• 제목/요약/키워드: Phase Mixture Model

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Simulation and Modeling of Polyethylene/Clay Nanocomposite for Dielectric Application

  • Zazoum, Bouchaib;David, Eric;Ngo, Anh Dung
    • Transactions on Electrical and Electronic Materials
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    • 제15권4호
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    • pp.175-181
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    • 2014
  • In this paper, the simulation and modeling of a polyethylene/clay nanocomposite were undertaken to predict the nanocomposite's dielectric behavior and to help design a nanocomposite material with optimum electrical properties for electrotechnical or electronic applications. A 3-D simulation model using the finite elements method was employed in order to study the effective permittivity and electric field distribution of two-phase nanocomposite materials for ordered and random distributions of inclusions in a low-loss host matrix such as polyethylene. The influence of the dispersion of reinforcing particles, and of the permittivity and radius of the inclusions, was analysed. The simulation results were compared with alternative, known theoretical solutions obtained from classical models, and were found to be in good agreement. The numerical results also indicate that for fixed volume fractions of nanoparticles the effective permittivity of the mixture, for ordered and random distributions, does not vary with the degree of dispersion. The variation of the effective permittivity with the particle radius is shown, using numerical data, to agree with the analytical modules.

막냉각 효과를 고려한 액체로켓 엔진의 연소 특성에 관한 연구 (A Numerical Study on the Combustion Characteristics in a Liquid Rocket Engine with Film Cooling Effect)

  • 변도영;김만영;백승욱
    • 한국항공우주학회지
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    • 제31권8호
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    • pp.69-76
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    • 2003
  • 액체로켓 연소기 내의 막냉각 특성 분석을 위한 비회체 분무연소에 대한 수치해석을 수행하였다. 막냉각 연료의 특성에 따른 연소기 벽면의 온도변화를 살펴보기 위하여 막냉각용 연료의 유랑, 막냉각용 액적의 직경, 그리고 공기/연료 혼합비를 매개변수로 한 수치해석을 수행하여 연소기 벽면의 온도는 막냉각용 연료 액적 직경의 변화에는 큰 영향을 받지 않지만 막냉각용 연료 유량 및 공기/연료 혼합비에 영향을 받고 있음을 확인하였다. 또한, 추진기관 벽면으로 전달되는 전도 및 복사열유속을 고찰함으로서 이러한 액체 추진기관의 연소특성을 이해하기 위해서는 열복사 및 물성치의 적절한 고찰이 필요함을 지적하였다.

Liposome의 광산화반응에 미치는 인삼추출물의 영향 제1보. Hydroperoxide 생성 억제 효과 (The Effect of Ginseng Extracts on the Photooxidation of Liposome I. The protective effect of the formation of hydroperoxides)

  • 백태홍;김영호;이준홍
    • Journal of Ginseng Research
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    • 제14권3호
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    • pp.379-384
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    • 1990
  • In order to study the lipid peroxidation caused by light and the protective action it in biological memberane, reverse-phase evaporation liposome (REV) was employed as a model memberance and the effect of several antioxidants and ginseng water extracts were tested. In the presence of photosensitizer, liposome was oxidized easily and the oxidation index dut to the peroxidation was increased. The oxidation index of liposome was increased according to the increase in temperature. When dl-${\alpha}$-tocopherol, ${\beta}$-carotene or L-ascorbic acid was added into the reaction mixture, the photooxidation of liposome was inhibited. Ginseng water extract and crude saponin inhibited the rate of oxidation index of liposome in low concentration but increase in high concentration. On the other hand, when lipid hydroperoxide of liposome was tested by ferrothiocyanate method, ginseng water extract and crude saponin acted as antioxidants.

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The Structure Determination of La2/3-xLi3x1/3-2xTiO3 by the Powder Neutron and X-ray Diffraction

  • Kang, Eun-Tae;Kwon, Young-Jean
    • 한국세라믹학회지
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    • 제40권6호
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    • pp.513-518
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    • 2003
  • La/sub 2/3-x/Li/sub 3x/□/sub 1/3-2x/TiO₃ compounds with x=0.13 and 0.12 were prepared by slow cooling (x=0.13) and rapid quenching (x=0.12) into the liquid nitrogen after sintering at 1350℃ for 6 h. Their crystal structure has been determined by Rietveld refinement of both the powder neutron and X-ray diffraction data. From neutron diffraction data, we found that the main phase was not tetragonal (P4/mmm), but trigonal (R3cH). The refinement of neutron diffraction for the slow cooled samples were in a good agreement with a new model; a mixture of trigonal (R3cH, 45.7 wt%), tetragonal (p4/mmm, 37.0 wt%), and Li/sub 0.57/Ti/sub 0.86/O₂(pbnm, 17.2 wt%), but the quenched sample was found not to contain tetragonal (p4/mmm). X-ray diffraction data couldn't be well fitted because of the Poor scattering factor of lithium ions and the similar reflection patterns among trigonal (R3cH), tetragonal (p4/mmm), and cubic (Pm3m). We also knew that one transport bottlenecks is destroyed by one La vacancy in the case of trigonal (R3cH).

