• Title/Summary/Keyword: Phase Mixture Model

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A Boundary diffusion creep model of grain boundary phase of materials (재료결정립계상의 입계확산크립 모델)

  • 김형섭
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2000.04a
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    • pp.192-195
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    • 2000
  • In describing the plastic deformation behaviour of fine grained materials a phase mixture model in which a polycrystalline material is regarded as a mixture of a crystalline phase and a grain boundary phase has been successful. The deformation mechanism for the grain boundary phase which is necessary for applying the phase mixture model is modelled as a diffusional flow of matter though the grain boundary. The proposed model can explain the strain rate and grain size dependence of the strength of the grain boundary phase.

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A Boundary Diffusion Creep Model for the Plastic Deformation of Grain Boundary Phase of Nanocrystalline Materials (나노재료 입계상의 소성변형에 대한 입계확산크립 모델)

  • 김형섭;오승탁;이재성
    • Transactions of Materials Processing
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    • v.10 no.5
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    • pp.383-388
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    • 2001
  • In describing the plastic deformation behaviour of ultrafine-grained materials, a phase mixture model in which a polycrystalline material is regarded as a mixture of a crystalline phase and a grain boundary phase has been successful. The deformation mechanism for the grain boundary phase, which is necessary for applying the phase mixture model to polycrystalline materials, is modelled as a diffusional flow of matter along the grain boundary. A constitutive equation for the boundary diffusion creep of the boundary phase was proposed, in which the strain rate is proportional to (stress/grain siz $e^{2}$). The upper limit of the stress of the boundary phase was set to equal to the strength to the amorphous phase. The proposed model can explain the strain rate and grain size dependence of the strength of the grain boundary phase. Successful applications of the model compared with published experimental data are described.

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Numerical investigation of detonation characteristics in hybrid ethylene-air and RDX mixture using two-phase model (Two-phase 모델을 활용한 에틸렌-공기와 RDX 혼합물의 데토네이션 특성 연구)

  • Gwak, Min-cheol;Kim, Wuhyun;Yoh, Jai-ick
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.686-690
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    • 2017
  • In this study, we numerically investigate the detonation characteristics (detonation velocity and pressure) of a hybrid ethylene-air and RDX mixture using two-phase model. Compared with detonation of pure ethylene-air mixture, the detonation of the hybrid ethylene-air and RDX mixture has higher pressure and stronger impulse because the hybrid mixture has additional chemical heat release of RDX particles. To validate the numerical results using two-phase model, we compare the experimental data which show changes of detonation pressure and velocity according to concentration of RDX particles.

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Multi-Scale Modelling of a Phase Mixture Model and the Finite Element Method for Nanocrystalline Materials (나노결정 재료의 상혼합모델과 유한요소법을 결합한 멀티스케일 모델링)

  • 윤승채;서민홍;김형섭
    • Transactions of Materials Processing
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    • v.13 no.2
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    • pp.174-179
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    • 2004
  • The effect of grain refinement on the plastic deformation behaviour of nanocrystalline metallic materials is investigated. A phase mixture model in which a single phase material is considered as an effectively two-phase one is discussed. A distinctive feature of the model is that grain boundaries are treated as a separate phase deforming by a diffusion mechanism. For the grain interior phase two concurrent mechanisms are considered: dislocation glide and mass transfer by diffusion. The proposed constitutive model was implemented into a finite element code (DEFORM) using a semicoupled approach. The finite element method was applied to simulating room temperature tensile deformation of Cu down to the nanoscale grain size in order to investigate the pre- and post-necking behaviour.

Deformation Mechanism Map of Nanocrystalline Metallic Materials (나노결정립 금속재료의 변형기구지도)

  • Yoon, S.C.;Bok, C.H.;Kwak, E.J.;Kim, H.S.
    • Transactions of Materials Processing
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    • v.16 no.6
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    • pp.473-478
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    • 2007
  • In this study, a deformation mechanism map of metallic nanocrystalline materials(NCMs) using the phase mixture model is proposed. It is based on recent modeling that appears to provide a conclusive description of the phenomenology and the mechanisms underlying the mechanical properties of NCMs. The proposed models adopted the concept of a 'phase mixture' in which the grain interior and the grain boundaries are treated as separate phases. The volume fraction of this grain boundary 'phase' may be quite appreciable in a NCM. Based on the theoretical model that provides an adequate description of the grain size dependence of plasticity covering all grain size range from coarse down to the nanoscale, the tensile deformation response of NCMs, especially focusing on the deformation mechanisms was investigated. The deformation mechanism map is newly proposed with axes of strain rate, grain size and temperature.

Pervaporation Process for Water/Ethanol Mixture through IPN Membranes

  • Jeon, Eun-Jin;Kim, Sung-Chul
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.04a
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    • pp.52-53
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    • 1993
  • The pervaporation behavior of EtOH/Water mixture through IPN membranes was predicted in this study. The pervaporation characteristics of single polymer membrane were modeled according to the "six-coefficients model" proposed by Brun. In the case of the IPN membrane, two models were proposed according to the phase structure of the IPN. For a uniphase membrane with no phase separation, the compositional average of the single polymer membrane was used. in the case of the phase separated IPN's two cases existed. The first was the island and sea model: in which one phase was continuous and the other was dispersed. The second was the co-continuous model where two continuous phases existed. For these cases, the permeation rate and the separation factor of the IPN membrane were calculated using the experimental sorption data and the cornponent polymer properties. Comparison with the experimental data indicated that these models could be used to predict the performances of IPN membranes depending on the morphology of the IPN.

