• Title/Summary/Keyword: Phase potential

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Reaction Characteristics of Rubbers and LPG fuels in LPLi Fuel Supply System (고무류 반응특성이 LPG액상공급시스템의 연료분사기 성능에 미치는 영향)

  • Kim, Chang-Up;Park, Cheol-Woong;Choi, Kyo-Nam;Kang, Kern-Yong
    • Journal of ILASS-Korea
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    • v.12 no.2
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    • pp.94-100
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    • 2007
  • The liquid phase LPG injection (LPLi) system (the third generation technology) has been considered as one of the next generation fuel supply systems for LPG vehicles, since it has a very strong potential to accomplish the higher power, higher efficiency, and lower emission characteristics than the mixer type (the second generation technology) fuel supply system. To investigate the characteristics of LPG residue in liquid phase LPG injection system, various rubbers in LPG fuel system were reacted with LPG fuels during 3 months. The experimental results showed that the residue of a cover rubber in a fuel pump after test increased 10 times higher than that before test. Furthermore, the amount of sulfur, nitrogen species which are considered as main sources in deposit formation in the LPLi fuel injector were also found to be higher than that in original LPG fuel. And rubber properties of fuel pump cover were decreased after reaction test compared with those of the original rubber. Therefore, the rubber for fuel pump cover is not suitable for a proper material in LPLi fuel system. And these results can provide more information if a motor company shares the data of core rubber parts in field test LPLi vehicles.

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The antitumor activities of Acanthopanax senticosus Harms(ASH) in human gastric cancer AGS cell lines (가시오가피 에탄올추출물의 AGS위암세포주에서 세포주기억제효과)

  • Lee, Sun-Dong;Ko, Seong-Gyu;Shin, Heon-Tae;Shin, Yong-Cheol
    • Journal of Society of Preventive Korean Medicine
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    • v.15 no.3
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    • pp.127-140
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    • 2011
  • Objectives : The research was conducted to confirm the effect of Acanthopanax senticosus harms(ASH) on the anti-tumor activities in AGS human gastric cancer cells. Methods : To examine the potential anti-tumor effect of ASH, we performed many experiments. After processing AGS cancer cells with varying concentrations 80% ethanol ASH extract, analyses by MTT, flow cytometer(FACS) and western blot were used. Results : AGS cancer cells showed decreased cell proliferation and increased contents of S phase when treated with ASH. Moreover, the Western blot experiment showed that ASH affected S phase cell cycle-related molecules(Cyclin A, p21 and p16) in AGS cells. ASH also inhibited EGFR-STAT3 pathway in AGS human gastric cancer cells. Conclusion : Based on these results, we observed that ASH arrested the cell cycle at S phase and inhibited the phosphorylation of EGFR and STAT3 proteins which reduce the cell cycle and the manifestation of the genes that are related to inhibiting cell growth in AGS cells. It can be concluded that ASH can be used in developing medicine for gastric cancer.

THERMAL SHOCK FRACTURE OF SILICON CARBIDE AND ITS APPLICATION TO LWR FUEL CLADDING PERFORMANCE DURING REFLOOD

  • Lee, Youho;Mckrell, Thomas J.;Kazimi, Mujid S.
    • Nuclear Engineering and Technology
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    • v.45 no.6
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    • pp.811-820
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    • 2013
  • SiC has been under investigation as a potential cladding for LWR fuel, due to its high melting point and drastically reduced chemical reactivity with liquid water, and steam at high temperatures. As SiC is a brittle material its behavior during the reflood phase of a Loss of Coolant Accident (LOCA) is another important aspect of SiC that must be examined as part of the feasibility assessment for its application to LWR fuel rods. In this study, an experimental assessment of thermal shock performance of a monolithic alpha phase SiC tube was conducted by quenching the material from high temperature (up to $1200^{\circ}C$) into room temperature water. Post-quenching assessment was carried out by a Scanning Electron Microscopy (SEM) image analysis to characterize fractures in the material. This paper assesses the effects of pre-existing pores on SiC cladding brittle fracture and crack development/propagation during the reflood phase. Proper extension of these guidelines to an SiC/SiC ceramic matrix composite (CMC) cladding design is discussed.

