• Title/Summary/Keyword: Phase Behavior

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Improvement of the Resistivity in High Field for the New Piezoelectric Compositions in the Bi(NiaX1-a)O3-PbTiO3(X=Ti,Nb) System (Bi(NiaX1-a)O3-PbTiO3 계 압전 신조성(X-Ti,Nb)의 내전압 특성 향상)

  • Choi, Soon-Mok;Seo, Won-Seon
    • Journal of the Korean Ceramic Society
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    • v.45 no.4
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    • pp.220-225
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    • 2008
  • Lead-free ferroelectric ceramics are widely researched today for industrial applications as sensors, actuators and transducers. Since $Pb(Zr_aTi_{1-a})O_3$-(PZT) has high Curie temperature($T_C$), high piezoelectric properties near its morphotropic phase boundary(MPB) composition and small temperature dependence electrical behavior, it has been used to commercial materials for wide temperature range and different application fields. According to the tolerance factor concept, since the $Bi^{3+}$ cation with 12-fold coordinate has a smaller ionic radius than 12-fold coordinate $Pb^{2+}$, most bismuth based perovskites possess a smaller tolerance factor. Therefore, MPBs with a higher $T_C$ may be expected in $Bi(Me^{3+})O_3PbTiO_3$ solid solutions. As in lead based perovskite systems, it is clear that we need to explore more materials in simple or complex bismuth based MPB systems. The objective of this study is to investigate the $Bi(Ni_{1_a}X_a)O_3-PbTiO_3(X=Ti^{4+},\;Nb^{5+})$ perovskite solid-solution. For improving the electronic conduction problem, the magnesium and manganese modified system was also studied.

An Effect of Fe2O3 Additive on a Seebeck Coefficient and a Power Factor for SmCoO3 Perovskite System (SmCoO3 페롭스카이트 계 열전소재에서 Fe2O3 첨가제가 출력인자에 미치는 영향)

  • Jung, Kwang-Hee;Choi, Soon-Mok;Seo, Won-Seon;Park, Hyung-Ho
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.457-460
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    • 2010
  • $SmCoO_3$ system was investigated for their application to themoelectric materials. All specimens showed p-type semiconducting behavior and their electrical conductivity ($\sigma$), Seebeck coefficient (S) and power factor were measured at high temperature. And the effect of dopant ions on their thermoelectrical properties were also investigated. $Fe^{3+}$ ion doped into $Co^{3+}$ site enhanced the Seebeck coefficient and decreased the electrical conductivity simultaneously. The maximum Seebeck coefficient value for 60% doping case reached to 780 ${\mu}V$/K at $240^{\circ}C$. However $Fe^{3+}$ doped system cause an negative effect on power factor value. In case of the pure phase, the maximum Seebeck coefficient value reached to 290 ${\mu}V$/K at $240^{\circ}C$ and the maximum electrical conductivity was obtained 748 1/(ohm$\times$cm) at $960^{\circ}C$. As a result, the maximum power factor was obtained $1.49\times10^{-4}$ W/$mK^2$ at $550^{\circ}C$.

On the Efficiency Comparison of Dynamic Program Slicing Algorithm using Multiple Criteria Variables (다중 기준변수를 사용한 동적 프로그램 슬라이싱 알고리즘의 효율성 비교)

  • Park, Sun-Hyeong;Park, Man-Gon
    • The Transactions of the Korea Information Processing Society
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    • v.6 no.9
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    • pp.2384-2392
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    • 1999
  • Software engineers are used to analyse the error behavior of computer programs using test cases which are collected for the testing phase when software errors are detected. In actual software testing and debugging, it is important to adopt dynamic slicing technique which is concerned on all the statements to be affected by the variables of current inputs and to use technique of its implementations. The traditional dynamic slicing has focused on the single slicing criterion algorithm. It has been thought that it is needed to develope and implement algorithm for used multiple criteria variables program slicing, which finds every slicing criterion variable where it is used multiple criteria variables. In this paper, we propose an efficient algorithm to make dynamic program slices when it has used multiple criteria variables. The results of the implementation are presented by the making table on execution history and the dynamic dependence graph. Also we can find that the proposed dynamic program slicing approach using multiple criteria variables is more efficient than the traditional single case algorithm on the practical testing environment.