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Studies on the Detergency of Oily Soils (Part 1) - Detergency of Soild Oily Soils - (유성오염의 세척성에 관한 연구(제1보) -개체유성오염의 세척성-)

  • 김영희;정두진
    • Journal of the Korean Society of Clothing and Textiles
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    • v.18 no.4
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    • pp.524-535
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    • 1994
  • The interaction and detergency between oily soil and surfactant solution were studied Samples used were tristearin, tripalmitin and their mixture as a triglyceride, myristic acid as a fatty acid and sodium dodecyl sulfate (SDS) as surfactant. The results were as follows: 1. The mixtures of model oily soils were formed of eutectic point and their melting point were lower than them of individual oily soils. 2. The formation of liquid crystalline (LC) phase was recognized in the triangle phase diagram for SDS~ water~model oily soil system. The areas of LC phase region were in the order of SHS~ water~myristir acid> SDS~ water~mixture of tristearin, tripalmitin and myristic acid (TS/TP/M)>SDS~water~mixture of tristearin and tripalmitin (TS/TP) 3. The LC phase region expanded to wide concentration range of SDS solution and high concentration range of model oily soil with increasing temperature. Particularity, the LC phase region expanded highly at $30~40^{\circ}C$ but when the temperature was elevated above $40^{\circ}C$, expanding tendency decreased. 4. In the system of myristic acid and TS/TP/M contacted with SDS solution, the LC phase was already formed at $28^{\circ}C$ and the region of the LC phase were expanded with increasing temperature. But in the system of TS/TP contacted with SDS solution, the LC phase was not formed in whole experiment temperature. 5. The detergency of myristic acid was very high ann it was recognized that the formation of the LC phase played an important role in the detergency. The detergency of TS/TP was very for low, but when TS/TF was mixed with myristic acid, the detergency of TS/TP increased. It is supposed that the LC phase was formed butween SDS solution and myristic acid promoted to penetration of SDS solution into the inner parts of TS/TP.

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Energy Ratio Factor and Phase Angle Based Fatigue Prediction Model for Flexible Pavements

  • Kim, Nak-Seok
    • Journal of the Korean Society of Hazard Mitigation
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    • v.11 no.2
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    • pp.75-80
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    • 2011
  • The main objective of this research is to develop fatigue prediction model for flexible pavements using energy ratio factor and phase angle. The two parameters are considered as fundamental properties of time and temperature dependent viscoelastic asphalt concrete materials. The energy ratio factor is defined as the ratio of the pseudo-total cumulative dissipated energy to the cumulative dissipated energy to failure during the test. The phase angle between the stress and strain ware signals stems from the intrinsic the dependent asphalt mixture behavior. The phase angle was computed and the relationship between the initial mixture stiffness and the initial phase angle is presented. As a result, fatigue prediction model for flexible pavements was proposed using intrinsic properties of viscoelastic asphalt concrete materials.

Pridiction of Adsorption Equilibrium for Binary Gas Mixtures on Cation Exchanged Forms of ZSM-5

  • Going Yim;Chai Suck Yim
    • The Journal of Engineering Research
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    • v.6 no.2
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    • pp.85-98
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    • 2004
  • The adsorption equilibrium data for the binary gas mixture system from the pure gas adsorption data of carbon dioxide and ethylene on ZSM-5 prepared were predicted. The binary gas mixture adsorption data have been examined against predicted values by two models-the vacancy solution model(VSM) and the statistical thermodynamic model(STM), using parameters obtained from the single component isotherm. The binary gas mixture data for the carbon dioxide-ethylene system were obtained for cation exchanged forms of ZSM-5 for the gas phase carbon dioxide mole fraction of 0.752 at $37^{\circ}C$ and 1 atm. The experimental adsorption phase diagrams were obtained for carbon dioxide-ethylene on sodium form ZSM-5 synthesized. The single component adsorption isotherms for carbon dioxide and ethylene were also obtained for this zeolite. The single component data were used to obtain parameters derived in two models. These parameters were, in turn, used to predict the binary mixture isotherms for this zeolite. Both the vacancy solution and the statistical thermodynamic models give satisfactory predictions of adsorption phase diagrams for the binary gas mixtures of carbon dioxide and ethylene on sodium exchanged ZSM-5. Also the correlation between the experimental data and the predicted values is generally in good agreement. The system appears to show ideal behavior with a relatively constant separation factor. The slight increase in adsorption capacity with an increase in ionic radius is due, in part, to the higher polarizability associated with larger cations.

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Language Model Adaptation Based on Topic Probability of Latent Dirichlet Allocation

  • Jeon, Hyung-Bae;Lee, Soo-Young
    • ETRI Journal
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    • v.38 no.3
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    • pp.487-493
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    • 2016
  • Two new methods are proposed for an unsupervised adaptation of a language model (LM) with a single sentence for automatic transcription tasks. At the training phase, training documents are clustered by a method known as Latent Dirichlet allocation (LDA), and then a domain-specific LM is trained for each cluster. At the test phase, an adapted LM is presented as a linear mixture of the now trained domain-specific LMs. Unlike previous adaptation methods, the proposed methods fully utilize a trained LDA model for the estimation of weight values, which are then to be assigned to the now trained domain-specific LMs; therefore, the clustering and weight-estimation algorithms of the trained LDA model are reliable. For the continuous speech recognition benchmark tests, the proposed methods outperform other unsupervised LM adaptation methods based on latent semantic analysis, non-negative matrix factorization, and LDA with n-gram counting.