• Proceedings of the KIEE Conference
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• 2000.07b
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• pp.1171-1173
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• 2000

This paper was analyzed the high-frequency harmonics, power conversion rate, results of the system's monitor, and measuring data of the system power output of a 3-phase photovoltaic power system for grid-connection. The photovoltaic power system consists of a 3-phase inverter array, and data acquisition system. The result of an analyzing data of the 50 kW class grid-connected photovoltaic system showed the stable behavior in utility-interactive operation.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.916-917
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• 2008

In this paper, Switching damage of switches that is used to proposed power conversion system is reduced by soft switching way. dissipation by part resonance and my resonance stress for resonance of resonance circuit are decreased. Is acted by conversion system high effectiveness. Have following characteristic. Design snubber circuit that is used by switch protection in existent hard work rate Topology by resonant circuit for sogt switching, circuit structure was simple and control system is easy. Also, Can generate free output voltage by multi level Tuesday of output that use individuation Power Cell's Phase Shift PWM, and Low-end switching frequency the harmonic is few.

• Macromolecular Research
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• v.10 no.5
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• pp.259-265
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• 2002

The cure kinetics of blends of epoxy (DGEBA, diglycidyl ether of bisphenol A)/anhydride resin with polyamide copolymer, poly(dimmer acid-co-alkyl polyamine), were studied using differential scanning calorimetry (DSC) under isothermal condition. On increasing the amount of polyamide copolymer in the blends, the reaction rate was increased and the final cure conversion was decreased. Lower values of final cure conversions in the epoxy/(polyamide copolymer) blends indicate that polyamide hinders the cure reaction between the epoxy and the curing agent. The value of the reaction order, m, for the initial autocatalytic reaction was not affected by blending polyamide copolymer with epoxy resin, and the value was approximately 1.3, whereas the reaction order, n, for the general n-th order of reaction was increased by increasing the amount of polyamide copolymer in the blends, and the value increased from 1.6 to 4.0. A diffusion-controlled reaction was observed as the cure conversion increased and the rate equation was successfully analyzed by incorporating the diffusion control term for the epoxy/anhydride/(polyamide copolymer) blends. Complete miscibility was observed in the uncured blends of epoxy/(polyamide copolymer) up to 120 $^{\circ}C$, but phase separations occurred in the early stages of the curing process at higher temperatures than 120 "C. During the curing process, the cure reaction involving the functional group in polyamide copolymer was detected on a DSC thermogram.gram.

• Korean Journal of Materials Research
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• v.12 no.12
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• pp.947-954
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• 2002

HCl concentration and reaction time are the decisive factors in determining the structure of precipitates in the process of synthesis of $TiO_2$ particles from aqueous $TiOCl_2$ solution by precipitation and the volumetric proportion of brookite phase in $TiO_2$ particles can be controlled by these two factors. As reaction rate increases with increase of reaction temperature, the reaction time, at which maximum volumetric proportion of brookite phase in $TiO_2$ particles was obtained, was reduced. The brookite was transformed directly to rutile phase with only increase of reaction time. And precipitation was delayed with increase of HCl concentration because the amount of $H_2$O, which is necessary source of oxygen for conversion of $Ti^{+4}$ to $TiO_2$, was relatively reduced with increase of that. Brookite in the mixture phase powder was finally transformed to rutile phase via anatase through heat-treatment.

• Journal of Ceramic Processing Research
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• v.19 no.6
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• pp.492-498
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• 2018

In this study, a sea shell was converted into bioceramic phases at three different sintering temperatures ($450^{\circ}C$, $850^{\circ}C$, $1000^{\circ}C$). Among the obtained bioceramic phases, a valuable ${\beta}-TCP$ was produced via mechanochemical conversion method from sea snail Turritella terebra at $1000^{\circ}C$ sintering temperature. For this reason, only the bioceramic sintered at $1000^{\circ}C$ was concentrated on and FT-IR, SEM/EDX, BET, XRD, ICP-OES analyses were carried out for the complete characterization of ${\beta}-TCP$ phase. Biodegradation test in Tris-buffer solution, bioactivity tests in simulated body fluid (SBF) and cell studies were conducted. Bioactivity test results were promising and high rate of cell viability was observed in MTT assay after 24 hours and 7 days incubation. Results demonstrated that the produced ${\beta}-TCP$ bioceramic is qualified for further consideration and experimentation with its features of pore size and ability to support bone tissue growth and cell proliferation. This study suggests an easy, economic method of nanobioceramic production.

• Korean Journal of Optics and Photonics
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• v.17 no.5
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• pp.430-436
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• 2006

Polarization-independent $Ti:LiNbO_3\;2{\times}2$ optical add/drop multiplexer for the 1550nm wavelength region is fabricated. The device consists of two input waveguides, two polarization beam splitters. two polarization conversion/electrooptic tuning waveguide sections, and two output waveguides. The single mode channel waveguides for both TE and TM polarizations are fabricated on a x-cut $Ti:LiNbO_3$substrate by Ti diffusion. Spectral section is based on phase-matched polarization conversion due to shear strain induced by a thick $SiO_2$ grating overlay film. An applied voltage tunes the device by changing the waveguide birefringence, hence the optical wavelength at which most efficient polarization conversion occurs. Tuning rate of 0.094nm/V with a maximum range of 17nm has been obtained. The nearest side-lobe is about 8.2dB. The FWHM is 3.72nm.

