• 전기화학회지
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• 제15권1호
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• pp.54-66
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• 2012

The phase-shift method and correlation constants, which are unique electrochemical impedance spectroscopy techniques for studying the linear relationship between the phase shift ($90^{\circ}{\geq}-{\varphi}{\geq}0^{\circ}$) vs. potential (E) behavior for the optimum intermediate frequency ($f_o$) and the fractional surface coverage ($0{\leq}{\theta}{\leq}1$) vs. E behavior, are proposed and verified to determine the Frumkin, Langmuir, and Temkin adsorption isotherms and the related electrode kinetic and thermodynamic parameters. At Ni/0.5 M $H_2SO_4$ and 0.1M LiOH aqueous solution interfaces, the Frumkin and Temkin adsorption isotherms (${\theta}$ vs. E) of H for the cathodic hydrogen ($H_2$) evolution, interaction parameters (g), equilibrium constants (K), standard Gibbs energies (${\Delta}G^0_{\theta}$) of H adsorption, and rates of change (r) of ${\Delta}G^0_{\theta}$ with ${\theta}$ have been determined using the phase-shift method and correlation constants. A lateral repulsive interaction (g>0) between the adsorbed H species appears. The value of K in the alkaline aqueous solution is much greater than that in the acidic aqueous solution.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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• pp.475-481
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• 2017

본 실험에서는 추진기관 연료의 주 성분으로 사용되는 액체 탄화수소 화합물의 초임계 분사 거동 특성을 분석하기 위해서 고속카메라 이미지를 활용한 실험을 수행하였다. 케로신의 구성성분 중 임계점의 차이가 있는 Decane과 Methylcyclohexane (MCH)를 실험 유체로 선정하였으며, 분석을 위해 Shadowgraphy 기법을 사용하였다. 제트 분사 시 임계온도 조건 하에서 각 유체의 환산압력에 따라 케이스를 나누었다. 아임계 조건의 동일한 인젝터 초기상태에서 기화가 발생하기까지 온도변화량의 차이에 따라 Decane과 MCH는 서로 다른 거동을 보였다. 하지만 초임계 조건에서는 같은 온도변화량이 필요하더라도 임계점 부근에서는 증발엔탈피가 0에 가까워져 기화과정이 아닌 초임계 유체로의 상변화가 일어나고 급격한 밀도변화가 없어 Decane과 MCH 모두 원기둥 형상의 액주가 관측되었다.

• 한국분말재료학회지
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• 제29권6호
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• pp.468-476
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• 2022

Yttria-stabilized zirconia (YSZ) has a low thermal conductivity, high thermal expansion coefficient, and excellent mechanical properties; thus, it is used as a thermal barrier coating material for gas turbines. However, during long-time exposure of YSZ to temperatures of 1200℃ or higher, a phase transformation accompanied by a volume change occurs, causing the YSZ coating layer to peel off. To solve this problem, YSZ has been doped with trivalent and tetravalent oxides to obtain coating materials with low thermal conductivity and suppressed phase transformation of zirconia. In this study, YSZ is doped with trivalent oxides, Nd₂O₃, Yb₂O₃, Al₂O₃, and tetravalent oxide, TiO₂, and the thermal conductivity of the obtained materials is analyzed according to the composition; furthermore, the relative density change, microstructure change, and m-phase formation behavior are analyzed during long-time heat treatment at high temperatures.

• 열처리공학회지
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• 제34권5호
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• pp.226-232
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• 2021

The relationship between precipitation and coefficient of thermal expansion of Al-6%Si-0.4%Mg-0.9%Cu-(Ti) alloy (in wt.%) after various heat treatments were studied by the thermodynamic analyzer (TMA) and differential scanning calorimetry (DSC). Solution heat treatment of the alloy was carried out at 535℃ for 6 h followed by water quenching, and the samples were artificially aged in the air at 180℃ and 220℃ for 5 h. The coefficient of thermal expansion (CTE) curve showed some residual strain and decreased with increasing aging temperature. The CTE curves changed sharply in the temperature range of 200℃ to 400℃, and the corresponding peak shifted for the aged samples due to the change in the precipitation behavior of the secondary phase. These transformation peaks in the aged sample are related to the volume of the precipitation of the Si phase as determined by DSC analysis. The change in CTE is mainly caused by the precipitation of the Si phase in the Al-Si alloy, and the size of the change occurs simultaneously with the size of the precipitate.

• 한국가시화정보학회지
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• 제21권3호
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• pp.75-84
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• 2023

In this study, we conducted analysis of bubble dynamics and flow of liquid phase change material(PCM) using shadowgraphy and particle image velocimetry(PIV). Characteristics of internal flow varied depending on locations of injection when solid PCM was liquefied from heated vertical wall. When bubbles rose immediately, they exhibited elliptical shape and zigzag trajectory. In contrast, when bubbles rose after merging at the bottom of solid PCM, with equivalent diameter for the inter-wall distance of 0.64 or greater, they showed a jellyfish shape and strong rocking behavior. It was observed by the PIV that the small ellipse bubbles made most strong flow inside the liquid PCM. Furthermore, the flow velocity was highest in the case of front injection, as the directions of temperature gradients and bubble-driven flow were aligned. The results underscore the significant influence of injection location on various characteristics, including bubble size, shape, rising path of bubbles, and internal flow.

