gas/LCM/YSZ. The surface diffusion of adsorbed oxygen on LCM has been proposed as the rate determining process, assuming the gradient of oxygen chemical potential from the outer surface of porous layer to TPB. Along with the formation of this gradient, oxygen nonstoichiometry in the bulk of LCM may varies. In this paper, an electrochemical technique was described precisely to determine the variation of oxygen content in LCM of porous LCM/YSZ under polarization. It was shown that the oxygen potential in LCM layer under large cathodic polarization is much lower than that in the gas phase, being determined from the electrode potential and Nernst equation.

  • PDF

Voltammetric Studies of Anion Transfer Reactions Across a Microhole Array-Water/PVC-NPOE Gel Interface

  • Hossain, Md. Mokarrom;Girault, Hubert H.;Lee, Hye-Jin
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.5
    • /
    • pp.1734-1740
    • /
    • 2012
  • Voltammetric characterization of hydrophilic anion transfer processes across a 66 microhole array interface between the water and polyvinylchloride-2-nitrophenyloctylether gel layer is demonstrated. Since the transfer of hydrophilic anions including $Br^-$, $NO_3{^-}$, $I^-$, $SCN^-$ and $ClO_4{^-}$ across the liquid/gel interface usually sets the potential window within a negative potential region, a highly hydrophobic organic electrolyte, tetraoctylammonium tetrakis(pentafluorophenyl)borate, providing a wider potential window was incorporated into the gel phase. The transfer reaction of perchlorate anions across the microhole-water/gel interface was first studied using cyclic voltammetry and differential pulse voltammetry. The full voltammetric response of perchlorate anion transfer was then used as a reference for evaluating the half-wave transfer potentials, the formal transfer potentials and the formal Gibbs transfer energies of more hydrophilic anions such as $Br^-$, $NO_3{^-}$, $I^-$, and $SCN^-$. The current response associated with the perchlorate anion transfer across the micro-water/gel interface versus the perchlorate concentration was also demonstrated for sensing applications.

MicroRNA-497 Suppresses Proliferation and Induces Apoptosis in Prostate Cancer Cells

  • Wang, Li;Li, Bo;Li, Lei;Wang, Te
    • Asian Pacific Journal of Cancer Prevention
    • /
    • v.14 no.6
    • /
    • pp.3499-3502
    • /
    • 2013
  • MicroRNAs (miRNAs) are a class of endogenously expressed small, non-coding, single-stranded RNAs that negatively regulate gene expression, mainly by binding to 3'- untranslated regions (3'UTR) of their target messenger RNAs (mRNAs), which cause blocks of translation and/or mRNA cleavage. Recently, miRNAprofiling studies demonstrated the microRNA-497 (miR-497) level to be down-regulated in all prostate carcinomas compared with BPH samples. The purpose of this study was to investigate the potential role of miR-497 in human prostate cancer. Proliferation, cell cycle and apoptosis assays were conducted to explore the potential function of miR-497 in human prostate cancer cells. Results showed that miR-497 suppressed cellular growth and initiated G0/G1 phase arrest of LNCaP and PC-3 cells. We also observed that miR-497 increased the percentage of apoptotic cells by increasing caspase-3/7 activity. Taken together, our results demonstrated that miR-497 can inhibit growth and induce apoptosis by caspase-3 activation in prostate cancer cells, which suggest its use as a potential therapeutic target in the future.

Emulsification of Chloroprene Rubber (CR) by Interfacial Chemistry; Stabilization and Enhancement of Mechanical Properties

  • Lee, Eun-Kyoung
    • Elastomers and Composites
    • /
    • v.52 no.4
    • /
    • pp.257-265
    • /
    • 2017
  • In this work, CR (Chloroprene Rubber) was emulsified by phase-inversion emulsification with nonionic surfactants (NP-1025, LE-1017, and OP-1019) and an anionic surfactant (SDBS; sodium dodecylbenzenesulfonate), and its stabilization was investigated through a study of its adsorption characteristics, zeta potential, and flow behavior. As the amount of the mixed surfactant increased, the droplet size decreased, resulting in the increase of viscosity. In particular, a CR emulsion with a lower absorbance in the UV spectrum exhibited the highest zeta potential. The results of this experiment showed that the CR emulsion prepared using (LE-1017) and SDBS was the most stable. In this study, calcium hydroxide and aluminum hydroxide were added to enhance the mechanical properties of the CR emulsion, and the relationship between tensile strength, tear strength and surface free energy were investigated. The tensile and tear strengths of the CR emulsion incresed as the amount of calcium hydroxide and aluminum hydroxide increased. The highest tensile and tear strengths and surface free energy were observed for additions of 1.0% calcium hydroxide and 0.80% aluminum hydroxide, respectively. It was concluded that the interfacial bonding strength was improved by the even dispersion of calcium hydroxide and aluminum hydroxide in the CR emulsion.

