• 제목/요약/키워드: Peak Degradation

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Hydrolytic Stability of Sulfonic Acid-Containing Polyimides for Fuel Cell Membranes

  • Kim Hyoung-Juhn;Litt Morton H.;Shin Eun-Mi;Nam Sang Yong
    • Macromolecular Research
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    • v.12 no.6
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    • pp.545-552
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    • 2004
  • The long-term stability of sulfonic acid-containing polyimides has been investigated. The hydrolytic degradation of homopolyimide and the block copolyimide comprising $27\;mol\%$ of 2,2'-bis(trifluoromethyl)benzidine and $9\;mol\%$ of m-phenylenediamine (BTFMB27mPl0[7/(3+1)]), was quantified through viscosity measurements and FT-IR spectroscopic analyses. The viscosity decrease with respect to time and the degradation rate were similar. The degrees of degradation with respect to time under ambient conditions and at elevated temperature in water were monitored by FT-IR spectroscopy. A new absorption peak was observed at $1786\;cm^{-1},$ which we corresponds to the presence of anhydride end groups formed by hydrolytic scission of the imide rings.

Degradation Estimation Of Material by Barkhausen Noise Analysis (바크하우젠 노이즈 해석에 의한 재료의 열화도 평가)

  • Lee Myung Ho
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.3
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    • pp.38-46
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    • 2005
  • The destructive method is reliable and widely used for the estimation of material degradation but it have time-consuming and a great difficulty in preparing specimens from in-service industrial facilities. Therefore, the estimation of degraded structural materials used at high temperature by nondestructive evaluation such as electric resistance method, replica method, Barkhausen noise method, electro-chemical method and ultrasonic method are strongly desired. In this study, various nondestructive evaluation(NDE) parameters of the Barkhausen noise method, such as MPA(Maximum Peak Amplitude), RMS, IABNS(Internal Area of Barkhausen Noise on Signal) and average amplitude of frequency spectrum are investigated and correlated with thermal damage level of 2.25cr-1.0Mo steel using wavelet analysis. Those parameters tend to increase while thermal degradation proceeds. It also turns out that the wavelet technique can help to reduce experimental false call in data analysis.

A study hot-carrier degradation on submicron devices (Submicron device에서의 hot-carrier 열화에 관한 연구)

  • 이용희;김현호;최영규;이천희
    • Proceedings of the IEEK Conference
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    • 1998.06a
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    • pp.867-870
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    • 1998
  • In this paper we simulated 0.30um NMOS transitor to analysis hot carrier degradation depend on As, As+P, P LDD structure. As a result we obtained As+P LDD structure was good hot carrier immunity. Also we find that hog carrier life time improved a sincresing P dose due to P dose helps in grading the nLDD junction. However As-only junction was poor due to junction high peak position located near the surface.

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A study on the asperity degradation of rock joint surfaces using rock-like material specimens (유사 암석 시편을 사용한 암석 절리면 돌출부 손상 연구)

  • Hong, Eun-Soo;Kwon, Tae-Hyuk;Cho, Gye-Chun
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.11 no.3
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    • pp.303-314
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    • 2009
  • Image analyses for sheared joint specimens are performed to study asperity degradation characteristics with respect to the roughness mobilization of rock joints. Four different types of joint specimens, which are made of high-strength gypsum materials, are prepared by replicating the three-dimensional roughness of rock joints. About twenty jointed rock shear tests are performed at various normal stress levels. The characteristic and scale of asperity degradation on the sheared joint specimens are analyzed using the digital image analysis technique. The results show that the asperity degradation characteristic mainly depends on the normal stress level and can be defined by asperity failure and wear. The asperity degradation develops significantly around the peak shear displacement and the average amount of degraded asperities remains constant with further displacement because of new degradation of small scale asperities. The shear strength results using high-strength gypsum materials can not fully represent physical properties of each mineral particles of asperities on the natural rock joint surface. However the results of this quantitative estimation for the relationship between the peak shear displacement and the asperity degradation suggest that the characterization of asperity degradation provides an important insight into mechanical characteristics and shear models of rock joints.

Electrical properties of a resistive SFCL with shunt resistor (분로저항을 가진 저항형 초전도 한류기의 전기적 특성)

  • Choi, Hyo-Sang;Hyun, Ok-Bae;Kim, Hye-Rim;Hwang, Si-Dole;Kim, Sang-Joon
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.343-347
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    • 1999
  • We fabricated a resistive SFCL having a shunt resistor parallel to it in order to bifurcate the transient current at faults. The SFCL consists of a YBCO film coated with an Au layer (10 ${\omega}$ at room temperature), which is to disperse the heat generated at hot spots in the YBCO film, and the 5 ${\omega}$ shunt resistor. The minimum quench current of the SFCL was found to be 12.2 A$_{peak}$. This SFCL successfully controlled the fault current below 23 A$_{peak}$ which is otherwise to increase up to 113 A$_{peak}$. Bifurcation of the current resulted in the temperature rise of the YBCO/Au film 3 times slower than without the shunt, protecting the SFCL at high currents.

