• 제목/요약/키워드: Pd complex

검색결과 180건 처리시간 0.022초

DC 변전소 몰드변압기 온라인 상태 감시 시스템 구현 (Implementation of a Condition Monitoring System for Mold Transformers in DC Substations)

  • 박영;정호성;박철민;장순호
    • 전기학회논문지
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    • 제60권9호
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    • pp.1788-1794
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    • 2011
  • The mold transformer is a complex and critical component of DC substations in Metro system. In this paper, a cost effective and intelligent condition monitoring system for mold transformers in DC substations was developed. This paper also provides an overview of the management program using PD (partial discharge) data on mold transformers. Prior to application of the proposed system to Metro DC substations, experiments were performed at the metro line substation located in Seoul and presented case studies for the use of the intelligent condition monitoring system for mold transformer in DC substations. The experiment results indicated that the developing system can be need in helping mange the risk of unexpected failure of mold type transformers.

선형 시변 시스템에 대한 잘 정의된 (well-defined) 직렬 및 병렬 D-스펙트럼 (Well-Defined series and parallel D-spectra for preparation for linear time-varying systems)

  • ;이호철;최재원
    • 제어로봇시스템학회논문지
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    • 제5권5호
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    • pp.521-528
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    • 1999
  • The nth-order, scalar, linear time-varying (LTV) systems can be dealt with operators on a differential ring. Using this differential algebraic structure and a classical result on differential operator factorizaitons developed by Floquet, a novel eigenstructure(eigenvalues, eigenvectors) concepts for linear time0varying systems are proposed. In this paper, Necessary and sufficient conditions for the existence of well-defined(free of finite-time singularities) SD- and PD- spectra for SPDOs with complex- and real-valued coefficients are also presented. Three numerical examples are presented to illustrate the proposed concepts.

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공기 및 복합유전체 갭에서의 방사전자파의 거리 및 편파특성 (The distance and polarization characteristics of electromagnetic wave radiated at needle-to-plane electrodes in Air and complex dielectric)

  • 김충년;이현동;박광서;박원주;이광식;이동인;이동헌
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2000년도 학술대회논문집
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    • pp.241-245
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    • 2000
  • In this paper, VHF(30~230[MHz]) electromagnetic waves radiated from partial discharge(PD) at two-type electrodes in air are measured and the peculiar patterns of their spectra are reported. Also, the polarization and distance characteristics of electromagnetic wave rediated by PD, were investigated. In case of epoxy insulator in inserted, the noise level of radiated electromagnetic waves is 0.6~6.2[dB] higher than the case in air at below 90[MHz]. The frequency spectrum distribution of radiated electromagnetic waves appears different in the whole frequency range according to the arrangement of antenna.

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뉴로-퍼지 제어기 설계 연구 (A Study on a Neuro-Fuzzy Controller Design)

  • 임정홈;정태진
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 하계학술대회 논문집 D
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    • pp.2120-2122
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    • 2002
  • There are several types of control systems that use fuzzy logic controller as a essential system component. The majority of research work on fuzzy PID controller focuses on the conventional two-input PI or PD type controller. However, fuzzy PID controller design is a complex task due to the involvement of a large number of parameters in defining the fuzzy rule base. In this paper we combined conventional PI type and PD type fuzzy controller and set the initial parameters of this controller from the conventional PID controller gains obtained by Ziegler-Nichols tuning or other coarse tuning methods. After that, by replacing some of these parameters with sing1e neurons and making them to be adjusted by back-propagation learning algorithm we designed a neuro-fuzzy controller which showed good performance characteristics in both computer simulation and actual application.

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범죄예방 환경설계 관점에서 공동주택 단지 내 공공보행통로의 개선방안 연구 (Improvements of the Public Pedestrian Passage in the Apartment Complex from Crime Prevention Through Environmental Design Aspect)