Studies on the surface charge and coagulation characteristics of suspended particles in the aqueous phase (수용액상에서 부유 미립자의 표면전위와 응집특성에 관한 연구)

  • 박상원;김성국;홍대일
    • Journal of Environmental Science International
    • /
    • v.8 no.3
    • /
    • pp.363-369
    • /
    • 1999
  • This study aimed to elucidate the relationship between theoretical parameters affecting the coagulation process and the real coagulation phenomenon applied to the dye wastewater. Emphasis was placed on the effective removal of the suspend particulates. Parameters studied in this study are pH, coagulant concentration and surface potential. Optimal dosages of coagulants by the measurement of the zeta potential at lower then $25^{\circ}C$ are 5\times$10^P-3}$ M of $FeCl_3 and 1.4\times10^{-6}M of Fe_2(SO_4)_3$. The results were well agreeded with the separate Jar-test results. Emphasis was also placed on the relationship between water quality and the content of SS. It was found that the COD and DOC were reduced to 65% and 85%, respectively. The turbidity at the above condition was reduced from 300 NTU to 0~1 NTU. Efforts were made to clarify the behavior of the suspend solid as affecting the water quality. 12,000~13,000 particles/10mL in $1~50\mu$m size range particulates in the raw wastewater were reduced to 300 particle/10mL in the same range after treatment. This research has proposed the methodology to find out the optimal condition of coagulation for small scale wastewater treatment plant or chemical coagulation process.

  • PDF

Oxygen Reduction Mechanism and Electrode Properties of (La,Sr)$MnO_3$-YSZ Composite Cathode for Solid Oxide Fuel Cell (Part II: Electrode Properties) (고체산화물 연료전지용 (La,Sr)$MnO_3$-YSZ 복합체 양극의 산소환원 반응기구 및 전극 특성 (Part II: 전극 특성))

  • 김재동;김구대;이기태
    • Journal of the Korean Ceramic Society
    • /
    • v.38 no.1
    • /
    • pp.93-99
    • /
    • 2001
  • (La,Sr)MnO$_3$(LSM)-YSZ 복합체 양극에 있어서 소결온도 및 전극두께와 cathodic potential이 전극 특성에 미치는 영향을 고찰하였다. 양극의 소결은 삼상계면의 양을 결정하는 중요한 변수로 LSM 단미 양극과 YSZ가 40 wt% 포함된 LSM-YSZ 복합체 양극 모두 120$0^{\circ}C$에 소결했을 때 가장 낮은 분극저항을 나타내었다. 또한 양극 후막의 두께가 얇아지면 양극의 in-plane 저항이 증가하여 ohmic 저항이 증가하였는데, LSM-YSZ 복합체 양극의 경우 약 30$mu extrm{m}$ 정도의 전극두께가 가장 효과적인 전극 특성을 나타내었다. 한편, LSM-YSZ 복합체 양극에 -0.5 V의 cathodic potential을 인가함에 따라 양극에서 일어나는 산소환원반응의 활성이 증가하였는데, 1가 산소이온의 표면확산반응의 분극저항은 감소하였으나, 고주파수 영역에서 나타나는 산소이온전달반응의 저항은 거의 변화하지 않았다. 이것은 Mn의 환원에 의한 양극표면에 생성된 산소공공에 기인한다.