Breakdown characteristics of SF6 and Imitation Air in Temperature Decline

  • Lim, Chang-Ho;Choi, Eun-Hyeok;Kim, Do-Seok;Kim, Young-Su;Park, Won-Zoo;Lee, Kwang-Sik
    • 조명전기설비학회논문지
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    • 제21권4호
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    • pp.115-121
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    • 2007
  • This paper describes experiments of the breakdown characteristics by temperature change of $SF_6$ gas and Imitation Air(I-Air) in model GIS(Gas Insulated Switchgear). From the results of the experiments, the breakdown characteristics classify the vapor stage of $SF_6$ according to Paschen's law, in which the stage of coexistence for gas & liquid of the voltage value increases. This results in large deviation and the breakdown of the voltage(VB) low stage as the interior of the chamber is filled with a mixture of $SF_6$ that is not liquefacted and remaining air that can not be ventilated. The ability of $SF_6$ liquid($LSF_6$) insulation is higher than high-pressurize $SF_6$ gas. The VB of the I-Air decreases as the temperature drops and the VB also drops. It is considered that the results of this paper are fundamental data for the electric insulation design of superconductor and cryogenic equipment that will be studied and developed in the future.

가연성물질의 폭발한계에 관한 연구 - 액상 조성에 의한 가연성 2성분 액체혼합물의 폭발한계 - (A Study on Explosive Limits of Flammable Materials - Explosive Limits of Flammable Binary liquid Mixture by Liquid Phase Compositions -)

  • 하동명
    • 한국안전학회지
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    • 제16권4호
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    • pp.103-108
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    • 2001
  • Explosive limit is one of the major physical properties used to determine the fire and explosion hazards of the flammable substances. Explosive limits are used to classify flammable liquids according to their relative flammability. Such a classification is important for the safe handling of flammable liquids which constitute the solvent mixtures. Explosive limits of all compounds and solvent mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Dalton, Le Chatelier and activity coefficient models. In this paper, Raoult,s law and van Laar equation(activity coefficient model) are shown to be applicable for the prediction of the explosive limits in the flammable ethylacetate-toluene system. The values calculated by the proposed equations were a good agreement with literature data within a given percent. From a given results, by the use of the proposed equations, it is possible to predict explosive limits of the other flammable mixtures. It is hoped eventually that this method will permit the estimation of the explosive Properties of flammable mixtures with improved accuracy and the broader application for other flammable stances.

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정년제도와 사회보장 : 1980년 이후 OECD 회원국들의 노후 소득보장 정책의 변화 (Retirement Age and Social Security)

  • 나병균
    • 한국사회복지학
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    • 제42권
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    • pp.169-198
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    • 2000
  • This paper attempts to analyze the early retirement in the OECD countries and discuss implication of that in the old age policy in Korea. The increase of the early retirement in the almost all OECD countries is a common fact. Especially the rate of early retirement rapidly increased in the 1980s, mostly reflecting the high rate of unemployment and states' policies to reduce it. However, it varies across countries: the unemployment compensation pathway in France, the mixture of social assistance and private insurance in England, VUT in Netherland, the privatization of the early retirement in the U. S., and partial retirement and labor market policy in Sweden. The early retirement in the advanced countries contributes to de-institutionalization and de-standardization in life course model. It resulted in the erosion of the ordinary conception that the retirement was the beginning of the old age. And the last phase of life course became blurred. With respect to the problem of the early retirement, there is a big difference between Korea and the OECD countries. Above all, the retirement age is 55 years in many companies and the public pension is not universalized in Korea. Accordingly the policy for income security of the old age in Korea should be connected with social security policy such as the gradual extension of the retirement age and the expansion of the public pension and labor market policy such as job training for the old age, transformation of the seniority wage system etc.

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Breakdown Characteristics of SF6 in Different State and Bubble Movements under AC High-Voltage

  • Choi, Eun-Hyeok;Lim, Chang-Ho;Yoon, Dae-Hee;Park, Kwang-Seo;Kim, Lee-Kook;Lee, Kwang-Sik
    • Journal of Electrical Engineering and Technology
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    • 제2권2호
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    • pp.257-262
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    • 2007
  • In this paper the experiments of breakdown characteristics by temperature change of $SF_6$ gas($GSF_6$), and $SF_6$ liquid ($LSF_6$) in model GIS (Gas Insulated Switchgear) are described. From the experiment's results, the breakdown characteristics classify the vapor stage of $SF_6$ according to Paschen's law, in which the gas & liquid coexisted stage of voltage value increases, resulting in much deviation and the breakdown of voltage ($V_B$) low stage as the interior of the chamber gets filled with a mixture of $SF_6$ that is not liquefacted and remaining air that cannot be ventilated. The ability of $LSF_6$ insulation is higher than the high-pressurized $SF_6$ gas. The breakdown characteristics of $LSF_6$ were produced by bubble formed evaporation of $LSF_6$ and bubbles caused by high electric emission. It is considered in this paper that the results are fundamental data for electric insulation design of superconductor and cryogenic equipments machinery that will be studied and developed in the future.

