• Title/Summary/Keyword: Phase change behavior

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A Numerical Study on Various Energy and Environmental System (II) (에너지${\cdot}$환경 제반 시스템에 관한 수치해석적 연구(II))

  • Jang D. S.;Park B. S.;Kim B. S.;Lee E. J.;Song W. Y.
    • 한국전산유체공학회:학술대회논문집
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    • 1996.05a
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    • pp.58-67
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    • 1996
  • This paper describes some computational results of various energy and environmental systems using Patankar's SIMPLE method. The specific topics handled in this study are jet bubbling reactor for flue gas desulfurization, cyclone-type afterburner for incineration, 200m tall stack for 500 MW electric power generation, double skin and heat storage systems of building energy saving for the utilization of solar heating, finally turbulent combustion systems with liquid droplet or pulverized coal particle. A control-volume based finite-difference method with the power-law scheme is employed for discretization. The pressure-velocity coupling is resolved by the use of the revised version of SIMPLE, that is, SIMPLEC. Reynolds stresses are closed using the standard $k-{\varepsilon}$ and RNG $k-{\varepsilon}$ models. Two-phase turbulent combustion of liquid drop or pulverized coal particle is modeled using locally-homogeneous, gas-phase, eddy breakup model. However simple approximate models are incorporated for the modeling of the second phase slip and retardation of ignition without consideration of any detailed particle behavior. Some important results are presented and discussed in a brief note. Especially, in order to make uniform exit flow for the jet bubbling reactor, a well-designed structure of distributor is needed. Further, the aspect ratio in the double skin system appears to be one of important factors to give rise to the visible change of the induced air flow rate. The computational tool employed in this study, in general, appears as a viable method for the design of various engineering system of interest.

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Low Temperature Synthesis and Characterization of Sol-gel TiO2 Layers

  • Jin, Sook-Young;Reddy, A.S.;Park, Jong-Hyurk;Park, Jeong-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.353-353
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    • 2011
  • Titanium dioxide is a suitable material for industrial use at present and in the future because titanium dioxide has efficient photoactivity, good stability and low cost [1]. Among the three phases (anatase, rutile, brookite) of titanium dioxide, the anatase form is particularly photocatalytically active under ultraviolet (UV) light. In fabrication of photocatalytic devices based on catalytic nanodiodes [2], it is challenging to obtain a photocatalytically active TiO2 thin film that can be prepared at low temperature (< 200$^{\circ}C$). Here, we present the synthesis of a titanium dioxide film using TiO2 nanoparticles and sol-gel methods. Titanium tetra-isopropoxide was used as the precursor and alcohol as the solvent. Titanium dioxide thin films were made using spin coating. The change of atomic structure was monitored after heating the thin film at 200$^{\circ}C$ and at 350$^{\circ}C$. The prepared samples have been characterized by X-ray diffraction (XRD), scanning electron microcopy, X-ray photoelectron spectroscopy, transmission electron microscopy, ultraviolet-visible spectroscopy (UV-vis), and ellipsometry. XRD spectra show an anatase phase at low temperature, 200$^{\circ}C$. UV-vis confirms the anatase phase band gap energy (3.2 eV) when using the photocatalyst. TEM images reveal crystallization of the titanium dioxide at 200$^{\circ}C$. We will discuss the switching behavior of the Pt /sol-gel TiO2 /Pt layers that can be a new type of resistive random-access memory.