  • 이승지
    • 대한건축학회논문집:계획계
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    • 제34권6호
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    • pp.135-142
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    • 2018
  • A public pedestrian passage induces traffic into the apartment complex, and therefore, it requires the application of Crime Prevention Through Environmental Design(CPTED). This paper aims to analyze the conditions and to suggest the improvements of public pedestrian passages in apartment complexes, applying a 3-D approach from CPTED aspect. The first aspect is "Designation": 1)The linkage between the public pedestrian passages is weak, and their designated purpose becomes unclear. 2)When the designated purpose is not considered for each complex, the closure rate is high. 3)The closure rate of the "Through type" is high. It suggests that the pedestrian network should be built and vitalized at the local urban level. The second aspect is "Definition." The public pedestrian passage lacks a social, cultural, and legal definition and only has a passive physical definition. It suggests that a legal definition and specialized guildline be prepared. The third aspect is "Design": 1)Insufficient territoriality exists between the public pedestrian passage and the inside of the complex. Territoriality should be reinforced between the public pedestrian passage and the rest of the internal territory. 2)The landscaping adjacent to the public pedestrian passage lacks deliberation. Since this is where safety and privacy collide, detailed design and maintenance of the landscaping is required. 3)It lacks systematical crime prevention facilities and should compensate accordingly.

일본 UR임대주택단지의 커뮤니티활성화 지원실태에 관한 고찰 (A Consideration of the Present Status of Support for Community Revitalization in the Japanese UR Rental Housing Complex)

  • 이수진
    • 대한건축학회논문집:계획계
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    • 제36권3호
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    • pp.103-111
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    • 2020
  • This study aims to analyze community support methods and specific attainments of UR rental housing complex S in Japan and examine the present state of community formation.. UR rental housing S is part of the community revitalization support project launched by UR Urban Agency for creating exchanges among residents in the rental housing complex and in this study, the community support project from February to November 2013 was considered. As community revitalization support tasks, five types of events and exchange meetings were held. While the events and exchange meetings continued, even the residents who did not join the residents' association began to make an exchange with each other and their identity as residents enhanced, which means there was a change in the sense of community. Moreover, it is thought that a good solution to maintaining the chance for the events and exchange meetings after the support project is that residents of the younger generation actively cooperate in management as the residents' association members. 5 years after the support project, the present condition of activities of complex residents was examined, but the Residents' Association was disbanded due to the aging of residents, a growth in residents and low participation rates of the younger generation. Besides, there is a complete absence of community activities in the complex now.

Protocol of a Nationwide Observational Study among Patients with Nontuberculous Mycobacterium Pulmonary Disease in South Korea (NTM-KOREA)

  • Kwak, Nakwon;Choi, Hongjo;Jeon, Doosoo;Jhun, Byung Woo;Jo, Kyung-Wook;Kang, Young Ae;Kwon, Yong-Soo;Lee, Myungsun;Mok, Jeongha;Shim, Tae-Sun;Shin, Hong-Joon;Whang, Jake;Yim, Jae-Joon
    • Tuberculosis and Respiratory Diseases
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    • 제83권2호
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    • pp.141-146
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    • 2020
  • Background: The burden of nontuberculous mycobacterial (NTM) pulmonary disease (PD) is increasing globally. To understand the treatment outcomes and prognosis of NTM-PD, a unified registry is needed. In this project, we aim to construct a multicenter prospective observational cohort with NTM-PD in South Korea (NTM-KOREA). Methods: The primary objective of this study is to analyze treatment outcomes according to the species. In addition, recurrence rate, adverse events, the impact of each drug on treatment outcomes as well as the impact of characteristics of mycobacteriology will be analyzed. The inclusion criteria for the study are as follows: fulfilling the criteria for NTM-PD having one of the following etiologic organisms: Mycobacterium avium complex, M. abscessus subspecies abscessus, M. abscessus subspecies massiliense, or M. kansasii; receiving the first treatment for NTM-PD after enrollment; age >20 years; and consenting to participate in the study. Seven institutions will participate in patient enrollment and about 500 patients are expected to be enrolled. Participants will be recruited from 1 March 2020 until 19 March 2024 and will be observed through 19 March 2029. During the follow-up period, participants' clinical course will be tracked and their clinical data as well as NTM isolates will be collected. Conclusion: NTM-KOREA will be the first nationwide observational cohort for NTM-PD in South Korea. It will provide the information to optimize treatment modalities and will contribute to deeper understanding of the treatment outcomes and long-term prognosis of patients with NTM-PD in South Korea.

