• Title/Summary/Keyword: Petrogenesis

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Petrochemistry of the Soyeonpyeong titaniferous iron ore deposits, South Korea (소연평도 함티타늄 자철광상의 암석지구화학적 연구)

  • Kim, Kyu Han;Lee, Jung Eun
    • Economic and Environmental Geology
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    • v.27 no.4
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    • pp.345-361
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    • 1994
  • Lens shaped titanomagnetite ore bodies in the Soyeonpyeong iron mine are embedded in amphibolites, which were intruded into Precambrian metasediments such as garnet-mica schist, marble, mica schist, and quartz schist. Mineral chemistry, K-Ar dating and hydrogen and oxygen stable isotopic analysis for the amphibolites and titanomagnetite ores were conducted to interpret petrogenesis of amphibolite and ore genesis of titanomagnetite iron ore deposits. Amphibolites of igneous origin have unusually high content of $TiO_2$, ranging from 0.94 to 6.39 wt.% with an average value of 4.05 wt.%. REE patterns of the different lithology of the amphibolite show the similar trend with an enrichment of LREE. Amphiboles of amphibolites are consist mainly of calcic amphiboles such as ferro-hornblende, tschermakite, ferroan pargasite, and ferroan pargasitic hornblende. K-Ar ages of hornblende from amphibolite and gneissic amphibolite were determined as $440.04{\pm}6.39Ma$ and $351.03{\pm}5.21Ma$, respectively. This indicates two metamorphic events of Paleozoic age in the Korean peninsula which are correlated with Altin orogeny in China. The titanomagnetite mineralization seems to have occurred before Cambrian age based on occurrence of orebodies and ages of host amphibolites. The Soyeonpyeong iron ores are composed mainly of titanomagnetite, ilmenite, and secondary minerals such as ilmenite and hercynite exsolved in titanomagnetite. The temperature and the oxygen fugacity estimated by the titanomagnetite-ilmenite geothermometer are $500{\sim}600^{\circ}C$ (ave. $550^{\circ}C$) and about $2{\pm}10^{-23}bar$, respectively. Hornblendes from ores and amphibolites which responsible for magnetite ore mineralization, have a relatively homogeneous isotopic composition ranging from +0.8 to +3.9 ‰ in ${\delta}^{18}O$ and from -87.8 to -113.3 ‰ in ${\delta}D$. The calculated oxygen and hydrogen isotopic compositions of the fluids which were in equilibrium with hornblende at $550^{\circ}C$, range from 2.8 to 5.9‰ in ${\delta}^{18}O_{H2O}$ and from -60.41 to -81.31 ‰ in ${\delta}D_{H2O}$. The ${\delta}^{18}O_{H2O}$ value of magnetite ore fluids are in between +6.4 to + 7.9 ‰. All of these values fall in the range of primary magmatic water. A slight oxygen shift means that $^{18}O$-depleted meteoric water be acted with basic fluids during immiscible processes between silicate and titaniferous oxide melt. Mineral chemistry, isotopic compositions, and occurences of amphibolites and orebodies, suggest that the titanomagnetite melt be separated immisciblely from the titaniferous basic magma.

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Deterioration Analysis and Source Area on Rock Properties of the Seokgatap Pagoda in the Bulguksa Temple, Korea (불국사 석가탑의 풍화훼손도 분석 및 기원암의 산지추정)

  • Lee, Myeong-Seong;Lee, Chan-Hee;Suh, Man-Cheol;Choi, Seok-Won
    • 한국문화재보존과학회:학술대회논문집
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    • 2004.10a
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    • pp.15-24
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    • 2004
  • The Seokgatap pagoda composed of mainly alkali granite and other minor pink-feldspar granite, fine-grained granite, granodiorite, diorite, gabbro, and tuff. Despite the small loss and damage derived from joints, its peel-off and exfoliation are serious enough to cause the heavy deterioration on the stone surface. The chemical and petrological weathering has partly replaced the original rock-forming minerals with clay minerals and iron oxyhydroxides. Based on the petrogenesis, rock materials of the pagoda is very similar to rocks of Dabotap pagoda and the Namsan granite in the Gyeongju. The central fart of the pagoda has sunken highly, which caused all the corners to split and the structural transformation to become worse. The reverse V-shaped gaps between the materials have broken stones filled in a coarse way. The iron plates inserted between the upper flat stone laid on other stones and tile pagoda body in the north and east side has been exposed in the air and corroded, discoloring of the adjacent stones. The overall diagnosis of the Seokgatap pagoda is the deteriorated functions of the stone materials, which calls for a long-term monitoring and plans to reinforce the stone surfaces. But the main body including the pagoda roof stone needs washing on a regular basis, and the many different cracks should be fixed with glue by using the fillers or hardeners designed for stone cultural properties after removing the cement mortar. In case of the replacement of the stone materials with new stones, it's necessary to examine the pagoda for the center of gravity and support intensity of the materials. The structural stability of the pagoda can be attained by taking a reinforce measure in geotechnical engineering and making a drainage. The ground humidity, which has aggravated weathering and structural instability, should be resolved by setting up a humidity reduction facility. The contamination of lichens and bryophyte around the pagoda and on the surface is serious. Thus biochemical treatments should be given too in order to prevent further biological damages and remove the vegetation growing on the discontinuous planes.

