• 대한금속재료학회지
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• 제48권12호
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• pp.1109-1115
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• 2010

ZnO thin films were deposited on Si(100) substrates at low temperatures ($44^{\circ}C{\sim}210^{\circ}C$) by atomic layer deposition using DEZn (diethyl zinc) and water as precursors. The film thickness was measured by ellipsometry calibrated with cross-sectional TEM. The phase formation, microstructure evolution, UV-absorbance, and chemical composition changes were examined by XRD, SEM, AFM, TEM, UV-VIS-NIR, and AES, respectively. A uniform amorphous ZnO layer was formed even at $44^{\circ}C$ while stable crystallized ZnO films were deposited above $90^{\circ}C$. All the samples showed uniform surface roughness below 3 nm. Fully crystallized ZnO layers with a band-gap of 3.37 eV without carbon impurities can be formed at substrate temperatures of less than $90^{\circ}C$.

• 대기
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• 제29권2호
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• pp.219-226
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• 2019

Generally, the weather forecast system has been run using prescribed ocean condition. As it is widely known that coupling between atmosphere and ocean process produces consistent initial condition at all-time scales to improve forecast skill, there are many trials on the application of data assimilation of coupled model. In this study, we implemented a weakly coupled data assimilation (short for WCDA) system in global NWP model with low horizontal resolution for coupled forecast with uncoupled initialization, following WCDA system at the Met Office. The experiment is carried out for a typhoon evolution forecast in 2017. Air-sea exchange process provides SST cooling and gives a substantial impact on tendency of central pressure changes in the decaying phase of the typhoon, except the underestimated central pressure. Coupled data assimilation is a challenging new area, requiring further work, but it would offer the potential for improving air-sea feedback process on NWP timescales and finally contributing forecast accuracy.

• 한국습지학회지
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• 제20권4호
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• pp.410-416
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• 2018

본 연구는 탄소나노튜브(MWCNT)와 활성탄을 이용한 니켈과 구리의 흡착특성을 평가하였다. 산성조건에서 활성탄의 제거성능이 낮은 반면, MWCNT만 니켈과 구리를 흡착 제거하는데 효율적이었다. MWCNT와 중금속의 흡착반응은 유사 일차반응식을 따랐다. 초기 pH가 중성일 때, 니켈은 MWCNT에 의해 신속히 제거되었고, 활성탄은 4시간에 각각 99.02%와 80.30%를 나타냈다. 또한, 구리이온은 초기 pH가 중성일 때 4시간내에 효율적으로 제거되었다. 흡착제 주입량을 증가함에 따라 pH가 증가하였고, 중금속 제거율도 증가하였다. 또한, 산화 전처리 공정은 MWCNT의 중금속 제거율을 증가시켰다.

• 천문학회보
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• 제43권2호
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• pp.59.2-59.2
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• 2018

We introduce a new project of constructing a large spectro-photometric samples of metal-poor (i.e. [Fe/H] < -1.0) subdwarfs in the Galactic halo. The sample is collected from a compilation of the stellar objects that are cross-identified both in the Sloan Digital Sky Survey (SDSS) and recently published data from GAIA mission. The color range of the selected stars covers 0.0 < (g-r) < 2.0; thus the spectral types of our sample span from early F- through late K-type stars on the metal-poor main sequence (i.e. the local subdwarf sequence). We scrutinized the physical, chemical, and kinematical properties of our samples using their SDSS medium-resolution (R ~ 2000) spectra, combined with accurately measured proper motions from GAIA satellite. Our study will provide useful information on the global trend in the various properties (e.g. abundance pattern as a function of the galactocentric distance; rotational velocity vs [Fe/H] ${\cdots}$ etc) of the metal-poor subdwarf populations in the Galactic halo, which is ultimately important to better understand metal-poor stellar evolutionary models and chemical evolution of the Milky Way halo in the early phase of its formation. Further our comprehensive catalog of the Galactic field halo subdwarfs collected in this study will serve a solid groundwork for future follow-up high resolution spectroscopic observations on many interesting individual targets.

• Current Applied Physics
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• 제18권11호
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• pp.1201-1204
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• 2018

The effect of electric current pulses on a sub-100 nm magnetic bubble state in a symmetric Pt/Co multilayer was directly observed using a full-field transmission soft X-ray microscope (MTXM). Field-induced evolution of the magnetic stripe domains into isolated bubbles with their sizes down to 100 nm was imaged under varying external magnetic fields. Electric current pulses were then applied to the created magnetic bubbles, and it was observed that the bubbles could be either created or annihilated by the current pulse depending on the strength of applied magnetic field. The results suggest that the Joule heating plays a critical role in the formation and/or elimination of the bubbles and skyrmions. Finally, the schematic phase diagram for the creation and annihilation of bubbles is presented, suggesting an optimized scheme with the combination of magnetic field and electric current necessary to utilize skyrmions in the practical devices.