• Journal of Environmental Science International
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• v.17 no.2
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• pp.211-224
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• 2008

Characteristics of the esterification reaction between free fatty acid in rice bran oil and methanol was investigated in the presence of catalysts, such as PTS(p-toluene sulfonic acid), Amberlyst 15 dry and SCX(silica gel based strong cation exchange resin). While reaction temperature was kept constant at $65^{\circ}C$, initial feed content of free fatty acid was varied from 100% to 1% by addition of pure free fatty acid which was previously made from rice bran oil. Also, the effect of mole ratio of methanol to fatty acid on the final conversion was examined. When esterification of pure free fatty acid was catalyzed by several acids, final conversions were increased in order of Amberlyst 15 dry, SCX and PTS. Using PTS catalyst, initially the reaction proceeded in homogeneous 2nd oder reaction mechanism. However, phase of reaction mixture changed from homogeneous to heterogeneous along the reaction time and then reaction rate was retarded by mass transfer resistance of methanol. Final conversion of free fatty acid in reaction mixture was depended on initial feed content of free fatty acid, and had maximum value at 30% of initial feed free fatty acid content for all kinds of catalysts used. And the final conversion was increased with mole ratio of methanol by the improvement of reaction rate. When initial feed free fatty acid content below 10% and the reaction was catalyzed by PTS, concentration of free fatty acid in reaction mixture was increased in the middle of reaction time by hydrolysis of triglyceride in reaction mixture. Also, if silica gel was added into the reaction mixture which had initial feed free fatty acid content below 50%, final conversion was increased by the adsorption of moisture produced. The SCX catalyst made the esterification reaction of free fatty acid to progress like in case of PTS catalyst. However, when initial feed free fatty acid content below 10%, concentration of free fatty acid in. reaction mixture was decreased monotonically and not increased in the middle of reaction time on the contrary to the case of PTS. Thus, SCX catalyst accomplished more high value of final conversion than PTS catalyst for the initial feed fatty acid content range from 50% to 5% In case of initial feed free fatty acid content of 1% and mole ratio of methanol was 2, concentration of free fatty acid in reaction mixture increased over the initial feed free fatty acid content for all kind of catalysts used. Although SCX catalyst was added into reaction mixture which had 1% of initial feed fatty acid content, final conversion was hardly raised by mole ratio of methanol.

• The Transactions of the Korean Institute of Power Electronics
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• v.19 no.6
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• pp.538-548
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• 2014

This study provides a robust control of a grid-connected three-phase two-level photo voltaic inverter. The introduced control method uses the cascade control strategy to regulate AC-side current and DC-link voltage. A robust controller with integration action is used for the inner-loop AC-side current control, which maximizes the convergence rate using a linear matrix inequality-based optimization design method and eliminates the offset error. The robust controller design method considers the parameter uncertainty set to accommodate parameter mismatch and un-modeled components in the inverter model. An outer-loop proportional-integral controller is used to regulate DC-link voltage with linearization of DC/AC relation. The proposed control strategy is applied to a grid-connected 100 kW photo voltaic inverter.

• Journal of the Korean institute of surface engineering
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• v.32 no.3
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• pp.281-288
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• 1999

Electrodeposited Zn-Ni alloy coatings are of particular interest for improving the corrosion resistance of steel in a number of enviornments. Of particular interest is the relationship between composition, structure and corrosion rate. This paper firstly reviews the literature regarding composition-structure relationships of Zn-Ni electrodeposits and compares them with the equilibrium phase diagram. Secondly, research was carried out on a wide range of coatings which were produced in the laboratory and their structure and corrosion rates determined. It was found that unambiguous identification of phases from XRD data can be difficult. Maximum corrosion resistance of deposits is obtained at 12-13% Ni, with a $\gamma$ phase structure and predomination of (600) and (411) reflections. Compatibility is important with regard to chromate conversion coatings.

• Applied Chemistry for Engineering
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• v.4 no.4
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• pp.715-720
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• 1993

Diphenylmethane (pKa=33.4), which is difficult to be oxidized in normal oxidation conditions, was oxidized to produce benzophenone at ambient temperature and atmospheric pressure by using phase transfer catalysts and solid potassium tert-butoxide as base. Quaternary salt such as benzyltriethylammonium chloride, tetrabutyl ammonium bisulfate, tetrabutylphosponium chloride, are ineffective catalysts for this reaction, but 18-crown-6 and polyethylene glycols showed catalytic activity. The conversion of diphenylmethane was increased with increasing chain length of PEG molecules when they are used as phase transfer catalysts both in equal molar and equal weight basis. The conversion of diphenylmethane was increased with the agitation speed, and aprotic solvent like DMF showed higher reaction rate compared with benzene.