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The Densification Properties of Distaloy AE-TiC Cermet by Spark Plasma Sintering (방전 플라즈마 소결에 의한 Distaloy AE-TiC 써멧의 치밀화 특성)

  • Cho, Ho-Jung;Ahn, In-Shup;Lee, Young-Hee;Park, Dong-Kyu
    • Journal of Powder Materials
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    • v.14 no.4
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    • pp.230-237
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    • 2007
  • The fabrication of Fe alloy-40 wt.%TiC composite materials using spark plasma sintering process after ball-milling was studied. Raw powders to fabricate Fe alloy-TiC composite were Fe alloy, $TiH_{2}$ and activated carbon. Fe alloy powder was Distaloy AE (4%Ni-1%Cu-0.5%Mo-0.01%C-bal.%Fe) made by Hoeganes company with better toughness and lower melting point. These powders were ball-milled in horizontal attrition ball mill at a ball-to-powder weight ratio of 30 : 1. After that, these mixture powders were sintered by using spark plasma sintering apparatus for 5 min at $1200-1275^{\circ}C$ in vacuum atmosphere under $10^{-3}$ torr. DistaloyAE-40 wt.%TiC composite was directly synthesized by dehydrogenation and carburization reaction during sintering process. The phase transformation of as-milled powders and sintered materials was confirmed using X-ray diffraction (XRD) and transmission electron microscope (TEM). The density and harness materials was measured in order to confirm the densification behavior. In case of DistaloyAE-40 wt.%TiC composite retained for 5 min at $1275^{\circ}C$, it has the relative density of about 96% through the influence of rapid densification and fine TiC particle reinforced Fe-based composites materials.

Isotropic Compression Behavior of Lawsonite Under High-pressure Conditions (로소나이트(Lawsonite)의 압력에 따른 등방성 압축거동 연구)

  • Im, Junhyuck;Lee, Yongjae
    • Economic and Environmental Geology
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    • v.49 no.1
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    • pp.23-30
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    • 2016
  • Powder samples of natural lawsonite (Ca-lawsonite, $CaAl_2Si_2O_7(OH)_2{\cdot}H_2O$) was studied structurally up to 8 GPa at room temperature using monochromatic synchrotron X-ray powder diffraction and a diamond anvil cell (DAC) with a methanol : ethanol : water (16 : 3 : 1 by volume) mixture solution as a penetrating pressure transmitting medium (PTM). Upon pressure increase, lawsonite does not show any apparent pressure induced expansion (PIE) or phase transition. Pressure-volume data were fitted to a second-order Birch-Murnaghan equation of state using a fixed pressure derivative of 4 leading to a bulk modulus ($B_0$) of 146(6) GPa. This compression is further characterized to be isotropic with calculated linear compressibilities of ${\beta}^a=0.0022GPa^{-1}$, ${\beta}^b=0.0024GPa^{-1}$, and ${\beta}^c=0.0020GPa^{-1}$.

Antinociceptive Effects of Transcytosed Botulinum Neurotoxin Type A on Trigeminal Nociception in Rats

  • Kim, Hye-Jin;Lee, Geun-Woo;Kim, Min-Ji;Yang, Kui-Ye;Kim, Seong-Taek;Bae, Yong-Cheol;Ahn, Dong-Kuk
    • The Korean Journal of Physiology and Pharmacology
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    • v.19 no.4
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    • pp.349-355
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    • 2015
  • We examined the effects of peripherally or centrally administered botulinum neurotoxin type A (BoNT-A) on orofacial inflammatory pain to evaluate the antinociceptive effect of BoNT-A and its underlying mechanisms. The experiments were carried out on male Sprague-Dawley rats. Subcutaneous (3 U/kg) or intracisternal (0.3 or 1 U/kg) administration of BoNT-A significantly inhibited the formalin-induced nociceptive response in the second phase. Both subcutaneous (1 or 3 U/kg) and intracisternal (0.3 or 1 U/kg) injection of BoNT-A increased the latency of head withdrawal response in the complete Freund's adjuvant (CFA)-treated rats. Intracisternal administration of N-methyl-D-aspartate (NMDA) evoked nociceptive behavior via the activation of trigeminal neurons, which was attenuated by the subcutaneous or intracisternal injection of BoNT-A. Intracisternal injection of NMDA up-regulated c-Fos expression in the trigeminal neurons of the medullary dorsal horn. Subcutaneous (3 U/kg) or intracisternal (1 U/kg) administration of BoNT-A significantly reduced the number of c-Fos immunoreactive neurons in the NMDA-treated rats. These results suggest that the central antinociceptive effects the peripherally or centrally administered BoNT-A are mediated by transcytosed BoNT-A or direct inhibition of trigeminal neurons. Our data suggest that central targets of BoNT-A might provide a new therapeutic tool for the treatment of orofacial chronic pain conditions.