• 한국재료학회지
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• 제24권8호
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• pp.401-406
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• 2014

In this study, we investigated the precipitation behavior of the R-phase precipitated at the initial stage of aging and its effects on the mechanical properties of 25%Cr-7%Ni-2%Mo-4%W super duplex stainless steel. The R-phase was mainly precipitated at the interface of ferrite/austenite phases and inside of the ferrite phase during the initial stage of aging. It was transformed into the ${\sigma}$-phase with an increase of the aging time. The ferrite phase was decomposed into a new austenite(${\gamma}_2$)phase and the ${\sigma}$-phase by an aging treatment. The R phase was an intermetallic compound showing higher molybdenum and tungsten concentrations than the matrix and also showed higher molybdenum and tungsten concentrations than the ${\sigma}$ phase. In the initial stage of aging, precipitation of the R-phase did not change the hardness, the strength and the elongation. The hardness and the strength increased upon a longer aging time, but the elongation rapidly decreased. These results show that the R-phase did not significantly affect the hardness and the strength, though it did influence the elongation.

• 한국해양공학회지
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• 제5권2호
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• pp.58-66
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• 1991

Not only difference of fatigue crack growth and propagation behavior resulted from the grain size, the hardness ratio and volume fraction in M.E.F. dual phase steel composed of martensite in hard phase and ferrite in soft phase, but also the effects of the plastic constraint were investigated by fracture mechanics and microstructural method. The main results obtained are as follows: 1) The fatigue endurance of M.E.F. steel increases with decreasing the grain size, increasing the ratio of hardness and volume fraction. 2) The initiation of slip and crack occures faster as the stress level goes higher. These phenomena result from the plastic constraint effect of the second phase. 3) The crack propagation rate in the constant stress level is faster as the grain size gets larger, the ratio of hardness lower and volume fraction smaller.

• Nuclear Engineering and Technology
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• 제56권3호
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• pp.1002-1012
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• 2024

To remove insoluble fission products, which could possibly cause reactor instability and significantly reduce heat transfer efficiency from primary system of molten salt reactor, a helium bubbling method is employed into a passive molten salt fast reactor. In this regard, two-phase flow behavior of molten salt and helium bubbles was investigated experimentally because the helium bubbles highly affect the circulation performance of working fluid owing to an additional drag force. As the helium flow rate is controlled, the change of key thermal-hydraulic parameters was analyzed through a two-phase experiment. Simultaneously, to assess the applicability of numerical model for the analysis of two-phase flow behavior, the numerical calculation was performed using the OpenFOAM 9.0 code. The accuracy of the numerical analysis code was evaluated by comparing it with the experimental data. Generally, numerical results showed a good agreement with the experiment. However, at the high helium injection rates, the prediction capability for void fraction of helium bubbles was relatively low. This study suggests that the multiphaseEulerFoam solver in OpenFOAM code is effective for predicting the helium bubbling but there exists a room for further improvement by incorporating the appropriate drag flux model and the population balance equation.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2005년도 춘계 학술발표회 논문집
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• pp.320-327
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• 2005

Liquefaction characteristics of saturated sand under various dynamic loadings such as sinusoidal, wedge, increasing wedge and real earthquake loading are investigated focusing on the excess pore water pressure build up instead of liquefaction resistance strength in this paper. There are large differences between two types of earthquake loading - impact and vibration in liquefaction characteristics. The angle of phase change line of sinusoidal loading is very close to the vibration type, whereas the cumulative deviator stress and cumulative plastic strain are larger than two types of real earthquake loadings. On the other hand, the liquefaction characteristics of increasing wedge loadings are located in the range between vibration and impact earthquake loadings. It is concluded that the sinusoidal loading overestimates the resistance of soil under real earthquake loading. Based on results obtained, the increasing wedge loading can reflect the liquefaction behavior under real earthquake loadings more efficiently than sinusoidal loading based on equivalent uniform stress concept.

• Journal of Magnetics
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• 제18권1호
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• pp.30-33
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• 2013

The magnetocaloric effect and magnetization behavior have been analyzed in the double-perovskite $La_{0.7}Ba_{0.3}Mn_{1-X}Fe_XO_3$ compound with the sintering temperature at 1273 K. Samples were fabricated by the conventional solid-state reaction method. X-ray diffraction measurement revealed that all the samples had a single phase in orthorhombic. Detailed investigations of the magnetic entropy behavior of the samples were discussed with the variation of $T_C$. The magnetic entropy changes, ${\Delta}S_M$ of approximately 0.36-1.14 J/kg K were obtained in the temperature range of 145-350 K for the $La_{0.7}Ba_{0.3}Mn_{1-X}Fe_XO_3$ compound. The enhancement of the magnetic entropy change is believed to be due to changes in the microstructure, which changes the magnetic part of the entropy of a solid around the magnetic ordering temperature.