• Title/Summary/Keyword: Phase Characteristic

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Characteristics of the Black Surface Layer on Carbonate Stone Pagoda in Urban Area and Its Origin (도심지역에 위치한 탄산염암 석탑 표면에 형성된 흑색층의 특성과 그 기원)

  • Do, Jin-Young;Kim, Jeong-Jin;Cho, Hyen-Goo
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.383-392
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    • 2006
  • Calcium carbonate stone deterioration has been intensified in urban area, mainly due to the action of atmospheric pollutant. Samples from the black surface layer were examined under petrographic and scanning electron microscope, coupled with energy dispersive X-ray analyser X-ray fluorescence and X-ray diffraction analysis was also carried out for chemical composition and mineral phase analysis, respectively. Moreover, sulphur isotope ratio was measured, in order to identify the origin of sulphate compounds in the black surface layer. Optical and electronic petrographic analysis indicated that gypsum and Quartz were contained in the black surface layer and led to microcracks. Microstructure and chemical composition analysis showed that the interface between black layer and original stone is not black but its characteristic is similar to black layer The results indicated that during deterioration process the black layer can be expanded gradually into the interface by adsorption of atmospheric pollutants. The sulphur isotope analysis demonstrates that there are different origins of the sulphur component in black surface layer.

Sorption Characteristics of Uranium on Goethite and Montmorillonite under Biogeochemical Reducing Conditions (생지화학적 환원조건에서 우라늄의 침철석 및 몬모릴로나이트에 대한 수착 특성)

  • Lee, Seung Yeop;Cho, Hye-Ryun;Baik, Min Hoon;Jung, Euo Chang;Jeong, Jongtae
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.4
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    • pp.263-270
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    • 2012
  • Two kinds of uranium species, oxidized uranium(VI) and reduced uranium(IV), were prepared to be interacted with goethite and montmorillonite to identify sorption characteristic of uranium species, which are very sensitive to the redox-reaction. The reduced uranium was prepared by diluting a substantial uranium(IV) that was concomitantly produced during a sulfate reduction via a sulfate-reducing bacterium. The sorption amount of uranium(IV) by the minerals was relatively lower than that of uranium(VI) because the aqueous uranium(IV) had fine colloidal forms to cause its weak adsorption onto the mineral surfaces. We found that the uranium(IV) phase has a nano-colloid character by the transmission electron microscope, suggesting that the uranium species possibly migrating with the flow of groundwater in underground environments can be the colloidal uranium(IV) as well as the ionic uranium(VI).

Characteristic of ferroelectric properties of $(Bi,Ce)_4Ti_3O_{12}$ thin films deposited by pulsed laser deposition (Pulsed laser deposition 방법으로 증착된 $(Bi,Ce)_4Ti_3O_{12}$ 박막의 강유전 특성)

  • Oh, Young-Nam;Seong, Nak-Jin;Yoon, Soon-Gil;Jeon, Min-Gu;Woo, Seong-Ihl;Kim, Chang-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.168-171
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    • 2003
  • Bismuth layered structure, Cerium-substituted $Bi_4Ti_3O_{12}$ ($(Bi,Ce)_4Ti_3O_{12}$) thin films were prepared on the $Pt/TiO_2/SiO_2/Si$ substrates by the pulsed laser deposition method. We investigated the Ce-subsitituted effect on the grain orientation and ferroelectric properties. $Ce^{3+}$ ion substitution for $Bi^{3+}$ ion in perovskite layers of BTO decreased the deeree of c-axis orientation and increased the remanent polariation (2Pr). The structure and morphology of the films were characterized using X-ray diffraction and atomic force microscopy. The $(Bi,Ce)_4Ti_3O_{12}$ (BCT) thin films, which were annealed $700^{\circ}C\;and\;800^{\circ}C$ for 10min and 30min, showed a perovskite phase and dense microstructure. As the thickness of the BCT film was decresed that the ferroelectric properties of the BCT thin films were good.

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A Robust Multiple Set-Top Box Authentication Scheme for IPTV Against Smart Card Cloning Attack (IPTV 환경에서 스마트카드 복제에 강건한 다중 셋톱박스 인증기법)

  • Lim, Ji-Hwan;Oh, Hee-Kuck;Kim, Sang-Jin
    • The KIPS Transactions:PartC
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    • v.17C no.1
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    • pp.37-46
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    • 2010
  • In an IPTV system, the rights of the content and service provider can be protected by using Conditional Access System (CAS) and Digital Right Management (DRM). In case of the CAS, only the authorized user who has structured authentication keys can decrypt the encrypted content. However, since the CAS establishes a secure channel only between content provider and Smart Card (SC), it cannot protect the system against McCormac Hack attack which eavesdrops on unsecure channel between SC and Set-Top Box (STB) and SC cloning attack. In this paper, we propose a robust multi-STB assisted SC / STB authentication protocol which can protect the IPTV system against not only McCormac Hack attack, but also SC cloning attack. The previous works which bind a STB and a SC during the SC registration phase against the SC cloning attack does not support multi-STB environments. The proposed system which dynamically updates the STB information in subscriber management system using the bi-directional channel characteristic of IPTV system can support the user's multi-STB device effectively.

