• Title/Summary/Keyword: Phase change behavior

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New parametric approach to decomposition of disk averaged spectra of potential extra terrestrial planet I. Surface type ratio of the Earth

  • Ryu, Dong-Ok;Seong, Se-Hyun;Yu, Jin-Hee;Oh, Eun-Song;Ahn, Ki-Beom;Hong, Jin-Suk;Lee, Jae-Min;Kim, Suk-Whan
    • Bulletin of the Korean Space Science Society
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    • 2010.04a
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    • pp.34.2-34.2
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    • 2010
  • We built 7 potential extra-terrestrial planets including the full 3D Earth model with various surface types and 6 planet models, each with uniform surface characteristics. The surface types include ice, tundra, forest, grass, ground and ocean. We then imported these 7 planets into integrated ray tracing(IRT) model to compute their disk averaged spectra and to understand the spectral behavior depending on the geometrical view, illumination phase and seasonal change. The IRT computation show that the 6 planets with uniform surfaces exhibit clear spectral differences from that of the Earth. We then built a phase and seasonal DAS database for the 6 uniform surface planets and used them for parametric spectral decomposition technique to derive the Earth DAS. This computation resulted in the first potential solution to the surface type ratio of the Earth compared to the measured earth surface type ratio. The computational details and the implications are discussed.

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Effects of Chrysanthemum coronarium L. on the Thermotropic Behavior of DPPC Liposomal Membrane

  • Bae, Song-Ja;Noh, Ok-Jeong;Roh, Sung-Bae
    • Journal of Life Science
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    • v.10 no.2
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    • pp.27-32
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    • 2000
  • To understand the effects of the fraction from Chrysanthemum coronarium L. (CC), we prepared five different types of samples, denoted here as CCMM, CCMH, CCMEA, CCMB and CCMA. We studied the effects of these samples on the phase transition of liposomal membranes by high-sensitivity differential scanning calorimetry (nano-DSC). We used dipalmitoylphosphatidylcholine (DPPC) bilayers which make most stable liposomes among the other phosphatidylcholines. When the samples were added to the bilayers, the phase transition temperatures of DPPC liposomes incorporated with CCMH and CCMEA were decreased by 1.5 and 2^{\circ}C$, while the other three fractions showed less tendencies. The CCMH and CCMEA fractions markedly affected the thermotropic properties of DPPC liposomes, broadened and shifted the thermograms of DSC. It also significantly reduced the size of cooperative unit of the transition. In all cases, there was no change in enthalpy of transition within the concentration range of the CC fractions studied. We concluded that the incorporation of the CCMH and CCMEA into DPPC liposomes was preferentially located in the hydrophobic core of DPPC bilayers compared to the other three fractions CCMM, CCMB and CCMA. These results suggest that certain substances in CCMH and CCMEA fractions might have biologically significant effects on the fluidity of biological membrane.

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Modeling of Fin-Tube Heat Exchanger (핀-관 열교환기의 모델링)

  • 박희용;이관수;박동규
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.5
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    • pp.952-961
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    • 1989
  • The purpose of this study is to investigate the behavior of operational and design factors on the performance characteristics of a horizontal fin-tube heat exchanger under phase change conditions for refrigerant. The flow and heat transfer in the heat exchanger are simulated numerically taking into account the variations of heat transfer coefficients, thermodynamic and flow properties of refrigerant, and the axial heat conduction in the tube wall. As the results of this study, it was found that the annular flow model was more reasonable physically than the homogeneous one for the two phase flow of refrigerant and axial heat conduction of tube wall did not have a great influence on the analysis. The effects of refrigerant pressure, mass flow rate of air, diameter of tube and the number of fins per unit length of tube were also discussed.

Thermal Compatibility of High Density U-Mo Powder Fuels Prepared by Centrifugal Atomization

  • Kim, Ki-Hwan;Ahn, Hyun-Suk;Chang, Se-Jung;Ko, Young-Mo;Lee, Don-Bae;Kim, Chang-Kyu;Kuk, Il-Hyun
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05b
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    • pp.165-170
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    • 1997
  • Samples of extruded dispersions of 24 vol.% spherical U-2wt%Mo and U-10wt.%Mo powders in an aluminum matrix were annealed for over 2,000 hours at 40$0^{\circ}C$. No significant dimensional changes occurred in the U-1025.%Mo/aluminum dispersions. The U-2wt.%Mo/aluminum dispersion, however, increased in volume by 26% after 2,000 hours at 40$0^{\circ}C$. This large volume change is mainly due to the formation of voids and cracks resulting from nearly complete interdiffusion of U-Mo and aluminum. Interdiffusion between U-10wt.%Mo and aluminum was found to be minimal. The different diffusion behavior is primarily due to the fact that U-2wt.%Mo decomposes from an as-atomized metastable r-phase(bcc) solid solution into the equilibrium r-U and U$_2$Mo two-phase structure during the experiment, whereas U-10wt.%Mo retains the metastable r-phase structure after the 2,000 hours anneal and thereby displays superior thermal compatibility with aluminum compared to U-2wt.%Mo. In addition, the molybdenium supersaturated in U-10wt.%Mo particles inhibits the diffusion of aluminum atoms along the grain boundary into the particle. Also, the dissolution of only a few Mo atoms in UAL$_3$ retards the formation of the intermediate phase, as Mo atoms need to migrate from new intermetallic compounds to unreacted islands.