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Petrologic and Geomorphologic Characteristics of Micrographic Granite in the Ijin-ri Area, Ulsan (울산 이진리 미문상화강암의 암석학적 및 지형학적 특성 연구)

  • Kim, Sun-Woong;Kim, Haang-Mook;Hwang, Byoung-Hoon;Yang, Kyoung-Hee;Kim, Jin-Seop
    • The Journal of the Petrological Society of Korea
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    • v.18 no.3
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    • pp.211-221
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    • 2009
  • This study illustrates the relationship between the petrographic characteristics of micrographic granite and the topographic features around Ijin-ri. Light-brown to light- gray granite is composed of intergrown fine-grained quartz + orthoclase, displaying micrographic textures. Miarolitic cavities are abundant. Many micro-landforms including tor, tafoni, and gnamma occurred in the micrographic granite of the study area. Tafoni is dominant in the north and gnamma is dominant in south. From our study of the occurrence and textural properties, two alteration zones were clearly identified; one is an external zone (A) characterized by abundant of small sized miarolitic cavities and the other is an internal zone (B) having them less than zone A. The former is dominant in north, and the latter is dominant in south. Particular geomorphologic features such as fluting cores and raised rims are present in the Ijin-ri area. This suggests that development of miarolitic cavities played an important role in the formation of the various geomorphologic features. Consequently, the petrogenesis of the micrographic granite is related to geomorphologic features in the external zone typified by abundant tafoni such as the tiger rock, and the formation of a platform as micro-landforms is influenced by thetextural differences of host rock in the internal zone.

Geochemical Studies on Petrogenesis of the Cretaceous Myeongseongsan Granite in the Northwestern Gyeonggi Massif (경기육괴 북서부에 분포하는 백악기 명성산 화강암의 성인에 대한 지화학적 연구)

  • Yi, Eun Ji;Park, Ha Eun;Park, Young-Rok
    • The Journal of the Petrological Society of Korea
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    • v.26 no.4
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    • pp.327-339
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    • 2017
  • The Cretaceous Myeongseongsan Granite in the northwestern Gyeonggi Massif consists of a major pale pink-colored biotite monzogranite and a minor white-colored biotite alkaligranite. Low Sr and high Ba concentrations, negative Eu-anomalies in REE plot, negative Sr anomalies in spider diagram, a negative correlation between Sr and Rb, and positive correlations between Sr and Ba and $Eu/Eu^*$ indicate that a fractional crystallization of both plagioclase and K-feldspar played a significant role during magma evolution. The Myeongseongsan Granite is plotted in I-& S-type granites on I, S, A-type granite classification scheme. While the biotite monzogranite is plotted in unfractionated I-& S-type granite, the biotite alkaligranite is plotted in fractionated I-& S-type granite, which indicates that the biotite alkaligranite is a more differentiated product. In order to elucidate the nature of the protoliths of the peraluminous Myeongseongsan magma, we plotted in $Al_2O_3/TiO_2$ vs. $CaO/Na_2O$ and Rb/Sr vs. Rb/Ba diagrams, and they suggest that the Myeongseongsan Granite was derived from clay-poor metagreywackes and meta-psammites or their igneous counterparts. Whole-rock zircon saturation temperature indicates that the Myeongseongsan magma was melted at $740-799^{\circ}C$.