Toluene diisocyanate(TDI) 합성을 위한 Pd/SiO2 촉매상 직접 카보닐화반응에서의 피리딘 첨가효과 (Effect of Pyridine on Toluene Diisocyanate (TDI) Synthesis Using Direct Carbonylation over Pd/SiO2)

  • 서명기;김성민;이대원;이관영
    • Korean Chemical Engineering Research
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    • 제50권3호
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    • pp.417-420
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    • 2012
  • 본 연구는 Pd/$SiO_2$ 촉매를 이용하여 2,4-dinitrotoluene(2,4-DNT)을 2,4-toluene diisocyanate(2,4-TDI)로 환원시키는 반응에 관한 연구이다. 반응 조건은 $200^{\circ}C$에서, 일산화탄소를 주입하여 100 bar에서 실험을 진행하였으며, 피리딘이 TDI의 수율에 미치는 영향에 대해 연구 하였다. 반응 실험 결과 피리딘을 넣지 않은 경우 TDI는 생성되지 않았고, 피리딘을 첨가하면 TDI가 생성되었다. 직접 카보닐화를 이용한 균질계상에서의 TDI 합성 연구 결과에 의하면 팔라듐과 피리딘의 착이온이 형성되어 촉매작용을 하는 것으로 알려져 있다. 피리딘을 첨가하였을 경우 TDI가 합성되는 것이 팔라듐 용출에 의한 것인지 확인하기 위해 ICP-AES 분석을 시행하였다. 20 vol% 피리딘을 첨가한 반응에서 반응 후 촉매의 팔라듐 함량이 반응 전에 비해 52% 감소하였다. 이러한 결과는 피리딘을 첨가한 반응실험에서 용출된 팔라듐이 피리딘과 착이온을 형성하는 과정을 거쳐 TDI가 생성되는 것으로 설명될 수 있다.

불꽃 및 비불꽃원자흡수분광법을 이용한 뇨중 카드뮴 분석 (Analysis of Cadmium in Urine using Flame and Flameless Atomic Absorption Spectrophotometry)

  • 함용규;이석기;전해홍;정창웅;손부순
    • 분석과학
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    • 제12권5호
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    • pp.355-359
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    • 1999
  • 뇨중 미량 카드뮴 분석에 흑연로 장치가 부착된 원자흡수분광광도계(GFAAS)를 사용하였다. 불꽃분광법에서 시료는 회화하여 Na-DDTC로 착물을 형성한 후 MIBK로 추출하였으며, 비불꽃분광법에서는 1% Triton X-100과 1% $HNO_3$으로 5배 희석시킨 후 $Pd(NO_3)_2$를 매트릭스 개선제로 농도를 변화시키면서 회화 온도 $450-750^{\circ}C$에서 pyrocoated 흑연 튜브를 사용하여 분석하였다. 그 결과 불꽃분광법보다는 비불꽃분광법이 전처리가 간단하고 재현성있게 나타났으며, 비불꽃분광법을 이용한 경우 $Pd(NO_3)_2$ 100 mg/L을 사용하여 회화온도 $550^{\circ}C$에서 분석시 가장 높은 흡광도를 나타냈다. 본 분석법을 표준뇨인 Lononorm-Metalle 3 중의 카드뮴 분석에 적용하였다.

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평면사각형 혼합 리간드 착물의 합성과 그 특성 (제 2 보) : Ni(II), Pd(II) 및 Pt(II)의 M(S-S)(N-N)형 착물의 친전자성 및 친핵성 반응 (Synthesis and Characterization of Square Planar Mixed-Ligand Complexes (II) : Electrophilic and Nucleophilic Reaction of M(S-S)(N-N) Type Complexes with Ni(II), Pd(II), and Pt(II))

  • 오상오;정덕영
    • 대한화학회지
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    • 제36권1호
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    • pp.81-86
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    • 1992
  • M(S-S,ph)(N-N,H) (M = Ni(II), Pd(II), Pt(II); (S-S,ph) = 1,2-diphenylethylenedithiolate; (N-N,H)=1,10-phenanthroline) 착물의 친전자성 및 친핵성 리간드 반응을 조사하였다. norbornadiene과의 반응성은 중심금속의 역결합의 정도에 의존하며 2,5-dithia-3,4-diphenyl-tricyclo[4,4,1,0]-undeca-3,8-diene을 생성하였다. methyl iodide와의 반응은 (N-N,H) 리간드의 이탈 능력에 지배되며 메틸화된 $M(S-S,ph)_2$ 착물을 생성하였다. 이 반응의 주생성무리은 열 분해에 의해 얻어진 ${\alpha},{\alpha}{\prime}$,-bismethylthiostibene $(CH_3S-SCH_3,ph)$의 구조로부터 M(S-S,CN)(N-N,H)((S-S,CN) = 1,2-dicyanoethylenedithiolate)의 새로운 혼합 리간드 착물을 합성하였다.

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