Parameters to Affect the Cirtical Characteristics of YBaCuO Bulk Prepared by MPMG (MPMG법을 이용한 YBaCuO 초전도체의 임계특성에 영향을 미치는 파라미터)

  • Gang, Hyeong-Gon;Im, Seong-Hun;Park, Seong-Jin;Han, Byeong-Seong
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.4
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    • pp.221-225
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    • 1999
  • This paper shows the parameters to affect the critical characteristic of YBaCuO superconducting bulk fabricated by MPMG (Melt Powdered Melt Growth)process. In order to investigate proper processing variables, the effect of the holding time at the melting temperature and that of the slow cooling time in $O_2\; ambient\; on\; the\; J_c$ were experimented. And then with the above obtained heat treatment conditions, the effects of addition of $Y_2BaCuO_5\; and\; Ag\; on\; the\; J_c$ were also investigated. A proper slow cooling time yields phase transformation from Tetragonal $(YBa_2Cu_3O_6)$ to Orthorhombic $(YBa_2Cu_3O_7)$ during an annealing time in $O_2$. Ag addition plays a role in increasing the $T_c\; and\; the J_c$, but the magnetization decreases. The $J_c$ and the magnetization increase with addition of Y211. $J_c$ of the sample added Ag 10wt% is superiorover 3000 G. Proper holding time, slow cooling time and amount of impurity addition are important parameters in fabricating the YBaCuO bulk by MPMG process with high $J_c$.

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Microwave Dielectric Characteristics of Ba(Mg1/3Nb2/3)O3-La(Mg2/3Nb1/3)O3 Ceramics with Crystal Structure (결정 구조에 따른 Ba(Mg1/3Nb2/3)O3-La(Mg2/3Nb1/3)O3세라믹스의 마이크로파 유전 특성)

  • Paik, Jong-Hoo;Lim, Eun-Kyeong;Lee, Mi-Jae;Jee, Mi-Jung;Choi, Byung-Hyun;Kim, Sei-Ki
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.1
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    • pp.30-37
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    • 2005
  • The microwave dielectric properties and their related structural characteristics in solid solutions of (1-$\chi$) Ba($Mg_{1/3}$Nb$_{2/3}$) $O_3$-$\chi$La(Mg$_{2/3}$Nb$_{1}$3) $O_3$(BLMN) have been investigated by measuring the dielectric constant($\varepsilon$r), Q value and temperature coefficient of resonant frequency($\tau$f) and by observing the crystal structure using high resolution transmission electron microscopy (HRTEM). Microwave dielectric properties showed characteristic features for specific composition. Dielectric constant($\varepsilon$$_{r}$) showed maximum value at the composition which corresponds to the phase boundary between 1 : 2 ordered and 1 : 1 ordered structure. The increase in $\varepsilon$$_{r}$ may be caused by the rattling of ions by incorporating smaller ions and the disordered structure. The variation of temperature coefficient of resonant frequency($\tau$$_{f}$) was investigated in terms of oxygen octahedra tilting.dra tilting.

The Action and Pacemaker Potential in the Frog Truncus Arteriosus (개구리 대동맥의 활동전압 및 Pacemaker 전압에 관한 연구)

  • Earm, Yung-E;Sung, Ho-Kyung
    • The Korean Journal of Physiology
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    • v.16 no.2
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    • pp.119-128
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    • 1982
  • The frog truncus arterious were studied with conventional glass microelectrode technique in order to elucidate the underlying mechanism of spontaneous pacemaker activity. The analyses were focussed on the ionic nature of pacemaker current by changing the concentrations of extracellular $K^+$ and, $Na^+$, or by using blockers of K- and Ca-current and chronotropic transmitters. 1) The action potential of the spontaneously active truncus arteriosus has some characteristic feature of maximal distolic potential ranged from -65 to -75 mV, resting potential from -45 to -50 mV and overshoot voltage about +30 mV, respectively. Duration of the action potential taken from rapid upstroke to maximal diastolic potential was about 600 msec. Usual discharge rate was $25{\sim}30/min$ at room temperature $(18{\sim}20^{\circ}C)$. 2) The sensitivity of the resting membrane potential to change extracellular potassium concentrations $(0{\sim}12\;mM)$ was relatively low. Transient hyperpolarization was appeared in the 12 mM K Ringer after 10 min exposure to 0 mM K and it could be related to Na-pump reactivation by high potassium. 3) Reduction of extracellular sodium concetrations diminished the amplitude and frequency of the action potential. In Ringer solution containing 30% Na (substituted by equimolar Tris), spontaneous activity stopped but reappeared as very slow and small action potential. There was no spotaneous activity in zero Na Ringer solution. 4) Caesium(10 mM), K-current blocker decreased the frequency of the action potential and also pacemaker depolarization. Manganese (2 mM) known to be Ca-current antagonist, blocked spontaneous activity completely. 5) Adrenaline and acetylcholine had no chronotropic effect. But adrenaline increased the duration of plateau phase and the magnitude of the action potential in the follower cell. It is concluded that K-, Na-and Ca-current components are involved in the genesis of spontaneous activity of the frog truncus arteriosus like cardiac pacemaker tissues. But the insensitivity of truncus arteriosus to adrenaline and acetylcholine indicates that there are some different control mechanisms of spontaneous rhythm in two tissues.