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Phase Equilibrium Study on the Ternary System of SBR/EPDM/Solvent (SBR, EPDM 및 Solvent로 이루어진 삼성분계의 상 평형에 관한 연구)

  • Go, Jin-Hwan;Park, Byung-Ho
    • Elastomers and Composites
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    • v.37 no.4
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    • pp.211-216
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    • 2002
  • The polymer-polymer interaction parameter, x 23t, of the styrene-butadiene polymer (SBR) and ethylene-propylene-diene terpolymer (EPDM) was investigated by observing the phase behavior of the ternary system of SBR/EPDM/solvent. The solvent used in this study was benzene acting as a good solvent for SBR but as a poor solvent for EPDM. Ternary solutions with various concentrations and mixing ratios of the two component polymers were separated into two phases by temperature change The cloud point curves (CPC) showed that the differerence of solvent affinities toward each polymer and the repulsive interaction between two polymers considerably affect the shape of CPC near 15℃. In the temperature range of 5℃ ~ 25℃, incompatible behaviours arised from both the difference of mixing ratios and concentration were clearly observed. Also the phase separation temperature greatly influenced on the composition of each separated phase. The calculated x 23t values from Flory-Huggins theory were in the range of 0.6301 ~ 1.0775, which suggest that the SBR/EPDM systems are incompatible.

Intra-articular Injection of $IL-1{\beta}$ Facilitated Formalin-induced Temporomandibular Joint Pain in Freely Moving Rats

  • Choi, Hyo-Soon;Jung, Sung-Chul;Choi, Byung-Ju;Ahn, Dong-Kuk
    • The Korean Journal of Physiology and Pharmacology
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    • v.9 no.1
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    • pp.23-27
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    • 2005
  • The present study was performed to investigate the effects of intra-articular injection of interleukin-1${\beta}$ (IL-1${\beta}$) on the formalin-induced temporomandibular joint (TMJ) pain. Under anesthesia, a 30-gauge needle was introduced into the right TMJ region for injection of formalin. Microinjection of 50 ${\mu}l$ of 5% formalin significantly produced noxious scratching behavioral response, and the scratching behavior lasted for 40 min. Although the responses produced by formalin injection were divided into two phases, the response of 1st phase did not significantly differ from the scratching behavior response in the saline-treated group. We examined the effects of intra-articular injection of IL-1${\beta}$ on the number of noxious behavioral responses produced by 50${\mu}l$ of 5% formalin injection. Intra-articular injection of 100 pg and 1 ng of IL-1${\beta}$ significantly increased the number of behavioral responses of the 2nd phase, while 10 pg of IL-1${\beta}$ did not change the formalin-induced behavioral responses. To investigate whether IL-1 receptor was involved in the intra-articular administration of IL-1${\beta}$-induced hyperalgesic response, IL-1 receptor antagonist (IL- ra, 50 ng) was administrated together with IL-1${\beta}$ injection. IL-1${\beta}$ receptor antagonist blocked IL-1${\beta}$- induced hyperalgesic response in the TMJ formalin test. These results suggest that intra-articular injection of IL-1${\beta}$ facilitated the transmission of nociceptive information in the TMJ area.

The Study of Sintering Behavior and Piezoelectric Properties in $Pd_{(1-x)}$$Cd_x$[(Mn, Sb), Zr, $Ti]O_3$ Ceramics ($Pd_{(1-x)}$$Cd_x$[(Mn, Sb), Zr, $Ti]O_3$ 세라믹스의 소결 거동 및 압전 특성에 대한 연구)

  • 나은상;최성철
    • Journal of the Korean Ceramic Society
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    • v.37 no.4
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    • pp.395-401
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    • 2000
  • In this study, we chose the basic composition which indicated the best electrical properties by change of x content(0, 0.05, 0.1, 0.15, 0.2, 0.25 mol respectively) in xPb(Mn1/3Sb2/3)O3-(1-x)Pb(Zr0.52Ti0.48)O3 ceramics. And we substituted Cd2+ for Pb2+ site, then observed the sintering behavior, microstructure and electrical propertties according to the various sintering temperature. The basic composition was the 0.05PMS-0.95PZt, and it showed single perovskite phase and excellent properties. In case of Cd2+ substitution, we were able to sinter at 90$0^{\circ}C$ which was lower than conventional sintering temperature(1200~130$0^{\circ}C$). Especially, when the 2mol% substituted PMS-PZT specimens were sintered at 90$0^{\circ}C$ for 2h, we obtained the p=7.6g/㎤, kp=56%, Qm=520 and made sure of a position of Cd2+ substitution by observing lattice parameter, phase transition temperature. From this results, we could infer that because Cd2+ substituted fro A-site, low temperature sintering of Cd2+ substituted PMS-PZT without any loss of electrical properties shows its applicability for the piezoelectric ceramic transformer.