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Effect of cold working on the thermal expansion and mechanical properties of Fe-29%-Ni-17%Co low thermal expansion alloy (Fe-29%Ni-17%Co 저열팽창성 합금의 기계적 및 열팽창 특성에 미치는 냉간 가공의 영향)

  • Lee, Kee-Ahn;Kim, Song-Yi;NamKung, Jung;Kim, Mun-Chul
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.355-356
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    • 2009
  • The change of thermal expansion and mechanical behaviors by cold working has been investigated in Fe-29%Ni-17%Co low thermal expansion Kovar alloy. Fe-29%Ni-17%Co alloy was cold rolled gradually and prepared to plates having reduction ratio of 0%, 20%, 40%, 60%, and 80%. Annealing effect on the properties was also studied. Thermal expansion was measured from $25^{\circ}C$ to $600^{\circ}C$ with a heating rate of $5^{\circ}C$/min by using vacuum differential dilatometer. It was found that thermal expansion coefficient ($\alpha_{30{\sim}400}$) slightly decreased (reduction ration of 20%) and then remarkably increased (above reduction ration of 40%) with increasing reduction ratio of cold rolling. Thermal expansion coefficient ($\alpha_{30{\sim}400}$) was sharply decreased after annealing heat-treatment. Yield and tensile strengths were continuously increased and elongation was decreased by cold roiling. Microstructural observation and X-ray diffraction analysis results showed that the $\alpha$ phase significantly increased as the reduction ratio increased. The slight decrease of thermal expansion coefficient bellow reduction ration of 20% could be explained by the destroying short-range ordering and the decreasing of grain size. The significant increase of thermal expansion coefficient with cold rolling mainly attributed to the appearance of $\alpha$ phase. The correlation between the microstructural cause and invar phenomena for the low thermal expansion behavior was also discussed.

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The Effects of Water Addition on the Color and Crystalline Phase of Y2O3 Coatings Fabricated by Plasma Suspension Spray

  • Park, Sang-Jun;Lee, Jung-Ki;Oh, Yoon-Suk;Kim, Seongwon;Kim, Hyungsun;Lee, Sung-Min
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.641-646
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    • 2016
  • The effects of water addition on $Y_2O_3$ coatings or thick films prepared by plasma suspension spray (SPS) have been investigated. Water addition in suspension media was found to be effective to control the color of a $Y_2O_3$ coating prepared by SPS. The color changed with water addition at the shortest stand-off distance of 50 mm even if samples had the same crystalline phase. Change was not correlated with fragmentation behavior of liquid suspension inside the plasma jet. Water content over 50 vol% was found to produce unmelted particles, indicating that water suppressed heat transfer to the particles. However, plasma jet temperature was not affected. Instead, the coating fabricated with water addition has higher oxygen and lower carbon content compared to these characteristics of the coating without water addition. This was attributed to the retarded complete evaporation of liquid media from the suspension droplet, resulting in inhibition of excessive heating and evaporation of the molten $Y_2O_3$ droplet. In this regard, crystalline phase development with respect to stand-off distance and water addition was discussed.

Numerical Analysis of CO2 Behavior in the Subsea Pipeline, Topside and Wellbore With Reservoir Pressure Increase over the Injection Period (시간 경과에 따른 저류층 압력 상승이 파이프라인, 탑사이드 및 주입정 내 CO2 거동에 미치는 영향에 대한 수치해석적 연구)

  • Min, Il Hong;Huh, Cheol;Choe, Yun Seon;Kim, Hyeon Uk;Cho, Meang Ik;Kang, Seong Gil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.19 no.4
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    • pp.286-296
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    • 2016
  • Offshore CCS technology is to transport and inject $CO_2$ which is captured from the power plant into the saline aquifer or depleted oil-gas fields. The more accumulated injected $CO_2$, the higher reservoir pressure increases. The increment of reservoir pressure make a dramatic change of the operating conditions of transport and injection systems. Therefore, it is necessary to carefully analyze the effect of operating condition variations over the injection period in early design phase. The objective of this study is to simulate and analyze the $CO_2$ behavior in the transport and injection systems over the injection period. The storage reservoir is assumed to be gas field in the East Sea continental shelf. The whole systems were consisted of subsea pipeline, riser, topside and wellbore. Modeling and numerical analysis were carried out using OLGA 2014.1. During the 10 years injection period, the change of temperature, pressure and phase of $CO_2$ in subsea pipelines, riser, topside and wellbore were carefully analyzed. Finally, some design guidelines about compressor at inlet of subsea pipeline, heat exchanger on topside and wellhead control were proposed.