Feeding Difficulty and its influencing factors of Elders with Dementia in Long-term Care Facilities (요양시설 치매노인의 식사행동장애와 관련요인)

  • Hong, Hyun-Hwa;Gu, Mee-Ock
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.2
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    • pp.1240-1252
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    • 2015
  • The purpose of this study was to investigate feeding difficulty and its influencing factors of elders with dementia in long-term care facilities. Participants were 158 elders with dementia residing in three nursing facilities. Data were collected from Aug. 18 to Sep. 12 in 2014. The feeding difficulty in dementia scale, Korean version-Activities of Daily Living and Mini-Mental State Exam-Korean version were used as instruments. Data were analyzed using descriptive statistics, t-test, ANOVA, Pearson correlation and stepwise multiple regression by SPSS 17.0. Mean feeding difficulty score was $0.62{\pm}0.43$(range of 0-2). The highest feeding difficulty item was "patient require close supervision while feeding". The variables influencing the feeding difficulty was ADL(${\beta}=.312$), cognitive function(${\beta}=-.172$) which explained about 20.0% of total variance. The results suggest the need of developing feeding difficulty coping strategy according to dietary behavior phase, In addition, the development and testing the educational program for caregivers to help feeding difficulty of the elders with dementia in long-term facility are recommended.

Effective Korean Speech-act Classification Using the Classification Priority Application and a Post-correction Rules (분류 우선순위 적용과 후보정 규칙을 이용한 효과적인 한국어 화행 분류)

  • Song, Namhoon;Bae, Kyoungman;Ko, Youngjoong
    • Journal of KIISE
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    • v.43 no.1
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    • pp.80-86
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    • 2016
  • A speech-act is a behavior intended by users in an utterance. Speech-act classification is important in a dialogue system. The machine learning and rule-based methods have mainly been used for speech-act classification. In this paper, we propose a speech-act classification method based on the combination of support vector machine (SVM) and transformation-based learning (TBL). The user's utterance is first classified by SVM that is preferentially applied to categories with a low utterance rate in training data. Next, when an utterance has negative scores throughout the whole of the categories, the utterance is applied to the correction phase by rules. The results from our method were higher performance over the baseline system long with error-reduction.

Synthesis and dielectric properties of the $ZnAl_2O_4$ ceramics for low-firing (저온소결용 $ZnAl_2O_4$ 세라믹스의 합성 및 유전 특성)

  • Kim, Kwan-Soo;Yoon, Sang-Ok;Kim, Shin;Kim, Nam-Hyup;Kim, Yun-Han;Shim, Sang-Heung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.279-279
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    • 2007
  • Synthesis and dielectric properties of glass-ceramic composites with zinc borosilicate glass(here after ZBS glass) were investigated as functions of $ZnAl_2O_4$ phase synthesis method, glass addition (50~60 vol%) and sintering temperature ($600{\sim}950^{\circ}C$ for 2 hrs). The 50 vol% ZBS glass-$Al_2O_3$ and 60 vol% ZBS glass-$ZnAl_2O_4$ ensured successful sintering below $900^{\circ}C$. But the composition of 100-x-y vol% ZBS glass-x vol% $Al_2O_3-y$ vol% ZnO exhibited poor sinterability below $900^{\circ}C$ and the swelling phenomenon occurred in this composite with the large amount of ZBS glass. The sintering behavior of Glass-ceramic composites was affected by the crystallization of $ZnAl_2O_4$ which was formed by the reaction between ZBS glass and $Al_2O_3$. Dielectric constant (${\varepsilon}_r$), $Q{\times}f$ value and temperature coefficient of resonant frequency (${\tau}_f$) of the composite with 50 and 60 vol% ZBS glass contents demonstrated $ZBS-Al_2O_3({\varepsilon}_r=5.7)$, $ZBS-ZnAl_2O_4({\varepsilon}_r=5.8)$ which is applicable to substrate requiring an low dielectric properties.

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Evaluation of the fabrications and properties of ultra-thin film for memory device application (메모리소자 응용을 위한 초박막의 제작 및 특성 평가)

  • Jeong, Sang-Hyun;Choi, Haeng-Chul;Kim, Jae-Hyun;Park, Sang-Jin;Kim, Kwang-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.169-170
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    • 2006
  • In this study, ultra thin films of ferroelectric vinylidene fluoride-trifluoroethylene (VF2-TrFE) copolymer were fabricated on degenerated Si (n+, $0.002\;{\Omega}{\cdot}cm$) using by spin coating method. A 1~5 wt% diluted solution of purified vinylidene fluoride-trifluoroethylene (VF2:TrFE=70:30) in a dimethylformamide (DMF) solvent were prepared and deposited on silicon wafers at a spin rate of 2000~5000rpm for 30 seconds. After annealing in a vacuum ambient at $200^{\circ}C$ for 60 min, upper gold electrodes were deposited by vacuum evaporation for electrical measurement. X-ray diffraction results showed that the VF2-TrFE films on Si substrates had $\beta$-phase of copolymer structures. The capacitance on $n^+$-Si(100) wafer showed hysteresis behavior like a butterfly shape and this result indicates clearly that the dielectric films have ferroelectric properties. The typical measured remnant polarization (2Pr) and coercive filed (EC) values measured using a computer controlled a RT-66A standardized ferroelectric test system (Radiant Technologies) were about $0.54\;C/cm^2$ and 172 kV/cm, respectively, in an applied electric field of ${\pm}0.75\;MV/cm$.

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