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Piezoelectric and Strain Properties of Lead-free (Bi1/2Na1/2)TiO3-Ba(Cu1/3Nb2/3)O3 Ceramics (비납계 (Bi1/2Na1/2)TiO3-Ba(Cu1/3Nb2/3)O3 세라믹의 압전 및 변위 특성)

  • Ryu, Jung-Ho;Jeong, Dae-Yong
    • Korean Journal of Materials Research
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    • v.21 no.11
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    • pp.628-633
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    • 2011
  • Studies on lead-free piezoelectrics have been attractive as means of meeting environmental requirements. We synthesized lead-free piezoelectric $(Bi_{1/2}Na_{1/2})TiO_3-Ba(Cu_{1/3}Nb_{2/3})O_3$ (BNT-BCN) ceramics, and their dielectric, piezoelectric, and strain behavior were characterized. As BCN with a tetragonal phase was incorporated into the rhombohedral BNT lattice, the lattice constant increased. A small amount of BCN increased the density and dielectric constant forming the complete solid solution with BNT. However, BCN above 10 mol% was precipitated into a separate phase, and which was detected with XRD. In addition, EDX measurement revealed that Cu in BCN was not distributed homogeneously but was accumulated in a certain area. A lower density with a large amount of BCN was attributed to the nonsinterable property of BCN with large tetragonaliy. The dielectric constant vs the temperature change and the strain vs the electric field indicated that the ferroelectric property of BNT was diminished and paraelectric behavior was enhanced with the BCN addition. BNT-7.5BCN showed a 0.11% unimorph strain with a 9.0 kV/mm electric field with little hysteresis.

Micromechanical Superplastic Model for the Analysis of Inhomogeneous Deformation in Heterogeneous Microstructure (비균일 조직에 따른 불균일 변형 해석을 위한 미시역학적 초소성 모텔)

  • Kim, Tae-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.12
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    • pp.1933-1943
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    • 2001
  • A micromechanical model is presented for superplasticity in which heterogeneous microstructures are coupled with deformation behavior. The effects of initial distributions of grain size, and their evolutions on the mechanical properties can be predicted by the model. Alternative stress rate models such as Jaumann rate and rotation incremental rate have been employed to analyze uniaxial loading and simple shear problems and the appropriate modeling was studied on the basis of hypoelasticity and elasto-viscoplasticity. The model has been implemented into finite element software so that full process simulation can be carried out. Tests have been conducted on Ti-6Al-4V alloy and the microstructural features such as grain size, distributions of grain size, and volume fraction of each phase were examined for the materials that were tested at different strain rates. The experimentally observed stress-strain behavior on a range of initial grain size distributions has been shown to be correctly predicted. In addition, the effect of volume fraction of the phases and concurrent grain growth were analyzed. The dependence of failure strain on strain rate has been explained in terms of the change in mechanism of grain growth that occurs with changing strain rate.

Chaos on the Rocking Vibration of Rigid Block Under Two Dimensional Sinusodial Excitation (In the Case of No Sliding Occurrence) (2차원 정현파 가진을 받는 강체블록의 록킹진동에 있어서의 카오스 (미끄럼이 없는 경우에 대하여))

  • 정만용;김정호;김지훈;양광영;양인영
    • Journal of the Korean Society of Safety
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    • v.14 no.2
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    • pp.42-51
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    • 1999
  • This research deals with the non-linearities associated with impact and sliding for the rocking behavior of rigid block subjected to two dimensional excitation of horizontal and vertical direction. The non-linearities examined of impact between block and base: The transition of two governing rocking equations, the abrupt reduction in kinetic energy associated with impact. In this study, the rocking vibration system of two types are considered for several friction condition. One is the undamped rocking vibration system, disregarding energy dissipation at impact and the other is the damped rocking system, including energy dissipation at impact. The response analysis by non-dimensional rocking equation is carried out for the change of excitation amplitude. The chaos responses were discovered in the wide response region, particularly, in the case of high vertical excitation and their chaos characteristics are examined by Poincare map, power spectra and Lyapunov Exponent. The complex behavior of chaos response, in the phase space, were illustrated by Poincare map. Therefore, Poincare map will be a significant material in order to understand chaos of rocking system.

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