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The Characteristic Changes of Sintered WC-10Co Fabricated by PIM Method with Different Carbon Content (금속분말사출성형법으로 제조된 WC-10Co계 초경합금 소결체의 탄소첨가량에 따른 특성변화)

  • Kang, Sang-Dae;Park, Dong-Wook;Kwon, Young-Sam;Cho, Kwon-Koo;Ahn, In-Shup
    • Journal of Powder Materials
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    • v.18 no.3
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    • pp.262-268
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    • 2011
  • In order to investigate the microstructure and mechanical properties of WC-10 wt% Co insert tool alloy fabricated by PIM (Powder Injection Molding) process, the feedstock of WC-10 wt% and wax used as a kind of binder were mixed together by two blade mixer. After injection molding, the debinding process was carried out by two-steps. First, solvent extraction, in which the binder was eliminated by putting the specimen into normal hexane for 24 hrs at $60^{\circ}C$, and subsequently thermal debinding which was conducted at $260^{\circ}C$ and $480^{\circ}C$ for 6 hrs in the mixed gas of $H_2/N_2$, respectively. Meantime, in order to compensate the decarburization due to hydrogen, 1.2~1.8% of carbon was added to ensure the integrity of the phase. Finally, the specimens were sintered in vacuum under different temperatures, and the relative density of 99.8% and hardness of 2100 Hv can be achieved when sintered at $1380^{\circ}C$, even the TRS is lower than the conventional sintering process.

Effect of Colchicine on the Induction of Prunella vulgaris for. albiflora Nakai

  • Kwon, Soo-Jeong;Roy, Swapan Kumar;Cho, Kab-Yeon;Moon, Young-Ja;Woo, Sun-Hee;Kim, Hag-Hyun
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.60 no.1
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    • pp.107-113
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    • 2015
  • This study was conducted to find out the effective induction method of tetraploid plants to obtain potential data for cultivating superior varieties by colchicine treatment. The seed germination were decreased by the higher concentration of colchicine treatment and longer soaking time. A total of 907 individuals were germinated in 16 treated plots except control (untreated plot) and 28 tetraploids were induced which was about 3.1% of the number of seed germinated. The plant regeneration rate by colchicine treatment on explant of Prunella vulgaris for. albiflora Nakai under in vitro culture was decreased with the higher concentration of colchicine. While a total of 312 individuals were regenerated in all treatments, the explant was soaked in more than 0.05% for over 1 hour, tetraploid could be obtained. In particular, for the soaking treatment in 0.05% for 6 hours and 12 hours, 37 tetraploids were induced, which was about 57.8% of the number of plant regenerated. In accordance with the observation on doubling of DNA contents in leaf in order to identify polyploid, the peak DNA content of G1 phase was 101.3 for diploid and 197.2 for tetraploid. The result confirmed the doubling of DNA content. Furthermore, the number of chloroplasts per guard cell depending on polyploid was around 10 in diploid and 19.3 in tetraploid, which was around 1.9 times as much as diploid.

Influence analysis of heat treatment on crystalline structure of ZrO2-SiO2 glass precursor synthesized by sol-gel method (졸-겔법으로 합성된 ZrO2-SiO2 유리전구체의 결정화구조에 미치는 열처리의 영향분석)

  • Chun, Kyung-Soo
    • Analytical Science and Technology
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    • v.25 no.1
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    • pp.3-6
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    • 2012
  • $xZrO_2-(1-x)SiO_2$ glass precursor with relatively high concentration of zirconium propoxide in metal alkoxide solution was obtained by sol-gel method and then heated at various temperature from 500 to $1,100^{\circ}C$ to investigate the effect of the thermal treatment on the crystalline structure of the glass precursor. Based on X-ray diffraction analysis, the crystalline peak was started to develop at temperature higher than $600^{\circ}C$, and the crystalline phase was considerably increased at $850^{\circ}C$ or higher. With increasing the thermal treatment temperature, the characteristic peaks, such as baddelyite, tetragonal-$ZrO_2$ and zircon, was shown at $35^{\circ}$, $50^{\circ}$ and $60^{\circ}$ of $2{\theta}$.