SHRIMP Zircon U-Pb Age and Geochemistry of Granites in the Gudambong-Sainam Geosites, Danyang Geopark (단양 지질공원 구담봉-사인암 지질명소 화강암의 SHRIMP 저어콘 U-Pb 연령과 지구화학)

  • Aum, Hyun Woo;Kim, Yoonsup;Cheong, Wonseok;Hau, Bui Vinh
    • The Journal of the Petrological Society of Korea
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    • v.28 no.2
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    • pp.143-156
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    • 2019
  • We carried out the sensitive high resolution ion microprobe zircon U-Pb age dating and whole rock geochemical analysis of granites in the Gudambong and Sainam geosites, Danyang Geopark. The granites crop out in the western and southern parts of Danyang County, and intruded sedimentary successions of the Yeongweol and Taebaek Groups, respectively. The U-Pb isotopic compositions of zircon from the Gudambong and Sainam granite samples yielded the Cretaceous intrusion ages of $90.4{\pm}0.5Ma(t{\sigma})$ and $90.0{\pm}1.5Ma(t{\sigma})$, respectively. The major and trace elements compositions of the samples showed an affinity of typical A-type granite, indicating their petrogenesis during the late stage of the Bulguksa orogeny or a tectonic dormancy. The geochronologic and geochemical results are identical to those of granites previously reported from the Cretaceous Muamsa and Wolaksan suites.

A Study on the Correlations between the Physical Characteristics of Rock Types by Multiple Regression Analysis and Artificial Neural Network (다중회귀분석 및 인공신경망을 통한 암종별 물리적 특성간의 상관관계에 대한 연구)

  • Kim, Byong-Kuk;Lee, Byok-Kyu;Jang, Seung-Jin;Lee, Su-Gon
    • The Journal of Engineering Geology
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    • v.28 no.4
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    • pp.673-686
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    • 2018
  • The physical properties of rocks constituting the rock mass were analyzed by using various methods such as 7 kinds of physical properties of about 2,400 data. The correlation equation was derived from the correlation equation with the dependent variables by screening independent variables through the significance level using multiple regression analysis. In order to verify the reliability of this equation, verification was performed through comparison with actual data using artificial neural network learning. The analysis results by petrogenesis and strength confirmed that the elastic wave velocity (compressional wave) and elastic modulus as the main influence factors for the independent variables affecting the dependent variables. This proves that most of the correlation equations using the above items are found in existing studies. And through this study, it is confirmed whether the rock classification is based on the above items in various standards. In addition, the analysis results of representative rocks showed a high correlation as the equation for estimating unconfined compressive strength and elastic modulus exceeds the coefficient of determination 0.8.

Geochemical Studies on the Petrogenesis of Jurassic Peraluminaous Granitic Rocks in the area of Gwangdeoksan in the Northern Gyeonggi Massif (경기육괴 북부 광덕산 일대에 분포하는 쥐라기 고알루미나 화강암질암의 성인에 대한 지화학적 연구)

  • Han, Chung Hee;Jeon, Hye Su;Park, Young-Rok
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.4
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    • pp.325-337
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    • 2020
  • The Jurassic granitic rocks in the area of Gwangdeoksan located along the boundary between Hwacheon and Cherwon in northern Gyeonggi Massif consist of two-mica granite, garnet-bearing two-mica granite, mica-granite, and porphyritic biotite granite. These granitic rocks are calc-alkaline series and plotted in peraluminious domain in A/CNK vs. A/NK diagram. Petrographical and geochemical data indicate that the porphyritic biotite granite which intruded at the last period originated from distinct parental magma from two-mica granite, garnet-bearing two-mica granite, and mica-granite. On the basis of Rb/Sr vs. Rb/Ba diagram and Al2O3/TiO2 vs. CaO/Na2O, it is inferred the porphyritic biotite granite originated from protolith with less pelitic composition than 3 other granitic rocks. The enriched values of lithophile elements of Cs, Rb, and Ba and negative trough of Nb, P, Ti on spider diagram suggest that the peraluminous Jurassic granitic rocks in Gwangdeoksan area formed in subduction tectonic environment. Whole-rock zircon saturation thermometer indicates that the granitic rocks in the study area were melted at 692-795℃.

Geochemical Study of the Cretaceous Granitic Rocks in Southwestern Part of the Korean Peninsula (한반도 남서부지역에 분포하는 백악기 화강암류에 대한 지화학적 연구)

  • Wee Soo Meen;Park Se Mi;Choi Seon Cyu;Ryu In Chang
    • Economic and Environmental Geology
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    • v.38 no.2 s.171
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    • pp.113-127
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    • 2005
  • Cretaceous intrusive and extrusive rocks are widely distributed in the southwestern part of the Korean peninsula, possibly the result of intensive magmatism which occurred in response to subduction of the western proto-Pacific plate beneath the north-eastern part of the Eurasian plate. Geochemical and petrological study on the Cretaceous granitic rocks were carried out in order to constrain the petrogenesis of the granitic magma and to establish the paleotectonic environment of the area. Whole rock chemical data of the granitic rocks from the study area indicate that the all the rocks have characteristics of calc-alkaline series in the subalkaline field. The overall geochemical features show systematic variations in each granitic body, but the source materials of each granitic body are thought to have been different in their chemical composition. Higher values of $Fe_2O_3/FeO$ of the granitic rocks in the western area suggest that the granitoids had been solidified under highly oxidizing environment. The granitic bodies in the eastern area also show higher contents of Li, Ni, Co, Sr, Cr, Sc and lower Rb and Nb compared to the those of the western area. Chondrite normalized REE patterns show generally enriched LREE and strong negative Eu anomalies in the western wet while slight to flat Eu anomalies in the east-ern area. The REE and $(La/Lu)_{CN}$ of the granites are $60{\~}499ppm$ and $8.9{\~}66$ correspond to the range of the continental margin granite. On the ANK vs. ACNK and tectonic discrimination diagrams, parental magma type of the granites corresponds to I-type, VAG and syn-collision granite. Interpretations of the chemical characteristics of the granitic rocks favor their emplacement in a compressional tectonic regime at continental margin during the subduction of proto-Pacific plate.