현탁된 고형지질나노입자 내로 친수성 약물의 봉입률을 증대시키기 위한 w/o/w 에멀션 가온용융유화법의 평가 (A Hot Melt w/o/w Emulsion Technique Suitable for Improved Loading of Hydrophilic Drugs into Solid Lipid Nanoparticles)

  • 이병무;최성업;이재휘;최영욱
    • Journal of Pharmaceutical Investigation
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    • 제35권1호
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    • pp.33-38
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    • 2005
  • Recently increasing attention has been focused on solid lipid nanoparticles (SLN) as a parenteral drug carrier due to its numerous advantages that can come from both polymeric particle and fat emulsions, together with the possibility of controlled release and increasing drug stability. Lipophilic drugs such as paclitaxel, cyclosporin A, and all-trans retinoic acid have been successfully entrapped in SLN but the incorporation of hydrophilic drugs in SLN is very limited because of their very low affinity to the lipid. Therefore, as a new approach to improve the loading of hydrophilic drugs, a w/o/w emulsion technique has been developed. The primary objective of the current study was to improve the loading efficiency of a model hydrophilic drug, glycine (Log P = -3.44) into SLN. The proposed preparation process is as follows: A heated aqueous phase consisting of 0.1 ml of glycine solution in water (100 mg/ml), and poloxamer 188 (5 mg) were then added to a molten oil phase containing precirol (100 mg) and lecithin (5 mg). This mixture was dispersed by sonicator, leading to a w/o emulsion. A double emulsion (w/o/w) was formed after the addition of 2% poloxamer solution to the above dispersed system. After cooling the double emulsion, solid lipid nanosuspensions were successfully formed. The lipid nanoparticles had the mean particle size of 441.25 nm, and the average zeta potential of -20.98 mV. The drug loading efficiency was measured to be 8.54% and the drug loading amount was measured to be 0.92%. The w/o/w emulsion method showed an increased loading efficiency compared to conventional o/w emulsion method.

Comparative analysis of two methods of laser induced boron isotopes separation

  • K.A., Lyakhov;Lee, H.J.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.407-408
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    • 2011
  • Natural boron consists of two stable isotopes 10B and 11B with natural abundance of 18.8 atom percent of 10B and 81.2 atom percent of 11B. The thermal neutron absorption cross-section for 10B and 11B are 3837 barn and 0.005 barn respectively. 10B enriched specific compounds are used for control rods and as a reactor coolant additives. In this work 2 methods for boron enrichment were analysed: 1) Gas irradiation in static conditions. Dissociation occurs due to multiphoton absorption by specific isotopes in appropriately tuned laser field. IR shifted laser pulses are usually used in combination with increasing the laser intensity also improves selectivity up to some degree. In order to prevent recombination of dissociated molecules BCl3 is mixed with H2S 2) SILARC method. Advantages of this method: a) Gas cooling is helpful to split and shrink boron isotopes absorption bands. In order to achieve better selectivity BCl3 gas has to be substantially rarefied (~0.01%-5%) in mixture with carrier gas. b) Laser intensity is lower than in the first method. Some preliminary calculations of dissociation and recombination with carrier gas molecules energetics for both methods will be demonstrated Boron separation in SILARC method can be represented as multistage process: 1) Mixture of BCl3 with carrier gas is putted in reservoir 2) Gas overcooling due to expansion through Laval nozzle 3) IR multiphoton absorption by gas irradiated by specifically tuned laser field with subsequent gradual gas condensation in outlet chamber It is planned to develop software which includes these stages. This software will rely on the following available software based on quantum molecular dynamics in external quantized field: 1) WavePacket: Each particle is treated semiclassicaly based on Wigner transform method 2) Turbomole: It is based on local density methods like density of functional methods (DFT) and its improvement- coupled clusters approach (CC) to take into account quantum correlation. These models will be used to extract information concerning kinetic coefficients, and their dependence on applied external field. Information on radiative corrections to equation of state induced by laser field which take into account possible phase transition (or crossover?) can be also revealed. This mixed phase equation of state with quantum corrections will be further used in hydrodynamical simulations. Moreover results of these hydrodynamical simulations can be compared with results of CFD calculations. The first reasonable question to ask before starting the CFD simulations is whether turbulent effects are significant or not, and how to model turbulence? The questions of laser beam parameters and outlet chamber geometry which are most optimal to make all gas volume irradiated is also discussed. Relationship between enrichment factor and stagnation pressure and temperature based on experimental data is also reported.

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