• 한국전산구조공학회논문집
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• 제35권2호
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• pp.101-107
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• 2022

본 논문에서는 지오폴리머의 상변화를 관찰하기 위하여 나노인덴테이션 데이터를 가우시안 믹스쳐 모델로 분석하는 방법을 제시하였다. 지오폴리머는 일반 시멘트 대비 CO₂ 발생량을 줄일 수 있어 시멘트 대체 재료로써 많은 연구가 이루어지고 있다. 기존 연구들로부터 최적의 실리콘/알루미늄 비율을 찾았으나 1.8 초과에서 압축강도 저하의 원인은 아직 불분명하다. 본 연구에서는 실리콘/알루미늄 비율이 재료에 미치는 영향을 조사하고자 나노인덴테이션 실험을 수행하였다. 실험 결과를 가우시안 믹스쳐 모델로 상분석하였고, 실리콘/알루미늄 비율이 증가할수록 재료가 균질거동을 하는 것을 관찰할 수 있었다. 본 연구결과는 강도저하를 규명하는데 직접적인 근거로 활용될 수 있을 것으로 기대된다.

• Journal of Mechanical Science and Technology
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• 제18권3호
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• pp.513-525
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• 2004

This paper reports an experimental study on flow boiling of pure refrigerants R l34a and R l23 and their mixtures in a uniformly heated horizontal tube. The flow pattern was observed through tubular sight glasses with an internal diameter of 10㎜ located at the inlet and outlet of the test section. Tests were run at a pressure of 0.6 MPa in the heat flux ranges of 5-50㎾/㎡, vapor quality 0-100 percent and mass velocity of 150-600㎏/㎡s. Both in the nucleate boiling-dominant region at low quality and in the two-phase convective evaporation region at higher quality where nucleation is supposed to be fully suppressed, the heat transfer coefficient for the mixture was lower than that for an equivalent pure component with the same physical properties as the mixture. The reduction of the heat transfer coefficient in mixture is explained by such mechanisms as mass transfer resistance and non-linear variation in physical properties etc. In this study, the contribution of convective evaporation, which is obtained for pure refrigerants under the suppression of nucleate boiling, is multiplied by the composition factor by Singal et al. (1984). On the basis of Chen's superposition model, a new correlation is presented for heat transfer coefficients of mixture.

• Nuclear Engineering and Technology
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• 제26권4호
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• pp.562-569
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• 1994

이 연구에서는 피동형원자로의 과도현상을 분석하기 위한 KOTRAC 코드의 모델을 수정한 것이다. 이 코드에서 열수력학 모델로 도입하고 있는 mixture drift flux model은 피동형원자로와 같이 비상냉각수가 중력으로 주입되는 경우를 잘 모사할 수 있으나, 만일 가압기 밀림관 또는 수평관에서 상의 완전분리가 일어나게 될 때에는 증기상에서의 거의 영에 가까운 밀도로 인해 상당한 어려움이 존재하는 것이 밝혀졌다. 이 연구에서는 이러한 어려움을 극복하기 위해 일부 모델을 개선하였는데 가장 두드러진 것은 KOTRAC에서 사용하고 있는 flow distribution parameter를 Ishii 상관식으로 대체하여 코드를 수정하고 해석하였다. 이렇게 수정된 코드를 사용한 결과는 과도상태 해석코드인 RELAP5 /MOD3 계산결과와 비교적 잘 일치함을 볼 수 있었다.

• 한국자기공명학회논문지
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• 제24권4호
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• pp.96-103
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• 2020

A new NMR method to monitor solvent-localized NMR signals in the two-phase liquid system is suggested. This method based on intermolecular single-quantum coherence (iSQC). Here, we exploited the feature of the local action of distant dipolar field (DDF) effect in order to filter out specific NMR signals dissolved in different solvents. This solvent specific iSQC spectroscopy was carried out on a model two-phase liquid system (D-glucose in water/palmitic acid in chloroform), and showed solvent-localized NMR signals. We believe our approaches might be useful in metabolic analysis such as two-phase liquid extraction scheme for labile chemical species.

• 설비공학논문집
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• 제7권4호
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• pp.589-599
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• 1995

The frictional pressure drop of a capillary tube flow is experimentally investigated for pure refrigerants such as R32, R125, and R134a and refrigerant mixtures such as R32/R134a(30/70 by mass percent), R32/R125(60/40), R125/R134a(30/70), and R32/R125/R134a(23/25/52). The binary interaction parameters for the calculation of viscosities of refrigerant mixtures are found based upon the data in the open literature. Several homogeneous flow models predicting the viscosity of two-phase region are compared to select the best model. Cicchitti's equation is known to be the most adequate for the prediction of the viscosity for refrigerant mixtures, which is used in the analysis of adiabatic capillary flows. A model for the prediction of the frictional pressure drop of single and two-phase flow is developed for refrigerant mixtures in this study. This model may be used to design and analyze the performance of a capillary tube in the refrigerating system.