Gas phase diagnostics of high-density $SiH_4/H_2$ microwave plasma

  • Toyoda, Hirotaka;Kuroda, Toshiyuki;Ikeda, Masahira;Sakai, Junji;Ito, Yuki;Ishijima, Tatsuo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.94-94
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    • 2010
  • As a new plasma source for the plasma enhanced chemical vapor deposition (PCVD) of ${\mu}c$-Si deposition, we have demonstrated a microwave-excited plasma source, which can produce high density (${\sim}10^{12}\;cm^{-3}$) plasma with low electron temperature (~1 eV) and low plasma potential (~10 V). In this plasma source, microwave power radiated from slot antenna is distributed along the plasma-dielectric interface in large area and this enables us to produce uniform high-density plasma in large area. To optimize deposition conditions, deep understanding of gas phase chemistry is indispensable. In this presentation, we will discuss on the gas phase diagnostics of microwave $SiH_4/H_2$ plasma such as $SiH_4$ dissociation or $SiH_3$ radical profile as well as deposited film properties.

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Synthesis and Analysis of Nanosized TiO2 Particles Using a Tube Furnace (튜브 전기로를 이용한 TiO2 나노입자의 합성 및 특성 분석)

  • 배귀남;현정은;이태규;정종수
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.3
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    • pp.411-419
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    • 2004
  • Titania particles are widely used as a photocatalyst to treat various contaminants in air and water. Titania particles were formed by vapor-phase oxidation of titanium tetraisopropoxide (TTIP) in a tube furnace between 773 and 1,273 K. The effect of process variables such as furnace temperature, flow rate of carrier air, and flow rate of sheath air on powder size and phase characteristics was investigated using a scanning mobility particle sizer (SMPS), transmission electron microscopy (TEM) and X-ray diffraction (XRD). The size distribution of synthesized titania particles was characterized with mode diameter and peak concentration. The mode diameter ranging from 20 to 80 nm decreased with increasing flow rates of sheath air and carrier air, and increased with increasing furnace temperature. The peak concentration increased with increasing flow rates of sheath air and carrier air The best synthetic condition for high production rate can be derived from the experimental data set represented by mode diameter and peak concentration. The crystal structure of synthesized titania particles was found to be anatase phase, ensuring high photocatalytic potential.

Enhanced Essential Oil Formation by Two-phase Culture of Mentha piperita Cells in Shake Flask and Air-lift Bioreactors

  • Kim, Teresa;Kim, Tae-Yong;Bae, Geun-Won;Chae, Young-Am;Lee, Hyong-Joo;Chung, In-Sik
    • Journal of Microbiology and Biotechnology
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    • v.5 no.6
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    • pp.364-369
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    • 1995
  • Effect of two-phase culture on Mentha piperita cell growth and essential oil formation was investigated using shake flask and air-lift bioreactors. LiChroprep RP-B(RP-B) addition did not impair M. piperita cell growth, but resulted in stimulated formation of essential oils and increased ratios of extracellular oil to intracellular oil formation. However, the combined use of RP-B and chitosan elicitor was not synergistic. Volumetric productivity of essential oils in RP-B treated culture using cell-recycled air-lift bioreactor was $6.9\;\mu\textrm{g}/l{\cdot}day$ which was substantially higher than that obtainable from the control. Our results demonstrate the potential of a second phase to enhance overall productivity for M. piperita cell culture.

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Effect of Aging Treatment on Pitting Corrosion of Super Duplex Stainless Steel Weld Metal (슈퍼듀플렉스강 용접금속의 공식에 미치는 시효처리의 영향)

  • Lee, Jae-Hyoung;Seo, Gi-Jeong;Jung, Byong-Ho;Kang, Chang-Yong
    • Journal of Power System Engineering
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    • v.18 no.2
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    • pp.70-76
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    • 2014
  • A specimen of weld metal was prepared by GTA welding with weld wire of super duplex stainless steel. Aging treatment was conducted for the sample at the temperature range of 700 to $900^{\circ}C$ for 5 to 300 minutes. The effect of aging temperature and time to pitting corrosion of weld metal has been investigated and the results were derived as follows. The volume fraction of ${\sigma}$ phase tends to increase with an increase of aging temperature and time. Pitting potential Ep representing pitting corrosion was found to tend to decrease with an increase of aging time at 700 to $900^{\circ}C$. And most of the pits formed near the ${\sigma}$-phase in the ferrite and seemed to propagated to austenite.