A Thermo-Hydro-Mechanical Coupled Numerical Simulation on the FE Experiment: Step 1 Simulation in Task C of DECOVALEX-2023 (Mont Terri FE 실험 대상 열-수리-역학 복합거동 수치해석: DECOVALEX-2023 Task C 내 Step 1 수치해석 연구)

  • Taehyun, Kim;Chan-Hee, Park;Changsoo, Lee;Jin-Seop, Kim
    • Tunnel and Underground Space
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    • v.32 no.6
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    • pp.518-529
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    • 2022
  • In Task C of the DECOVALEX-2023 project, nine institutes from six nations are developing their numerical codes to simulate thermo-hydro-mechanical coupled behavior for the FE experiment performed at Mont Terri underground rock laboratory, Switzerland. Currently, Step 1 for comparing the simulation results to field data is the ongoing stage, and we used the OGS-FLAC simulator for a series of numerical simulations. As a result, temperature increase depending on the heating hysteresis was well simulated, and saturation variation in the bentonite depending on phase change was observed. However, due to the suction overestimation, relative humidity and temperature change in the bentonite and the pressure variation in the Opalinus clay showed a difference compared to the field data. From the observation, it is confirmed that the effect of the bentonite capillary pressure is dominant to the flow analysis in the disposal system. We further plan to draw improved results considering tunnel support material and accurate initial water pressure distribution. Additionally, the thermal, hydrological, and mechanical anisotropy of the Opalinus clay was well simulated. From the simulation results, we confirmed the applicability of the OGS-FLAC simulator in the disposal system analysis.

An Equivalent Multi-Phase Similitude Law for Pseudodynamic Test on Small-scale RC Models : Verification Tests (RC 축소모형의 유사동적실험을 위한 Equivalent Multi-Phase Similitude Law : 검증실험)

  • Kim, Nam-Sik;Lee, Ji-Ho;Chang, Sung-Pil
    • Journal of the Earthquake Engineering Society of Korea
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    • v.8 no.5 s.39
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    • pp.35-43
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    • 2004
  • Small-scale models have been frequently used for seismic performance tests because of limited testing facilities and economic reasons. However, there are not enough studies on similitude law for analogizing prototype structures accurately with small-scale models, although conventional similitude law based on geometry is not well consistent in the inelastic seismic behavior. When fabricating prototype and small-scale model of reinforced concrete structures by using the same material, added mass is demanded from a volumetric change and scale factor could be limited due to aggregate size. Therefore, it is desirable that different material is used for small-scale models. Thus, a modified similitude law could be derived depending on geometric scale factor, equivalent modulus ratio and ultimate strain ratio. In this study, compressive strength tests are conducted to analyze the equivalent modulus ratio of micro-concrete to normal-concrete. Then, equivalent modulus ratios are divided into multi-phase damage levels, which are basically dependent on ultimate strain level. Therefore, an algorithm adaptable to the pseudodynamic test, considering equivalent multi-phase similitude law based on seismic damage levels, is developed. Test specimens, consisted of prototype structures and 1/5 scaled models as a reinforced concrete column, were designed and fabricated based on the equivalent modulus ratios already defined. Finally quasistatic and pseudodynamic tests on the specimens are carried out using constant and variable modulus ratios, and correlation between prototype and small-scale model is investigated based on their test results. It is confirmed that the equivalent multi-phase similitude law proposed in this study could be suitable for seismic performance tests on small-scale models.