• 방사성폐기물학회지
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• 제19권4호
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• pp.469-477
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• 2021

Safe storage of spent nuclear fuel in deep underground repositories necessitates an understanding of the long-term alteration of metal canisters and buffer materials. A small-scale laboratory alteration test was performed on metal (Cu or Fe) chips embedded in compacted bentonite blocks placed in anaerobic water for 1 year. Lactate, sulfate, and bacteria were separately added to the water to promote biochemical reactions in the system. The bentonite blocks immersed in the water were dismantled after 1 year, showing that their alteration was insignificant. However, the Cu chip exhibited some microscopic etch pits on its surface, wherein a slight sulfur component was detected. Overall, the Fe chip was more corroded than the Cu chip under the same conditions. The secondary phase of the Fe chip was locally found as carbonate materials, such as siderite (FeCO₃) and calcite ((Ca, Fe)CO₃). These secondary products can imply that the local carbonate occurrence on the Fe chip may be initiated and developed by an evolution (alteration) of bentonite and a diffusive provision of biogenic CO₂ gas. These laboratory scale results suggest that the actual long-term alteration of metal canisters/bentonite blocks in the engineered barrier could be possible by microbial activities.

• Nuclear Engineering and Technology
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• 제53권12호
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• pp.4033-4041
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• 2021

To better understand the permeability of uranium sandstone, improve the leaching rate of uranium, and explore the change law of pore structure characteristics and blocking mechanism during leaching, we systematically analyzed the microstructure of acid-leaching uranium sandstone. We investigated the variable rules of pore structure characteristics based on nuclear magnetic resonance (NMR). The results showed the following: (1) The uranium concentration change followed the exponential law during uranium deposits acid leaching. After 24 h, the uranium leaching rate reached 50%. The uranium leaching slowed gradually over the next 4 days. (2) Combined with the regularity of porosity variation, Stages I and II included chemical plugging controlled by surface reaction. Stage I was the major completion phase of uranium displacement with saturation precipitation of calcium sulfate. Stage II mainly precipitated iron (III) oxide-hydroxide and aluminum hydroxide. Stage III involved physical clogging controlled by diffusion. (3) In the three stages of leaching, the permeability of the leaching solution changed with the pore structure, which first decreased, then increased, and then decreased.

• 한국압력기기공학회 논문집
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• 제17권2호
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• pp.109-118
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• 2021

In the periodic surveillance material test for the spacer component of fuel channel assembly in CANDU, a microstructural characterization analysis is required in addition to the mechanical property evaluation test. In this study, detailed microstructure analysis and simple mechanical property evaluation of archive spacer parts were conducted to indirectly support the surveillance test and assist in the study of spacer material degradation. We investigated the microstructural characteristics of the spacer garter spring coil through comparative analysis with the plate material. The main microstructure characteristics of the garter spring coil X-750 are represented by the fine grain size distribution, the ordering phase distribution developed inside the matrix, the high dislocation density inside the grains, and the arrangement of coarse carbides. In addition, the yield strength of the garter spring coil X-750 was indirectly evaluated to be approximately 1 GPa. We also established an analytical method to elucidate the microstructural evolution of the radioactive spacer garter spring coil X-750 based on Canadian research experiences. Finally, we confirmed the measurement technique for helium bubble formation through TEM examination on the helium implanted X-750 material.

• 천문학회보
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• 제46권2호
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• pp.69.3-70
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• 2021

We present the chemical properties of star-forming dwarf galaxies (SFDGs) in five filamentary structures (Leo II A, Leo II B, Leo Minor, Canes Venatici, and Virgo III) around the Virgo cluster using the Sloan Digital Sky Survey optical spectroscopic data and Galaxy Evolution Explorer ultraviolet photometric data. We investigate the relationship between stellar mass, gas-phase metallicity, and specific star formation rate (sSFR) of SFDGs in the Virgo filaments in comparison to those in the Virgo cluster and field. We find that, at a given stellar mass, SFDGs in the Virgo filaments show lower metallicity and higher sSFR than those in the Virgo cluster on average. We observe that SFDGs in the Virgo III filament show enhanced metallicities and suppressed star formation activities comparable to those in the Virgo cluster, whereas SFDGs in the other four filaments exhibit similar properties to the field counterparts. Moreover, about half of the galaxies in the Virgo III filament are found to be morphologically transitional dwarf galaxies that are supposed to be on the way to transforming into quiescent dwarf early-type galaxies. Based on the analysis of the galaxy perturbation parameter, we propose that the local environment represented by the galaxy interactions might be responsible for the contrasting features in "chemical pre-processing" found in the Virgo filaments.

• Structural Engineering and Mechanics
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• 제86권6호
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• pp.779-791
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• 2023

Long-termly used in water supply, an underground concrete pipe is easily subjected to the coupled action of pressure loading and flowing water, which can cause the chemo-mechanical damage of the pipe, resulting in its premature failure and lifetime reduction. Based on the leaching characteristics and damage mechanism of concrete pipe, this paper proposes a coupled chemo-mechanical damage and failure model of underground concrete pipe for water supply, including a calcium leaching model, mechanical damage equation and a failure criterion. By using the model, a numerical simulation is performed to analyze the failure process of underground concrete pipe, such as the time-varying calcium concentration in concrete, the thickness variation of pipe wall, the evolution of chemo-mechanical damage, the distribution of concrete stress on the pipe and the lifetime of the pipe. Results show that, the failure of the pipe is a coupled chemo-mechanical damage process companied with calcium leaching. During its damage and failure, the concentrations of calcium phase in concrete decrease obviously with the time, and it can cause an increase in the chemo-mechanical damage of the pipe, while the leaching and abrasion induced by flowing water can lead to the boundary movement and wall thickness reduction of the pipe, and it results in the stress redistribution on the pipe section, a premature failure and lifetime reduction of the pipe.