  • PDF

Natural Inhibitors for $CO_2$ Hydrate Formation (천연 물질을 이용한 이산화탄소 하이드레이트 형성 억제)

  • Sa, Jeong-Hoon;Lee, Bo Ram;Park, Da-Hye;Han, Kunwoo;Chun, Hee Dong;Lee, Kun-Hong
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2011.11a
    • /
    • pp.122.1-122.1
    • /
    • 2011
  • The motivation for this work was the potential of hydrophobic amino acids such as glycine, L-alanine, and L-valine to be applied as thermodynamic hydrate inhibitors (THIs). To confirm their capabilities in inhibiting the formation of gas hydrates, three-phase (liquid-hydrate-vapor) equilibrium conditions for carbon dioxide hydrate formation in the presence of 0.1 to 3.0 mol% amino acid solutions were determined in the range of 273.05 to 281.45 K and 14.1 to 35.2 bar. From quantitative analyses, the inhibiting effects of the amino acids (on a mole concentration basis) decreased in the following order: L-valine > L-alanine > glycine. The application of amino acids as THIs has several potential advantages over conventional methods. First, the environmentally friendly nature of amino acids as compared to conventional inhibitors means that damage to ecological systems and the environment could be minimized. Second, the loss of amino acids in recovery process would be considerably reduced because amino acids are non-volatile. Third, amino acids have great potential as a model system in which to investigate the inhibition mechanism on the molecular level, since the structure and chemical properties of amino acids are well understood.

  • PDF

Polygonum cuspidatum Extract Induces Apoptosis in Human Uterine Cervical Carcinoma ME-180 Cells (호장근(虎杖根)이 자궁경부암세포(子宮經部癌細胞)의 성장억제(成長抑制) 및 세포고사(細胞枯死)에 미치는 영향)

  • Choi, Byun-Tak;Kim, Yeon-Hee;Lee, Dong-Nyung;Kim, Hyung-Jun
    • The Journal of Korean Obstetrics and Gynecology
    • /
    • v.19 no.1
    • /
    • pp.1-13
    • /
    • 2006
  • Purpose : Polygonum cuspidatum extract is an oriental herb which has been used for uterine diseases. In this study, the effects of Polygonum cuspidatum extract were investigated on inducing growth inhibition and apoptosis of human uterine cervical carcinoma cells. Methods : Viability of Polygonum cuspidatum extract-induced ME-180 cells was measured by MTT assay. Apoptotic cells were visualized by EtBr/AcOr staining under fluorescent microscope. Nucleosomal DNA fragmentation was assayed by agarose gel electrophoresis. Cell cycle distribution and changes in mitochondrial membrane potential were observed by flow cytometry. Results : Polygonum cuspidatum extract induced ME-180 cell death in a dose- and time-dependent manner. In the cells treated with Pc, the population of cells at sub-G1 phase significantly increased, and the condensed nuclei, apoptotic bodies and nucleosome-sized DNA were detected. Moreover, reduction in mitochondrial membrane potential was detected. Conclusion : Polygonum cuspidatum extract inhibits the growth and proliferation of ME-180 cells by apoptotic induction and facilitates its activity initiated by depolarization of mitochondria.

  • PDF

A study on the Stability of Rail way Construction on the Reclaimed Land for Domestic Marine Clay Using the Seismic Analysic (연약지반상 지진하중을 고려한 철도노반의 안정성 검토에 관한 연구)

  • Kim Young-Soo;Kim Moo-Ill
    • Proceedings of the KSR Conference
    • /
    • 2004.10a
    • /
    • pp.1071-1076
    • /
    • 2004
  • The purpose. in this study. is to analyze liquefaction potential of Inchon International Airport at the Area Phase ' I ' for Railway Construction of all, seismic response was analyzed using the computer program, Shake91. Four methods proposed by Seed & Idriss. Eurocode, Iwasaki & Tatsuoka. and Ishihara were used for assessment of liquefaction potential and safety factors calculated form these methods are compared. Based on the results of seismic response analysis, the maximum acceleration at the ground surface is larger than that evaluated site factor effect by using site factor because these areas are composed of very loose sand clay. Especially, in the case of analysis with long period earthquake data. it is appeared that the acceleration of earthquake is amplified more largely. Therefore, accurate seismic response analysis is suggested for the design on the important structures on reclaimed land. The analytical results of liquefaction potential show that the increments of N-value and effective overburden pressure with remediation make safety factors increase. Through comparing the safety factors evaluated from four method, the safety factor calculated by See & Idriss method in the lowest one and it is found that the SPT N-value effect the safety factor very largely. And, Iwasaki & Tatsuoka method is affected by various factors such as average grain size. fine contents, confining pressure. In conclusion. to minimize earthquake Risk by liquefaction, the efficient remediation is essential and seismic response analysis should be carride out.

  • PDF