• 한국산학기술학회논문지
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• 제11권5호
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• pp.1768-1772
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• 2010

분자내부 회합은 계면활성제계, 특히 콜로이드와 생체물질에 있어서 수소결합 중에서 매우 중요한 역할을 나타낸다. 미셀과 마이크로에멀젼을 형성하는 양친매성 계는 분자간 회합뿐만 아니라 분자내부 회합 때문에 매우 비이상적인 거동을 나타낸다. 본 연구의 목적은 계면활성제를 함유한 혼합물의 상거동을 계산하기 위하여, 내외부 분자 회합을 설명할 수 있는 수정된 베이츠만 통계역학이론과 결합된 유사화학반응 비무질도서 격자모델을 제시하는 것이다. 본 논문에서 제시된 격자모델은 알칸과 계면활성제의 실험결과를 매우 잘 설명할 수 있다.

• 한국지반공학회논문집
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• 제32권1호
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• pp.19-33
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• 2016

강우의 침투가 사면안정에 미치는 영향을 평가하기 위해 강우의 침투해석을 수행하고 그 결과를 한계평형해석에 적용하는 안정해석 절차가 널리 사용되고 있으나 지반은 흙 입자, 물과 공기로 이루어진 3상의 물질이므로 사면을 통한 강우의 침투를 엄밀하게 해석하기 위해서는 물, 공기의 흐름과 흙의 응력-변형거동이 완전 연관된(fully coupled) 식을 고려해야 한다. 본 연구에서는 공기와 물의 흐름이 사면의 역학적 안정에 미치는 영향을 연구하기 위하여 우리나라에 널리 분포하는 풍화잔류토 사면에 대하여 3상이 연동된 흐름해석을 수행하였다. 강우침투가 사면안정에 미치는 영향을 평가하기 위하여 강도감소법에 의한 사면 안정해석을 수행하였다. 해석결과에 의하면 침투하는 강우가 공기를 밀어내 공기의 흐름이 발생하고 공기압이 증가하였다. 이러한 간극에서의 물과 공기의 상호작용은 사면의 응력-변형거동에 영향을 미쳐 공기의 흐름을 고려하지 않은 흙 입자-물의 연관해석의 결과와는 다른 사면안정 거동을 보였다.

• Archives of Pharmacal Research
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• 제21권5호
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• pp.503-507
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• 1998

Percutaneous absorption and model membrane variations of melationin (MT) in aqueous-based propylene glycol and $2-hydroxypropyl-{\beta}-cyclodextrin $vehicles were investigatted. the excised hairless mouse skin (HMS) and two synthetic ethylene vinyl acetate (EVA) and microporous polyethylene (MPE) were selected as a model membrane. the solubility of MT was determined by phase equilibrium study. the vertical $Franz{\circledR}$ type cell was used for diffusion study. The concentration of MT was determined using reverse phse HPLC system. The MT solubility was the highest in a mixture of PG and $2-HP{\beta}CD$. The percutaneous absorption of MT through excised HMS increased as the solubility increased. However, the permeability coefficient decreased and then slightly increased in mixture of PG and $2-HP{\beta}CD$. On the other hand, both flux and permeability coefficient through EVA membrane decreased as the solubility increased. No MT was detected over 12 h after starting diffusion through MPE membrane. The flux of MT was dependent on the type of membrane selected. Flux of MT was greatest in excised HMS followed by EBA and MPE membrane. Flux of MT through EVA membrane was 5-20 times lower when compared to excised HMS. Interestingly, volumes of donor phase when MPE membrane was used, significantly increased during the study period. the HMS might be applicable to expect plasma concentration of MT in human subjects based on flux and pharmacokinetic parameters as studied previously. the current studies may be applied to deliver MT transdermally using aqueous-based vehicles and to fabricate MT dosage forms.

• Ocean and Polar Research
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• 제26권4호
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• pp.647-653
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• 2004

Experimental studies with 4.3m and enlarged 30m in height have been conducted to investigate the flow characteristics of solid-liquid mixture in a lifting pipe and to acquire the design data for sea tests that will be performed in the future. From the results, it was observed that the more the discharged volume fraction and the solid diameter increase, the more the hydraulic gradient increases. Also, the more the diameter of the lifting pipe increases, the smaller the friction loss, and consequently, the less pressure drop and hydraulic gradient. From the enlarged hydraulic pumping experiments, it was shown that the results of the experiments were matched with those of the numerical model previously developed. On the bases of these studies, we plan to conduct further experiments and validate the hydraulic pumping model.

• International Journal of Aeronautical and Space Sciences
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• 제4권2호
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• pp.51-60
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• 2003

An experimental research program is being undertaken to develop a regeneratively-cooled experimental thrust chamber of liquid rocket engine using liquefied natural gas and liquid oxygen as propellants. Prior to firing test using a regenerative cooling with liquefied natural gas in this program, several firing tests were conducted with water as a coolant. Experimental thrust chambers with a thrust of about 10tf were developed and their firing test facility was built up. Injector used in the thrust chamber was of shear-coaxial type appropriate for propellants of gas and liquid phase and cooling channels are of milled rectangular configuration. Periodical variation of the soot deposition and discoloration was observed through an eyes' inspection on the inner wall of a combustion chamber and a nozzle after each firing test, and an intuitive concept of the periodical variation of mixture ratio near the inner wall of a combustion chamber and a nozzle at once was brought about and analyzed quantitatively. Thermal heat flux to the coolant was calculated and modified with the periodical variation model of mixture ratio, and the increment of coolant temperature at cooling channels was compared with measured one.