Analysis of Rebound Behavior of Blast-Resistant Door Subjected to Blast Pressure (폭압 작용에 의한 방폭문의 반발거동 해석)

  • Shin, Hyun-Seop
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.34 no.6
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    • pp.371-383
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    • 2021
  • Steel-concrete single-leaf blast-resistant doors, having steel box and slab inside, are installed on the wall using supporting members such as hinges and latches. Several studies have been conducted on their deflection behavior in the same direction as that of the blast pressure, but studies on their deflection behavior in the opposite direction, that is, studies on negative deflection behavior are relatively insufficient. In this study, we conducted a parameter analysis using finite element analysis on blast-resistant doors, on their rebound behavior in the negative deflection phase. Results revealed that the plastic deformation of the door, and the change in momentum and kinetic energy during rebound, were major factors influencing the rebound behavior. Greater rebound force was developed on the supporting members in the impulsive region, than in the quasi-static region; due to the characteristics in the impulsive region, where the kinetic energy developed relatively greater than the strain energy. In the design process, it is necessary to consider excessive deformation that could occur in the supporting members as the rebound behavior progresses. Additionally, it was found that in the case of steel-concrete blast doors, the rebound force increased relatively more, when the effects of both rebound and negative blast pressure contributed to the negative deflection of the door. Since conditions for the occurrence of this superposition effect could vary depending on structural characteristics and explosion conditions, further investigation may be required on this topic.

Effects of Nb Addition on Corrosion Resistance and Cytotoxicity Behavior of Ti Alloys (Nb이 첨가된 Ti합금의 내식성 및 생체안정성)

  • Lee, Doh-Jae;Lee, Kwang-Min;Lee, Kyung-Ku;Ryu, Chang-Nam;Oh, Tae-Wook;Kim, Soo-Hag;Yoon, Tack-Lim
    • Korean Journal of Materials Research
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    • v.13 no.11
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    • pp.761-768
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    • 2003
  • The corrosion resistance and cytotoxicity behavior of Ti alloys were studied as a function of Nb contents(3wt.%Nb, 20wt.%Nb, 40wt.%Nb). Ti-Nb alloys were melted by vacuum arc furnace and then rolled to 50% reduction ratio after homogenized at 105$0^{\circ}C$ for 24hrs. The corrosion resistance of Ti-Nb alloys were investigated by potentiodynamic polarization test in the 0.9% NaCl and 5% HCI solution. Biocompatibility of Ti-Nb alloys was evaluated by cytotoxicity test. The results can be summarized as follows 1) The microstructure change from equiaxial to acicular and the increased $\beta$ phase in Ti-Nb alloys were obtained as the Nb content increased. 2) For the corrosion test in the solution of 0.9% NaCl and 5% HCI, the corrosion behavior of Ti-Nb alloys was similar to ASTM grade 2 CP Ti. 3) For the cytotoxicity test, Ti-Nb alloys showed excellent biocompatibility compared to ASTM grade 2 CP Ti, 316L STS and Co-Cr alloys.

The Oxidation Behavior of Sintered STS 316L at High-Temperature in the Air (STS 316L 소결체의 대기중 고온산화 거동)

  • Kim, Hye Seong;Lee, Jong Pil;Park, Dong Kyu;Ahn, In Shup
    • Journal of Powder Materials
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    • v.20 no.6
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    • pp.432-438
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    • 2013
  • In this study, analysis on the oxidation behavior was conducted by a series of high-temperature oxidation tests at both $800^{\circ}C$, $900^{\circ}C$ and 1000 in the air with sintered STS 316L. The weight gain of each oxidized specimen was measured, the oxidized surface morphologies and composition of oxidation layer were analyzed with Scanning Electron Microscope-Energy Dispersive x-ray Spectroscopy (SEM-EDS), finally, the phase change and composition of the oxidized specimen were shown by X-Ray Diffraction (XRD). As a result, the weight gain increased sharply at $1000^{\circ}C$ when oxidation test was conducted for 210 hours. Also, a plentiful of pores were observed in the surface oxidation layers at $900^{\circ}C$ for 210 hours. In addition, the following conclusions on oxidation behavior of sintered STS 316L can be obtained: $Cr_2O_3$ can be formed on pores by influxing oxygen through open-pores, $(Fe_{0.6}Cr_{0.4})_2O_3$ can be generated on the inner oxidation layer, and $Fe_2O_3$ was on the outer oxidation layer. Also, $NiFe_2O_4$ could be precipitated if the oxidation time was kept longer.