Synthesis of CuSbS2 and CuSbSe2 Nanocrystals by a Mechanochemical Method (기계화학적 방법에 의한 CuSbS2와 CuSbSe2 나노입자의 합성)

  • Park, Bo-In;Lee, Seung Yong;Lee, Doh-Kwon
    • Current Photovoltaic Research
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    • v.5 no.4
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    • pp.140-144
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    • 2017
  • $CuSbS_2$ (CAS) and $CuSbSe_2$ (CASe) nanocrystals (NCs), which consist of earth-abundant elements, were synthesized by a mechanochemical method. Elemental precursors such as copper, antimony, sulfur, and selenium were used without adding any organic solvents or additives. The NCs were synthesized by milling for a few hours. The sudden phase changes occurred by self-ignition and propagation, as previously observed in other mechanochemical synthetic processes. The XRD, Raman, and TEM analysis were carried out to determine the crystallinity and secondary phase of the as-synthesized CAS and CASe NCs, confirming the phase-pure synthesis of CAS and CASe. Optical properties were investigated by UV-Vis spectroscopy and it was observed that the band gap energies were about 1.1 and 1.5 eV, respectively for CAS and CASe, suggesting the potential for the use as solar cell materials. The NC colloids dispersed in anhydrous ethanol were prepared and coated on Mo substrates by a facile doctor-blade method. The investigation on the solar cell properties of the as-synthesized materials is underway.

Ab Initio Conformational Study on Ac-Flp-NHMe: Stereoelectronic Effects on Proline Conformation

  • Song, Il-Keun;Kang, Young-Kee
    • Proceedings of the Korean Biophysical Society Conference
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    • 2003.06a
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    • pp.76-76
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    • 2003
  • We report here the results on N-acetyl-N'-methylamide of 4-fluoroproline (Ac-Flp-NHMe) calculated using the ab initio molecular orbital method with the self-consistent reaction field (SCRF) theory at the HF level with the 6-31+G(d) basis set to investigate the stereoelectronic effects on the conformational preference of proline depending on the cis/trans peptide bonds and down/up puckerings along the backbone torsion angle $\square$ in the gas phase, chloroform, and water. In the gas phase, all potential energy surfaces for Ac-Flp-NHMe are quite similar to those of Ac-Pro-NHMe, except that up-puckered conformations are more stabilized than down-puckered ones. In chloroform and water, polyproline structures become dominant, whose populations are larger than those of Ac-Pro-NHMe. In chloroform and water, the populations of polyproline II (i.e., tF conformations) are quite similar to each other, but those of polyproline I (i.e., cF conformations) are larger by 5% in water than in chloroform. In particular, all cis populations for Ac-Flp-NHMe in the gas phase, chloroform, and water are decreased than those of Ac-Pro-NHMe.

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Velocity Field Measurements of Propeller Wake Using a Phase-averaged PTV Technique (위상평균 PTV 기법을 이용한 프로펠러 후류의 속도장 측정)

  • Bu-Geun Paik;Sang-Joon Lee
    • Journal of the Society of Naval Architects of Korea
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    • v.39 no.3
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    • pp.41-47
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    • 2002
  • Turbulent wake behind a ship propeller has been investigated using the adaptive hybrid 2-frame PTV(Particle Tracking Velocimetry). 400 instantaneous velocity fields were measured according to 4 different blade phases and ensemble-averaged to investigate the spatial evolution of the vortical structure of near wake within one propeller diameter downstream. The phase averaged mean velocity fields show the potential wake and the viscous wake formed by the boundary layers developed on the blade surfaces. As the tip vortex evolves downstream, the slipstream is contracted and the turbulent intensity is decreased with viscous dissipation and turbulent diffusion.