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Visible light assisted photocatalytic degradation of methylene blue dye using Ni doped Co-Zn nanoferrites

  • Thakur, Preeti;Chahar, Deepika;Thakur, Atul
    • Advances in nano research
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    • v.12 no.4
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    • pp.415-426
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    • 2022
  • Nickel substituted cobalt-zinc ferrite nanoparticles with composition Co0.5Zn0.5NixFe2-xO4 (x = 0.25, 0.5, 0.75, 1.0) were synthesized using a wet chemical method named citrate precursor method. Various characterizations of the prepared nanoferrites were done using X-ray powder diffractometry (XRD), Scanning electron microscopy (SEM), UV visible spectroscopy and Fourier transform spectroscopy technique (FT-IR). XRD confirmed the formation of cubic spinel structure of the samples with single phase having one characteristic peak at (311). The value of optical band gap (Eg) was found to decrease with Ni substitution and have values in the range 2.30eV to 1.69eV. A Fenton-type system was created by photocatalytic activity using source of visible light for removal of methylene blue dye. Observations revealed increase in the degradation of methylene blue dye with increasing nickel content in the samples. The degradation percentage was increased from 77.32% for x = 0.25 to 90.16% for x = 1.0 in one hour under the irradiation of visible light. Also, the degradation process was found to have pseudo first order kinetics model. Hence, it can be observed that synthesized nickel doped cobalt-zinc ferrites have good capability for water purification and its degradation efficiency enhanced with increase in nickel concentration.

A New Peak-Windowing Algorithm with Window-length Adaptation for PAPR Reduction of OFDM Systems (OFDM 시스템의 PAPR 저감을 위한 가변적인 윈도우 크기를 적용한 Peak Windowing 기법)

  • Lee, Sung-Eun;Bang, Keuk-Joon;Park, Myong-Hee;Lee, Young-Soo;Hong, Dae-Sik
    • Proceedings of the IEEK Conference
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    • 2005.11a
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    • pp.185-188
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    • 2005
  • This paper proposes a new peak-windowing algorithm with window-length adaptation for peak-to-average power reduction (PAPR) of orthogonal frequency division multiplexing (OFDM) systems. Conventional peak windowing algorithm has advantages, such as moderate system complexity with good spectral shape. However, adjacent peak signals within the length of window functions produce the distortion of signal amplitude since window functions might overap with each other. These undesired characteristics of conventional peak windowing algorithm result in the degradation of BER performance. The proposed algorithm outperforms the conventional one with the aid of window-length adaptation. Simulation results show the efficiency of the proposed algorithm under the environments of WiBro downlink systems.

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Peak-to-Average Ratio Reduction for DS/CDMA Reverse Link (DS/CDMA 역방향 링크 Peak-to-Average Ratio 개선 방법)

  • 우정효;이채관;안재민;윤순영;김제우
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.24 no.6A
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    • pp.845-854
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    • 1999
  • In the reverse link of DS/CDMA systems, the Peak-to-Average Ratio(PAR) performance can be analyzed by phase variations of spread signals. In the paper, we propose s PAR analysis method using phase variations of signals. Using this method, we analyze the PAR performances of existing spreading methods and suggest several methods improving the PAR performances. Also we show the proposed methods have negligible BER degradation compared to the existing ones.

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Intrinsic UV Reflection and Fluorescence Studies for Water Sorption in Polycarbonate, Polyurethane and Poly(Ethylene Terephthalate) Films

  • Kim Min Sun;Sung Chong Sook Paik
    • Fibers and Polymers
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    • v.6 no.2
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    • pp.127-130
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    • 2005
  • Intrinsic UV reflection and fluorescence behaviors of polycarbonate, polyurethane and poly(ethylene terephthalate) films were investigated in order to characterize the interaction of water in these films. During water sorption process, UV reflection spectra of polycarbonate and polyurethane films showed little peak position changes. Fluorescence emission spectra of polycarbonate films showed red spectral shifts from 332 nm with water immersion time. This red-shifted peak could be due to phenyl-2-phenoxybenzoate, which is one of the major thermal degradation products in polycarbonate. Fluorescence peaks of polyurethane films appeared at two different positions and the ratio of these peak intensities increased with increasing immersion time. In the case of PET films, the UV reflection spectrum showed the peak intensity around 340 nm to change in response to water sorption. The fluorescence near 388 nm probably due to ground state dimer exhibited sensitivity with water sorption, when excited at 340 nm.

A Study on the Initial Performance Degradation of Hydrogen-Fueled Ceramic Fuel Cell with Atomic Layer-Deposited Thin-Film Electrolyte (수소연료를 이용하는 원자층증착 박막전해질 세라믹연료전지의 초기성능 저하에 관한 연구)

  • JI, SANGHOON
    • Journal of Hydrogen and New Energy
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    • v.32 no.5
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    • pp.410-416
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    • 2021
  • The initial electrochemical performance of ceramic fuel cell with thin-film electrolyte was evaluated in terms of peak power density ratio, open circuit voltage ratio, and activation/ohmic resistance ratios at 500℃. Hydrogen and air were used as anode fuel and cathode fuel, respectively. The peak power density ratio reduced as ~17% for 40 minutes, which rapidly decreased in the early stage of the performance evaluation but gradually decreased. The open circuit voltage ratio decreased with respect time; however, its time behavior was remarkably different with the reduction behavior of the peak power density ratio. The activation resistance ratio increased as ~15% for 40 minutes, which was almost similar with the time behavior of the peak power density ratio.