Concentration of Radioactive Materials for the Phanerozoic Plutonic Rocks in Korea and Its Implication (국내 현생 심성암류의 방사성 물질의 농도 및 의미)

  • Kim, Sung Won
    • Economic and Environmental Geology
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    • v.53 no.5
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    • pp.565-583
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    • 2020
  • In recent years, various social issues related to the natural radioactive elements detected in household goods and building materials are addressed, and should be solved promptly. In Korea, for more than 20 years, the Ministry of Environment has investigated the natural radioactive materials such as heavy metals, uranium, and radon in soil or groundwater. The origins of natural radioactive materials in them may have a close correlation with the geological factors including classification of rocks, petrogenetic origins, and deformation characteristics, but the exact geological correlations are not clarified because of the absence of the government policy preserved in the basement rocks, soils as well as groundwater in fault-related reservoirs. This study aims to perform a research on the correlation between the petrogeneses of the Phanerozoic plutonic rocks and natural radioactive concentrations in rocks (radon, uranium, thorium, potassium etc.) in Korea. Among the Phanerozoic plutonic rocks, alkaline plutonic rocks (syenite, monzonite and monzodiorite and alkali granite) show high U and Th concentrations by high solubilities of U, Th, Zr, REE, and Nb until the most extreme stages of magmatic fractionation (viz. crystal fractionation) due to high magma temperature and high alkalinity tendency. The highly fractionated high-K calalkaline and peraluminous granitic rocks (leucogranite, two-mica granite and leucocratic pegmatite are also U and Th concentrations compared with other less or medium fractionated granitic rocks (diorite, granodiorite and granite). The alkaline plutonic rocks are associated with intracontinental rifting and extensional environment after crustal thickening by collisional and subductional processes. In contrast, the dominant calc-alkaline granitic rocks in Korea are related to the arc environment of the subduction zone. In summary, the trends of the U, Th and K concentration from the Phanerozoic plutonic rocks in Korea are closely linked to the petrogenesis of the rocks in tectonic environment. The preliminary data for gamma-spectrometric mesurments of natural radionuclide contents (226Ra, 232Th and 40K) in the Phanerozoic plutonic rocks show high values in the alkaline and highly fractionated granitic rocks.

Petrogenesis of Plutonic Rocks in the Andong Batholith (안동저반 심성암류의 암석성인)

  • 황상구;장윤득;이윤종
    • The Journal of the Petrological Society of Korea
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    • v.11 no.3_4
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    • pp.200-213
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    • 2002
  • The Andong granitoid batholith represents five temporally distinct episodes (phases) of igneous activity. The batholith represents a plutonic complex of five pulsatively emplaced distinct intrusive multiphases. The petrochemical data show that the plutons fall into calc-alkaline series except for the Yean pluton, and plot within the diaenostic range for I-type origin and continental arc orogenic tectonic setting. Each pluton reveals systematic compositional variations of major and trace elements with $SiO_2$ or MgO, but different variation trends for some elements and considerably different REE patterns. Thus discontinuous, inconsistent variations in the elements indicate that the five plutons can not be explained by simple fractional crystallization from the same primary magma, but were intruded and solidified from the independent magmas of chemically heterogeneous origin. In the Andong, Dosan and Pungsan plutons, high values of molar CaO/(MgO+$FeO^{t}$ ) combined with low $Al_2$$O_3$/(MgO+$FeO^{t}$ ) and $K_2$O$Na_2$O ratios suggest a magma originated by dehydration melting of a metabasaltic to metatonalitic protolith. Whereas the Imha pluton show similar values of CaO/(MgO+$FeO^{t}$ ), but significantly higher ratios of $Al_2$$O_3$/(MgO+$FeO^{t}$ ) and $K_2$O$Na_2$O implying to a metagreywacke protolith.